CN111066815A - Chlorine dioxide disinfectant special for livestock and poultry and preparation method thereof - Google Patents
Chlorine dioxide disinfectant special for livestock and poultry and preparation method thereof Download PDFInfo
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- CN111066815A CN111066815A CN201911369073.7A CN201911369073A CN111066815A CN 111066815 A CN111066815 A CN 111066815A CN 201911369073 A CN201911369073 A CN 201911369073A CN 111066815 A CN111066815 A CN 111066815A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
Abstract
The invention discloses a chlorine dioxide disinfectant special for livestock and poultry, belonging to the technical field of disinfection. The invention is prepared from the following raw materials in parts by weight: chlorite, monopersulfate, acidifying agent, bromide salt, stabilizing and forming agent and desiccant; wherein the chlorite is at least one of an alkali metal salt of chlorous acid and an alkaline earth metal salt of chlorous acid; the acidifier is at least one of sodium bisulfate, sodium bicarbonate, potassium bicarbonate and boric acid; the bromide salt is selected from at least one of sodium bromide, lithium bromide, potassium bromide, calcium bromide, magnesium bromide, ammonium bromide and aluminum bromide; the stable forming agent comprises at least one of sodium sulfate, magnesium hydroxide, sodium chloride and magnesium chloride; the desiccant is at least one of calcium chloride, calcium sulfate and calcium stearate. The invention also provides a preparation method of the disinfectant. The disinfectant does not generate substances such as chloroform, cyanuric acid and the like in the activation process, so the disinfectant is suitable for occasions such as livestock breeding and the like.
Description
Technical Field
The invention belongs to the technical field of chlorine dioxide disinfection, and particularly relates to a special chlorine dioxide disinfectant for livestock and poultry and a preparation method thereof.
Background
Chlorine dioxide as a water-soluble strong oxidant has high-efficiency and broad-spectrum sterilization capability, so that the chlorine dioxide is classified as A1 grade by the world health organization. However, since the gaseous chlorine dioxide is unstable in properties, it is difficult to prepare a compressed gas, and it has explosive characteristics, and thus it is inconvenient to transport and store. And the liquid chlorine dioxide is volatile and not easy to concentrate, thereby limiting the use of chlorine dioxide. Therefore, the chlorine dioxide solid preparation is widely used at present, and refers to a solid product capable of releasing chlorine dioxide gas under certain operating conditions, and the product can be colloid, paste, powder, tablet, group and other various shapes. The existing common chlorine dioxide solid releasing agent can generate chloroform, cyanuric acid and other substances in the using process, and is not suitable for being used in livestock and poultry and other breeding places.
Disclosure of Invention
In order to solve the above problems in the prior art, embodiments of the present application provide a chlorine dioxide disinfectant special for livestock and poultry and a preparation method thereof, the bromine-containing compound generated in the activation process of the disinfectant has higher oxidation performance than the chlorine-containing compound, and does not generate substances such as chloroform and cyanuric acid, so that the disinfectant is suitable for livestock and poultry breeding and other occasions.
In order to achieve the above purpose, the embodiments of the present application adopt the following technical solutions:
in a first aspect, an embodiment of the present application provides a chlorine dioxide disinfectant special for livestock and poultry, which is prepared from the following raw materials in parts by weight:
20-36 parts of chlorite, 20-35 parts of monopersulfate, 5-12 parts of an acidifying agent, 10-40 parts of bromide salt, 20-30 parts of a stable forming agent and 7-12 parts of a drying agent;
wherein the chlorite is at least one of an alkali metal salt of chlorous acid and an alkaline earth metal salt of chlorous acid;
the acidifier is at least one of sodium bisulfate, sodium bicarbonate, potassium bicarbonate and boric acid;
the bromide salt is selected from at least one of sodium bromide, lithium bromide, potassium bromide, calcium bromide, magnesium bromide, ammonium bromide and aluminum bromide;
the stable forming agent comprises at least two of sodium sulfate, magnesium hydroxide, sodium chloride and magnesium chloride;
the desiccant is at least one of calcium chloride, calcium sulfate and calcium stearate.
Preferably, the chlorite is sodium chlorite, the monopersulfate is potassium monopersulfate, the acidifying agent is boric acid, the bromide salt is sodium bromide, the stabilizing and forming agent is sodium sulfate, and the drying agent is calcium chloride.
Preferably, the feed is prepared from the following raw materials in parts by weight: 20-30 parts of sodium chlorite, 25-33 parts of potassium monopersulfate, 7-8 parts of boric acid, 15-40 parts of sodium bromide, 20-30 parts of sodium sulfate and 7-8 parts of calcium chloride.
In a second aspect, embodiments of the present application provide a method for preparing a chlorine dioxide disinfectant special for livestock and poultry as described above, comprising the steps of:
step one, weighing chlorite, monopersulfate, an acidifier and a stable forming agent according to the weight parts and the particle size requirement, and after drying and dehydration, ensuring that the water content of each component is less than 0.5%;
step two, uniformly mixing the components obtained in the step one to obtain mixed powder;
thirdly, putting the mixed powder and bromide salt into a stirrer to be stirred at the rotating speed of 10-15r/min for 60min to obtain powdery chlorine dioxide generating tablets;
and step four, tabletting the powdery chlorine dioxide generation tablets to obtain finished chlorine dioxide generation tablets.
Preferably, in the step one to the step three, the ambient temperature is controlled to be 17-26 ℃.
Preferably, in the step one to the step three, the relative humidity of the environment is controlled to be lower than 40%.
Preferably, in the fourth step, the tabletting pressure is controlled to be 20-28 KN.
Compared with the prior art, the embodiment of the application adopts inorganic salt as a raw material, has good stability and is convenient to store, transport and use. In addition, the bromine-containing inorganic salt is adopted, hypobromous acid is generated firstly, and then chlorine dioxide is released, and in the process, chloroform, cyanuric acid and other qualities are not generated. And the hypobromous acid substance has stronger oxidizing sterilization capability, and the sterilization effect is improved compared with the common chlorine dioxide fixed release agent.
In addition, the hydrogen monopersulfate in the invention can continuously generate hydrogen peroxide, hypochlorous acid and organic acid peroxide due to the existence of bromine-containing inorganic salt, continuously release active oxygen and acid to form dynamic equilibrium, maintain the pH value of the solution between 3 and 4, and react with chlorite to generate chlorine dioxide.
The monopersulfate can be used for killing various pathogenic microorganisms, is not influenced by organic matters, and metabolites of the monopersulfate cannot influence the breeding of livestock and poultry.
Reference will now be made in detail to the present embodiments of the invention, examples of which are illustrated in the accompanying drawings. It should be understood that the embodiments of the invention are not so limited in scope. The embodiments of the invention include many variations, modifications and equivalents within the spirit and scope of the appended claims.
Features that are described and/or illustrated with respect to one embodiment may be used in the same way or in a similar way in one or more other embodiments, in combination with or instead of the features of the other embodiments.
It should be emphasized that the term "comprises/comprising" when used herein, is taken to specify the presence of stated features, integers, steps or components but does not preclude the presence or addition of one or more other features, integers, steps or components.
Detailed Description
In order to make those skilled in the art better understand the technical solutions in the present invention, the technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be obtained by a person skilled in the art without any inventive step based on the embodiments of the present invention, shall fall within the scope of protection of the present invention.
It will be understood that when an element is referred to as being "disposed on" another element, it can be directly on the other element or intervening elements may also be present. When an element is referred to as being "connected" to another element, it can be directly connected to the other element or intervening elements may also be present. The terms "vertical," "horizontal," "left," "right," and the like as used herein are for illustrative purposes only and do not represent the only embodiments.
Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. The terminology used herein in the description of the invention is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used herein, the term "and/or" includes any and all combinations of one or more of the associated listed items.
The technical scheme of the invention is further explained by combining specific examples. In the following examples, the water content of each raw material was less than 0.5%, the ambient temperature was controlled at 17-26 ℃, the air relative humidity was controlled at 10-30%, and the tablet press pressure was controlled at 20-28KN during the preparation.
And in the second step, a V-shaped anti-corrosion mixer is selected, the rotating speed is 12-16r/min, and the mixing time is 25-30 min.
In the third step, an anti-corrosion mixer is selected, the rotating speed is 10-15r/min, and the mixing is carried out for 60 min.
Example 1
A chlorine dioxide disinfectant special for livestock and poultry is prepared from the following raw materials in parts by weight: 21kg of sodium chlorite, 32kg of potassium monopersulfate, 5kg of boric acid, 30kg of sodium bromide, 20kg of sodium sulfate and 8kg of calcium chloride.
Step one, sieving sodium chlorite at the ambient temperature of 17 ℃, taking 21kg of 100-mesh material, and drying at the temperature of 80 ℃ until the water content is 0.44%; sieving potassium monopersulfate to obtain 32kg of 100-mesh material, drying at 80 deg.C to water content of 0.43%, sieving sodium sulfate to obtain 20kg of 100-mesh material, and drying at 60 deg.C to water content of 0.36%; after sieving the calcium chloride, 8kg of the 150-mesh material was taken and dried at 70 ℃ until the water content was 0.08%. 5kg of boric acid is taken. And storing the above materials in moisture-proof sealed plastic bags respectively, and placing the plastic bags into a plastic bucket for storage.
And step two, uniformly mixing the components obtained in the step one for 30min under the condition that the relative humidity is 30% to obtain mixed powder.
And step three, sieving the sodium bromide, taking 30kg of 140-mesh material, and drying at 80 ℃ until the water content is 0.22%. And then putting the mixed powder and sodium bromide into a stirrer to be stirred at the rotating speed of 10-15r/min for 60min to obtain the powdery chlorine dioxide generating tablet.
And step four, tabletting the powdery chlorine dioxide generation tablets to obtain finished chlorine dioxide generation tablets.
Example 2
A chlorine dioxide disinfectant special for livestock and poultry is prepared from the following raw materials in parts by weight: 30kg of sodium chlorite, 33kg of potassium monopersulfate, 12kg of boric acid, 15kg of sodium bromide, 30kg of sodium sulfate and 7kg of calcium chloride.
Step one, sieving sodium chlorite at 20 ℃ to obtain 30kg of 100-mesh material, and drying at 80 ℃ to ensure that the water content is 0.44%; sieving potassium monopersulfate to obtain 33kg of 100-mesh material, drying at 80 deg.C to water content of 0.43%, sieving sodium sulfate to obtain 30kg of 100-mesh material, and drying at 60 deg.C to water content of 0.36%; after sieving the calcium chloride, 7kg of the 150-mesh material was taken and dried at 70 ℃ until the water content was 0.08%. Taking 12kg of boric acid. And storing the above materials in moisture-proof sealed plastic bags respectively, and placing the plastic bags into a plastic bucket for storage.
And step two, uniformly mixing the components obtained in the step one for 30min under the condition that the relative humidity is 30% to obtain mixed powder.
And step three, sieving the sodium bromide, taking 15kg of 140-mesh material, and drying at 80 ℃ until the water content is 0.22%. And then putting the mixed powder and sodium bromide into a stirrer to be stirred at the rotating speed of 10-15r/min for 60min to obtain the powdery chlorine dioxide generating tablet.
And step four, tabletting the powdery chlorine dioxide generation tablets to obtain finished chlorine dioxide generation tablets.
Example 3
A chlorine dioxide disinfectant special for livestock and poultry is prepared from the following raw materials in parts by weight: 22kg of sodium chlorite, 30kg of potassium monopersulfate and 10kg of boric acid. 20kg of sodium bromide, 26kg of sodium sulfate and 7.5kg of calcium chloride.
Step one, sieving sodium chlorite at 26 ℃ to obtain 22kg of 100-mesh material, and drying at 80 ℃ to ensure that the water content is 0.44%; sieving potassium monopersulfate to obtain 30kg of 100-mesh material, drying at 80 deg.C to water content of 0.43%, sieving sodium sulfate to obtain 26kg of 100-mesh material, and drying at 60 deg.C to water content of 0.36%; after sieving the calcium chloride, 7.5kg of the 150-mesh material was taken and dried at 70 ℃ until the water content was 0.08%. 10kg of boric acid is taken. And storing the above materials in moisture-proof sealed plastic bags respectively, and placing the plastic bags into a plastic bucket for storage.
And step two, uniformly mixing the components obtained in the step one for 30min under the condition that the relative humidity is 30% to obtain mixed powder.
And step three, sieving the sodium bromide, taking 20kg of 140-mesh material, and drying at 80 ℃ until the water content is 0.22%. And then putting the mixed powder and sodium bromide into a stirrer to be stirred at the rotating speed of 10-15r/min for 60min to obtain the powdery chlorine dioxide generating tablet.
And step four, tabletting the powdery chlorine dioxide generation tablets to obtain finished chlorine dioxide generation tablets.
Example 4
A chlorine dioxide disinfectant special for livestock and poultry is prepared from the following raw materials in parts by weight: 22kg of sodium chlorite, 25kg of potassium monopersulfate, 7kg of boric acid, 40kg of sodium bromide, 22kg of sodium sulfate and 8kg of calcium chloride.
Step one, sieving sodium chlorite at 21 ℃ to obtain 22kg of 100-mesh material, and drying at 80 ℃ to ensure that the water content is 0.44%; sieving potassium monopersulfate to obtain 25kg of 100-mesh material, drying at 80 deg.C to water content of 0.43%, sieving sodium sulfate to obtain 22kg of 100-mesh material, and drying at 60 deg.C to water content of 0.36%; after sieving the calcium chloride, 8kg of the 150-mesh material was taken and dried at 70 ℃ until the water content was 0.08%. 7kg of boric acid is taken. And storing the above materials in moisture-proof sealed plastic bags respectively, and placing the plastic bags into a plastic bucket for storage.
And step two, uniformly mixing the components obtained in the step one for 30min under the condition that the relative humidity is 30% to obtain mixed powder.
And step three, sieving the sodium bromide, taking 40kg of 140-mesh material, and drying at 80 ℃ until the water content is 0.22%. And then putting the mixed powder and sodium bromide into a stirrer to be stirred at the rotating speed of 10-15r/min for 60min to obtain the powdery chlorine dioxide generating tablet.
And step four, tabletting the powdery chlorine dioxide generation tablets to obtain finished chlorine dioxide generation tablets.
It should be noted that each component may be selected from a plurality of compounds listed in the summary of the invention or a combination thereof, and as to the use of the collective compounds, the specific content of each compound is selected and adjusted by those skilled in the art according to the use cases and the production environment. Often, one or both are selected for ease of preparation and are combined, and the above examples are merely illustrative of experiments conducted in connection with applicants.
The finished product chlorine dioxide generating tablet obtained by the invention is subjected to the following quality detection:
1. stability determination
The packaged propellant tablets were subjected to accelerated testing at a temperature of 54 ℃ and a relative humidity of 75%, and the content loss value was measured for 14 days.
2. Solubility test
The concentration of chlorine dioxide solution was determined by dissolving 1g of the tablet in 100ml of water and measuring the photometric value of chlorine dioxide at 455mm wavelength after 5 hours.
4. Suspension sterilization test
Bacillus subtilis var niger, Staphylococcus aureus, and Escherichia coli were selected, and the suspension was diluted with 0.03ml/L phosphate buffer. The bacterial carrier is a 1.0cm × 1.0cm degreased white plain cloth piece. 0.02ml of the bacterial suspension is drop-dyed on a cloth piece, the cloth piece is dried for 30min at 37 ℃ to prepare a bacterial piece, and the bacterial piece is put into 5ml of chlorine dioxide solution with different concentrations for acting for different time, and then the average killing rate of the solution on the microorganisms is observed.
5. Poliovirus inactivation assay
Mixing 100ml of the preserved poliovirus suspension with 100ml of 3% calf serum protein, placing in a water bath at 19-21 ℃ for 5min at constant temperature, adding 500ml of chlorine dioxide solution with different concentrations, and uniformly mixing. Acting for 30min, taking out 0.1ml, adding into a small test tube with 0.9ml of neutralizer, neutralizing for 10min, taking neutralized sample liquid, inoculating cells, observing cytopathic condition, and calculating the blackboard-writing cell infection dose.
The test results of the properties of the finished chlorine dioxide generating tablets prepared in the above examples are as follows:
table 1: property measurement indexes of examples
| Index (I) | Example 1 | Example 2 | Example 3 | Example 4 |
| Loss ratio (wt%) | 2.20 | 1.73 | 1.96 | 2.01 |
Table 2: the chlorine dioxide solution prepared by the above embodiment has killing effect on different microorganisms
Table 3: effect of the above examples on cell growth Rate
| Cell survival Rate (%) | |
| Example 1 | 100 |
| Example 2 | 100 |
| Example 3 | 100 |
| Example 4 | 100 |
Namely, the finished product chlorine dioxide generating tablet provided by the embodiment of the application can completely achieve the expected sterilizing effect.
Any numerical value recited herein includes all values from the lower value to the upper value that are incremented by one unit, provided that there is a separation of at least two units between any lower value and any higher value. For example, if it is stated that the number of a component or a value of a process variable (e.g., temperature, pressure, time, etc.) is from 1 to 90, preferably from 20 to 80, and more preferably from 30 to 70, it is intended that equivalents such as 15 to 85, 22 to 68, 43 to 51, 30 to 32 are also expressly enumerated in this specification. For values less than 1, one unit is suitably considered to be 0.0001, 0.001, 0.01, 0.1. These are only examples of what is intended to be explicitly recited, and all possible combinations of numerical values between the lowest value and the highest value that are explicitly recited in the specification in a similar manner are to be considered.
Unless otherwise indicated, all ranges include the endpoints and all numbers between the endpoints. The use of "about" or "approximately" with a range applies to both endpoints of the range. Thus, "about 20 to about 30" is intended to cover "about 20 to about 30", including at least the endpoints specified.
All articles and references disclosed, including patent applications and publications, are hereby incorporated by reference for all purposes. The term "consisting essentially of …" describing a combination shall include the identified element, ingredient, component or step as well as other elements, ingredients, components or steps that do not materially affect the basic novel characteristics of the combination. The use of the terms "comprising" or "including" to describe combinations of elements, components, or steps herein also contemplates embodiments that consist essentially of such elements, components, or steps. By using the term "may" herein, it is intended to indicate that any of the described attributes that "may" include are optional.
A plurality of elements, components, parts or steps can be provided by a single integrated element, component, part or step. Alternatively, a single integrated element, component, part or step may be divided into separate plural elements, components, parts or steps. The disclosure of "a" or "an" to describe an element, ingredient, component or step is not intended to foreclose other elements, ingredients, components or steps.
It is to be understood that the above description is intended to be illustrative, and not restrictive. Many embodiments and many applications other than the examples provided will be apparent to those of skill in the art upon reading the above description. The scope of the present teachings should, therefore, be determined not with reference to the above description, but should instead be determined with reference to the appended claims, along with the full scope of equivalents to which such claims are entitled. The disclosures of all articles and references, including patent applications and publications, are hereby incorporated by reference for all purposes. The omission in the foregoing claims of any aspect of subject matter that is disclosed herein is not intended to forego such subject matter, nor should the inventors be construed as having contemplated such subject matter as being part of the disclosed subject matter.
Claims (7)
1. The chlorine dioxide disinfectant special for livestock and poultry is characterized by being prepared from the following raw materials in parts by weight:
20-36 parts of chlorite, 20-35 parts of monopersulfate, 5-12 parts of an acidifying agent, 10-40 parts of bromide salt, 20-30 parts of a stable forming agent and 7-12 parts of a drying agent;
wherein the chlorite is at least one of an alkali metal salt of chlorous acid and an alkaline earth metal salt of chlorous acid;
the acidifier is at least one of sodium bisulfate, sodium bicarbonate, potassium bicarbonate and boric acid;
the bromide salt is selected from at least one of sodium bromide, lithium bromide, potassium bromide, calcium bromide, magnesium bromide, ammonium bromide and aluminum bromide;
the stable forming agent comprises at least one of sodium sulfate, magnesium hydroxide, sodium chloride and magnesium chloride;
the desiccant is at least one of calcium chloride, calcium sulfate and calcium stearate.
2. A chlorine dioxide disinfectant special for livestock and poultry according to claim 1, wherein said chlorite is sodium chlorite, said monopersulfate is potassium monopersulfate, said acidifying agent is boric acid, said bromide salt is sodium bromide, said stabilizing agent is sodium sulfate, and said drying agent is calcium chloride.
3. The chlorine dioxide disinfectant special for livestock and poultry according to claim 1 or 2, which is characterized by being prepared from the following raw materials in parts by weight: 20-30 parts of sodium chlorite, 25-33 parts of potassium monopersulfate, 7-8 parts of boric acid, 15-40 parts of sodium bromide, 20-30 parts of sodium sulfate and 7-8 parts of calcium chloride.
4. The method for preparing the chlorine dioxide disinfectant special for the livestock and poultry according to claim 1 is characterized by comprising the following steps of:
step one, weighing chlorite, monopersulfate, an acidifier and a stable forming agent according to the weight parts and the particle size requirement, and after drying and dehydration, ensuring that the water content of each component is less than 0.5%;
step two, uniformly mixing the components obtained in the step one to obtain mixed powder;
thirdly, putting the mixed powder and bromide salt into a stirrer to be stirred at the rotating speed of 10-15r/min for 60min to obtain powdery chlorine dioxide generating tablets;
and step four, tabletting the powdery chlorine dioxide generation tablets to obtain finished chlorine dioxide generation tablets.
5. The method for preparing a chlorine dioxide disinfectant special for livestock and poultry according to claim 4, wherein in the step one to the step three, the environmental temperature is controlled to be 17-26 ℃.
6. The method for preparing a chlorine dioxide disinfectant special for livestock and poultry according to claim 5, wherein in the step one to the step three, the relative humidity of the environment is controlled to be lower than 40%.
7. The method for preparing a chlorine dioxide disinfectant special for livestock and poultry according to claim 4, wherein in the fourth step, the tabletting pressure is controlled to be 20-28 KN.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112294907A (en) * | 2020-10-27 | 2021-02-02 | 青岛翼科新程生物科技有限公司 | Chlorine dioxide nano-zinc disinfection and bacteriostasis wash-free gel |
| CN112352785A (en) * | 2020-10-29 | 2021-02-12 | 青岛翼科新程生物科技有限公司 | Chlorine dioxide nano zinc disinfection and bacteriostasis tablet |
| CN112913853A (en) * | 2021-02-01 | 2021-06-08 | 深圳市南门科技有限公司 | Multipurpose new coronavirus sterilizing disinfectant and preparation method thereof |
| CN114027319A (en) * | 2021-12-15 | 2022-02-11 | 佛山市南海东方澳龙制药有限公司 | Chlorine dioxide disinfectant and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090232903A1 (en) * | 2005-12-16 | 2009-09-17 | Sanderson William D | Biocide compositions |
| CN101999405A (en) * | 2010-11-09 | 2011-04-06 | 定州市荣鼎水环境生化技术有限公司 | Unitary solid chlorine dioxide sustained-release generating agent and preparation method thereof |
| CN106857668A (en) * | 2016-12-26 | 2017-06-20 | 江阴瑞灵生物技术有限公司 | Store fowl disinfection tablet |
| CN109819999A (en) * | 2019-04-04 | 2019-05-31 | 开封恩科生物科技有限公司 | Chlorine dioxide solid releasing agent and preparation method thereof |
-
2019
- 2019-12-26 CN CN201911369073.7A patent/CN111066815A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090232903A1 (en) * | 2005-12-16 | 2009-09-17 | Sanderson William D | Biocide compositions |
| CN101999405A (en) * | 2010-11-09 | 2011-04-06 | 定州市荣鼎水环境生化技术有限公司 | Unitary solid chlorine dioxide sustained-release generating agent and preparation method thereof |
| CN106857668A (en) * | 2016-12-26 | 2017-06-20 | 江阴瑞灵生物技术有限公司 | Store fowl disinfection tablet |
| CN109819999A (en) * | 2019-04-04 | 2019-05-31 | 开封恩科生物科技有限公司 | Chlorine dioxide solid releasing agent and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 《通用技术》编写组 编: "《现代农业技术 专题一 绿色食品》", 31 July 2006, 地质出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112294907A (en) * | 2020-10-27 | 2021-02-02 | 青岛翼科新程生物科技有限公司 | Chlorine dioxide nano-zinc disinfection and bacteriostasis wash-free gel |
| CN112352785A (en) * | 2020-10-29 | 2021-02-12 | 青岛翼科新程生物科技有限公司 | Chlorine dioxide nano zinc disinfection and bacteriostasis tablet |
| CN112913853A (en) * | 2021-02-01 | 2021-06-08 | 深圳市南门科技有限公司 | Multipurpose new coronavirus sterilizing disinfectant and preparation method thereof |
| CN114027319A (en) * | 2021-12-15 | 2022-02-11 | 佛山市南海东方澳龙制药有限公司 | Chlorine dioxide disinfectant and preparation method thereof |
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