CN110917073A

CN110917073A - Fulvic acid moisturizing and anti-dandruff shampoo and preparation method thereof

Info

Publication number: CN110917073A
Application number: CN201911316653.XA
Authority: CN
Inventors: 宋洁; 牛育华; 张康; 韩玉英; 孙永会; 王晨; 韩星星
Original assignee: Shaanxi University of Science and Technology
Current assignee: Shaanxi University of Science and Technology
Priority date: 2019-12-19
Filing date: 2019-12-19
Publication date: 2020-03-27

Abstract

本发明公开了一种黄腐酸滋润去屑洗发剂及其制备方法，属于日用化妆品技术领域。主要成份包括黄腐酸、月桂酸聚醚硫酸酯胺、椰油酰胺MEA、壳聚糖、吡罗克酮乙醇胺盐、黄酮类植物提取物、瓜尔胶羟丙基三甲基氯化铵和山嵛醇，各组分协同作用，可以有效去污去屑，缓解头皮瘙痒刺激，使用后使发质柔顺滋润、头皮环境更稳定不刺激；且原料安全、环保可靠。其制备方法操作简单，原料易得且成本低廉，来源天然安全无污染，适于批量生产和大规模推广。The invention discloses a fulvic acid moisturizing and antidandruff shampoo and a preparation method thereof, belonging to the technical field of daily cosmetics. The main ingredients include fulvic acid, lauric acid polyether sulfate amine, cocamide MEA, chitosan, piroctone ethanolamine salt, flavonoid plant extract, guar hydroxypropyltrimonium chloride and Behenyl alcohol, the synergistic effect of each component, can effectively decontaminate and remove dandruff, relieve scalp itching and irritation, make hair soft and moisturizing after use, and the scalp environment is more stable and non-irritating; and the raw materials are safe, environmentally friendly and reliable. The preparation method is simple to operate, the raw materials are readily available and the cost is low, the source is natural, safe and pollution-free, and is suitable for mass production and large-scale promotion.

Description

Fulvic acid moisturizing and anti-dandruff shampoo and preparation method thereof

Technical Field

The invention belongs to the technical field of daily cosmetics, and particularly relates to fulvic acid moisturizing and dandruff removing shampoo and a preparation method thereof.

Background

The problems of oil production and scurf of the scalp bother many people, and the shampoo products become necessary daily necessities in life, not only need to have good effects of cleaning, decontaminating and controlling oil, be suitable for the scalp characteristics of users, but also need to be safe and nontoxic to human bodies. Under the trend of returning to nature and harmlessness of water resources, the products are increasingly popular with the public in terms of naturalization, nontoxicity and functionalization. Therefore, higher requirements on the selection and performance of the main surfactant are required.

Disclosure of Invention

In order to solve the problems, the invention discloses fulvic acid moisturizing and dandruff removing shampoo and a preparation method thereof, and the components have synergistic effect, so that the shampoo can decontaminate and remove dandruff, relieve the stimulation of scalp itching, make hair smooth and moist after being used, and make scalp environment more stable and not stimulated; and the raw materials are safe, environment-friendly and reliable.

The invention is realized by the following technical scheme:

the invention discloses fulvic acid moistening and dandruff removing shampoo which comprises the following raw materials in parts by weight:

15-20 parts of fulvic acid, 5-6 parts of laureth sulfate amine, 3-6 parts of cocamide MEA, 3-5 parts of chitosan solution, 1-3 parts of piroctone olamine, 3-5 parts of flavonoid plant extract, 3-4 parts of guar gum hydroxypropyl trimethyl ammonium chloride, 2-3 parts of behenyl alcohol, 1-2 parts of cross-linking agent and 50-60 parts of deionized water.

Preferably, the flavonoid plant extract is one or more of rose, pomegranate rind and peanut shell extracts.

Preferably, the cross-linking agent is hyaluronic acid or/and dimethicone.

The invention discloses a preparation method of fulvic acid moisturizing and dandruff removing shampoo, which comprises the following steps in parts by mass:

step 1: carrying out ultrasonic dispersion on 15-20 parts of fulvic acid by using 30-40 parts of deionized water at 50-60 ℃ to obtain a fulvic acid solution;

step 2: adding 5-6 parts of lauric polyether sulfate amine, 3-6 parts of cocamide MEA and 1-3 parts of piroctone olamine into the fulvic acid solution in the step (1), and stirring and dispersing in a water bath at 60 ℃ to obtain a uniform solution for later use;

and step 3: slowly dripping 3-5 parts of chitosan solution into the uniform solution obtained in the step (2), stirring while dripping at 60 ℃, and cooling to room temperature to obtain a blended solution;

and 4, step 4: adding 3-5 parts of flavonoid plant extract and 3-5 parts of guar gum hydroxypropyl trimethyl ammonium chloride into the blending solution obtained in the step (3) after fully stirring and dissolving with 10-20 parts of deionized water at 40-50 ℃ to obtain a mixed viscous solution;

and 5: adding 1-2 parts of cross-linking agent into the viscous mixed solution obtained in the step (4), fully cross-linking at 50-60 ℃, stirring for 1-2h until the system becomes viscous fluid state, and standing to obtain fulvic acid moistening and dandruff removing shampoo.

Preferably, in step 1, the power of ultrasonic dispersion is 40KHz, and the time is 30-60 min.

Preferably, in step 2, the preparation method of the chitosan solution comprises the following steps: and (3) dissolving chitosan by using a glacial acetic acid solution with the mass concentration of 2%, wherein the mass ratio of the chitosan to the glacial acetic acid solution is 1: 30.

Preferably, the flavonoid plant extract is obtained by pulverizing or pulverizing flos Rosae Rugosae, pericarpium Granati and/or testa Arachidis Hypogaeae, ultrasonic dissolving with 75% ethanol solution at 40 deg.C for 40min, and rotary steaming at 50 deg.C for concentrating.

Preferably, in step 3, the dropping rate is 1 drop/s.

Preferably, in step 5, the standing time is 48 h.

Compared with the prior art, the invention has the following beneficial technical effects:

the fulvic acid moisturizing and dandruff removing shampoo disclosed by the invention has the advantages that the fulvic acid surfactant is natural and belongs to an amphoteric substance simultaneously containing a hydrophilic group and a hydrophobic group, and compared with a chemically synthesized surfactant, the fulvic acid surfactant is more green and environment-friendly, non-toxic and good in environmental compatibility, has better selectivity and specificity under extreme temperature, pH value and salt concentration, has more active groups, and has bidirectional effects of adjusting acidity and alkalinity and the like. The chitosan and flavonoid plant extracts belong to natural antibacterial macromolecules, the macromolecules and fulvic acid are crosslinked to generate a strong synergistic effect, the growth environment of hair roots is improved, and meanwhile, natural nutrient components can be provided, and the healthy, environment-friendly and high-activity natural macromolecules have great development potential in the field of cosmetics. The lauric polyether sulfate amine macromolecular surfactant is similar to a fabric softener, and can form a layer of fatty hair conditioner to remove static. Cocoamide MEA is a foaming agent capable of generating a plurality of foams, piroctone olamine can generate tissue dandruff, and behenyl alcohol and the plant extract not only have antibacterial components, but also have certain nutritional components and can nourish and care hair roots. Guar hydroxypropyltrimonium chloride has a film-forming type besides thickening, and can fix other surfactants and nutritional ingredients to form a thin film, thereby being beneficial to contacting hair and roots for a long time and playing a better role. The components have synergistic effect, so that the shampoo can effectively remove dirt and dandruff, relieve the stimulation of scalp itching, make hair smooth and moist after being used, and make scalp environment more stable and not irritated; and the raw materials are safe, environment-friendly and reliable.

Furthermore, the rose, the pomegranate peel and the peanut shell contain broad-spectrum flavonoid antibacterial components, and also have special fragrance and nutrient components such as saccharides, amino acids, proteins, enzymes and the like, so that the rose, the pomegranate peel and the peanut shell can effectively resist bacteria and remove dirt and provide nutrition for the scalp.

Furthermore, the cross-linking agent adopts hyaluronic acid or/and simethicone, the hyaluronic acid has functional groups such as hydroxyl, carboxyl, acetamido and the like, can generate certain hydrogen bonds or cross-linking esterification reaction with other raw materials, the simethicone is a silane coupling agent which is tasteless, odorless and nontoxic, corrosion-resistant, mildew-proof and smooth in surface, and the simethicone can be used as the cross-linking agent when being applied to the field of cosmetics, so that certain interaction exists among systems, and the cross-linking agent also has respective functionality.

The invention discloses a preparation method of the fulvic acid moistening and dandruff removing shampoo, which comprises 5 steps, wherein fulvic acid is a substance which is easy to dissolve in water, can be fully dissolved and dispersed after ultrasonic dispersion at 50-60 ℃, and then effective ingredients which are easy to dissolve in water, such as laureth sulfate amine, cocamide MEA and piroctone olamine, are added, and the functions of fulvic acid surfactant are utilized to reduce the surface tension of water, so that the emulsion dispersion effect is realized on other ingredients, hydrogen bond association or ion exchange reaction with different degrees is generated, and the functional activity of each ingredient is stimulated. The existence of a large amount of amino groups in chitosan can cause chemical reaction between chitosan and an anion system, and in order to avoid the structural damage of the chitosan, the neutral mixed stable system needs to be dripped, and then the chitosan is dispersed in the system under the action of hydrogen bonds and the like to exert the effects of antibiosis, moisture preservation and the like. In order to further endow the nutritional components and thickening and shaping the konjac glucomannan gel with the similar compatible function, flavonoid plant extract organic matter active molecules are added, but the flavonoid plant extract organic matter active molecules are difficult to disperse because the flavonoid plant extract organic matter active molecules contain sugar after concentration, and the konjac glucomannan thickening organic macromolecule is mixed, heated and stirred. And finally, adding a cross-linking agent to generate hydrogen bonds among polar groups of the components or partially and directly cross-link the polar groups to generate a bonding effect, relieving external stimulation, performing cooperative response, and exerting the effects of chitosan, flavonoid physical property, fulvic acid and the like to the maximum extent to obtain a high-quality moistening and dandruff-removing product. The method has the advantages of simple operation, easily obtained raw materials, low cost, natural, safe and pollution-free sources, and suitability for batch production and large-scale popularization.

Furthermore, the power of ultrasonic dispersion is 40KHz, and the time is 30-60 min. The fulvic acid is used as a main surfactant of the shampoo product, has an amphiphilic structure, can generate micelles with outward hydrophilic groups when being stirred and dispersed in water, can be dispersed into a solution with finer particles and more random molecular arrangement after being subjected to high-power and longer-time ultrasonic dispersion, is beneficial to mixing with an additive material in the next step, and improves the compatibility of the shampoo product.

Further, the dropping speed of the chitosan is controlled to be 1 drop/s, the chitosan is a slightly soluble cationic high molecular substance sensitive to pH and cannot be added all at once for blending and compatibility, the dropping needs to be slowly performed in order to avoid the influence of the pH of the system, and the chitosan can be well stably blended with other systems at the speed of 1 drop/s.

Detailed Description

The present invention will now be described in further detail with reference to specific examples, which are intended to be illustrative, but not limiting, of the invention. The parts referred to in the examples are in parts by mass.

Example 1

Dissolving 15 parts of fulvic acid in 30 parts of deionized water, ultrasonically dispersing and dissolving for 30min at 50 ℃ and 40KHz power, adding 5 parts of lauric polyether ammonium sulfate, 3 parts of cocamide MEA (membrane electrode assembly) and 1 part of piroctone olamine, and stirring and dispersing in a water bath at 60 ℃ to obtain a mixed solution A. Dripping 3 parts of chitosan solution into the system by using a dropper at the speed of 1 drop/s, stirring after 10min, and cooling to room temperature to obtain a solution B; fully stirring and dissolving 3 parts of rose extract and 3 parts of guar gum hydroxypropyl trimethyl ammonium chloride by 10 parts of deionized water at 45 ℃ and adding the mixture into the solution B to obtain a mixed viscous solution C; adding 1 part of hyaluronic acid into the viscous mixed solution C, fully crosslinking at 60 ℃, fully stirring for 2 hours until the hyaluronic acid becomes viscous fluid state, standing for 48 hours without precipitation, and obtaining the final product, namely the fulvic acid moisturizing and dandruff removing shampoo.

Example 2

Dissolving 16 parts of fulvic acid in 30 parts of deionized water, ultrasonically dispersing and dissolving for 40min at 50 ℃ and 40KHz power, adding 5 parts of lauric polyether sulfate amine, 4 parts of cocamide MEA (membrane electrode assembly) and 2 parts of piroctone olamine, and stirring and dispersing in a water bath at 60 ℃ to obtain a mixed solution A. Dripping 3 parts of chitosan solution into the system by using a dropper at the speed of 1 drop/s, stirring after 10min, and cooling to room temperature to obtain a solution B; fully stirring and dissolving 3 parts of rose plant extract and pomegranate peel extract and 3 parts of guar gum hydroxypropyl trimethyl ammonium chloride in a mass ratio of 1:1 at 40 ℃ by using 10 parts of deionized water, and adding the mixture into the solution B to obtain a mixed viscous solution C; adding 1 part of simethicone into the viscous mixed solution C, fully crosslinking at 60 ℃, fully stirring for 2 hours until the viscous mixed solution is changed into a viscous fluid state, standing for 48 hours without precipitation, and obtaining the final product, namely the fulvic acid moisturizing and dandruff removing shampoo.

Example 3

Dissolving 16 parts of fulvic acid in 30 parts of deionized water, ultrasonically dispersing and dissolving for 30min at 50 ℃ and 40KHz power, adding 6 parts of lauric polyether ammonium sulfate, 4 parts of cocamide MEA (membrane electrode assembly) and 2 parts of piroctone olamine, and stirring and dispersing in a water bath at 60 ℃ to obtain a mixed solution A. Dripping 4 parts of chitosan solution into the system by using a dropper at the speed of 1 drop/s, stirring after dripping for 20min, and cooling to room temperature to obtain a solution B; fully stirring and dissolving 3 parts of pomegranate peel extract and 4 parts of guar gum hydroxypropyl trimethyl ammonium chloride by using 20 parts of deionized water at 40 ℃ and adding the mixture into the solution B to obtain a mixed viscous solution C; adding 1 part of simethicone into the viscous mixed solution C, fully crosslinking at 60 ℃, fully stirring for 2 hours until the viscous mixed solution is changed into a viscous fluid state, standing for 48 hours without precipitation, and obtaining the final product, namely the fulvic acid moisturizing and dandruff removing shampoo.

Example 4

Dissolving 18 parts of fulvic acid in 35 parts of deionized water, ultrasonically dispersing and dissolving for 50min at 50 ℃ and 40KHz power, adding 6 parts of lauric polyether ammonium sulfate, 5 parts of cocamide MEA (membrane electrode assembly) and 1 part of piroctone olamine, and stirring and dispersing in a water bath at 60 ℃ to obtain a mixed solution A. Dripping 4 parts of chitosan solution into the system by using a dropper at the speed of 1 drop/s, stirring after 10min, and cooling to room temperature to obtain a solution B; 4 parts of rose extract, pomegranate peel extract and peanut shell extract in a mass ratio of 2:1:1 and 3 parts of guar gum hydroxypropyl trimethyl ammonium chloride are fully stirred and dissolved at 50 ℃ by 10 parts of deionized water, and then added into the B to obtain a mixed viscous solution C; adding 1 part of hyaluronic acid into the viscous mixed solution C, fully crosslinking at 60 ℃, fully stirring for 2 hours until the hyaluronic acid becomes viscous fluid, standing for 48 hours without precipitation, and obtaining the fulvic acid moisturizing and dandruff removing shampoo.

Example 5

Dissolving 15 parts of fulvic acid in 30 parts of deionized water, ultrasonically dispersing and dissolving for 60min at 50 ℃ and 40KHz power, adding 6 parts of lauric polyether ammonium sulfate, 5 parts of cocamide MEA (membrane electrode assembly) and 2 parts of piroctone olamine, and stirring and dispersing in a water bath at 60 ℃ to obtain a mixed solution A. Dripping 4 parts of chitosan solution into the system by using a dropper at the speed of 1 drop/s, stirring after dripping for 20min, and cooling to room temperature to obtain a solution B; fully stirring and dissolving 3 parts of pomegranate peel extract and 4 parts of guar gum hydroxypropyl trimethyl ammonium chloride by using 20 parts of deionized water at 40 ℃ and adding the mixture into the solution B to obtain a mixed viscous solution C; adding 1 part of simethicone into the viscous mixed solution C, fully crosslinking at 60 ℃, fully stirring for 2 hours until the viscous mixed solution is changed into a viscous fluid state, standing for 48 hours without precipitation to obtain the fulvic acid moistening and dandruff removing shampoo.

Example 6

Dissolving 18 parts of fulvic acid in 35 parts of deionized water, ultrasonically dispersing and dissolving for 30min at the temperature of 60 ℃ and the power of 40KHz, adding 5 parts of lauric polyether ammonium sulfate, 4 parts of cocamide MEA and 3 parts of piroctone olamine, and stirring and dispersing in a water bath at the temperature of 60 ℃ to obtain a mixed solution A. Dripping 4 parts of chitosan solution into the system by using a dropper at the speed of 1 drop/s, stirring after dripping for 20min, and cooling to room temperature to obtain a solution B; adding 4 parts of a rose extract and a peanut shell extract in a mass ratio of 1:1 and 4 parts of guar gum hydroxypropyl trimethyl ammonium chloride into the mixture B after fully stirring and dissolving the mixture at 45 ℃ by 15 parts of deionized water to obtain a mixed viscous solution C; adding 2 parts of hyaluronic acid and simethicone in a mass ratio of 1:1 into the viscous mixed solution C, fully crosslinking at 60 ℃, fully stirring for 2 hours until the viscous mixed solution is changed into a viscous fluid state, standing for 48 hours without precipitation, and obtaining the fulvic acid moisturizing and dandruff removing shampoo.

Example 7

Dissolving 18 parts of fulvic acid in 40 parts of deionized water, ultrasonically dispersing and dissolving for 60min at 55 ℃ and 40KHz power, adding 6 parts of lauric polyether ammonium sulfate, 5 parts of cocamide MEA (membrane electrode assembly) and 1 part of piroctone olamine, and stirring and dispersing in a water bath at 60 ℃ to obtain a mixed solution A. Dripping 5 parts of chitosan solution into the system by using a dropper at the speed of 1 drop/s, stirring after dripping for 20min, and cooling to room temperature to obtain a solution B; fully stirring and dissolving 5 parts of rose, pomegranate peel and peanut shell extracts and 3 parts of guar gum hydroxypropyl trimethyl ammonium chloride in a mass ratio of 2:2:1 by using 20 parts of deionized water at 45 ℃, and adding the solution into the solution B to obtain a mixed viscous solution C; adding 2 parts of hyaluronic acid and simethicone in a mass ratio of 1:1 into the viscous mixed solution C, fully crosslinking at 60 ℃, fully stirring for 2 hours until the hyaluronic acid and simethicone become viscous fluid, standing for 48 hours without precipitation, and obtaining the fulvic acid moisturizing and dandruff removing shampoo.

Example 8

Dissolving 18 parts of fulvic acid in 40 parts of deionized water, ultrasonically dispersing and dissolving for 40min at 55 ℃ and 40KHz power, adding 6 parts of lauric polyether sulfate amine, 4 parts of cocamide MEA and 3 parts of piroctone olamine, and stirring and dispersing in a water bath at 60 ℃ to obtain a mixed solution A. Dripping 3 parts of chitosan solution into the system by using a dropper at the speed of 1 drop/s, stirring after dripping for 15min, and cooling to room temperature to obtain a solution B; fully stirring and dissolving 3 parts of rose and peanut shell extracts and 3 parts of guar gum hydroxypropyl trimethyl ammonium chloride in a mass ratio of 2:1 at 45 ℃ by using 20 parts of deionized water, and adding the mixture into the solution B to obtain a mixed viscous solution C; adding 1 part by mass of hyaluronic acid and dimethicone into the viscous mixed solution C, fully crosslinking at 60 deg.C, stirring for 2 hr until it becomes viscous fluid state, standing for 48 hr without precipitate to obtain fulvic acid moistening and dandruff removing shampoo.

Effect verification:

the viscosity, the smoothness degree, the drape feeling, the anti-dandruff effect and the like of the fulvic acid moisturizing and anti-dandruff shampoo prepared in the above examples 1-8 are researched and evaluated for 20 groups of people in one month, each person uses the product of different examples each time, the viscosity data and the score are recorded, and 200 groups of data (full score is 100) are obtained. The using method of the product is as follows:

taking 3-5g of the product, rubbing out foam with hands, uniformly smearing on hair and hair roots, gently kneading for 2min, keeping hair with towel for 3-5min for better effect, washing with water, drying, and observing hair.

The kinematic viscosity of the 8 example products was determined by the capillary method. At ambient temperature, the time for a volume of liquid to flow under gravity through a calibrated glass capillary viscometer was measured. The product of this time and the calibration constant of the capillary viscometer is the kinematic viscosity of the test liquid at that temperature. Ensuring that the flow time of the product in the capillary viscometer is between 200 and 500 s. The kinematic viscosity of the cleaning agent was measured according to the national standards. The temperature control instrument selects a constant temperature and humidity test chamber.

Product evaluation and investigation result statistical table:

according to the using effect experiment and research of the product, the fulvic acid active anti-dandruff moisturizing shampoo obtained in the example 8 is comprehensively obtained, the color is brown, the average score of smoothness and drape of hair is more than 90 points, and the effect is relatively good, and the anti-dandruff percentage research result of the example 6 is relatively good, but the difference is not great from the example 8, and the product under the condition of the example 8 has a good result in the current data.

Claims

1. The fulvic acid moisturizing and dandruff removing shampoo is characterized by comprising the following raw materials in parts by mass:

2. The fulvic acid moisturizing and dandruff removing shampoo of claim 1, wherein the flavonoid plant extract is one or more of rose, pomegranate rind and peanut shell extracts.

3. The fulvic acid moisturizing and antidandruff shampoo according to claim 1 wherein the cross-linking agent is hyaluronic acid or/and dimethicone.

4. The preparation method of the fulvic acid moisturizing and dandruff removing shampoo is characterized by comprising the following steps of:

5. The fulvic acid moisturizing and dandruff removing shampoo according to claim 4, wherein in step 1, the ultrasonic dispersion power is 40KHz and the time is 30-60 min.

6. The fulvic acid moisturizing and dandruff removing shampoo of claim 4, wherein in step 2, the chitosan solution is prepared by: and (3) dissolving chitosan by using a glacial acetic acid solution with the mass concentration of 2%, wherein the mass ratio of the chitosan to the glacial acetic acid solution is 1: 30.

7. The method for preparing the fulvic acid moisturizing and dandruff removing shampoo as claimed in claim 4, wherein the flavonoid plant extract is obtained by crushing or pulverizing rose, pomegranate rind and/or peanut shell, ultrasonic dissolving the crushed rose, pomegranate rind and/or peanut shell in 75% ethanol solution at 40 ℃ for 40min, and rotary steaming and concentrating the crushed rose, pomegranate rind and/or peanut shell at 50 ℃.

8. The method of making the fulvic acid moisturizing and dandruff removing shampoo of claim 4, wherein in step 3, the dropping rate is 1 drop/s.

9. The method of preparing the fulvic acid moisturizing and dandruff removing shampoo of claim 4, wherein in step 5, the standing time is 48 hours.