CN110863281A - Preparation process of wool blended overcoat woolen - Google Patents
Preparation process of wool blended overcoat woolen Download PDFInfo
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- CN110863281A CN110863281A CN201910975699.6A CN201910975699A CN110863281A CN 110863281 A CN110863281 A CN 110863281A CN 201910975699 A CN201910975699 A CN 201910975699A CN 110863281 A CN110863281 A CN 110863281A
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- Prior art keywords
- wool
- treatment
- fiber strips
- plasma treatment
- grey cloth
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- 210000002268 wool Anatomy 0.000 title claims abstract description 48
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 239000004744 fabric Substances 0.000 claims abstract description 63
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims abstract description 56
- 239000000835 fiber Substances 0.000 claims abstract description 41
- 238000009832 plasma treatment Methods 0.000 claims abstract description 36
- 229910052786 argon Inorganic materials 0.000 claims abstract description 28
- 238000001035 drying Methods 0.000 claims abstract description 14
- 238000009941 weaving Methods 0.000 claims abstract description 13
- 238000004140 cleaning Methods 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 238000005406 washing Methods 0.000 claims abstract description 8
- 238000009987 spinning Methods 0.000 claims abstract description 7
- 239000004952 Polyamide Substances 0.000 claims abstract description 6
- 229920002647 polyamide Polymers 0.000 claims abstract description 6
- 238000010409 ironing Methods 0.000 claims abstract description 4
- 238000010008 shearing Methods 0.000 claims abstract description 4
- 238000011282 treatment Methods 0.000 claims description 46
- 238000000034 method Methods 0.000 claims description 15
- DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 claims description 14
- 239000007788 liquid Substances 0.000 claims description 13
- 229920001778 nylon Polymers 0.000 claims description 9
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 claims description 8
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 claims description 8
- 229940112669 cuprous oxide Drugs 0.000 claims description 8
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 7
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 7
- 239000004202 carbamide Substances 0.000 claims description 7
- 235000014676 Phragmites communis Nutrition 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 238000005507 spraying Methods 0.000 claims description 6
- 241000123589 Dipsacus Species 0.000 claims description 3
- 238000003801 milling Methods 0.000 claims description 3
- 238000007383 open-end spinning Methods 0.000 claims description 3
- 238000004321 preservation Methods 0.000 claims description 3
- 238000010010 raising Methods 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 6
- 229920006052 Chinlon® Polymers 0.000 abstract description 2
- 238000002156 mixing Methods 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 238000009963 fulling Methods 0.000 abstract 1
- XUJNEKJLAYXESH-UHFFFAOYSA-N cysteine Natural products SCC(N)C(O)=O XUJNEKJLAYXESH-UHFFFAOYSA-N 0.000 description 7
- 235000018417 cysteine Nutrition 0.000 description 7
- 239000000126 substance Substances 0.000 description 5
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 3
- LEVWYRKDKASIDU-QWWZWVQMSA-N D-cystine Chemical compound OC(=O)[C@H](N)CSSC[C@@H](N)C(O)=O LEVWYRKDKASIDU-QWWZWVQMSA-N 0.000 description 3
- 102000011782 Keratins Human genes 0.000 description 3
- 108010076876 Keratins Proteins 0.000 description 3
- 229910001431 copper ion Inorganic materials 0.000 description 3
- 229960003067 cystine Drugs 0.000 description 3
- 230000005611 electricity Effects 0.000 description 3
- 230000003068 static effect Effects 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethyl mercaptane Natural products CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- XUJNEKJLAYXESH-REOHCLBHSA-N L-Cysteine Chemical compound SC[C@H](N)C(O)=O XUJNEKJLAYXESH-REOHCLBHSA-N 0.000 description 1
- 102000004316 Oxidoreductases Human genes 0.000 description 1
- 108090000854 Oxidoreductases Proteins 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000005661 hydrophobic surface Effects 0.000 description 1
- 238000011221 initial treatment Methods 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000007788 roughening Methods 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
- D03D15/533—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads antistatic; electrically conductive
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/26—Electrically protective, e.g. preventing static electricity or electric shock
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D13/00—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
- D03D13/008—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft characterised by weave density or surface weight
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/02—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
- D06M10/025—Corona discharge or low temperature plasma
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
- D06M11/42—Oxides or hydroxides of copper, silver or gold
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/252—Mercaptans, thiophenols, sulfides or polysulfides, e.g. mercapto acetic acid; Sulfonium compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/262—Sulfated compounds thiosulfates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D2500/00—Materials for garments
- A41D2500/20—Woven
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2211/00—Protein-based fibres, e.g. animal fibres
- D10B2211/01—Natural animal fibres, e.g. keratin fibres
- D10B2211/02—Wool
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2501/00—Wearing apparel
- D10B2501/04—Outerwear; Protective garments
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention discloses a preparation process of wool blended overcoat woolen, which comprises the following steps: preparing raw materials, namely selecting wool fiber strips and polyamide fiber strips; respectively carrying out argon plasma treatment on the wool fiber strips and the polyamide fiber strips through a plasma treatment machine, after the argon plasma treatment is finished, cleaning and drying the wool fiber strips, then carrying out matching spinning according to weight percentage to obtain wool yarns with different specifications, weaving the wool yarns into grey cloth by adopting a weaving machine, and carrying out fulling, washing, dewatering, drying, decating, burdening, drying, ironing and shearing on the grey cloth to obtain a finished product. The overcoat woolen prepared by the preparation process disclosed by the invention is formed by blending and weaving wool and chinlon, has fluffy and soft hand feeling and has good heat retention and wear resistance; the argon plasma treatment makes the fiber surface rough, improves the hydrophilicity of the fiber surface, increases the water absorption capacity of the fabric, and the charges quickly escape through a large amount of water absorbed by the fabric surface, thereby realizing the antistatic effect of the fabric.
Description
Technical Field
The invention relates to the technical field of fabric preparation, in particular to a preparation process of wool blended overcoat woolen.
Background
The wool fiber has the advantages of good elasticity, strong hygroscopicity, good heat retention property and the like, is widely applied to textile raw materials, plays an increasingly important role in textile processing, has the characteristics of plump texture, smooth hand feeling, good drapability, noble, light and comfortable wearing and the like, and is popular with consumers all the time. The outermost scale layer of wool is made of highly hydrophobic substances such as keratin, lipid, and carbohydrate, and wool is a fiber having hydrophobic surface. When the relative humidity of the surrounding environment is low, the charging capability of the wool fibers is suddenly increased, static electricity is generated due to low relative humidity, and when a large amount of charge cannot be dissipated quickly, the static electricity phenomenon is generated.
Disclosure of Invention
The invention aims to overcome the defects in the prior art and provide the preparation process of the wool blended overcoat woolen cloth.
In order to achieve the purpose, the technical scheme of the invention is to design a preparation process of wool blended overcoat woolen, which comprises the following steps:
s1: preparing raw materials, namely selecting wool fiber strips and nylon fiber strips according to the weight percentage of the components of the overcoat woolen;
s2: performing antistatic pretreatment, namely performing argon plasma treatment on the wool fiber strips and the polyamide fiber strips through a plasma treatment machine respectively, wherein the vacuum degree of the plasma treatment is 50Pa, the power is 100-150W, and the treatment time is 10-50 min; cleaning and drying the argon plasma for later use;
s3: spinning and weaving, wherein the wool fiber strips and the nylon fiber strips processed in the step S2 are respectively matched and spun into yarn A with the specification of 18NM/2 and yarn B with the specification of 46NM/2 according to the weight percentage, the yarn A is made through open-end spinning, and the yarn B is made through combing spinning; then weaving the yarn A and the yarn B into grey cloth by a weaving machine;
s4: and (4) milling, washing, dehydrating, drying, decating, teasel raising, drying and ironing and shearing the grey cloth woven in the step S3 to obtain a finished product. The scales on the surface of the wool fiber are etched or stripped by argon plasma treatment, so that the micro-roughening degree of the surface of the wool fiber is increased, the hydrophilicity of the surface of the fiber is improved, and when the wool fiber absorbs more moisture from the outside, the charges accumulated on the surface of the fabric quickly escape through the moisture, thereby realizing the antistatic effect of the fabric.
The preferred technical scheme is that the antistatic pretreatment comprises two times of argon plasma treatment, wherein the first time of argon plasma treatment has the parameters of power of 150W and the treatment time of 21-30 min; the second argon plasma treatment parameter is 100W, and the treatment time is 10-20 min. The argon plasma treatment adopts a primary high-power and primary low-power treatment mode to treat the surface of wool fibers, the high-power plasma treatment is used for performing obvious texture and deep etching on scale layers on the surfaces of the wool fibers, the low-power plasma treatment can further generate fine stripe structures on the inner walls of the formed deep textures on the surfaces of the wool fibers, the roughness and the hydrophilic area of the fibers are increased, and the scale layers which are not stripped in the primary treatment process and are not closely loose in structure can be stripped.
Further preferably, the heat preservation treatment at 30-50 ℃ is carried out simultaneously in the second argon plasma treatment process. And the drying and heat preservation are carried out simultaneously in the secondary low-power plasma treatment process, the internal structure of the fiber can be protected, the deep layer inside the fiber is prevented from being damaged, and the mechanical property of the fabric is reduced.
A further preferable technical scheme is that the step S4 further comprises an antistatic post-treatment process for the grey cloth, wherein the antistatic post-treatment process comprises spraying an electrostatic treatment liquid on both sides of the grey cloth to wet the grey cloth, keeping the temperature at 40-45 ℃, standing for 7-10h, then heating to 50-60 ℃, keeping the temperature for 1-2h, and cleaning the fabric after the treatment is finished; wherein the electrostatic treatment liquid comprises 1-2% of 2-mercaptoethanol by volume concentration, 1-2% of sodium dodecyl sulfate by mass concentration, 7-10mol/L of urea and 5-10g/L of cuprous oxide. The keratin content in the wool is up to 95 percent, the keratin contains more cystine, the cystine contains disulfide bonds, and when the wool is treated at the temperature of 40-45 ℃, reducing disulfide bond of cystine to cysteine with mercaptoethanol, reducing disulfide bond to sulfhydryl group with mercaptoethanol and oxidase at 50-60 deg.C to generate cysteine, meanwhile, cuprous oxide monovalent copper ions are oxidized into divalent copper ions, and cysteine sulfydryl is combined with the divalent copper ions to generate a cysteine cuprous substance with low solubility, so that the copper substance is introduced to the surface of the fabric, the conductivity of the surface of the fabric is improved, when the external environment is dry and the plasma treated wool fiber can not absorb enough moisture from the outside to perform electrostatic dissipation, the conductive performance of the cuprous cysteine on the fabric can also transfer and dissipate static electricity on the fabric to the outside; meanwhile, the generated cuprous cysteine substance has a stable structure and low solubility, and the copper substance on the surface of the fabric is less lost after being washed for many times, so that the anti-washing performance of the anti-static performance of the fabric is improved; sodium dodecyl sulfate is adopted to prevent cysteine generated by reduction from being oxidized again to generate disulfide bonds; the urea solution is decomposed at a high temperature of 50-60 ℃ to generate ammonia water, so that the solubility of cuprous oxide in the electrostatic treatment solution is improved.
The further preferable technical scheme is that the raw materials comprise the following components in percentage by mass: 80% of wool fiber strips and 20% of nylon fiber strips.
The further preferred technical scheme is that the arrangement sequence of warp yarns of the grey cloth is 4A.1B.4A, the arrangement sequence of weft yarns is 1A, the upper weft density of the grey cloth is 215/10 cm, the total number of warp yarns is 4399, the upper reed width is 188cm, the reed number/penetration number is 36/9, and the gram weight of the grey cloth is 960g/cm2. The overcoat woollen cloth manufactured by the knitting method has plump and soft hand feeling, stereoscopic rice-shaped patterns, increased stereoscopic effect of the fabric and novel style,the style is elegant.
The invention has the advantages and beneficial effects that: the overcoat woolen prepared by the preparation process is formed by blending and weaving wool and chinlon, has fluffy and soft hand feeling and has good heat retention and wear resistance; the scales on the surface of the wool fiber are etched or stripped by argon plasma treatment, the surface is microscopically roughened, the hydrophilicity of the surface of the fiber is improved, and when the wool fiber absorbs more moisture from the outside, the charges accumulated on the surface of the fabric quickly escape through the moisture, so that the antistatic effect of the fabric is realized. The fabric is further subjected to antistatic treatment by adopting the electrostatic treatment liquid, the antistatic fabric treated by the treatment method is more resistant to washing, the fabric has a good antistatic effect after being washed for multiple times, and the antistatic performance is more stable.
Detailed Description
The following further describes embodiments of the present invention with reference to examples. The following examples are only for illustrating the technical solutions of the present invention more clearly, and the protection scope of the present invention is not limited thereby.
The invention relates to a preparation process of wool blended overcoat woolen, which comprises the following steps:
s1: preparing raw materials, namely selecting wool fiber strips and nylon fiber strips according to the weight percentage of the components of the overcoat woolen, wherein the raw materials comprise the following components in percentage by mass: 80% of wool fiber strips and 20% of nylon fiber strips;
s2: performing antistatic pretreatment, namely performing argon plasma treatment on the wool fiber strips and the polyamide fiber strips through a plasma treatment machine respectively, wherein the vacuum degree of the plasma treatment is 50Pa, the power is 100W, and the treatment time is 30 min; cleaning and drying the argon plasma for later use;
s3: spinning and weaving, wherein the wool fiber strips and the nylon fiber strips processed in the step S2 are respectively matched and spun into yarn A with the specification of 18NM/2 and yarn B with the specification of 46NM/2 according to the weight percentage, the yarn A is made through open-end spinning, and the yarn B is made through combing spinning; then weaving the yarn A and the yarn B into a grey fabric by a weaving machine, wherein the arrangement sequence of warp yarns of the grey fabric is 4A.1B.4A,the arrangement sequence of the weft yarns is 1A, the on-machine weft density of the grey cloth is 215/10 cm, the total warp number is 4399, the on-machine reed width is 188cm, the reed number/penetration number is 36/9, and the gram weight of the grey cloth is 960g/cm2;
S4: and (4) milling, washing, dehydrating, drying, decating, teasel raising, drying and ironing and shearing the grey cloth woven in the step S3 to obtain a finished product.
Example 2
Example 2 differs from example 1 in that S2: performing antistatic pretreatment, namely performing argon plasma treatment on the wool fiber strips and the polyamide fiber strips through a plasma treatment machine respectively, wherein the antistatic pretreatment comprises two times of argon plasma treatment, the first time of argon plasma treatment has the power of 150W, and the treatment time is 25 min; the second argon plasma treatment parameter is 100W, and the treatment time is 15 min; and (5) cleaning and drying after the argon plasma treatment is finished for later use.
Example 3
Example 3 differs from example 2 in that the antistatic pretreatment comprises two argon plasma treatments, the first argon plasma treatment parameter being 150W and the treatment time being 20 min; the second argon plasma treatment parameter is 100W, and the treatment time is 10 min.
Example 4
Embodiment 4 is different from embodiment 3 in that the step S4 further includes an antistatic post-treatment process for the grey cloth, the antistatic post-treatment process includes spraying an electrostatic treatment liquid on both sides of the grey cloth to wet the grey cloth, keeping the temperature at 40 ℃, standing for 7h, then heating to 50 ℃ and keeping the temperature for 1h, and after the treatment is finished, cleaning the fabric; the electrostatic treatment liquid comprises 1% volume concentration of 2-mercaptoethanol, 1% mass concentration of sodium dodecyl sulfate, 7mol/L urea and 5g/L cuprous oxide.
Example 5
The difference between the embodiment 5 and the embodiment 4 is that the antistatic post-treatment process comprises the steps of spraying the electrostatic treatment liquid on two sides of the grey cloth to soak the grey cloth, keeping the temperature at 42 ℃, standing for 8.5 hours, then heating to 55 ℃, keeping the temperature for 1.5 hours, and cleaning the fabric after the treatment is finished; the electrostatic treatment liquid comprises 1.5% volume concentration of 2-mercaptoethanol, 1.5% mass concentration of sodium dodecyl sulfate, 8.5mol/L urea and 7.5g/L cuprous oxide.
Example 6
Embodiment 6 is different from embodiment 4 in that the antistatic post-treatment process comprises spraying the electrostatic treatment liquid on both sides of the grey cloth to wet the grey cloth, keeping the temperature at 45 ℃, standing for 10 hours, then heating to 60 ℃, keeping the temperature for 2 hours, and cleaning the fabric after the treatment is finished; the electrostatic treatment liquid comprises 2-mercaptoethanol with the volume concentration of 2%, sodium dodecyl sulfate with the mass concentration of 2%, 10mol/L urea and 10g/L cuprous oxide.
Example 7
Example 7 is different from example 4 in that the antistatic post-treatment process comprises spraying the electrostatic treatment liquid on both sides of the grey cloth to wet the grey cloth, keeping the temperature at 40 ℃, standing for 10 hours, then heating to 55 ℃, keeping the temperature for 2 hours, and cleaning the fabric after the treatment is finished; the electrostatic treatment liquid comprises 1% of 2-mercaptoethanol by volume concentration, 2% of sodium dodecyl sulfate by mass concentration, 10mol/L of urea and 10g/L of cuprous oxide.
The half-life period of the fabric in examples 1 to 7 was measured by the method FZ/T01042-1996 "measurement of electrostatic half-life period of textile material", and the results showed that the half-life period of example 7 was the shortest, the antistatic property was the best, and the fabric was resistant to washing; next, example 5 was carried out. The antistatic treatment of examples 1 to 3, which is performed by using plasma alone, has a great effect on the strength of the fabric and poor antistatic performance and washing resistance, although the operation is simple.
The foregoing is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, various modifications and decorations can be made without departing from the technical principle of the present invention, and these modifications and decorations should also be regarded as the protection scope of the present invention.
Claims (6)
1. A preparation process of wool blended overcoat woolen cloth is characterized by comprising the following steps:
s1: preparing raw materials, namely selecting wool fiber strips and nylon fiber strips according to the weight percentage of the components of the overcoat woolen;
s2: performing antistatic pretreatment, namely performing argon plasma treatment on the wool fiber strips and the polyamide fiber strips through a plasma treatment machine respectively, wherein the vacuum degree of the plasma treatment is 50Pa, the power is 100-150W, and the treatment time is 10-50 min; cleaning and drying the argon plasma for later use;
s3: spinning and weaving, wherein the wool fiber strips and the nylon fiber strips processed in the step S2 are respectively matched and spun into yarn A with the specification of 18NM/2 and yarn B with the specification of 46NM/2 according to the weight percentage, the yarn A is made through open-end spinning, and the yarn B is made through combing spinning; then weaving the yarn A and the yarn B into grey cloth by a weaving machine;
s4: and (4) milling, washing, dehydrating, drying, decating, teasel raising, drying and ironing and shearing the grey cloth woven in the step S3 to obtain a finished product.
2. The preparation process of the wool blended overcoat woolen material as claimed in claim 1, wherein the antistatic pretreatment comprises two times of argon plasma treatment, the first time of argon plasma treatment has the parameters of power of 150W, and the treatment time is 21-30 min; the second argon plasma treatment parameter is 100W, and the treatment time is 10-20 min.
3. The process for preparing the wool blended overcoat woolen material as claimed in claim 2, wherein the second argon plasma treatment is performed while the heat preservation treatment at 30-50 ℃.
4. The preparation process of the wool blended overcoat woolen material according to claim 3, wherein the step S4 further comprises an antistatic post-treatment process of the grey cloth, wherein the antistatic post-treatment process comprises spraying an electrostatic treatment liquid on two sides of the grey cloth to wet the grey cloth, keeping the temperature at 40-45 ℃, standing for 7-10h, then heating to 50-60 ℃, keeping the temperature for 1-2h, and cleaning the fabric after the treatment is finished; wherein the electrostatic treatment liquid comprises 1-2% of 2-mercaptoethanol by volume concentration, 1-2% of sodium dodecyl sulfate by mass concentration, 7-10mol/L of urea and 5-10g/L of cuprous oxide.
5. The preparation process of the wool blended overcoat woolen material as claimed in claim 4, wherein the raw materials comprise the following components in percentage by mass: 80% of wool fiber strips and 20% of nylon fiber strips.
6. The preparation process of the wool blended overcoat woollen material as claimed in claim 5, wherein the arrangement sequence of the warp yarn of the grey cloth is 4A.1B.4A, the arrangement sequence of the weft yarn is 1A, the on-machine weft density of the grey cloth is 215/10 cm, the total number of the warp yarn is 4399, the on-machine reed width is 188cm, the reed number/number of passes is 36/9, and the gram weight of the grey cloth is 960g/cm2。
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