CN111040891A - 低表面张力低气味厨具清洗剂及制备方法 - Google Patents

低表面张力低气味厨具清洗剂及制备方法 Download PDF

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CN111040891A
CN111040891A CN201911335673.1A CN201911335673A CN111040891A CN 111040891 A CN111040891 A CN 111040891A CN 201911335673 A CN201911335673 A CN 201911335673A CN 111040891 A CN111040891 A CN 111040891A
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卢建明
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Dalian Sandaaoke Chemistry Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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    • C11D3/20—Organic compounds containing oxygen
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    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/28—Heterocyclic compounds containing nitrogen in the ring
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
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    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
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    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
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    • C11D1/72—Ethers of polyoxyalkylene glycols

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Abstract

本发明公开一种低表面张力低气味厨具清洗剂，所用原料及质量百分比如下：N‑烷基全氟己基磺酰亚胺羧酸钠1.0～1.4%、N‑全氟丁基磺酰基‑N‑全氟己基磺酰基亚胺磺酸钠0.6～1.0%、8‑12碳醇聚氧乙烯醚5～7％、8‑10碳烷基糖苷3～5％、十二烷基苯磺酸钠3～5%、葡萄糖酸钠2～4％、两性咪唑啉6～8％、碳酸钠3～5%、萜烯4～6%及去离子水余量。表面张力低（20~22达因/厘米），泡沫丰富细腻持久，不仅可充分与污垢发生反应、去污力强且容易清洗；低气味（日本气味检测仪XP329型检测数值145~150），即使家庭厨房密闭且温度超过40度，亦没有感觉气味大，更没有因有气味而无法继续清洗操作的现象。

Description

低表面张力低气味厨具清洗剂及制备方法
技术领域
本发明涉及一种厨具清洗剂及制备方法，尤其是一种低表面张力低气味厨具清洗剂及制备方法。
背景技术
目前，市售的厨具清洗剂一般含有大量短碳链的溶剂和强碱，不仅表面张力高而且有较大的刺鼻气味。表面张力高（30-40达因/厘米）的结果使其泡沫不够丰富，不能长时间与厨具表面顽渍接触而迅速流淌下来，直接影响去污效果；刺鼻异味（日本气味检测仪XP329型检测数值为230以上），在大多空间狭小且比较封闭的家庭厨房内难以迅速消除，为此强烈刺激人的呼吸道，有时则无法继续清洗操作。
发明内容
本发明是为了解决现有技术所存在的上述技术问题，提供一种低表面张力低气味厨具清洗剂及制备方法。
本发明的技术解决方案是：一种低表面张力低气味厨具清洗剂，其特征在于所用原料及质量百分比如下：N-烷基全氟己基磺酰亚胺羧酸钠1.0～1.4%、N-全氟丁基磺酰基-N-全氟己基磺酰基亚胺磺酸钠0.6～1.0%、8-12碳醇聚氧乙烯醚5～7％、8-10碳烷基糖苷3～5％、十二烷基苯磺酸钠3～5%、葡萄糖酸钠2～4％、两性咪唑啉6～8％、碳酸钠3～5%、萜烯 4～6%及去离子水余量。
上述低表面张力低气味厨具清洗剂的制备方法，依次按照如下步骤进行：
a. 将称量的去离子水投入搅拌釜中；
b. 将碳酸钠、葡萄糖酸钠及十二烷基苯磺酸钠投入搅拌釜中搅拌15分钟；
c. 将8-12碳醇聚氧乙烯醚投入到搅拌釜中，继续搅拌12分钟；
d.将两性咪唑啉、萜烯及8-10碳烷基糖苷投入罐中，搅拌至澄清透明；
e.将N-烷基全氟己基磺酰亚胺羧酸钠、N-全氟丁基磺酰基-N-全氟己基磺酰
基亚胺磺酸钠投入搅拌釜中，搅拌30分钟即可。
本发明表面张力低（20~22达因/厘米），使用原液清洗厨具，泡沫丰富细腻持久，不仅可充分与污垢发生反应、去污力强且容易清洗；低气味（日本气味检测仪XP329型检测数值145~150），即使家庭厨房密闭且温度超过40度，亦没有感觉气味大，更没有因有气味而无法继续清洗操作的现象。
具体实施方式
实施例1：
所用原料及质量百分比如下：N-烷基全氟己基磺酰亚胺羧酸钠1.2%、N-全氟丁基磺酰基-N-全氟己基磺酰基亚胺磺酸钠0.8 %、8-12碳醇聚氧乙烯醚6％、8-10碳烷基糖苷4％、十二烷基苯磺酸钠4%、葡萄糖酸钠3％、两性咪唑啉7％、碳酸钠4%、萜烯（馏程170~190℃）5%及去离子水余量。
制备方法依次按照如下步骤进行：
a. 将称量的去离子水投入搅拌釜中；
b. 将碳酸钠、葡萄糖酸钠及十二烷基苯磺酸钠投入搅拌釜中搅拌15分钟；
c. 将8-12碳醇聚氧乙烯醚投入到搅拌釜中，继续搅拌12分钟；
d. 将两性咪唑啉、萜烯及8-10碳烷基糖苷投入罐中，搅拌至澄清透明；
e. 将N-烷基全氟己基磺酰亚胺羧酸钠、N-全氟丁基磺酰基-N-全氟己基磺酰基亚胺磺酸钠投入搅拌釜中，搅拌30分钟即可。
原料来源：
所有原料均为外购，其中N-烷基全氟己基磺酰亚胺羧酸钠、N-全氟丁基磺酰基-N-全氟己基磺酰基亚胺磺酸钠、8-12碳醇聚氧乙烯醚购于购于南京古田化工有限公司；8-10碳烷基糖苷购于巴斯夫（中国）有限公司；十二烷基苯磺酸钠购于江苏清婷洗涤用品有限公司、葡萄糖酸钠、两性咪唑啉、萜烯（馏程170~190℃）购于慧山科技有限公司，碳酸钠购于大连化工厂。
实施例2：
所用原料及质量百分比如下：N-烷基全氟己基磺酰亚胺羧酸钠1.0%、N-全氟丁基磺酰基-N-全氟己基磺酰基亚胺磺酸钠1.0%、8-12碳醇聚氧乙烯醚5％、8-10碳烷基糖苷5％、十二烷基苯磺酸钠3%、葡萄糖酸钠4％、两性咪唑啉6％、碳酸钠5%、萜烯（馏程170~190℃） 4%及去离子水余量。
制备方法及原料来源同实施例1。
实施例3：
所用原料及质量百分比如下：N-烷基全氟己基磺酰亚胺羧酸钠1.4%、N-全氟丁基磺酰基-N-全氟己基磺酰基亚胺磺酸钠0.6%、8-12碳醇聚氧乙烯醚7％、8-10碳烷基糖苷3％、十二烷基苯磺酸钠5%、葡萄糖酸钠2％、两性咪唑啉8％、碳酸钠3%、萜烯（馏程170~190℃）6%及去离子水余量。
制备方法及原料来源同实施例1。
采用上海梭伦科技的全自动表面/界面张力仪（型号A201）用白金环法表面/界面张力测试法分别测试本发明实施例1、2、3表面张力；采用日本气味检测仪（型号XP329），检测原理为氧化铟传导方式，分别测试本发明实施例1、2、3气味，结果如表1所示。
Figure DEST_PATH_IMAGE001

Claims (2)

1.一种低表面张力低气味厨具清洗剂，其特征在于所用原料及质量百分比如下：N-烷基全氟己基磺酰亚胺羧酸钠1.0～1.4%、N-全氟丁基磺酰基-N-全氟己基磺酰基亚胺磺酸钠0.6～1.0%、8-12碳醇聚氧乙烯醚5～7％、8-10碳烷基糖苷3～5％、十二烷基苯磺酸钠3～5%、葡萄糖酸钠2～4％、两性咪唑啉6～8％、碳酸钠3～5%、萜烯 4～6%及去离子水余量。
2.一种如权利要求1所述低表面张力低气味厨具清洗剂的制备方法，其特征在于依次按照如下步骤进行：
a. 将称量的去离子水投入搅拌釜中；
b. 将碳酸钠、葡萄糖酸钠及十二烷基苯磺酸钠投入搅拌釜中搅拌15分钟；
c.将8-12碳醇聚氧乙烯醚投入到搅拌釜中，继续搅拌12分钟；
d.将两性咪唑啉、萜烯及8-10碳烷基糖苷投入罐中，搅拌至澄清透明；
e.将N-烷基全氟己基磺酰亚胺羧酸钠、N-全氟丁基磺酰基-N-全氟己基磺酰基亚胺磺酸钠投入搅拌釜中，搅拌30分钟即可。
CN201911335673.1A 2019-12-23 2019-12-23 低表面张力低气味厨具清洗剂及制备方法 Pending CN111040891A (zh)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014080500A (ja) * 2012-10-16 2014-05-08 Kao Corp 食器洗い用液体洗浄剤組成物
CN104263531A (zh) * 2014-09-09 2015-01-07 青岛市高科专利技术转移平台有限公司 一种环保型厨具清洗剂
CN106675828A (zh) * 2016-12-01 2017-05-17 三达奥克化学股份有限公司 工业高泡型厨具清洗剂及生产方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014080500A (ja) * 2012-10-16 2014-05-08 Kao Corp 食器洗い用液体洗浄剤組成物
CN104263531A (zh) * 2014-09-09 2015-01-07 青岛市高科专利技术转移平台有限公司 一种环保型厨具清洗剂
CN106675828A (zh) * 2016-12-01 2017-05-17 三达奥克化学股份有限公司 工业高泡型厨具清洗剂及生产方法

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