CN116407457A - Emulsifier composition containing polyglycerol ester and sucrose ester and application thereof - Google Patents
Emulsifier composition containing polyglycerol ester and sucrose ester and application thereof Download PDFInfo
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- CN116407457A CN116407457A CN202310366764.1A CN202310366764A CN116407457A CN 116407457 A CN116407457 A CN 116407457A CN 202310366764 A CN202310366764 A CN 202310366764A CN 116407457 A CN116407457 A CN 116407457A
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- Prior art keywords
- decapolyglycerol
- sucrose
- polyglycerol
- hexapolyglycerol
- ester
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- 239000000203 mixture Substances 0.000 title claims abstract description 39
- 229920000223 polyglycerol Polymers 0.000 title claims abstract description 35
- 239000003995 emulsifying agent Substances 0.000 title claims abstract description 34
- 150000002148 esters Chemical class 0.000 title claims abstract description 30
- 229930006000 Sucrose Natural products 0.000 title claims abstract description 17
- 239000005720 sucrose Substances 0.000 title claims abstract description 17
- -1 sucrose ester Chemical class 0.000 title claims abstract description 12
- 239000002537 cosmetic Substances 0.000 claims abstract description 18
- 238000002360 preparation method Methods 0.000 claims abstract description 13
- 150000003445 sucroses Chemical class 0.000 claims abstract description 8
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 14
- 229930195729 fatty acid Natural products 0.000 claims description 14
- 239000000194 fatty acid Substances 0.000 claims description 14
- 150000004665 fatty acids Chemical class 0.000 claims description 14
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 claims description 12
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 11
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 11
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 claims description 8
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims description 8
- 238000006116 polymerization reaction Methods 0.000 claims description 8
- 229940049964 oleate Drugs 0.000 claims description 7
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 5
- SZYSLWCAWVWFLT-UTGHZIEOSA-N [(2s,3s,4s,5r)-3,4-dihydroxy-5-(hydroxymethyl)-2-[(2r,3r,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxolan-2-yl]methyl octadecanoate Chemical compound O([C@@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)[C@]1(COC(=O)CCCCCCCCCCCCCCCCC)O[C@H](CO)[C@@H](O)[C@@H]1O SZYSLWCAWVWFLT-UTGHZIEOSA-N 0.000 claims description 5
- 229940116224 behenate Drugs 0.000 claims description 5
- UKMSUNONTOPOIO-UHFFFAOYSA-M behenate Chemical compound CCCCCCCCCCCCCCCCCCCCCC([O-])=O UKMSUNONTOPOIO-UHFFFAOYSA-M 0.000 claims description 5
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 4
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 4
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 4
- 235000021357 Behenic acid Nutrition 0.000 claims description 4
- 239000005642 Oleic acid Substances 0.000 claims description 4
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 4
- 235000021314 Palmitic acid Nutrition 0.000 claims description 4
- 235000021355 Stearic acid Nutrition 0.000 claims description 4
- 125000003342 alkenyl group Chemical group 0.000 claims description 4
- 229940116226 behenic acid Drugs 0.000 claims description 4
- 238000009472 formulation Methods 0.000 claims description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 claims description 4
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 4
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 claims description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 4
- 239000008117 stearic acid Substances 0.000 claims description 4
- FOLJTMYCYXSPFQ-CJKAUBRRSA-N [(2r,3s,4s,5r,6r)-6-[(2s,3s,4s,5r)-3,4-dihydroxy-5-(hydroxymethyl)-2-(octadecanoyloxymethyl)oxolan-2-yl]oxy-3,4,5-trihydroxyoxan-2-yl]methyl octadecanoate Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](COC(=O)CCCCCCCCCCCCCCCCC)O[C@@H]1O[C@@]1(COC(=O)CCCCCCCCCCCCCCCCC)[C@@H](O)[C@H](O)[C@@H](CO)O1 FOLJTMYCYXSPFQ-CJKAUBRRSA-N 0.000 claims description 2
- GCSPRLPXTPMSTL-IBDNADADSA-N [(2s,3r,4s,5s,6r)-2-[(2s,3s,4s,5r)-3,4-dihydroxy-2,5-bis(hydroxymethyl)oxolan-2-yl]-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[C@@]1([C@]2(CO)[C@H]([C@H](O)[C@@H](CO)O2)O)O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O GCSPRLPXTPMSTL-IBDNADADSA-N 0.000 claims description 2
- ZPVGIKNDGJGLCO-VGAMQAOUSA-N [(2s,3r,4s,5s,6r)-2-[(2s,3s,4s,5r)-3,4-dihydroxy-2,5-bis(hydroxymethyl)oxolan-2-yl]-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl] hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)O[C@@]1([C@]2(CO)[C@H]([C@H](O)[C@@H](CO)O2)O)O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O ZPVGIKNDGJGLCO-VGAMQAOUSA-N 0.000 claims description 2
- UEYVMVXJVDAGBB-ZHBLIPIOSA-N [(2s,3s,4s,5r)-3,4-dihydroxy-5-(hydroxymethyl)-2-[(2r,3r,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxolan-2-yl]methyl tetradecanoate Chemical compound O([C@@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)[C@]1(COC(=O)CCCCCCCCCCCCC)O[C@H](CO)[C@@H](O)[C@@H]1O UEYVMVXJVDAGBB-ZHBLIPIOSA-N 0.000 claims description 2
- 229940071160 cocoate Drugs 0.000 claims description 2
- 239000000839 emulsion Substances 0.000 abstract description 11
- 239000002994 raw material Substances 0.000 abstract description 5
- 239000006071 cream Substances 0.000 abstract description 4
- 239000002245 particle Substances 0.000 abstract description 2
- 238000003756 stirring Methods 0.000 description 13
- 239000000463 material Substances 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 6
- 230000001804 emulsifying effect Effects 0.000 description 6
- 239000012071 phase Substances 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 238000005086 pumping Methods 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 238000001816 cooling Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 238000007599 discharging Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- WOKDXPHSIQRTJF-UHFFFAOYSA-N 3-[3-[3-[3-[3-[3-[3-[3-[3-(2,3-dihydroxypropoxy)-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]propane-1,2-diol Chemical compound OCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)CO WOKDXPHSIQRTJF-UHFFFAOYSA-N 0.000 description 1
- MMQZBEXYFLXHEN-UHFFFAOYSA-N OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.CCCCCCCCCCCCCCCCCC(O)=O Chemical compound OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.CCCCCCCCCCCCCCCCCC(O)=O MMQZBEXYFLXHEN-UHFFFAOYSA-N 0.000 description 1
- RUSIZKKQGFQEHZ-UHFFFAOYSA-N OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.CCCCCCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCCCCC(O)=O Chemical compound OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.CCCCCCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCCCCC(O)=O RUSIZKKQGFQEHZ-UHFFFAOYSA-N 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
- SELHWUUCTWVZOV-UHFFFAOYSA-N dodecanoic acid;propane-1,2,3-triol Chemical compound OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.CCCCCCCCCCCC(O)=O SELHWUUCTWVZOV-UHFFFAOYSA-N 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 235000003084 food emulsifier Nutrition 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- 150000002338 glycosides Chemical class 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- KMNJKLJBUHNCQM-UHFFFAOYSA-N octadecanoic acid propane-1,2,3-triol Chemical compound OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.CCCCCCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCCCCC(O)=O KMNJKLJBUHNCQM-UHFFFAOYSA-N 0.000 description 1
- GNYGXCHYOXCZON-UHFFFAOYSA-N octadecanoic acid;propane-1,2,3-triol Chemical compound OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO.CCCCCCCCCCCCCCCCCC(O)=O GNYGXCHYOXCZON-UHFFFAOYSA-N 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/10—General cosmetic use
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Emergency Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses an emulsifier composition containing polyglycerol ester and sucrose ester and application thereof, wherein the emulsifier composition is prepared from polyglycerol ester and sucrose ester, and the mass ratio of the polyglycerol ester to the sucrose ester is 1.5-6:1. the raw materials of polyglycerol esters and sucrose esters in the emulsifier composition of the invention are completely renewable, and the emulsifier composition of the invention does not contain PEG, and in addition, the emulsion particle size of the composition of the invention is very small and very stable. The composition of the invention has wide application range, and is applicable from thin emulsion to thick cream. The composition provided by the invention can be applied to the preparation of cosmetic preparations, so that the skin feel of cosmetics is fresh and cool, and long-acting moisture is kept.
Description
Technical Field
The invention relates to the technical field of cosmetics, in particular to an emulsifier composition containing polyglycerol ester and sucrose ester and application thereof.
Background
With the development of cosmetic emulsification technology, the selection of the emulsifier in the cosmetic formulation is also extended from the traditional span/tween series emulsifier to the glycoside emulsifier, and the emulsifier is also developed from the traditional PEG-containing structure to the PEG-free structure, and the source is natural and sustainable.
Polyglycerol esters are nonionic surfactants obtained by esterification of polyglycerol and fatty acid, and have natural sources and good biodegradability. As food emulsifiers have been used for many years. The polyglycerol ester emulsifier has the characteristics of strong emulsifying power, electrolyte resistance, suitability for wide pH value range and the like when being applied to cosmetics. However, the existing single polyglycerol ester emulsifier cannot achieve excellent skin feel and refreshing effect.
Sucrose esters are obtained by reacting sucrose with fatty acids, and belong to polyol type nonionic emulsifiers. Sucrose ester has fresh skin feel and good moisture retention, but has the defect of poor emulsifying power, and needs multiple sucrose ester emulsifying agents for compounding.
Disclosure of Invention
In view of the deficiencies of the prior art, the present invention is directed to an emulsifier composition comprising polyglycerol esters and sucrose esters and uses thereof.
In order to achieve the above purpose, the present invention adopts the following technical scheme:
an emulsifier composition comprising polyglycerol ester and sucrose ester is prepared from polyglycerol ester and sucrose ester; the mass ratio of the polyglycerol ester to the sucrose ester is 1.5-6:1.
further, the polyglycerol esters comprise at least two different polyglycerol esters;
preparing a first polyglyceride of fatty acids and polyglycerides, each selected from one fatty acid containing a C12 to C22 alkyl or alkenyl chain and from polyglycerides having a degree of polymerization of 3 to 10;
preparing a second polyglyceride of fatty acids and polyglycerides, respectively, selected from at least two fatty acids containing a C12 to C22 alkyl or alkenyl chain and from polyglycerides having a degree of polymerization of 3 to 10;
the mass ratio of the first polyglycerides to the second polyglycerides is 0.5-4:1.
as a further preferred embodiment, the fatty acid from which the first polyglycerides are prepared is one of behenic acid, stearic acid, isostearic acid, oleic acid and palmitic acid, and the polyglycerides from which the polyglycerides of the first polyglycerides are prepared have a degree of polymerization of 6 to 10.
As a still further preferred embodiment, the first polyglycerol ester is selected from any one or more of the following: hexapolyglycerol behenate, hexapolyglycerol stearate, hexapolyglycerol isostearate, hexapolyglycerol oleate, hexapolyglycerol palmitate, octapolyglycerol stearate, octapolyglycerol oleate, decapolyglycerol behenate, decapolyglycerol stearate, decapolyglycerol isostearate, decapolyglycerol oleate, decapolyglycerol palmitate.
As a further preferred embodiment, the fatty acid from which the second polyglycerides are prepared is one of behenic acid, stearic acid, isostearic acid, oleic acid and palmitic acid, and the polyglycerides from which the polyglycerides of the second polyglycerides are prepared are polyglycerides having a degree of polymerization of 6 to 10.
As a still further preferred embodiment, the second polyglycerol ester is selected from one or more of the following: hexapolyglycerol dibehenate, hexapolyglycerol distearate, hexapolyglycerol tristearate, hexapolyglycerol pentastearate, hexapolyglycerol diisostearate, hexapolyglycerol dioleate, hexapolyglycerol dipalmitate, decapolyglycerol dibehenate, decapolyglycerol distearate, decapolyglycerol tristearate, decapolyglycerol pentastearate, decapolyglycerol decastearate, decapolyglycerol diisostearate, decapolyglycerol triisostearate, decapolyglycerol pentaisostearate, decapolyglycerol decaiso-stearate, decapolyglycerol dioleate, decapolyglycerol trioleate, decapolyglycerol dipalmitate.
As a further preferred embodiment, the sucrose esters are selected from any one or more of the following; sucrose stearate, sucrose distearate, sucrose palmitate, sucrose myristate, sucrose laurate, sucrose cocoate.
The cosmetic emulsifier composition can be applied to preparation of cosmetic preparations.
The invention has the beneficial effects that:
1. the raw materials polyglycerol esters and sucrose esters in the emulsifier composition of the invention are completely renewable and the emulsifier composition of the invention does not contain PEG.
2. The composition of the invention has small emulsified particle size and is very stable.
3. The composition of the invention has wide application range, and is applicable from thin emulsion to thick cream.
4. The composition provided by the invention can be applied to the preparation of cosmetic preparations, so that the skin feel of cosmetics is fresh and cool, and long-acting moisture is kept.
Detailed Description
The present invention will be further described below, and it should be noted that, while the present embodiment provides a detailed implementation manner and a specific operation process on the premise of the present technical solution, the protection scope of the present invention is not limited to the present embodiment.
Example 1
150g of decaglycerol stearate, 37.5g of hexaglycerol pentastearate and 62.5g of sucrose stearate are heated to 80 ℃, mixed and stirred uniformly, and granulated and formed to obtain the cosmetic emulsifier composition.
Example 2
50g of hexaglycerol stearate, 100g of hexaglycerol distearate and 100g of sucrose stearate are heated to 80 ℃, mixed and stirred uniformly, and granulated and formed to obtain the cosmetic emulsifier composition.
Example 3
125g of hexapolyglycerol behenate, 87.5g of decapolyglycerol distearate and 37.5g of sucrose stearate are heated to 80 ℃, mixed and stirred uniformly, and granulated and formed to obtain the cosmetic emulsifier composition.
Comparative example 1
50g of decaglycerol oleate and 200g of sucrose hard laurate are heated to 80 ℃, mixed and stirred uniformly, and granulated and formed.
Comparative example 2
81.25g of hexaglycerol laurate and 168.75g of sucrose hard stearate are heated to 80 ℃, mixed and stirred uniformly, and granulated and formed.
The properties of examples 1-3 and comparative examples 1-2 were compared by emulsion stability experiments as follows. The feed compositions for each experimental and comparative group are shown in table 1.
TABLE 1
The emulsion is prepared by a known conventional emulsification method, and the preparation method comprises the following steps: heating the oil phase to 70-75deg.C; heating the aqueous phase to 70-75deg.C; pumping the water phase material into an emulsifying pot, starting stirring, pumping the oil phase material into the emulsifying pot, stirring and homogenizing at a high speed for 5 minutes, continuing stirring, preserving heat for 20 minutes, continuing stirring and cooling to 40 ℃, adding other components and homogenizing for 1-2 minutes, continuing stirring for 15 minutes, detecting, and discharging.
Emulsion stability test items generally comprise: centrifuging at 3000rpm for 30 minutes; storing for 3 months at normal temperature; storing at 48 ℃ for 1 month; storing at-15deg.C for 1 month. If one of the items is not satisfied, the stability is regarded as not passing.
As can be seen from Table 1, the emulsion stability experiments made with the emulsifier compositions described in examples 1-3 were all passed.
A comparative experiment was performed below on a spray emulsion containing the emulsifier composition of example 2 and a spray emulsion containing an emulsifier of PEG structure. In this experiment, the raw material compositions of the experimental group and the comparative group are shown in table 2.
TABLE 2
The preparation method of the spray emulsion comprises the following steps: adding the materials 1, 2 and 3 into a water boiler, adding the material 4 under stirring, continuously stirring, and heating to 80 ℃; adding 5-10 materials into an oil pan, stirring, and heating to 80 ℃; pumping the water phase material into an emulsifying pot, starting stirring, pumping the oil phase material into the emulsifying pot, stirring and homogenizing at a high speed for 5 minutes, continuing stirring, preserving heat for 20 minutes, cooling to 60 ℃, adding the material 11, continuing stirring and cooling to 40 ℃, adding the pre-dispersed material 12-15, homogenizing for 1-2 minutes, continuing stirring for 15 minutes, detecting, and discharging.
As is clear from Table 2, the emulsion spray containing example 2 has a good atomizing effect and a higher stability.
Example 4
This example provides an example of the use of the composition of example 2 in the preparation of a cosmetic formulation. The cosmetic preparation in this example is a moisturizing cream, and the raw material components are shown in table 3.
TABLE 3 Table 3
Example 5
This example provides another example of the use of the composition of example 2 in the preparation of a cosmetic formulation. The cosmetic preparation in this example is a repair cream, and the raw material components are shown in table 4.
TABLE 4 Table 4
Various modifications and variations of the present invention will be apparent to those skilled in the art in light of the foregoing teachings and are intended to be included within the scope of the following claims.
Claims (8)
1. An emulsifier composition comprising polyglycerol esters and sucrose esters, characterized in that it is made of polyglycerol esters and sucrose esters, the mass ratio of polyglycerol esters to sucrose esters being 1.5-6:1.
2. the emulsifier composition of claim 1 wherein the polyglycerol ester comprises at least two different polyglycerol esters;
preparing a first polyglyceride of fatty acids and polyglycerides, each selected from one fatty acid containing a C12 to C22 alkyl or alkenyl chain and from polyglycerides having a degree of polymerization of 3 to 10;
preparing a second polyglyceride of fatty acids and polyglycerides, respectively, selected from at least two fatty acids containing a C12 to C22 alkyl or alkenyl chain and from polyglycerides having a degree of polymerization of 3 to 10;
the mass ratio of the first polyglycerides to the second polyglycerides is 0.5-4:1.
3. the emulsifier composition of claim 2 wherein the fatty acid from which the first polyglycerol ester is made is one of behenic acid, stearic acid, isostearic acid, oleic acid and palmitic acid and the polyglycerol from which the first polyglycerol ester is made is a polyglycerol having a degree of polymerization of 6 to 10.
4. An emulsifier composition according to claim 2 or 3, wherein the first polyglycerol ester is selected from any one or more of the following: hexapolyglycerol behenate, hexapolyglycerol stearate, hexapolyglycerol isostearate, hexapolyglycerol oleate, hexapolyglycerol palmitate, octapolyglycerol stearate, octapolyglycerol oleate, decapolyglycerol behenate, decapolyglycerol stearate, decapolyglycerol isostearate, decapolyglycerol oleate, decapolyglycerol palmitate.
5. The emulsifier composition of claim 2 wherein the fatty acid from which the second polyglycerol ester is made is one of behenic acid, stearic acid, isostearic acid, oleic acid and palmitic acid and the polyglycerol from which the second polyglycerol ester is made is a polyglycerol having a degree of polymerization of 6 to 10.
6. An emulsifier composition according to claim 2 or 5, wherein the second polyglycerol ester is selected from one or more of the following: hexapolyglycerol dibehenate, hexapolyglycerol distearate, hexapolyglycerol tristearate, hexapolyglycerol pentastearate, hexapolyglycerol diisostearate, hexapolyglycerol dioleate, hexapolyglycerol dipalmitate, decapolyglycerol dibehenate, decapolyglycerol distearate, decapolyglycerol tristearate, decapolyglycerol pentastearate, decapolyglycerol decastearate, decapolyglycerol diisostearate, decapolyglycerol triisostearate, decapolyglycerol pentaisostearate, decapolyglycerol decaiso-stearate, decapolyglycerol dioleate, decapolyglycerol trioleate, decapolyglycerol dipalmitate.
7. An emulsifier composition according to claim 1, wherein the sucrose ester is selected from any one or more of the following; sucrose stearate, sucrose distearate, sucrose palmitate, sucrose myristate, sucrose laurate, sucrose cocoate.
8. Use of an emulsifier composition according to any one of claims 1-7 for the preparation of a cosmetic formulation.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2942135A1 (en) * | 2009-02-13 | 2010-08-20 | Oreal | COMPOSITION COMPRISING A SUCROSE ESTER AND A POLYGLYCEROL ESTER |
| CN110897918A (en) * | 2019-12-25 | 2020-03-24 | 广州欧正化妆品技术研究院有限公司 | Polyglycerol compound emulsifier and preparation method thereof |
| CN110897907A (en) * | 2019-12-11 | 2020-03-24 | 花安堂生物科技集团有限公司 | Water-in-oil lip glaze without PEG emulsifier and preparation method thereof |
| US20230081952A1 (en) * | 2020-06-12 | 2023-03-16 | Merry Plus Corporation | Cleansing composition |
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2023
- 2023-04-07 CN CN202310366764.1A patent/CN116407457A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2942135A1 (en) * | 2009-02-13 | 2010-08-20 | Oreal | COMPOSITION COMPRISING A SUCROSE ESTER AND A POLYGLYCEROL ESTER |
| CN110897907A (en) * | 2019-12-11 | 2020-03-24 | 花安堂生物科技集团有限公司 | Water-in-oil lip glaze without PEG emulsifier and preparation method thereof |
| CN110897918A (en) * | 2019-12-25 | 2020-03-24 | 广州欧正化妆品技术研究院有限公司 | Polyglycerol compound emulsifier and preparation method thereof |
| US20230081952A1 (en) * | 2020-06-12 | 2023-03-16 | Merry Plus Corporation | Cleansing composition |
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