CN110973134A - Pesticide composition - Google Patents

Pesticide composition Download PDF

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Publication number
CN110973134A
CN110973134A CN201911051496.4A CN201911051496A CN110973134A CN 110973134 A CN110973134 A CN 110973134A CN 201911051496 A CN201911051496 A CN 201911051496A CN 110973134 A CN110973134 A CN 110973134A
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agent
pesticide
chitosan
valienamine
auxiliary agent
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Inventor
陈佳佳
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Zhejiang Zhongshan Chemical Industry Group Co ltd
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Zhejiang Zhongshan Chemical Industry Group Co ltd
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/14Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
    • A01N43/16Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring

Abstract

The invention relates to the field of plant sterilization, in particular to a pesticide composition, which solves the technical problem of poor sterilization effect of a single type of bactericide in the prior art, and comprises the following components in parts by weight: 2% -30% of valienamine; 0.5% -14% of chitosan; the balance of auxiliary agents. According to the pesticide composition, after the valienamine and the chitosan are compounded, the late blight can be effectively prevented, the prevention effect is better than that of a single pesticide, the lasting period is long, the prevention effect reaches over 79.8% in 14 days after the last pesticide application of a plant, no phytotoxicity is caused to target crops in the experimental pesticide application range, and after the valienamine and the chitosan are compounded according to different proportions, the use amount of effective components is greatly reduced under the condition of the same prevention and control effect, so that the harm to the environment is reduced, and the resistance of pests is delayed.

Description

Pesticide composition
Technical Field
The invention relates to the field of plant sterilization, and in particular relates to a pesticide composition.
Background
Chitosan, also called chitin, crab chitin, etc., is widely present in the shells of lower animals, such as arthropods of crustacea, entomophytes and arachnids, and the cell walls of lower plants, such as fungi, algae, yeast, etc., and is one of the most abundant natural high molecular compounds and the second most nitrogen-containing compound in nature, and the annual biosynthesis amount of the chitosan can be estimated to be as much as 100 hundred million tons. The chitosan has the advantages of being used as a natural polymer, has good safety, biodegradability, biocompatibility, unique physicochemical property and biological activity, and has become a hotspot in pesticide research in recent years by utilizing and researching chitin for hundreds of years, particularly in recent years under the background of sustainable agriculture and production of harmless agricultural products.
The chitosan can inhibit the growth of pathogenic matter and raise the disease resistance and immunity of crop through altering the structure and function of pathogenic matter cell membrane. The chitosan can effectively prevent and control crop diseases such as cucumber downy mildew, powdery mildew, tomato late blight, virus diseases, apple anthracnose, rice blast and the like, and has a wide bactericidal spectrum.
Because people depend on using a single type of bactericide for a long time, pathogenic bacteria are easy to generate drug resistance, so that the chemical dosage of the bactericide is increased sharply, the economic burden of farmers is increased, and the environment is polluted.
Accordingly, the present invention is directed to a method of making a semiconductor device.
Disclosure of Invention
The invention aims to provide a pesticide composition, which solves the technical problem that a single type of bactericide in the prior art has poor sterilizing effect.
In order to solve the problems, the invention adopts the following technical scheme:
a pesticide composition comprises the following components in parts by weight:
4% -30% of valienamine;
0.5% -14% of chitosan;
the balance of auxiliary agents.
Valienamine, which is called Valifenaflate in English and is called N- (isopropoxycarbonyl) -L-valyl- (3RS) -3- (4-chlorphenyl) -R-alanine methyl ester in chemical name, belongs to amino acid derivatives, has strong systemic activity, has high biological activity on plant diseases caused by oomycetes, and plays roles of protection, treatment and eradication on the surface and in the body of the plant.
The method for preparing the pesticide preparation by combining the effective components of different pesticides is a quick and effective method for developing and researching new pesticides at present. The mixing of different types of pesticidal active ingredients generally shows three types of action: additive action, synergistic action and antagonistic action.
However, after different types of pesticide active ingredients are mixed, the specific action is unpredictable; the pesticide active ingredients are not simply mixed, and auxiliary ingredients of the pesticide preparation are required to be added, the type and the dosage of the auxiliary ingredients of the pesticide preparation directly influence the exertion of the pesticide active ingredients, and the relationship between the dosage and the pesticide effect is not linear.
According to the pesticide composition provided by the invention, after the valienamine and the chitosan are compounded, late blight can be effectively prevented and treated, the prevention and treatment effect is superior to that of a single agent, and the lasting period is long. The control effect of the plant reaches over 79.8 percent in 14 days after the last application of the plant, and the plant has no phytotoxicity to target crops in the application range of the test. After the valienamine and the chitosan are compounded according to different proportions, the use amount of effective components is greatly reduced under the condition of the same control effect, thereby reducing the harm to the environment and delaying the resistance of pests.
Preferably, the auxiliary agent comprises an auxiliary agent and a filler, wherein the auxiliary agent accounts for 10-20% of the total weight of the composite material. Different auxiliaries and/or fillers are selected from different pesticide formulations.
After the content of the auxiliary agent is limited, the amount of the filler can be obtained by calculation.
After the contents of validamine, chitosan and the auxiliary agent are determined, the tonic is filled in 100 percent.
The technical scheme of the method is characterized in that the dosage of valienamine and chitosan enables the pesticide to have a better sterilization effect and to have a longer pesticide effect, so that the dosage of the pesticide is greatly reduced, and the pesticide residue on the plants is reduced.
The influence of the filler on the pesticide effect is smaller than the influence of the auxiliary agent on the pesticide effect, so that the limitation of the content of the auxiliary agent is beneficial to improving the pesticide effect.
The dosage of the auxiliary agent adopts the content, which is beneficial to full play of drug effect.
The auxiliary agent has multiple optional schemes, and is beneficial to reducing the manufacturing cost of the pesticide.
Preferably, the auxiliary agent is one or more of a solvent, a cosolvent, an emulsifier, a dispersant, a wetting agent, a disintegrating agent, a binder, a defoaming agent, an antifreeze agent and a thickening agent.
Further, the solvent can be one or more of xylene, 100 # solvent oil, 150 # solvent oil, 200 # solvent oil and formaldehyde.
Further, the cosolvent may be one or more of methanol, ethanol, ethyl acetate, cyclohexanone, toluene, acetone, and N-methylpyrrolidone.
Further, the emulsifier can be one or more of fatty acid diethanolamide, calcium dodecylbenzene sulfonate, fatty alcohol polyoxyethylene ether, alkylphenol polyoxyethylene ether, agricultural emulsifier No. 500, agricultural emulsifier No. 700, alkyl glycoside and α -sodium alkenyl sulfonate.
Further, the dispersant can be one or more of sodium lignosulfonate, calcium lignosulfonate, sodium naphthalene sulfonate formaldehyde condensate, sodium methylene bis-naphthalene sulfonate, formaldehyde condensate sulfate, polycarboxylate, alkylphenol polyoxyethylene phosphate, alkylphenol polyoxyethylene ether and fatty acid polyoxyethylene ester.
Further, the humectant may be one or more of sodium dodecyl sulfate, nekal BX, fructus Gleditsiae Abnormalis powder, sodium dodecylbenzene sulfonate, faeces Bombycis, fructus Sapindi Mukouossi powder, alkyl polyglycoside, and tea seed cake powder.
Further, the disintegrating agent can be one or more of bentonite, ammonium sulfate, aluminum chloride, urea, magnesium chloride and glucose.
Further, the binder may be one or more of starch, diatomaceous earth, cyclodextrin, PVA, rosin, carboxymethyl (ethyl) cellulose.
Further, the defoaming agent can be one or more of C8-210 fatty alcohol compounds, epoxidized soybean oil, ethanol, silicone compounds, organic silicone oil and C10-C20 saturated fatty acid compounds.
Further, the antifreeze can be one or more of sorbitol, ethylene glycol, polyethylene glycol, propylene glycol, glycerol, urea and sodium chloride.
Further, the thickening agent is selected from one or more of gelatin, xanthan gum, polyethylene glycol and polyvinyl alcohol.
The filler has multiple optional schemes, and is beneficial to reducing the manufacturing cost of the pesticide.
Preferably, the filler is one or more of light calcium carbonate, diatomite, bentonite, attapulgite, white carbon black and deionized water.
The specific components used for the fillers and the auxiliaries can be freely selected by those skilled in the art, and are not specifically limited herein.
In a second aspect, a pesticide composition is provided, wherein the pesticide is a suspending agent and comprises the following components in parts by weight:
2% -18% of valienamine and 2% of chitosan;
the auxiliary agent comprises:
3% -4% of dispersing agent;
0.4 to 2.5 percent of antifreeze agent;
0.2% -5% of thickening agent;
the filler is as follows:
the balance of deionized water.
Preferably, the adjuvant further comprises a wetting agent or an emulsifier.
In a third aspect, there is provided a pesticidal composition, which is a wettable powder, comprising the following components in parts by weight:
2-30% of valienamine and 3-14% of chitosan;
the auxiliary agent is:
3% -4% of a humectant;
2% -3% of cosolvent;
4% -5% of dispersing agent;
the filler is as follows:
diatomaceous earth.
In a fourth aspect, a pesticide composition is provided, wherein the pesticide is an aqueous dispersion agent and comprises the following components in parts by weight:
3% -15% of valienamine and 3% -12% of chitosan;
the auxiliary agent comprises:
4% -5% of a dispersant;
2% -2.5% of disintegrating agent;
2% -2.5% of dispersing agent;
2% -3% of a binder;
the filler is as follows:
light calcium carbonate.
In a fifth aspect, a pesticide composition is provided, and the pesticide is an aqueous agent and comprises the following components in parts by weight:
2 to 4.5 percent of valienamine and 0.5 to 2 percent of chitosan;
the auxiliary agent comprises:
2% -4% of cosolvent;
4% -5% of a humectant;
the filler is as follows:
deionized water.
Preferably, the auxiliary agent also comprises a dispersant.
Detailed Description
In order to make the objects, technical solutions and advantages of the present disclosure more apparent, the present disclosure is described with the following specific examples, but the present disclosure is by no means limited to these examples. The following description is merely illustrative of the present disclosure and should not be taken as limiting the scope of the disclosure. It should be understood that any modification, equivalent replacement, and improvement made within the spirit and principle of the present disclosure should be included in the scope of the present disclosure.
Example 1
18.0% of valienamine, 3% of chitosan, 2.5% of saponin powder, 3% of calcium lignosulfonate, 0.4% of sodium chloride, 1.8% of propylene glycol, 5% of sodium carboxymethylcellulose and the balance of deionized water to 100%.
The suspending agent is prepared by mixing the raw materials according to a conventional method for preparing the suspending agent.
Example 2
2.0% of valienamine, 6% of chitosan, 4.5% of sodium dodecyl benzene sulfonate, 4% of calcium lignosulfonate, 2.5% of ethylene glycol, 0.2% of xanthan gum and deionized water for making up 100%.
The suspending agent is prepared by mixing the raw materials according to a conventional method for preparing the suspending agent.
In a third aspect, a wettable powder is provided.
Example 3
2.0% of valienamine, 14.0% of chitosan, 4% of tea seed cake powder, 3% of ethanol, 4% of sodium lignin sulfonate and the balance of diatomite to 100%.
The raw materials are mixed and crushed into wettable powder according to a conventional method for preparing the wettable powder.
Example 4
30% of valienamine, 3% of chitosan, 3% of tea seed cake powder, 2% of ethanol, 5% of sodium lignosulfonate and 100% of diatomite. The raw materials are mixed and crushed according to a conventional method for preparing wettable powder to prepare wettable powder.
In a fourth aspect, an aqueous dispersion is provided.
Example 5
3% of valienamine, 12% of chitosan, 4% of sodium lignosulfonate, 2.5% of ammonium sulfate, 2.5% of polycarboxylate, 3% of starch and the balance of light calcium carbonate to 100%.
The raw materials are mixed according to a conventional method for preparing the water dispersible granule to prepare the water dispersible granule.
Example 6
Valine 15%, chitosan 3%, sodium lignosulfonate 5%, ammonium sulfate 2.5%, polycarboxylate 2%, starch 2% and light calcium carbonate to make up 100%.
The raw materials are mixed according to a conventional method for preparing the water dispersible granule to prepare the water dispersible granule.
In a fifth aspect, an aqueous formulation is provided.
Example 7
2% of valienamine, 2% of chitosan, 4% of N-methyl pyrrolidone, 5% of alkyl polyglycoside and deionized water to make up to 100%.
Mixing the above materials according to conventional method for preparing water aqua.
Example 8
4.5% of valinamide, 0.5% of chitosan, 2% of N-methyl pyrrolidone, 4% of sodium dodecyl benzene sulfonate, 4% of calcium lignosulfonate and deionized water for making up 100%.
Mixing the above materials according to conventional method for preparing water aqua.
The combination of validamine and chitosan has obvious synergistic effect on resisting downy mildew and late blight, and the bactericidal effect of two pesticide active ingredients is simply added, and the specific description is provided in the following control example.
Indoor toxicity determination of compounding of valinamide and chitosan:
1. and (3) testing the joint toxicity of the valienamine and the chitosan to downy mildew according to different proportions.
1.1 test agent
98 percent of validamine original drug, chitosan mother liquor, validamine and chitosan mixed preparation in different proportions.
1.2 preparation of test specimens
Selecting a Chunbao cucumber variety, cutting 4-6 leaves from top to bottom, cutting the same part with consistent growth vigor and leaves with 1-2 cm petioles, wrapping the petioles with wet cotton balls, placing in a culture dish, and keeping moisture for later use.
1.3 sporangia suspension formulation
Selecting diseased leaf, washing the sporocyst of downy mildew (late blight) fungus on the back of leaf with distilled water at 4 deg.C, and making into suspension (concentration of 1 × 10/ml)5-1×107Spores) and stored at 4 ℃ for later use.
1.4 pharmaceutical agent treatment
Uniformly spraying the liquid medicine on the back of the leaves until the liquid medicine is completely wetted, naturally drying the liquid medicine for later use, and performing blank control by using treatment only containing a solvent and a surfactant but not containing active ingredients.
1.5 inoculation and culture
The prepared fresh sporangium suspension is sprayed and inoculated on the back of the leaf, and each place has no less than 5 pots, and each pot has 2 strains. Inoculation was performed 24 hours after the treatment with the agent. Covering the inoculated seeds with a dish cover, placing the inoculated seeds in an artificial climate box, and culturing the seeds under the conditions of continuously illuminating/darkness for 12 hours each day, the temperature of 17-22 ℃ and relative humidity of more than 90%.
1.6 investigation
And (3) investigation: when the blank control disease leaf rate reaches more than 50%, the disease occurrence condition of each treatment is investigated in a grading way, and at least 30 leaves are investigated in each place.
The classification standard is as follows:
level 0: no scab
Level 1: the area of the lesion spots accounts for less than 5 percent of the area of the whole leaf
And 3, level: the area of the lesion spots accounts for 5 to 15 percent of the area of the whole leaf
And 5, stage: the area of the lesion spots accounts for 15 to 25 percent of the area of the whole leaf
And 7, stage: the area of the lesion spots accounts for 25 to 50 percent of the area of the whole leaf
And 9, stage: the area of the lesion spots accounts for more than 50 percent of the area of the whole leaf
Statistical analysis of the data, the correlation formula is as follows
Disease index:
Figure BDA0002255431290000071
in the formula: x-disease index
Ni-number of leaves with disease in each grade
i-relative grade number
N-survey of Total leaf number
The prevention and treatment effect is as follows:
Figure BDA0002255431290000072
in the formula: p-controlling effect, unit is (%)
CK-blank control disease index
PT-index of disease treated by pharmaceutical agent
1.7 combined virulence determination method based on different proportions
According to the toxicity test result of single agent, valinamine and chitosan with different proportions are tested by the method of 1.6, and LC is calculated50Calculating co-toxicity coefficient (CTC) by Sun Yunpei method, and pressingThe following formula is calculated:
ATI=(S/M)*100
in the formula:
ATI-actually measured toxicity index of mixed agent;
S-LC 50 for standard bactericide in mg/l;
M-LC 50 in unit mg/l for the combination.
TTI=TIA*PA+TIB*PB
In the formula:
TTI-mixture theory virulence index;
TIA-A Agents theoretical virulence index;
the PA-A medicament accounts for the percentage of the mixture and the unit is percentage;
TIB — B agent theoretical virulence index;
the percentage content of the PB-B medicament in the mixed medicament is percentage;
CTC=(ATI/TTI)*100
in the formula:
CTC-co-toxicity coefficient;
ATI-actually measured toxicity index of mixed agent;
TTI-mixture theory virulence index.
The co-toxicity coefficient (CTC) is more than or equal to 120 and shows a synergistic effect; CTC is less than or equal to 80 and shows antagonism; 80 < CTC < 120 showed additive effect, and the results are shown in tables 1 and 2.
Table 1: results of determination of toxicity of valinamide and chitosan on downy mildew pathogen in different ratios
Figure BDA0002255431290000081
Figure BDA0002255431290000091
It can be seen from table 1 that the co-toxicity coefficient of each proportion of the combination of valienamine and chitosan is higher than 120, which shows that the combination of the two components has obvious synergistic effect, therefore, the combination of the two components has strong rationality.
Table 2: results of determining toxicity of validamine and chitosan on late blight bacteria at different ratios
Medicament EC50(mg/L) TTI ATI CTC
Valcinamine 21.65 100.0
Chitosan 10.84 199.7
Valine bacteria amine: chitosan 1:7 8.65 185.5 250.4 135
Valine bacteria amine: chitosan 1:4 9.41 179.8 230.1 128
Valine bacteria amine: chitosan 1:3 9.29 166.5 233.1 140
Valine bacteria amine: chitosan 1:1 10.62 149.9 203.8 136
Valine bacteria amine: chitosan-5: 1 13.78 119.9 157.1 131
Valine bacteria amine: chitosan ═ 6:1 14.58 114.2 148.5 130
Valine bacteria amine: chitosan 9:1 15.35 111.1 141.1 127
Valine bacteria amine: tea tableButaneglycan 10:1 14.38123 109.1 150.5 138
It can be seen from table 2 that the co-toxicity coefficient of each proportion of the combination of valienamine and chitosan is higher than 120, which shows that the combination of the two components has obvious synergistic effect, therefore, the combination of the two components has strong rationality.
Drug effect test of compounding of valienamine and chitosan
The compound preparation obtained in example 1 to example 8 and each component are used for field efficacy test. Selecting windless and rainless weather for testing, taking downy mildew and late blight as test objects in the whole investigation stage, taking the interval period of each pesticide application as 7 days, applying the pesticides for 3 times, respectively investigating the downy mildew and the late blight in the last pesticide application for 7 days and 14 days, and calculating the control effect.
The control effect is calculated according to the following formula:
four points are randomly selected for investigation in each cell, two plants are investigated in each point, and all leaves are investigated in each plant.
Classification method (in units of leaves):
level 0: no disease spots;
level 1: the lesion area accounts for less than 5% of the whole leaf area;
and 3, level: the lesion area accounts for 6% -l 0% of the whole leaf area;
and 5, stage: the lesion area accounts for 11% -25% of the whole leaf area;
and 7, stage: the lesion area accounts for 26-50% of the whole leaf area;
and 9, stage: the lesion area accounts for more than 50% of the whole leaf area.
The drug effect is calculated by the following formulae (1) and (2):
Figure BDA0002255431290000101
Figure BDA0002255431290000102
CK0a blank control zone pre-dose disease index;
CK 1-index of disease after administration to placebo;
PT0-pre-dose disease index in the agent treatment area;
PT1-disease index after administration to the agent treatment area.
The test results are as follows:
validamin-chitosan composition field test on downy mildew
Table 3: validamin-chitosan composition with effect of preventing and treating downy mildew
Figure BDA0002255431290000103
As can be seen from Table 3, after the valienamine and the chitosan are compounded, the downy mildew can be effectively prevented, the prevention effect is superior to that of a control medicament, the duration is long, the prevention effect reaches over 80.9 percent in 14 days after the last application, and in the application range of the test, the pesticide has no phytotoxicity on target crops.
Validamin-chitosan composition field test for late blight
Table 4: validamin-chitosan composition for preventing and treating late blight
Figure BDA0002255431290000111
As can be seen from Table 4, after the valienamine and the chitosan are compounded, the late blight can be effectively prevented and treated, the prevention and treatment effect is superior to that of a control medicament, the duration is long, the prevention effect reaches over 79.8 percent in 14 days after the last application, and in the application range of the test, the pesticide has no phytotoxicity on target crops.
The test results are combined, so that the control effect on the agricultural germs is obviously improved after the valinamide and the chitosan are compounded according to different proportions, and the use amount of the effective components is greatly reduced under the condition of the same control effect, thereby reducing the harm to the environment and delaying the resistance of pests.
The above are only some embodiments of the disclosure, and those skilled in the art will be able to obtain other embodiments according to the disclosure without any inventive step and still fall within the scope of the disclosure.

Claims (10)

1. The pesticide composition is characterized by comprising the following components in parts by weight:
2% -30% of valienamine;
0.5% -14% of chitosan;
the balance of auxiliary agents.
2. The pesticide composition as set forth in claim 1, wherein: the auxiliary agent comprises an auxiliary agent and a filler, wherein the auxiliary agent accounts for 10-20% of the total weight of the composite material.
3. A pesticidal composition according to claim 2, characterised in that: the auxiliary agent is one or more of solvent, cosolvent, emulsifier, dispersant, wetting agent, disintegrating agent, binder, defoamer, antifreeze agent and thickener.
4. A pesticidal composition according to claim 2 or 3, characterised in that: the filler is one or more of light calcium carbonate, diatomite, bentonite, attapulgite, white carbon black and deionized water.
5. The pesticide composition as set forth in claim 4, wherein: the pesticide is a suspending agent and comprises the following components in parts by weight:
2% -18% of valienamine and 2% of chitosan;
the auxiliary agent comprises:
3% -4% of dispersing agent;
0.4 to 2.5 percent of antifreeze agent;
0.2% -5% of thickening agent;
the filler is as follows:
the balance of deionized water.
6. A pesticidal composition according to claim 5, characterised in that: the adjuvant may also include a wetting agent or an emulsifier.
7. The pesticide composition as set forth in claim 4, wherein: the pesticide is wettable powder and comprises the following components in parts by weight:
4-30% of valienamine and 3-14% of chitosan;
the auxiliary agent is:
3% -4% of a humectant;
2% -3% of cosolvent;
4% -5% of dispersing agent;
the filler is as follows:
diatomaceous earth.
8. The pesticide composition as set forth in claim 4, wherein: the pesticide is water dispersant, and comprises the following components in parts by weight:
3% -15% of valienamine and 3% -12% of chitosan;
the auxiliary agent comprises:
4% -5% of a dispersant;
2% -2.5% of disintegrating agent;
2% -2.5% of dispersing agent;
2% -3% of a binder;
the filler is as follows:
light calcium carbonate.
9. The pesticide composition as set forth in claim 4, wherein: the pesticide is an aqueous agent and comprises the following components in parts by weight:
2 to 4.5 percent of valienamine and 0.5 to 2 percent of chitosan;
the auxiliary agent comprises:
2% -4% of cosolvent;
4% -5% of a humectant;
the filler is as follows:
deionized water.
10. A pesticidal composition according to claim 9, characterised in that: the auxiliary agent also comprises a dispersant.
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