CN110950861A - 以1,10-菲啰啉-2,9-二羧酸为配体的单核镝配合物及其制备方法和应用 - Google Patents
以1,10-菲啰啉-2,9-二羧酸为配体的单核镝配合物及其制备方法和应用 Download PDFInfo
- Publication number
- CN110950861A CN110950861A CN201911060845.9A CN201911060845A CN110950861A CN 110950861 A CN110950861 A CN 110950861A CN 201911060845 A CN201911060845 A CN 201911060845A CN 110950861 A CN110950861 A CN 110950861A
- Authority
- CN
- China
- Prior art keywords
- complex
- phenanthroline
- dicarboxylic acid
- mononuclear
- ligand
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 title claims abstract description 37
- 229910052692 Dysprosium Inorganic materials 0.000 title claims abstract description 35
- 239000003446 ligand Substances 0.000 title claims abstract description 33
- FXSVCROWUPWXBP-UHFFFAOYSA-N 1,10-phenanthroline-2,9-dicarboxylic acid Chemical compound C1=C(C(O)=O)N=C2C3=NC(C(=O)O)=CC=C3C=CC2=C1 FXSVCROWUPWXBP-UHFFFAOYSA-N 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 239000013078 crystal Substances 0.000 claims abstract description 24
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000000696 magnetic material Substances 0.000 claims abstract description 7
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 6
- 239000000126 substance Substances 0.000 claims abstract description 5
- 238000001816 cooling Methods 0.000 claims abstract description 4
- 238000010438 heat treatment Methods 0.000 claims abstract description 4
- 239000000376 reactant Substances 0.000 claims abstract description 3
- 238000006243 chemical reaction Methods 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 8
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 210000002858 crystal cell Anatomy 0.000 claims description 2
- 238000005424 photoluminescence Methods 0.000 abstract description 5
- 150000001875 compounds Chemical class 0.000 abstract 2
- 230000005291 magnetic effect Effects 0.000 description 21
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 11
- 150000002500 ions Chemical class 0.000 description 11
- 239000000463 material Substances 0.000 description 11
- 230000006399 behavior Effects 0.000 description 8
- 238000010586 diagram Methods 0.000 description 8
- 238000003860 storage Methods 0.000 description 7
- 238000002441 X-ray diffraction Methods 0.000 description 6
- 238000011160 research Methods 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 230000005284 excitation Effects 0.000 description 5
- 238000003786 synthesis reaction Methods 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 4
- 150000002503 iridium Chemical class 0.000 description 4
- 229910052747 lanthanoid Inorganic materials 0.000 description 4
- 150000002602 lanthanoids Chemical class 0.000 description 4
- 238000004020 luminiscence type Methods 0.000 description 4
- 230000007704 transition Effects 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 230000001419 dependent effect Effects 0.000 description 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 238000000862 absorption spectrum Methods 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 230000001588 bifunctional effect Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 238000002447 crystallographic data Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000000921 elemental analysis Methods 0.000 description 2
- 238000000695 excitation spectrum Methods 0.000 description 2
- 230000005283 ground state Effects 0.000 description 2
- 230000005415 magnetization Effects 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- -1 polytetrafluoroethylene Polymers 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- MFRIHAYPQRLWNB-UHFFFAOYSA-N sodium tert-butoxide Chemical compound [Na+].CC(C)(C)[O-] MFRIHAYPQRLWNB-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 125000004434 sulfur atom Chemical group 0.000 description 2
- 230000002194 synthesizing effect Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 230000004580 weight loss Effects 0.000 description 2
- 230000005343 Curie-Weiss law Effects 0.000 description 1
- 150000000914 Dysprosium Chemical class 0.000 description 1
- SJDPSXSELBBRFW-UHFFFAOYSA-K O.O.O.O.O.O.Cl(=O)(=O)(=O)[O-].[Dy+3].Cl(=O)(=O)(=O)[O-].Cl(=O)(=O)(=O)[O-] Chemical compound O.O.O.O.O.O.Cl(=O)(=O)(=O)[O-].[Dy+3].Cl(=O)(=O)(=O)[O-].Cl(=O)(=O)(=O)[O-] SJDPSXSELBBRFW-UHFFFAOYSA-K 0.000 description 1
- 230000005290 antiferromagnetic effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000001808 coupling effect Effects 0.000 description 1
- 238000013500 data storage Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000002050 diffraction method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- SIYZPSYZNCQFDV-UHFFFAOYSA-K dysprosium(3+);triacetate;tetrahydrate Chemical compound O.O.O.O.[Dy+3].CC([O-])=O.CC([O-])=O.CC([O-])=O SIYZPSYZNCQFDV-UHFFFAOYSA-K 0.000 description 1
- DCKWZDOAGNMKMX-UHFFFAOYSA-N dysprosium(3+);trinitrate;hexahydrate Chemical compound O.O.O.O.O.O.[Dy+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O DCKWZDOAGNMKMX-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005401 electroluminescence Methods 0.000 description 1
- 230000005281 excited state Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000002506 high-vacuum sublimation Methods 0.000 description 1
- 238000001027 hydrothermal synthesis Methods 0.000 description 1
- 238000003384 imaging method Methods 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 229910021644 lanthanide ion Inorganic materials 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004001 molecular interaction Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000013110 organic ligand Substances 0.000 description 1
- AICOOMRHRUFYCM-ZRRPKQBOSA-N oxazine, 1 Chemical compound C([C@@H]1[C@H](C(C[C@]2(C)[C@@H]([C@H](C)N(C)C)[C@H](O)C[C@]21C)=O)CC1=CC2)C[C@H]1[C@@]1(C)[C@H]2N=C(C(C)C)OC1 AICOOMRHRUFYCM-ZRRPKQBOSA-N 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 238000004746 piezoluminescence Methods 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 238000010183 spectrum analysis Methods 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000002411 thermogravimetry Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- HFEOHRWLEGXZHW-UHFFFAOYSA-K trichlorodysprosium;hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].[Cl-].[Cl-].[Dy+3] HFEOHRWLEGXZHW-UHFFFAOYSA-K 0.000 description 1
- ZMANZCXQSJIPKH-UHFFFAOYSA-O triethylammonium ion Chemical compound CC[NH+](CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-O 0.000 description 1
- 238000002061 vacuum sublimation Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D471/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
- C07D471/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
- C07D471/04—Ortho-condensed systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/003—Compounds containing elements of Groups 3 or 13 of the Periodic Table without C-Metal linkages
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/42—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of organic or organo-metallic materials, e.g. graphene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
- C09K2211/18—Metal complexes
- C09K2211/182—Metal complexes of the rare earth metals, i.e. Sc, Y or lanthanide
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Materials Engineering (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
Abstract
Description
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201911060845.9A CN110950861B (zh) | 2019-11-01 | 2019-11-01 | 以1,10-菲啰啉-2,9-二羧酸为配体的单核镝配合物及其制备方法和应用 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201911060845.9A CN110950861B (zh) | 2019-11-01 | 2019-11-01 | 以1,10-菲啰啉-2,9-二羧酸为配体的单核镝配合物及其制备方法和应用 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN110950861A true CN110950861A (zh) | 2020-04-03 |
CN110950861B CN110950861B (zh) | 2021-04-06 |
Family
ID=69975955
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201911060845.9A Active CN110950861B (zh) | 2019-11-01 | 2019-11-01 | 以1,10-菲啰啉-2,9-二羧酸为配体的单核镝配合物及其制备方法和应用 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN110950861B (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115850273A (zh) * | 2022-12-28 | 2023-03-28 | 西北大学 | 菲啰啉铁配合物、制备方法及其在电致变色方面的应用 |
CN115974873A (zh) * | 2023-01-20 | 2023-04-18 | 中国科学院长春应用化学研究所 | 一种稀土配合物、其制备方法及有机电致发光器件 |
Citations (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103965223A (zh) * | 2013-01-28 | 2014-08-06 | 首都师范大学 | 多铜咪唑-4,5-二羧酸邻菲啰啉聚合物及其制备方法和应用 |
CN104098612A (zh) * | 2014-07-01 | 2014-10-15 | 天津师范大学 | 3d-4f异核金属磁性配合物及其制备方法与应用 |
CN103965222B (zh) * | 2013-01-28 | 2017-02-01 | 首都师范大学 | 三核铜咪唑-4,5-二羧酸邻菲啰啉配合物及其制备方法和应用 |
CN106966972A (zh) * | 2017-05-19 | 2017-07-21 | 广西师范大学 | 一种以8‑羟基喹啉酰腙衍生物为配体构筑的镝配合物及其合成方法和应用 |
CN107129509A (zh) * | 2017-04-21 | 2017-09-05 | 广西师范大学 | 基于2‑甲基‑5,7‑二溴‑8‑羟基喹啉为配体的单核镝配合物及其制备方法和应用 |
CN108997389A (zh) * | 2018-08-09 | 2018-12-14 | 广西师范大学 | 8-羟基喹啉衍生物和1,10-林菲罗琳混合掺杂的镝配合物及其制备方法和应用 |
CN107021974B (zh) * | 2017-04-21 | 2019-02-05 | 广西师范大学 | 以2-甲基-5,7-二溴-8-羟基喹啉为配体的单核镝配合物及其制备方法和应用 |
CN107089999B (zh) * | 2017-04-21 | 2019-03-12 | 广西师范大学 | 一种单核镝配合物及其制备方法和应用 |
CN109678897A (zh) * | 2019-01-31 | 2019-04-26 | 洛阳师范学院 | 一种含有菲啰啉和修饰羧酸配体的Nd化合物发光材料及其制备方法 |
CN107089944B (zh) * | 2017-04-21 | 2019-05-14 | 广西师范大学 | 基于2-甲基-5,7-二氯-8-羟基喹啉为配体的单核镝配合物及其制备方法和应用 |
CN109796478A (zh) * | 2019-01-10 | 2019-05-24 | 广西师范大学 | 基于双席夫碱配体的单核镝配合物及其制备方法和应用 |
CN105944762B (zh) * | 2016-05-09 | 2019-06-11 | 武汉工程大学 | 菲啰啉类铜配合物催化剂及其制备方法和应用 |
EP3730505A1 (en) * | 2019-04-25 | 2020-10-28 | Uniwersytet Jagiellonski | A molecular magnetic material and a method for preparation thereof |
-
2019
- 2019-11-01 CN CN201911060845.9A patent/CN110950861B/zh active Active
Patent Citations (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103965223A (zh) * | 2013-01-28 | 2014-08-06 | 首都师范大学 | 多铜咪唑-4,5-二羧酸邻菲啰啉聚合物及其制备方法和应用 |
CN103965222B (zh) * | 2013-01-28 | 2017-02-01 | 首都师范大学 | 三核铜咪唑-4,5-二羧酸邻菲啰啉配合物及其制备方法和应用 |
CN104098612A (zh) * | 2014-07-01 | 2014-10-15 | 天津师范大学 | 3d-4f异核金属磁性配合物及其制备方法与应用 |
CN105944762B (zh) * | 2016-05-09 | 2019-06-11 | 武汉工程大学 | 菲啰啉类铜配合物催化剂及其制备方法和应用 |
CN107089944B (zh) * | 2017-04-21 | 2019-05-14 | 广西师范大学 | 基于2-甲基-5,7-二氯-8-羟基喹啉为配体的单核镝配合物及其制备方法和应用 |
CN107021974B (zh) * | 2017-04-21 | 2019-02-05 | 广西师范大学 | 以2-甲基-5,7-二溴-8-羟基喹啉为配体的单核镝配合物及其制备方法和应用 |
CN107089999B (zh) * | 2017-04-21 | 2019-03-12 | 广西师范大学 | 一种单核镝配合物及其制备方法和应用 |
CN107129509A (zh) * | 2017-04-21 | 2017-09-05 | 广西师范大学 | 基于2‑甲基‑5,7‑二溴‑8‑羟基喹啉为配体的单核镝配合物及其制备方法和应用 |
CN106966972A (zh) * | 2017-05-19 | 2017-07-21 | 广西师范大学 | 一种以8‑羟基喹啉酰腙衍生物为配体构筑的镝配合物及其合成方法和应用 |
CN108997389A (zh) * | 2018-08-09 | 2018-12-14 | 广西师范大学 | 8-羟基喹啉衍生物和1,10-林菲罗琳混合掺杂的镝配合物及其制备方法和应用 |
CN109796478A (zh) * | 2019-01-10 | 2019-05-24 | 广西师范大学 | 基于双席夫碱配体的单核镝配合物及其制备方法和应用 |
CN109678897A (zh) * | 2019-01-31 | 2019-04-26 | 洛阳师范学院 | 一种含有菲啰啉和修饰羧酸配体的Nd化合物发光材料及其制备方法 |
EP3730505A1 (en) * | 2019-04-25 | 2020-10-28 | Uniwersytet Jagiellonski | A molecular magnetic material and a method for preparation thereof |
Non-Patent Citations (5)
Title |
---|
MIN HUA等: "Four lanthanide-carboxylate coordination polymers with mixed 2,3-naphthalenedicarboxylate and phen ligands: syntheses, structures,luminescent and magnetic properties", 《POLYHEDRON》 * |
吴小说: "《首都师范大学硕士论文》", 31 December 2009 * |
杨玉: "《长春工业大学硕士论文》", 31 December 2017 * |
胡明等: "8-羟基喹啉-邻菲罗啉-稀土三元固体配合物的合成和表征 ", 《化学研究与应用》 * |
胡明等: "邻菲?咚?钏?稀土三元配合物的合成与表征 ", 《化学试剂》 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115850273A (zh) * | 2022-12-28 | 2023-03-28 | 西北大学 | 菲啰啉铁配合物、制备方法及其在电致变色方面的应用 |
CN115850273B (zh) * | 2022-12-28 | 2024-04-26 | 西北大学 | 菲啰啉铁配合物、制备方法及其在电致变色方面的应用 |
CN115974873A (zh) * | 2023-01-20 | 2023-04-18 | 中国科学院长春应用化学研究所 | 一种稀土配合物、其制备方法及有机电致发光器件 |
CN115974873B (zh) * | 2023-01-20 | 2024-06-25 | 中国科学院长春应用化学研究所 | 一种稀土配合物、其制备方法及有机电致发光器件 |
Also Published As
Publication number | Publication date |
---|---|
CN110950861B (zh) | 2021-04-06 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Wu et al. | Mesoporous crystalline silver-chalcogenolate cluster-assembled material with tailored photoluminescence properties | |
CN109400899B (zh) | 一种铅配位聚合物及其制备方法和应用 | |
CN105131942A (zh) | 光致黄色荧光锌配位聚合物[Zn(HL)(HBPEB)]及其合成方法 | |
Feng et al. | A facile route for tuning emission and magnetic properties by controlling lanthanide ions in coordination polymers incorporating mixed aromatic carboxylate ligands | |
CN110950861B (zh) | 以1,10-菲啰啉-2,9-二羧酸为配体的单核镝配合物及其制备方法和应用 | |
Eliseeva et al. | Synthesis, characterization and luminescence properties of europium (III) and terbium (III) complexes with 2-pyrazinecarboxylic acid: Crystal structure of [Eu (pyca) 3 (H2O) 2]· 6H2O | |
Feng et al. | Cationic bipy induced the three dimensional supramolecules based on azoxybenzene tetracarboxylate: Structures and NIR luminescence property | |
Huang et al. | Lanthanide coordination polymers assembled from triazine-based flexible polycarboxylate ligands and their luminescent properties | |
CN105885827A (zh) | 橙红色荧光材料锌配位聚合物[Zn(HL)(HBPEP)]及其合成方法 | |
Zheng et al. | A diamond-like cuprous coordination polymer based on the [Cu 8 I 6] 2+ cluster with multistimuli-responsive luminescence and iodine adsorption behavior | |
Yuan et al. | A series of lanthanide coordination polymers based on flexible bis‑(imidazole‑4, 5‑dicarboxylate) ligand: Syntheses, structures and fluorescent properties | |
CN108752382A (zh) | 三联苯双膦三配位卤化亚铜配合物及合成方法和应用 | |
CN103965225A (zh) | 8-氨基喹啉叠氮锌金属配合物及其制备方法和应用 | |
CN108659023B (zh) | 具有极高荧光量子产率的稀土-钾双金属配合物 | |
CN114685807B (zh) | 一种基于吡唑羧酸类配体的镉配位聚合物及其制法 | |
Liu et al. | A pair of homochiral trinuclear Zn (ii) clusters exhibiting unusual ferroelectric behaviour at high temperature | |
Du et al. | Lanthanide complexes supported via benzimidazole carboxylic acid ligand: Synthesis, luminescence and magnetic properties | |
CN110372733A (zh) | 一种具有荧光性能的金属有机铜配合物及其制备方法 | |
Jia et al. | Construction of multifunctional materials based on Tb 3+ and croconic acid, directed by K+ cations: synthesis, structures, fluorescence, magnetic and ferroelectric behaviors | |
Charytanowicz et al. | Lanthanide hexacyanidoruthenate frameworks for multicolor to white-light emission realized by the combination of dd, df, and ff electronic transitions | |
Zheng et al. | Acetonitrile-induced structure fine-tuning of a trinuclear zinc complex showing multistimuli responsive luminescence | |
CN114874145A (zh) | 一种水溶性三苯甲基类自由基材料及其制备方法和应用 | |
CN108676555B (zh) | 一种含铕离子液体红光材料及制备方法和应用 | |
CN103224536B (zh) | 一种有机杂化的稀土铅银碘四元化合物及其制备方法 | |
CN103242381B (zh) | 一种有机杂化的稀土铅银碘四元化合物和它的制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20230714 Address after: No.500-432, Hangshu Avenue, Dongsheng Street, Shuangliu District, Chengdu, 610000, Sichuan Patentee after: Chengdu Chongyuniao Environmental Protection Technology Co.,Ltd. Address before: 541004 No. 15 Yucai Road, Qixing District, Guilin, the Guangxi Zhuang Autonomous Region Patentee before: Guangxi Normal University |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20231213 Address after: 510000, No. 106, Fengze East Road, Nansha District, Guangzhou City, Guangdong Province (self-compiled building 1) X1301-E011212 (cluster registration) (JM) Patentee after: Guangzhou Specialized Enterprise Information Technology Co.,Ltd. Address before: No.500-432, Hangshu Avenue, Dongsheng Street, Shuangliu District, Chengdu, 610000, Sichuan Patentee before: Chengdu Chongyuniao Environmental Protection Technology Co.,Ltd. |
|
TR01 | Transfer of patent right |