CN110897907A - Water-in-oil lip glaze without PEG emulsifier and preparation method thereof - Google Patents

Water-in-oil lip glaze without PEG emulsifier and preparation method thereof Download PDF

Info

Publication number
CN110897907A
CN110897907A CN201911265260.0A CN201911265260A CN110897907A CN 110897907 A CN110897907 A CN 110897907A CN 201911265260 A CN201911265260 A CN 201911265260A CN 110897907 A CN110897907 A CN 110897907A
Authority
CN
China
Prior art keywords
polyglycerol
phase
oil
emulsifier
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201911265260.0A
Other languages
Chinese (zh)
Inventor
何志泉
谭灵飞
郭舒婷
李秋曦
杨小龙
周俊彬
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hua An Tang Biotech Group Co Ltd
Original Assignee
Hua An Tang Biotech Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hua An Tang Biotech Group Co Ltd filed Critical Hua An Tang Biotech Group Co Ltd
Priority to CN201911265260.0A priority Critical patent/CN110897907A/en
Publication of CN110897907A publication Critical patent/CN110897907A/en
Pending legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37Esters of carboxylic acids
    • A61K8/375Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31Hydrocarbons
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • A61K8/342Alcohols having more than seven atoms in an unbroken chain
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8105Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • A61K8/8111Homopolymers or copolymers of aliphatic olefines, e.g. polyethylene, polyisobutene; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/85Polyesters
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86Polyethers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • A61Q1/04Preparations containing skin colorants, e.g. pigments for lips
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/30Characterized by the absence of a particular group of ingredients
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59Mixtures
    • A61K2800/592Mixtures of compounds complementing their respective functions
    • A61K2800/5922At least two compounds being classified in the same subclass of A61K8/18

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)

Abstract

The invention discloses a water-in-oil lip glaze without PEG emulsifier, which comprises the following components in parts by weight: 45-65 parts of an oil phase; 1-15 parts of polyglycerol emulsifier; 1-15 parts of an oil phase thickener; 5-20 parts of a water phase; 0.1-5 parts of cosmetic pigments. According to the invention, the polyglycerol emulsifier with specific content and specific compound ratio is compounded with the oil phase, the oil phase thickener, the water phase and the cosmetic pigments with specific content, and the water-in-oil lip glaze without the PEG emulsifier is prepared by the synergistic cooperation of the components, so that the requirements of modern consumers on temperature and non-irritation during use are met, and the problems of ethylene oxide residue, irritation and the like caused by the PEG emulsifier can be avoided; meanwhile, the moisture is directly supplemented to the lips, so that the surface layers of the lips can be instantly softened, the moisturizing effect is better, the stability is good, and the special makeup effect is durable; and the preparation process is simple, easy to realize and capable of realizing large-scale mass production.

Description

Water-in-oil lip glaze without PEG emulsifier and preparation method thereof
Technical Field
The invention relates to a lip glaze (lip cream, lip mask, lip gloss and the like), in particular to an emulsified lip glaze without a PEG emulsifier and a preparation method thereof.
Background
Lip cosmetics are an important class of makeup cosmetics. The commercially available lip gloss product is generally an ointment formula system, and a sealing film is formed on the lip by using grease to prevent water from evaporating, so that the lip gloss product has a moisturizing effect. But have limited moisturizing capabilities for lips that are otherwise deficient in water. As such, developers tend to make lip gloss of emulsified systems.
The emulsification types are generally oil-in-water and water-in-oil. The human lip skin is relatively thin compared with other parts, and in order to obtain a continuous closed grease film to protect moisture from being easily evaporated, the dosage of the lip gloss grease is generally 70% or more. Oil-in-water formulations do not easily achieve this goal and water-in-oil formulations are preferred. Meanwhile, the PEG emulsifier is always popular with cosmetic formulators due to low manufacturing difficulty and strong emulsifying capacity. However, as consumer demand for safe and natural ingredients increases, the challenge for PEG-based emulsifiers is increasing.
Disclosure of Invention
In view of the defects of the prior art, the primary object of the invention is to provide a water-in-oil lip glaze which is green, safe, good in stability and moisturizing effect and has a lasting specific makeup effect.
Another object of the present invention is to provide a method for preparing the above water-in-oil lip glaze without PEG emulsifier.
The water-in-oil lip glaze without the PEG emulsifier comprises the following components in parts by weight:
45-65 parts of an oil phase;
1-15 parts of polyglycerol emulsifier;
1-15 parts of an oil phase thickener;
5-20 parts of a water phase;
0.1-5 parts of cosmetic pigments.
Wherein the oil phase is selected from one or more of octyldodecanol, dipentaerythritol tri-polyhydroxystearate, glyceryl caprylate, diisostearyl malate, phytosterol/behenyl/octyldecanol lauroyl glutamate, jojoba (SIMMONDSIA CHINENSIS) seed oil, VP/hexadecene copolymer, hydrogenated polyisobutene, neopentyl glycol diheptanoate, squalane, pentaerythritol tetra (ethyl hexanoate), trimethylsiloxyphenyl polydimethylsiloxane, and trimethylpentanediol/adipic acid/glycerol cross-linked polymer.
The oil phase content of the emulsified lip glaze of the present invention is preferably 45% or more, and particularly preferably 55% or more, based on 100% by weight of the emulsified lip glaze, relative to the ordinary lip glaze. If the content of the oil phase is too small, spreadability and stability are poor. The content of the oil phase is preferably 65% or less, and if the content of the oil phase is too large, stability and moisture retention are deteriorated.
Wherein the polyglycerol emulsifier is selected from two or more compounds of polyglycerol-3 diisostearate, (polyglycerol-3 polyricinoleate and polyglycerol-3 ricinoleate), (polyglycerol-6 polyhydroxystearate and polyglycerol-6 polyricinoleate); and said polyglyceryl-3 diisostearate: (polyglycerol-3 polyricinoleate and polyglycerol-3 ricinoleate): the compounding weight ratio of the polyglycerol-6 polyhydroxy stearate to the polyglycerol-6 polyricinoleate is (0.4-1.2): (0-2.8): (0-2.0).
Wherein the weight ratio of polyglycerol-3 polyricinoleate to polyglycerol-3 ricinoleate in the (polyglycerol-3 polyricinoleate and polyglycerol-3 ricinoleate) is 9: 1-9: 5; the weight ratio of the polyglycerol-6 polyhydroxyalkanoate to the polyglycerol-6 polyricinoleate in the (polyglycerol-6 polyhydroxystearate and polyglycerol-6 polyricinoleate) is 1: 1-3: 1.
wherein the oil phase thickener is one or more than one compound selected from glyceryl behenate/eicosanoate, (hydrogenated polydecene, hydrogenated (styrene/isoprene) copolymer and tocopherol), (caprylic/capric triglyceride, selea-lammonium hectorite, polyglyceryl-3 diisostearate and polyglyceryl-3 polyricinoleate).
Wherein the water phase is selected from one or more of 1, 2-hexanediol, 1, 2-pentanediol, dipropylene glycol, diglycerol, propylene glycol, butanediol, glycerol, deionized water, trehalose, and isoprene glycol.
Wherein the cosmetic pigments include, but are not limited to, one or more of alumina, silica, calcium sodium borosilicate, mica, synthetic fluorophlogopite, CI77891, CI77019, CI77491, CI77492, CI77499, CI15850, CI77120, CI19140, CI75470, CI17200, CI73360, CI77163, CI42090, CI45410, CI45380 and CI 16035.
The invention also discloses a preparation method of the water-in-oil lip glaze without the PEG emulsifier, which comprises the following steps:
(1) adding the oil phase and the polyglycerol emulsifier into an emulsifying pot, heating to 80-85 ℃, and then homogenizing at high speed until the oil phase and the polyglycerol emulsifier are completely and uniformly dissolved to obtain a phase A;
(2) grinding the cosmetic pigments and a part of the phase A for three times by a three-roll grinder and adding the ground cosmetic pigments and the part of the phase A back to the phase A; keeping the temperature at 80-85 ℃;
(3) uniformly mixing the oil phase thickening agents to obtain a phase B, adding the phase B into the rest phase A, and uniformly mixing at the speed of 2500-;
(4) adding the water phase into a water phase pot, heating to 30-40 ℃, and uniformly stirring to obtain a C phase;
(5) gradually adding the phase C into the phase A, B, stirring at the speed of 500-1000 rpm for 20-30min, mixing uniformly, stopping stirring, continuing stirring uniformly, and cooling to room temperature to obtain the water-in-oil lip glaze without the PEG emulsifier.
Compared with the prior art, the invention has the following beneficial effects:
1) according to the invention, the polyglycerol emulsifier with specific content and specific compound ratio is compounded with the oil phase, the oil phase thickener, the water phase and the cosmetic pigments with specific content, and the water-in-oil lip glaze without the PEG emulsifier is prepared by the synergistic cooperation of the components, so that the requirements of modern consumers on temperature and non-irritation during use are met, and the problems of ethylene oxide residue, irritation and the like caused by the PEG emulsifier can be avoided; meanwhile, the water is directly supplemented to the lips, the surface layers of the lips can be instantly softened, the moisturizing effect is better, the stability is good, and the special makeup effect is durable.
2) The preparation process is simple, easy to realize and capable of realizing large-scale mass production.
Detailed Description
The present invention is further illustrated by the following specific examples, which are, however, not intended to limit the scope of the invention.
The examples of the present invention and the comparative examples employ the following raw materials, but are not limited to these raw materials:
polyglycerol-based emulsifiers: polyglyceryl-3 diisostearate: purchasing in market;
polyglycerol-3 polyricinoleate and polyglycerol-3 ricinoleate, wherein the weight ratio of polyglycerol-3 polyricinoleate to polyglycerol-3 ricinoleate is 9: 3, purchased in the market;
polyglycerol-6 polyhydroxy stearate and polyglycerol-6 polyricinoleate in a weight ratio of 2: 1, purchased in the market;
oil phase: octyldodecanol, dipentaerythritol tri-polyhydroxystearate, glyceryl caprylate, diisostearyl malate, hydrogenated polyisobutene, neopentyl glycol diheptanoate, squalane: is purchased in the market;
oil phase thickener: glyceryl behenate/eicosanoate, (caprylic/capric triglyceride and salammonium hectorite and polyglyceryl-3 diisostearate and polyglyceryl-3 polyricinoleate): is purchased in the market;
water phase: isoprene glycol: purchasing in market;
cosmetic pigments: CI15850, CI 77891: is obtained by purchasing in the market.
Other raw materials or reagents used in the examples of the present invention and comparative examples were commercially available.
The efficacy evaluation methods were:
stability: filling 5 plastic flat-bottom wide-mouth small boxes in a sample room temperature, and cooling for 24 hours at room temperature; placing in constant temperature biological incubator at-15 deg.C, 4 deg.C, 25 deg.C, 40 deg.C, and 50 deg.C, respectively, and testing for 4 weeks; the observation period was 1 day, 1 week, 2 weeks, 3 weeks and 4 weeks.
And (3) moisture retention efficacy evaluation: selecting 35 female with dry lips and age of 20-55 years, and using the sample in morning and evening for 4 weeks; and testing and comparing the water content of the horny layer before and after use by using a horny layer water content tester, and calculating whether the horny layer water content is significant or not by using a formula.
And (3) durability evaluation: brushing 0.05g of lip glaze and uniformly coating the lip glaze on the lip. Taking pictures for comparison at 0 hour, 1 hour and 4 hours after smearing; the evaluation scale was good, general, and poor.
Evaluation of irritation (mildness): the blocking patch method in the human body patch test in the cosmetic hygiene Specification (2007 edition) was followed. Directly judging the adverse reaction with the evaluation grade of more than 2 grades to be unqualified; in this case, the smaller the number of patients with grade 1 adverse reactions, the better.
Examples 1 to 8 and comparative examples 1 to 5: preparation of water-in-oil lip glaze without PEG emulsifier
Adding the oil phase and the polyglycerol emulsifier into an emulsifying pot according to the proportion in the table 1, heating to 80-85 ℃, and then homogenizing at high speed until the oil phase and the polyglycerol emulsifier are completely and uniformly dissolved to obtain a phase A; grinding the cosmetic pigments and a part of the phase A for three times by a three-roll grinder and adding the ground cosmetic pigments and the part of the phase A back to the phase A; keeping the temperature at 80-85 ℃; uniformly mixing the oil phase thickening agents to obtain a phase B, adding the phase B into the rest phase A, and uniformly mixing at the speed of 2500-; adding the water phase into a water phase pot, heating to 30-40 ℃, and uniformly stirring to obtain a C phase; gradually adding the phase C into the phase A, B, stirring at the speed of 500-1000 rpm for 20-30min, mixing uniformly, stopping stirring, continuing stirring uniformly, and cooling to room temperature to obtain the water-in-oil lip glaze without the PEG emulsifier; the test results of stability, moisturizing efficacy, durability, irritation (mildness) of the prepared water-in-oil lip glaze without a PEG emulsifier are shown in table 1.
TABLE 1 test results of the component ratios (parts by weight) and performance indexes of examples 1 to 8 and comparative examples 1 to 5
Figure 656307DEST_PATH_IMAGE002
TABLE 1
Figure 245552DEST_PATH_IMAGE004

Claims (8)

1. The water-in-oil lip glaze without the PEG emulsifier is characterized by comprising the following components in parts by weight:
45-65 parts of an oil phase;
1-15 parts of polyglycerol emulsifier;
1-15 parts of an oil phase thickener;
5-20 parts of a water phase;
0.1-5 parts of cosmetic pigments.
2. The PEG emulsifier free water-in-oil lip glaze according to claim 1, wherein the oil phase is selected from one or a mixture of octyldodecanol, dipentaerythritol tri-hydroxystearate, glyceryl caprylate, diisostearyl malate, phytosterol/behenyl/octyldecanol lauroyl glutamate, jojoba (SIMMONDSIA CHINENSIS) seed oil, VP/hexadecene copolymer, hydrogenated polyisobutene, neopentyl glycol diheptanoate, squalane, pentaerythritol tetra (ethyl hexanoate), trimethylsiloxyphenyl polydimethylsiloxane, trimethylpentanediol/adipic acid/glycerol cross-linked polymer.
3. The PEG emulsifier-free water-in-oil lip glaze according to claim 1, wherein the polyglycerol emulsifier is selected from the group consisting of two or more compounds consisting of polyglycerol-3 diisostearate, (polyglycerol-3 polyricinoleate and polyglycerol-3 ricinoleate), (polyglycerol-6 polyhydroxystearate and polyglycerol-6 polyricinoleate); and said polyglyceryl-3 diisostearate: (polyglycerol-3 polyricinoleate and polyglycerol-3 ricinoleate): the compounding weight ratio of the polyglycerol-6 polyhydroxy stearate to the polyglycerol-6 polyricinoleate is (0.4-1.2): (0-2.8): (0-2.0).
4. The PEG emulsifier free water-in-oil lip glaze according to claim 3, wherein the weight ratio of polyglycerol-3 polyricinoleate to polyglycerol-3 ricinoleate in the (polyglycerol-3 polyricinoleate and polyglycerol-3 ricinoleate) is 9: 1-9: 5; the weight ratio of the polyglycerol-6 polyhydroxyalkanoate to the polyglycerol-6 polyricinoleate in the (polyglycerol-6 polyhydroxystearate and polyglycerol-6 polyricinoleate) is 1: 1-3: 1.
5. the PEG emulsifier free water-in-oil lip glaze according to claim 1, wherein the oil phase thickener is selected from one or more of the group consisting of glyceryl behenate/eicosanoate, (hydrogenated polydecene and hydrogenated (styrene/isoprene) copolymer and tocopherol), (caprylic/capric triglyceride and selea chloride hectorite and polyglyceryl-3 diisostearate and polyglyceryl-3 polyricinoleate).
6. The PEG emulsifier free water-in-oil lip glaze according to claim 1, wherein the aqueous phase is selected from one or more of 1, 2-hexanediol, 1, 2-pentanediol, dipropylene glycol, diglycerol, propylene glycol, butylene glycol, glycerin, deionized water, trehalose, and isoprene glycol.
7. The PEG emulsifier free water-in-oil lip glaze according to claim 1, wherein the cosmetic pigments include, but are not limited to, one or more of alumina, silica, calcium sodium borosilicate, mica, synthetic fluorophlogopite, CI77891, CI77019, CI77491, CI77492, CI77499, CI15850, CI77120, CI19140, CI75470, CI17200, CI73360, CI77163, CI42090, CI45410, CI45380, and CI 16035.
8. A process for the preparation of a water-in-oil lip glaze without PEG emulsifier according to any of claims 1 to 7, characterized in that it comprises the following steps:
(1) adding the oil phase and the polyglycerol emulsifier into an emulsifying pot, heating to 80-85 ℃, and then homogenizing at high speed until the oil phase and the polyglycerol emulsifier are completely and uniformly dissolved to obtain a phase A;
(2) grinding the cosmetic pigments and a part of the phase A for three times by a three-roll grinder and adding the ground cosmetic pigments and the part of the phase A back to the phase A; keeping the temperature at 80-85 ℃;
(3) uniformly mixing the oil phase thickening agents to obtain a phase B, adding the phase B into the rest phase A, and uniformly mixing at the speed of 2500-;
(4) adding the water phase into a water phase pot, heating to 30-40 ℃, and uniformly stirring to obtain a C phase;
(5) gradually adding the phase C into the phase A, B, stirring at the speed of 500-1000 rpm for 20-30min, mixing uniformly, stopping stirring, continuing stirring uniformly, and cooling to room temperature to obtain the water-in-oil lip glaze without the PEG emulsifier.
CN201911265260.0A 2019-12-11 2019-12-11 Water-in-oil lip glaze without PEG emulsifier and preparation method thereof Pending CN110897907A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201911265260.0A CN110897907A (en) 2019-12-11 2019-12-11 Water-in-oil lip glaze without PEG emulsifier and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201911265260.0A CN110897907A (en) 2019-12-11 2019-12-11 Water-in-oil lip glaze without PEG emulsifier and preparation method thereof

Publications (1)

Publication Number Publication Date
CN110897907A true CN110897907A (en) 2020-03-24

Family

ID=69824389

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201911265260.0A Pending CN110897907A (en) 2019-12-11 2019-12-11 Water-in-oil lip glaze without PEG emulsifier and preparation method thereof

Country Status (1)

Country Link
CN (1) CN110897907A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112641679A (en) * 2020-12-29 2021-04-13 广州环亚化妆品科技有限公司 Microcapsule and preparation method and application thereof
CN113476344A (en) * 2021-07-05 2021-10-08 广州市百好博有限公司 Cosmetic composition, cosmetic, oil-in-water lip glaze and preparation method thereof
CN113967172A (en) * 2021-11-16 2022-01-25 马应龙大健康有限公司 Water-in-oil cream containing emulsifier from natural source and preparation method thereof
CN114392206A (en) * 2022-01-20 2022-04-26 广州市百好博有限公司 Emulsified composition and easily emulsified and easily layered emulsifying system
CN114869807A (en) * 2022-06-08 2022-08-09 上海臻臣化妆品有限公司 All-natural water-containing lip glaze and preparation method thereof
WO2023100140A1 (en) * 2021-12-02 2023-06-08 Shiseido Company, Ltd. Cosmetic w/o emulsion composition
CN116407457A (en) * 2023-04-07 2023-07-11 广州弗曼生物科技有限公司 Emulsifier composition containing polyglycerol ester and sucrose ester and application thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104606093A (en) * 2014-12-31 2015-05-13 上海创馨化妆品有限公司 Emulsified lipstick
CN107496201A (en) * 2017-09-09 2017-12-22 上海禾雅化妆品有限公司 One kind emulsification lipstick and preparation method thereof
CN108578274A (en) * 2018-08-02 2018-09-28 高宝化妆品(中国)有限公司 A kind of aqueous lipstick and preparation method thereof
CN109908021A (en) * 2019-04-30 2019-06-21 广东三好科技有限公司 One kind aqueous lip balm product having repairing effect and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104606093A (en) * 2014-12-31 2015-05-13 上海创馨化妆品有限公司 Emulsified lipstick
CN107496201A (en) * 2017-09-09 2017-12-22 上海禾雅化妆品有限公司 One kind emulsification lipstick and preparation method thereof
CN108578274A (en) * 2018-08-02 2018-09-28 高宝化妆品(中国)有限公司 A kind of aqueous lipstick and preparation method thereof
CN109908021A (en) * 2019-04-30 2019-06-21 广东三好科技有限公司 One kind aqueous lip balm product having repairing effect and preparation method thereof

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112641679A (en) * 2020-12-29 2021-04-13 广州环亚化妆品科技有限公司 Microcapsule and preparation method and application thereof
CN113476344A (en) * 2021-07-05 2021-10-08 广州市百好博有限公司 Cosmetic composition, cosmetic, oil-in-water lip glaze and preparation method thereof
CN113476344B (en) * 2021-07-05 2023-04-28 广州市百好博有限公司 Cosmetic composition, cosmetic, oil-in-water lip glaze and preparation method thereof
CN113967172A (en) * 2021-11-16 2022-01-25 马应龙大健康有限公司 Water-in-oil cream containing emulsifier from natural source and preparation method thereof
CN113967172B (en) * 2021-11-16 2023-05-16 马应龙大健康有限公司 Water-in-oil cream containing natural source emulsifier and preparation method thereof
WO2023100140A1 (en) * 2021-12-02 2023-06-08 Shiseido Company, Ltd. Cosmetic w/o emulsion composition
CN114392206A (en) * 2022-01-20 2022-04-26 广州市百好博有限公司 Emulsified composition and easily emulsified and easily layered emulsifying system
CN114392206B (en) * 2022-01-20 2023-05-26 广州市百好博有限公司 Emulsifying composition and emulsifying system easy to emulsify and delaminate
CN114869807A (en) * 2022-06-08 2022-08-09 上海臻臣化妆品有限公司 All-natural water-containing lip glaze and preparation method thereof
CN116407457A (en) * 2023-04-07 2023-07-11 广州弗曼生物科技有限公司 Emulsifier composition containing polyglycerol ester and sucrose ester and application thereof

Similar Documents

Publication Publication Date Title
CN110897907A (en) Water-in-oil lip glaze without PEG emulsifier and preparation method thereof
JP5743887B2 (en) Ester compounds for use in personal care products
JP5628019B2 (en) Mascara containing aqueous polyurethane dispersion and hard wax
KR102223040B1 (en) O/w type sunblock cosmetic
ES2716306T3 (en) Cosmetic composition for coating keratin fibers
AU2011332251B2 (en) Moisturizing compositions for lip
CN107428790B (en) Dextrin fatty acid ester and cosmetic
WO2009145344A1 (en) Oil‑in‑water type topical agent for skin
JPH1053510A (en) Composition for external use
TW200812634A (en) Dermatological anti-wrinkle agent
US20130330287A1 (en) Cosmetic composition comprising a cucurbic acid compound and a hydrophobic inulin
KR101781566B1 (en) Nanoemulsion cosmetic composition produced by using polyglyceryl ester alone as an emulsifier and the method for preparing thereof
EP2931242B1 (en) Oil-in-water emulsion composition
WO2012127852A1 (en) Solid cosmetic
CN109248113B (en) Emulsified lip gloss and preparation method thereof
JP2008201753A (en) Skin preparation for external use
JP5851725B2 (en) Water-based or oil-in-water emulsified makeup cosmetics
JP2008247859A (en) Cosmetic composition
RU2428167C2 (en) Preparation for external application on skin, which possesses higher stability
CN112912061A (en) Long-lasting moisturizing cosmetic compositions
KR102431188B1 (en) External skin preparation for wrinkle improvement
JPH11263721A (en) Oil-in-water type gommage (peeling) cosmetic
TWI725002B (en) Oil-in-water type ultraviolet protective cosmetic composition
JPWO2017179356A1 (en) Overfat and personal care compositions
JP5662750B2 (en) Water-in-oil emulsion composition

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20200324

RJ01 Rejection of invention patent application after publication