CN110858638B - 3d镁电池用电聚合的保护层 - Google Patents
3d镁电池用电聚合的保护层 Download PDFInfo
- Publication number
- CN110858638B CN110858638B CN201910781786.8A CN201910781786A CN110858638B CN 110858638 B CN110858638 B CN 110858638B CN 201910781786 A CN201910781786 A CN 201910781786A CN 110858638 B CN110858638 B CN 110858638B
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- magnesium
- anode
- foam
- methacrylate
- monomer
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- 239000011777 magnesium Substances 0.000 title claims abstract description 107
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 title claims abstract description 101
- 229910052749 magnesium Inorganic materials 0.000 title claims abstract description 99
- 239000011241 protective layer Substances 0.000 title claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 32
- 239000000178 monomer Substances 0.000 claims abstract description 27
- 239000006260 foam Substances 0.000 claims abstract description 26
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical group CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims abstract description 19
- KFNGWPXYNSJXOP-UHFFFAOYSA-N 3-(2-methylprop-2-enoyloxy)propane-1-sulfonic acid Chemical compound CC(=C)C(=O)OCCCS(O)(=O)=O KFNGWPXYNSJXOP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 150000003839 salts Chemical class 0.000 claims abstract description 11
- -1 poly(3-sulfopropyl methacrylate) Polymers 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims abstract description 3
- 230000001351 cycling effect Effects 0.000 claims description 6
- 239000000758 substrate Substances 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- FBSOFCDJBBJYKT-UHFFFAOYSA-M potassium;2-methyl-6-sulfohex-2-enoate Chemical group [K+].[O-]C(=O)C(C)=CCCCS(O)(=O)=O FBSOFCDJBBJYKT-UHFFFAOYSA-M 0.000 claims description 3
- 239000006262 metallic foam Substances 0.000 claims 2
- 229920000642 polymer Polymers 0.000 abstract description 15
- 239000011253 protective coating Substances 0.000 abstract description 10
- 239000003792 electrolyte Substances 0.000 abstract description 5
- 239000011248 coating agent Substances 0.000 abstract description 3
- 238000000576 coating method Methods 0.000 abstract description 3
- 229920001577 copolymer Polymers 0.000 abstract description 3
- 239000010410 layer Substances 0.000 description 12
- 239000000243 solution Substances 0.000 description 9
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 6
- 238000000026 X-ray photoelectron spectrum Methods 0.000 description 5
- 238000000157 electrochemical-induced impedance spectroscopy Methods 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
- 239000011888 foil Substances 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 239000011591 potassium Substances 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 3
- 238000002161 passivation Methods 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 3
- 239000002344 surface layer Substances 0.000 description 3
- PHMNXPYGVPEQSJ-UHFFFAOYSA-N Dimethoxane Chemical compound CC1CC(OC(C)=O)OC(C)O1 PHMNXPYGVPEQSJ-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000002484 cyclic voltammetry Methods 0.000 description 2
- 239000008151 electrolyte solution Substances 0.000 description 2
- 238000009713 electroplating Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229920002454 poly(glycidyl methacrylate) polymer Polymers 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000010406 cathode material Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- NHGXDBSUJJNIRV-UHFFFAOYSA-M tetrabutylammonium chloride Chemical compound [Cl-].CCCC[N+](CCCC)(CCCC)CCCC NHGXDBSUJJNIRV-UHFFFAOYSA-M 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
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Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/628—Inhibitors, e.g. gassing inhibitors, corrosion inhibitors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/134—Electrodes based on metals, Si or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0438—Processes of manufacture in general by electrochemical processing
- H01M4/045—Electrochemical coating; Electrochemical impregnation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0438—Processes of manufacture in general by electrochemical processing
- H01M4/0464—Electro organic synthesis
- H01M4/0466—Electrochemical polymerisation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1395—Processes of manufacture of electrodes based on metals, Si or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/366—Composites as layered products
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/381—Alkaline or alkaline earth metals elements
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
- H01M4/661—Metal or alloys, e.g. alloy coatings
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/70—Carriers or collectors characterised by shape or form
- H01M4/80—Porous plates, e.g. sintered carriers
- H01M4/808—Foamed, spongy materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/027—Negative electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Composite Materials (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Cell Electrode Carriers And Collectors (AREA)
- Secondary Cells (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US16/111,366 | 2018-08-24 | ||
| US16/111,366 US10541419B1 (en) | 2018-08-24 | 2018-08-24 | Electro-polymerized protective layer for 3D magnesium battery |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN110858638A CN110858638A (zh) | 2020-03-03 |
| CN110858638B true CN110858638B (zh) | 2021-07-23 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910781786.8A Active CN110858638B (zh) | 2018-08-24 | 2019-08-23 | 3d镁电池用电聚合的保护层 |
Country Status (3)
| Country | Link |
|---|---|
| US (2) | US10541419B1 (enExample) |
| JP (1) | JP6839738B2 (enExample) |
| CN (1) | CN110858638B (enExample) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102019219010A1 (de) * | 2019-12-05 | 2021-06-10 | Honda Motor Co., Ltd. | Mg-Anodenschutz mit Membranen aus einer ionischen Polymerflüssigkeit |
| US20230223543A1 (en) * | 2020-07-15 | 2023-07-13 | Schaeffler Technologies AG & Co. KG | Anode for a magesium battery and method for the production thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1612377A (zh) * | 2003-10-31 | 2005-05-04 | 三星Sdi株式会社 | 锂金属电池的负极及包含它的锂金属电池 |
| CN101997107A (zh) * | 2009-08-11 | 2011-03-30 | 中国电子科技集团公司第十八研究所 | 一种镁电池用镁电极及其制备方法 |
| CN102020753A (zh) * | 2009-09-10 | 2011-04-20 | 第一毛织株式会社 | 聚合物膜组合物、聚合物膜、膜电极组件和燃料电池 |
| CN103563130A (zh) * | 2011-06-02 | 2014-02-05 | 协立化学产业株式会社 | 电池电极或隔板用涂布剂组合物 |
| CN105789695A (zh) * | 2016-05-17 | 2016-07-20 | 中国科学院化学研究所 | 一种复合聚合物电解质及其在电池负极保护中的应用 |
| CN107123788A (zh) * | 2017-03-30 | 2017-09-01 | 中国科学院青岛生物能源与过程研究所 | 一种具有有机无机双重保护层的金属锂负极 |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3036141A (en) * | 1956-12-18 | 1962-05-22 | Goldenberg Leo | Magnesium galvanic cell |
| JP2003007337A (ja) * | 2001-06-21 | 2003-01-10 | Daiso Co Ltd | ポリマー二次電池 |
| CN101499528A (zh) * | 2009-03-06 | 2009-08-05 | 武汉孚安特科技有限公司 | 改善锂亚硫酰氯电池电压滞后性的方法及其带涂层的阳极 |
| JP2011249175A (ja) * | 2010-05-28 | 2011-12-08 | Honda Foundry Co Ltd | マグネシウム電池用電極材料とその製造方法、および該電極材料を用いた電極を用いる電池 |
| CN103190015A (zh) * | 2010-09-03 | 2013-07-03 | 日本电气株式会社 | 非水系二次电池及非水系二次电池的制造方法 |
| WO2012153866A1 (ja) * | 2011-05-11 | 2012-11-15 | 日本電気株式会社 | 非水系二次電池の積層構造、および非水系二次電池の積層方法 |
| WO2013036802A1 (en) * | 2011-09-07 | 2013-03-14 | 24M Technologies, Inc. | Stationary semi-solid battery module and method of manufacture |
| JP2013084351A (ja) * | 2011-10-06 | 2013-05-09 | Nippon Zeon Co Ltd | 電気化学素子電極用複合粒子、電気化学素子電極材料、及び電気化学素子電極 |
| WO2014063138A1 (en) | 2012-10-19 | 2014-04-24 | Colorado State University Research Foundation | Detection of defects in solid-polymer coatings |
| JP2014175055A (ja) * | 2013-03-06 | 2014-09-22 | Nippon Zeon Co Ltd | 二次電池用多孔膜、二次電池多孔膜用スラリー、及び二次電池用多孔膜の製造方法、並びに二次電池用電極、二次電池用セパレータ、及び二次電池 |
| US9714173B2 (en) * | 2013-08-09 | 2017-07-25 | Cornell University | Gyroidal mesoporous carbon materials and methods thereof |
| CN103474697B (zh) * | 2013-09-10 | 2016-09-07 | 东莞新能源科技有限公司 | 一种凝胶聚合物锂离子电池 |
| TWI553948B (zh) * | 2015-08-31 | 2016-10-11 | 吳佳典 | 電池 |
| US10276856B2 (en) * | 2015-10-08 | 2019-04-30 | Nanotek Instruments, Inc. | Continuous process for producing electrodes and alkali metal batteries having ultra-high energy densities |
| US10741846B2 (en) * | 2016-05-09 | 2020-08-11 | Samsung Electronics Co., Ltd. | Negative electrode for lithium metal battery and lithium metal battery comprising the same |
| US10199637B2 (en) * | 2016-06-07 | 2019-02-05 | Nanotek Instruments, Inc. | Graphene-metal hybrid foam-based electrode for an alkali metal battery |
| US10297829B2 (en) * | 2016-08-24 | 2019-05-21 | Uchicago Argonne, Llc | Polyanthraquinone-based organic cathode for high-performance rechargeable magnesium-ion batteries |
| US10559826B2 (en) * | 2017-03-20 | 2020-02-11 | Global Graphene Group, Inc. | Multivalent metal ion battery having a cathode of recompressed graphite worms and manufacturing method |
| US20200264663A1 (en) * | 2017-09-15 | 2020-08-20 | University Of Pittsburgh - Of The Commonwealth System Of Higher Education | An all-in-one integrated, inter-convertible fold-able cell phone, tablet and personal computer |
| US10680280B2 (en) * | 2017-09-26 | 2020-06-09 | Toyota Jidosha Kabushiki Kaisha | 3D magnesium battery and method of making the same |
-
2018
- 2018-08-24 US US16/111,366 patent/US10541419B1/en active Active
-
2019
- 2019-08-22 JP JP2019152228A patent/JP6839738B2/ja active Active
- 2019-08-23 CN CN201910781786.8A patent/CN110858638B/zh active Active
- 2019-12-10 US US16/708,884 patent/US11201333B2/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1612377A (zh) * | 2003-10-31 | 2005-05-04 | 三星Sdi株式会社 | 锂金属电池的负极及包含它的锂金属电池 |
| CN101997107A (zh) * | 2009-08-11 | 2011-03-30 | 中国电子科技集团公司第十八研究所 | 一种镁电池用镁电极及其制备方法 |
| CN102020753A (zh) * | 2009-09-10 | 2011-04-20 | 第一毛织株式会社 | 聚合物膜组合物、聚合物膜、膜电极组件和燃料电池 |
| CN103563130A (zh) * | 2011-06-02 | 2014-02-05 | 协立化学产业株式会社 | 电池电极或隔板用涂布剂组合物 |
| CN105789695A (zh) * | 2016-05-17 | 2016-07-20 | 中国科学院化学研究所 | 一种复合聚合物电解质及其在电池负极保护中的应用 |
| CN107123788A (zh) * | 2017-03-30 | 2017-09-01 | 中国科学院青岛生物能源与过程研究所 | 一种具有有机无机双重保护层的金属锂负极 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN110858638A (zh) | 2020-03-03 |
| US11201333B2 (en) | 2021-12-14 |
| JP6839738B2 (ja) | 2021-03-10 |
| US10541419B1 (en) | 2020-01-21 |
| JP2020031059A (ja) | 2020-02-27 |
| US20200112028A1 (en) | 2020-04-09 |
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