CN106489931A - It is used as sodium chlorite gel and its preparation technology of disinfectant - Google Patents

It is used as sodium chlorite gel and its preparation technology of disinfectant Download PDF

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Publication number
CN106489931A
CN106489931A CN201610808254.5A CN201610808254A CN106489931A CN 106489931 A CN106489931 A CN 106489931A CN 201610808254 A CN201610808254 A CN 201610808254A CN 106489931 A CN106489931 A CN 106489931A
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CN
China
Prior art keywords
sodium chlorite
water
gel
solution
disinfectant
Prior art date
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Pending
Application number
CN201610808254.5A
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Chinese (zh)
Inventor
刘建成
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Tianjin Borui Kaiyuan Environmental Protection Technology Co Ltd
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Tianjin Borui Kaiyuan Environmental Protection Technology Co Ltd
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Priority to CN201610808254.5A priority Critical patent/CN106489931A/en
Publication of CN106489931A publication Critical patent/CN106489931A/en
Pending legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/22Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds

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  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Toxicology (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention relates to a kind of sodium chlorite gel as disinfectant, its constituent and percentage by weight are:Sodium chlorite 0.1 15%, sodium carbonate 0.1 5%, gellan gum 0.01 10%, water surplus.The present invention carries the gel for doing and is mainly used in sterilization processing and soil restoring technology, the elimination of contaminated air harmful components, the nontoxic process of harmful water quality in tap water process, industrial circulating water water process, the sterilization processing of quick drinking water, hospital environment sterilization processing, the soil in infectious disease epidemic-stricken area, water, air sterilization, passage of central air conditioner, the sterilization processing of air conditioning chamber, the sterilization processing of car air-conditioner, the sterilization processing of domestic air conditioning, refrigerator, refrigerator-freezer and cold storing and fresh-keeping warehouse etc..

Description

It is used as sodium chlorite gel and its preparation technology of disinfectant
Technical field
The invention belongs to sterilizing field, can be used as the sodium chlorite gel of disinfectant, it is strong oxidizer sodium chlorite For a kind of existence form of the product for civilian use, with good storage stability and ease for use.
Background technology
Chlorine dioxide is a kind of efficient, nontoxic, safety, sterilization purification agent.As which is colourless, odorless, stable in properties, sterilization Efficiency high, wide sterilization spectrum (antibacterial, bacterial spore, virus and funguses etc. can be killed), work fast, persistent period length, dosage Little, reactant non-residual toxicity, non-carcinogenesis, protein denaturation, nontoxic, nonirritant is not made to higher mammal, defended by the world Raw tissue is classified as IA level security disinfectant, is widely used in sterilizing, purification of water quality, deodorization, mould proof, food fresh keeping etc.. But some defects of chlorine dioxide itself cause application to be restricted, and are mainly manifested in:(1) chlorine dioxide is a kind of explosive Gas, is easy for exploding when in air, concentration is more than 10%;(2) chlorine dioxide is although soluble in water, dissolubility in water 8.3g/L, but which is volatile in aqueous, and slightly aeration is volatilizable;(3) in the presence of light and heat, chlorine dioxide easily divides , into hypochlorous acid, chlorine, oxygen etc., performance is very unstable for solution.These defects cause chlorine dioxide to need matching while using in application, Be inconvenient to use, moreover, the material performance for preparing chlorine dioxide is unstable, it is difficult to transport and keeping.
Sodium chlorite is the top quality predecessor of chlorine dioxide, can be reacted in acid, reducing agent or even air, Chlorine dioxide is discharged, but sodium chlorite belongs to strong oxidizer, high to movement requirement, transporting, depositing, using process In be susceptible to the perils such as blast, although sodium chlorite liquid market is present, with higher to safety requirements, liquid There is potential safety hazard in transport and policy is limited, and be to solve this difficult problem, need a more preferable carrier to guarantee sodium chlorite each Plant occasion safe and effective.
Content of the invention
The technical problem to be solved in the present invention is:The problem for overcoming prior art to exist, designs a kind of good stability, can hold Carry sodium chlorite and can control that water is not flowable wherein, after working substance volatilization residue do not result in environmental pollution, release Put that speed is controllable, a kind of sodium chlorite gel as disinfectant that one-component is convenient and practical and preparation method thereof.
The purpose of the present invention is achieved through the following technical solutions:
A kind of sodium chlorite gel as disinfectant, it is characterised in that:Its constituent and percentage by weight are:
And, the solvable sulfate is sulfate magnesium 0.01-10% and/or iron sulfate 0.01-5%.Can by adding Insoluble sulfates, the loading degree of sodium chlorite improve 20% stability and improve.Iron salt and magnesium salt is not added with, gel starts to melt in 60 Du Change, increase iron salt and magnesium salt, gel is insoluble at 90 °, maintains gel solid-state stability at high temperature.
And, it is additionally added SODIUM PERCARBONATE and adds 0.01-5% mass percents.
And, the gellan gum is low acyl gellan gum or high acyl gellan gum, or the mixture of the two.
A kind of preparation method of the sodium chlorite gel as disinfectant, it is characterised in that:The step of preparation, is as follows:
(1) gellan gum is dissolved in water, forms solution A;
(2) sodium carbonate, solvable sulfate are dissolved in water, add sodium chlorite dissolving, form solution B;
(3) solution A is added in solution B, mixed.
The step of a kind of preparation method of the sodium chlorite gel as disinfectant, preparation, is as follows:
(1) gellan gum is dissolved in water, forms solution A;
(2) sodium carbonate, solvable sulfate, SODIUM PERCARBONATE are dissolved in water, add sodium chlorite dissolving, form solution B;
(3) solution A is added in solution B, mixed.
Wherein, low acyl gellan gum and high acyl gellan gum are gel components;Sodium carbonate, magnesium sulfate, iron sulfate, SODIUM PERCARBONATE are The stabilizer of sodium chlorite;Sodium chlorite is in the form of ion in gel.
The stabilizer of sodium chlorite is sodium carbonate, magnesium sulfate, iron sulfate, one or more in SODIUM PERCARBONATE, and which adds Amount is relevant with application scenario, needs the increased sodium carbonate amount of quick release, reduces magnesium sulfate, iron sulfate consumption, needs to release Put.
The advantages of the present invention are:
1st, the present invention effectively solves the peace of sodium chlorite solid material using gellan gum as the carrier of sodium chlorite Full sex chromosome mosaicism, improves the safety convenient during storage, transport and use, meanwhile, solve sodium chlorite aqueous solution's fortune Defeated inconvenience, it is to avoid leakage problem, increased the range of application and application of sodium chlorite.
2nd, the present invention improves the stability of sodium chlorite by the synergism of each component, meanwhile, sulfate ion is deposited Increased loading degree of the sodium chlorite in gel.
3rd, the magnesium sulfate for adding in the present invention and iron sulfate increase gel strength, shorten gel time, improve production Efficiency.
4th, the present invention is raw materials used is food grade materials, easy to use, safe, environmental protection, nontoxic, is prevented effectively to environment Impact.
5th, preparation method according to the present invention is simple, and raw materials used wide material sources, obtains easily, is highly suitable for big rule The technique productions of mould.
6th, a kind of sodium chlorite gel that can be used as disinfectant that the application is provided, is mainly used in tap water process, work Industry recirculated water water process, the sterilization processing of quick drinking water, hospital environment sterilization processing, the soil in infectious disease epidemic-stricken area, water, air Sterilization processing, passage of central air conditioner, the sterilization processing of air conditioning chamber, the sterilization processing of car air-conditioner, the sterilization processing of domestic air conditioning, Refrigerator, the sterilization processing of refrigerator-freezer and cold storing and fresh-keeping warehouse and soil restoring technology, contaminated air harmful components are eliminated, harmful water Nontoxic process of matter etc..
Specific embodiment
With reference to embodiment, the present invention is further described, and following embodiments are illustrative, be not determinate, Protection scope of the present invention can not be limited with following embodiments.
Embodiment 1:
The raw material of the embodiment of the present invention is marketable material.
A kind of constituent of the sodium chlorite gel as disinfectant is (being counted as 100 with total amount):
A kind of the step of preparation method of sodium chlorite gel as disinfectant, is as follows:
(1) low acyl gellan gum and high acyl gellan gum are dissolved in 50g water, form solution 1;
(2) sodium carbonate, magnesium sulfate are dissolved in 37g water, add sodium chlorite dissolving, form solution 2;
(3) solution 1 is added in solution 2, placed, form gel.
Embodiment 2:
A kind of constituent of the sodium chlorite gel as disinfectant is (being counted as 100 with total amount):
A kind of the step of preparation method of sodium chlorite gel as disinfectant, is as follows:
(1) low acyl gellan gum is dissolved in 50g water, forms solution 1;
(2) sodium carbonate, iron sulfate, SODIUM PERCARBONATE are dissolved in 39g water, add sodium chlorite dissolving, form solution 2;
(3) solution 1 is added in solution 2, placed, form gel.
The mechanism of action of the present invention:
Mainly using gellan gum as gel rubber material, gellan gum has excellent resistance to acids and bases and excellent oxytolerant to the present invention The property changed, is very excellent gel forming materials, is particularly suitable for sodium chlorite, may insure chlorous acid when alkalescence material is compounded Sodium will not occur redox reaction and activate in advance, be simultaneously introduced sulfate, improve sodium chlorite dissolubility in the solution, Improve stability.Magnesium ion and iron ion increase gel strength, are conducive to technological forming.
Application example 1:
In the gel that chicken farm is obtained using embodiment 1, the citric acid of gel weight 10% is loaded into in gel, by gel Chicken farm ceiling position is placed on, can pre- avian influenza-prevention.Usage amount is according to the determination of chicken farm size, general 1000 square meter chicken farm Using 100g gels.
Application example 2:
Treatment fish diseasess:A kind of sodium chlorite gel that can be used as disinfectant for taking 10g embodiments 2 is placed on 100g concentration 1% Citric acid solution in activate 10min, by activation after solution add in the fish jar of 200 liters of water, be put into sick fish, 24 hours Disease fish can be cured so as to physical recovery health.
Conclusion:The sodium chlorite gelling performance prepared using the present invention is stable, and curable is good, safely and effectively, convenient transport, Easy-to-use can preferably be applied to productive life every field.
The sodium chlorite gel quality standard as disinfectant that the present invention is provided:
Outward appearance:Clear gel
Density:1.02-1.2(g/100ml)
Soak time:20min%
Using temperature:Room temperature
It should be noted that:The embodiment of the present invention using various components be commercially available prod.

Claims (8)

1. a kind of sodium chlorite gel as disinfectant, it is characterised in that:Its constituent and percentage by weight are:
2. the sodium chlorite gel as disinfectant according to claim 1, it is characterised in that:It is additionally added solvable sulphuric acid Salt, adds as 0.01-10wt%.
3. the sodium chlorite gel as disinfectant according to claim 2, it is characterised in that:The solvable sulfate is Magnesium sulfate 0.01-10wt% and/or iron sulfate 0.01-5wt%.
4. the sodium chlorite gel as disinfectant according to claim 1 or 2 or 3, it is characterised in that:It was additionally added carbon Sour sodium 0.01-5wt%.
5. the sodium chlorite gel as disinfectant according to claim 1, it is characterised in that:The gellan gum is low acyl Gellan gum or high acyl gellan gum, or the mixture of the two.
6. a kind of preparation method of the as claimed in claim 1 sodium chlorite gel for being used as disinfectant, it is characterised in that:Prepare The step of as follows:
(1) gellan gum is dissolved in water, forms solution A;
(2) sodium carbonate is dissolved in water, adds sodium chlorite dissolving, form solution B;
(3) solution A is added in solution B, mixed.
7. a kind of preparation method for being used as claimed in claim 2 or claim 3 the sodium chlorite gel of disinfectant, it is characterised in that: The step of preparation, is as follows:
(1) gellan gum is dissolved in water, forms solution A;
(2) by sodium carbonate, solvable sulfate is dissolved in water, and adds sodium chlorite dissolving, forms solution B;
(3) solution A is added in solution B, mixed.
8. a kind of preparation method of the as claimed in claim 4 sodium chlorite gel for being used as disinfectant, it is characterised in that:Prepare The step of as follows:
(1) gellan gum is dissolved in water, forms solution A;
(2) sodium carbonate, solvable sulfate, SODIUM PERCARBONATE are dissolved in water, add sodium chlorite dissolving, form solution B;
(3) solution A is added in solution B, mixed.
CN201610808254.5A 2016-09-08 2016-09-08 It is used as sodium chlorite gel and its preparation technology of disinfectant Pending CN106489931A (en)

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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610808254.5A CN106489931A (en) 2016-09-08 2016-09-08 It is used as sodium chlorite gel and its preparation technology of disinfectant

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113274953A (en) * 2020-12-01 2021-08-20 上海时宜品牌管理有限公司 Formaldehyde removal gel and preparation method thereof
WO2023214221A1 (en) * 2022-05-05 2023-11-09 Chiaphua Industries Ltd Composition and making of self-forming, continuous-release antimicrobial air gel

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1969633A (en) * 2006-12-06 2007-05-30 刘桂发 Monophyletic solid disinfectant of chlorine dioxide and preparation method thereof
CN101176469A (en) * 2007-12-04 2008-05-14 姜波 Powder preparation stability chlorine dioxide sanitizer and preparation method thereof
CN101411334A (en) * 2008-11-28 2009-04-22 新乡市康大消毒剂有限公司 A kind of production method of disinfection agent of chlorine dioxide
CN101658692A (en) * 2008-08-27 2010-03-03 山东省生物药物研究院 Gellan gum composition, preparation method thereof and application thereof
CN103565828A (en) * 2012-07-24 2014-02-12 殷豪章 Chlorine dioxide gel and preparation method thereof
CN105145626A (en) * 2015-07-30 2015-12-16 竹安(北京)生物科技发展有限公司 Aroma type immobilized gel-like chlorine dioxide air cleanser

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1969633A (en) * 2006-12-06 2007-05-30 刘桂发 Monophyletic solid disinfectant of chlorine dioxide and preparation method thereof
CN101176469A (en) * 2007-12-04 2008-05-14 姜波 Powder preparation stability chlorine dioxide sanitizer and preparation method thereof
CN101658692A (en) * 2008-08-27 2010-03-03 山东省生物药物研究院 Gellan gum composition, preparation method thereof and application thereof
CN101411334A (en) * 2008-11-28 2009-04-22 新乡市康大消毒剂有限公司 A kind of production method of disinfection agent of chlorine dioxide
CN103565828A (en) * 2012-07-24 2014-02-12 殷豪章 Chlorine dioxide gel and preparation method thereof
CN105145626A (en) * 2015-07-30 2015-12-16 竹安(北京)生物科技发展有限公司 Aroma type immobilized gel-like chlorine dioxide air cleanser

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113274953A (en) * 2020-12-01 2021-08-20 上海时宜品牌管理有限公司 Formaldehyde removal gel and preparation method thereof
WO2023214221A1 (en) * 2022-05-05 2023-11-09 Chiaphua Industries Ltd Composition and making of self-forming, continuous-release antimicrobial air gel

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Application publication date: 20170315

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