CN110846144B - 柴油颗粒捕集器灰分清洗液及其制备方法 - Google Patents
柴油颗粒捕集器灰分清洗液及其制备方法 Download PDFInfo
- Publication number
- CN110846144B CN110846144B CN201911100219.8A CN201911100219A CN110846144B CN 110846144 B CN110846144 B CN 110846144B CN 201911100219 A CN201911100219 A CN 201911100219A CN 110846144 B CN110846144 B CN 110846144B
- Authority
- CN
- China
- Prior art keywords
- parts
- ash
- surfactant
- diesel particulate
- cleaning fluid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000004140 cleaning Methods 0.000 title claims abstract description 47
- 239000012530 fluid Substances 0.000 title claims abstract description 14
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 239000004094 surface-active agent Substances 0.000 claims abstract description 26
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 13
- 239000002738 chelating agent Substances 0.000 claims abstract description 13
- 230000007797 corrosion Effects 0.000 claims abstract description 13
- 238000005260 corrosion Methods 0.000 claims abstract description 13
- 239000002270 dispersing agent Substances 0.000 claims abstract description 13
- 239000003112 inhibitor Substances 0.000 claims abstract description 13
- 239000002516 radical scavenger Substances 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 238000003756 stirring Methods 0.000 claims description 16
- -1 isopropyl alcohol amide Chemical class 0.000 claims description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- 238000013329 compounding Methods 0.000 claims description 6
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical group CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 4
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 claims description 4
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 4
- RBNPOMFGQQGHHO-UHFFFAOYSA-N glyceric acid Chemical compound OCC(O)C(O)=O RBNPOMFGQQGHHO-UHFFFAOYSA-N 0.000 claims description 4
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 4
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 4
- BAERPNBPLZWCES-UHFFFAOYSA-N (2-hydroxy-1-phosphonoethyl)phosphonic acid Chemical compound OCC(P(O)(O)=O)P(O)(O)=O BAERPNBPLZWCES-UHFFFAOYSA-N 0.000 claims description 2
- JSYPRLVDJYQMAI-ODZAUARKSA-N (z)-but-2-enedioic acid;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)\C=C/C(O)=O JSYPRLVDJYQMAI-ODZAUARKSA-N 0.000 claims description 2
- LPMBTLLQQJBUOO-KTKRTIGZSA-N (z)-n,n-bis(2-hydroxyethyl)octadec-9-enamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)N(CCO)CCO LPMBTLLQQJBUOO-KTKRTIGZSA-N 0.000 claims description 2
- HJVAFZMYQQSPHF-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;boric acid Chemical compound OB(O)O.OCCN(CCO)CCO HJVAFZMYQQSPHF-UHFFFAOYSA-N 0.000 claims description 2
- 229920002126 Acrylic acid copolymer Polymers 0.000 claims description 2
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims description 2
- 229920001732 Lignosulfonate Polymers 0.000 claims description 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Natural products P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims description 2
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 2
- 239000002671 adjuvant Substances 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 2
- 239000012964 benzotriazole Substances 0.000 claims description 2
- 239000002131 composite material Substances 0.000 claims description 2
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 229910000073 phosphorus hydride Inorganic materials 0.000 claims description 2
- 229920000141 poly(maleic anhydride) Polymers 0.000 claims description 2
- 229920001529 polyepoxysuccinic acid Polymers 0.000 claims description 2
- 229920001451 polypropylene glycol Polymers 0.000 claims description 2
- 239000001632 sodium acetate Substances 0.000 claims description 2
- 235000017281 sodium acetate Nutrition 0.000 claims description 2
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 2
- 235000002906 tartaric acid Nutrition 0.000 claims description 2
- 239000011975 tartaric acid Substances 0.000 claims description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N isopropyl alcohol Natural products CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims 2
- 235000019357 lignosulphonate Nutrition 0.000 claims 1
- 239000000243 solution Substances 0.000 abstract description 18
- 150000001875 compounds Chemical class 0.000 abstract description 6
- 239000002245 particle Substances 0.000 abstract description 6
- 229910019142 PO4 Inorganic materials 0.000 abstract description 4
- 150000001805 chlorine compounds Chemical class 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 4
- 229910044991 metal oxide Inorganic materials 0.000 abstract description 4
- 150000004706 metal oxides Chemical class 0.000 abstract description 4
- 235000021317 phosphate Nutrition 0.000 abstract description 4
- 150000003013 phosphoric acid derivatives Chemical class 0.000 abstract description 4
- 150000004760 silicates Chemical class 0.000 abstract description 4
- 239000004071 soot Substances 0.000 abstract description 4
- 150000003467 sulfuric acid derivatives Chemical class 0.000 abstract description 4
- 238000006243 chemical reaction Methods 0.000 abstract description 3
- 239000007864 aqueous solution Substances 0.000 abstract description 2
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 238000011156 evaluation Methods 0.000 description 6
- 239000013618 particulate matter Substances 0.000 description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 229910052878 cordierite Inorganic materials 0.000 description 1
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/8305—Mixtures of non-ionic with anionic compounds containing a combination of non-ionic compounds differently alcoxylised or with different alkylated chains
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/166—Organic compounds containing borium
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/228—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with phosphorus- or sulfur-containing groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/361—Phosphonates, phosphinates or phosphonites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Processing Of Solid Wastes (AREA)
- Detergent Compositions (AREA)
Abstract
本发明公开了一种柴油颗粒捕集器灰分清洗液及其制备方法，该灰分清洗液按质量份数计由如下原料组成：表面活性剂助剂1～10份、表面活性剂5～15份、灰分清除剂5～15份、螯合剂1～10份、缓蚀剂0.05～0.15份、消泡剂0.05～0.15份、分散剂0.05～0.15份，余量为水。本发明提供的清洗液可快速溶解DPF灰分中的金属氧化物、硫酸盐、磷酸盐、硅酸盐和氯化物，使其反应形成溶于水的化合物，被水溶液所带走并排出，经反应形成的化合物具有表面活性，有助于对碳烟颗粒的溶解清洗。
Description
技术领域
本发明涉及尾气排放装置颗粒捕集器清灰的技术领域，具体涉及一种柴油颗粒捕集器灰分清洗液及其制备方法。
背景技术
我国正式进入“国六”排放时代，国六除了对NOx和PM排放进行了更严格的规定，还规定了CO、HC、NH3等排放限值，同时也增加了对PM(颗粒物)排放的监控，这对发动机的尾气处理技术提出了更高的要求。国六对PM(颗粒物)的限值相对于国五严格了不少，通过优化标定、进排气相位等手段已经无法让原机PM排放在满足动力性的同时还满足法规要求，因此只能通过加装颗粒捕集器(DPF)后处理来解决。
柴油颗粒捕集器DPF成为国六后处理必备的组件。DPF是一种多孔的蜂窝结构，在使用过程中，碳烟颗粒和灰分会在DPF孔道内逐渐累积，进而导致排气背压升高，诱发DPF再生，绝大部分碳烟颗粒在DPF再生环节可以被烧掉，但是来自润滑油中的灰分会在DPF孔道中逐渐累积，灰分无法被烧掉，因此会在DPF中越积越多，灰分增多会导致发动机动力性和经济性下降，从而影响车辆的使用性能。在累积到一定程度后，必须进行DPF清灰操作。现有的清灰解决方案是，采用高压空气进行吹扫。空气吹扫清灰的主要有以下缺点：(1)清灰效果差，缩短DPF的清灰里程；(2)DPF尺寸不能过大，不适合中重型商用车清灰；(3)需要预加热，不节能；(4)设备价格昂贵，保养成本高。
发明内容
本发明的目的在于克服上述背景技术的不足，提供一种柴油颗粒捕集器灰分清洗液及其制备方法，该柴油颗粒捕集器灰分清洗液清灰效果好，对铂、钯、铑、铈等催化剂无损害，对氧化铝、不锈钢、碳化硅和菁青石等载体不反应，具有优异应用安全性。
为实现上述目的，本发明提供的一种柴油颗粒捕集器灰分清洗液，其特征在于：按质量份数计由如下原料组成：表面活性剂助剂1～10份、表面活性剂5～15份、灰分清除剂5～15份、螯合剂1～10份、缓蚀剂0.05～0.15份、消泡剂0.05～0.15份、分散剂0.05～0.15份，余量为水。
作为优选实施方式地，所述表面活性剂助剂选自正丁醇或正戊醇。
作为优选实施方式地，所述表面活性剂按质量份数计由20～40份十二烷基硫酸钠、10～30份月桂醇硫酸钠、40～60份异丙醇酰胺C13复配而成。
作为优选实施方式地，所述灰分清除剂按质量份数计由5～15份羟基乙叉二膦酸、45～55份乙酸、15～25份酒石酸、10～20份乙二醇、0～10份十二烷基苯磺酸钠复配而成。
作为优选实施方式地，所述螯合剂按质量份数计由40～60份EDTA-2Na、15～35份乙二胺二邻苯基乙酸钠、15～35份马来酸丙烯酸共聚物复配而成。
作为优选实施方式地，所述缓蚀剂选自膦羧酸、苯并三唑、磺化木质素、油酸二乙醇胺、聚环氧琥珀酸、三乙醇胺硼酸酯中的一种。
作为优选实施方式地，所述消泡剂选自聚氧乙烯聚氧丙烯季戊四醇醚、聚氧乙烯聚氧丙醇胺醚、聚氧丙烯甘油醚或聚氧丙烯聚氧乙烯甘油醚中的一种。
作为优选实施方式地，所述分散剂为水解聚马来酸酐。
本发明还提供一种上述的柴油颗粒捕集器灰分清洗液的制备方法，包括如下步骤：
1)按质量份数配比将表面活性剂助剂、表面活性剂、灰分清除剂、水加入反应器中加热至50℃～70℃；
2)向反应器中加入螯合剂，并搅拌均匀；
3)降温至20℃～25℃加入缓蚀剂、消泡剂、分散剂，并搅拌均匀，即可。
与现有技术相比，本发明具有如下优点：
其一，本发明提供的清洗液可快速溶解DPF灰分中的金属氧化物、硫酸盐、磷酸盐、硅酸盐和氯化物，使其反应形成溶于水的化合物，被水溶液所带走并排出，经反应形成的化合物具有表面活性，有助于对碳烟颗粒的溶解清洗。
其二，本发明提供的清洗液清灰效果好，对铂、钯、铑、铈等催化剂无损害，对氧化铝、不锈钢、碳化硅和菁青石等载体不反应，具有优异应用安全性。
其三，本发明所涉及的原料成本较低，成品具有价格优势，制备方法简单，设备投入低，节能环保。
具体实施方式
下面结合实施案例详细说明本发明的实施情况，但它们并不构成对本发明的限定，仅作举例而已。同时通过说明本发明的优点将变得更加清楚和容易理解。
实施例1
本实施例提供一种柴油颗粒捕集器灰分清洗液，按质量份数计由如下原料组成：
上述的柴油颗粒捕集器灰分清洗液的制备方法，包括如下步骤：
1)按质量份数配比将表面活性剂助剂、表面活性剂、灰分清除剂、水加入反应器中加热至50℃；
2)向反应器中加入螯合剂，并搅拌均匀；
3)降温至20℃加入缓蚀剂、消泡剂、分散剂，并搅拌均匀，即可。
采用上述清洗液清洗DPF，以清洗前后DPF质量变化率作为评价标准，用实施例1清洗前后DPF质量变化率为2.5％。
实施例2
本实施例提供一种柴油颗粒捕集器灰分清洗液，按质量份数计由如下原料组成：
上述的柴油颗粒捕集器灰分清洗液的制备方法，包括如下步骤：
1)按质量份数配比将表面活性剂助剂、表面活性剂、灰分清除剂、水加入反应器中加热至70℃；
2)向反应器中加入螯合剂，并搅拌均匀；
3)降温至25℃加入缓蚀剂、消泡剂、分散剂，并搅拌均匀，即可。
采用上述清洗液清洗DPF，以清洗前后DPF质量变化率作为评价标准，用实施例2清洗前后DPF质量变化率为3.1％。
实施例3
本实施例提供一种柴油颗粒捕集器灰分清洗液，按质量份数计由如下原料组成：
上述的柴油颗粒捕集器灰分清洗液的制备方法，包括如下步骤：
1)按质量份数配比将表面活性剂助剂、表面活性剂、灰分清除剂、水加入反应器中加热至60℃；
2)向反应器中加入螯合剂，并搅拌均匀；
3)降温至25℃加入缓蚀剂、消泡剂、分散剂，并搅拌均匀，即可。
采用上述清洗液清洗DPF，以清洗前后DPF质量变化率作为评价标准，用实施例3清洗前后DPF质量变化率为2.8％。
实施例4
本实施例提供一种柴油颗粒捕集器灰分清洗液，按质量份数计由如下原料组成：
上述的柴油颗粒捕集器灰分清洗液的制备方法，包括如下步骤：
1)按质量份数配比将表面活性剂助剂、表面活性剂、灰分清除剂、水加入反应器中加热至60℃；
2)向反应器中加入螯合剂，并搅拌均匀；
3)降温至25℃加入缓蚀剂、消泡剂、分散剂，并搅拌均匀，即可。
采用上述清洗液清洗DPF，以清洗前后DPF质量变化率作为评价标准，用实施例4清洗前后DPF质量变化率为3.0％。
实施例5
本实施例提供一种柴油颗粒捕集器灰分清洗液，按质量份数计由如下原料组成：
上述的柴油颗粒捕集器灰分清洗液的制备方法，包括如下步骤：
1)按质量份数配比将表面活性剂助剂、表面活性剂、灰分清除剂、水加入反应器中加热至60℃；
2)向反应器中加入螯合剂，并搅拌均匀；
3)降温至25℃加入缓蚀剂、消泡剂、分散剂，并搅拌均匀，即可。
采用上述清洗液清洗DPF，以清洗前后DPF质量变化率作为评价标准，用实施例5清洗前后DPF质量变化率为1.5％。
实施例6
本实施例提供一种柴油颗粒捕集器灰分清洗液，按质量份数计由如下原料组成：
上述的柴油颗粒捕集器灰分清洗液的制备方法，包括如下步骤：
1)按质量份数配比将表面活性剂助剂、表面活性剂、灰分清除剂、水加入反应器中加热至60℃；
2)向反应器中加入螯合剂，并搅拌均匀；
3)降温至25℃加入缓蚀剂、消泡剂、分散剂，并搅拌均匀，即可。
采用上述清洗液清洗DPF，以清洗前后DPF质量变化率作为评价标准，用实施例6清洗前后DPF质量变化率为1.2％。
以上，仅为本发明的具体实施方式，应当指出，任何熟悉本领域的技术人员在本发明所揭示的技术范围内，可轻易想到的变化或替换，都应涵盖在本发明的保护范围之内，其余未详细说明的为现有技术。
Claims (5)
1.一种柴油颗粒捕集器灰分清洗液，其特征在于：按质量份数计由如下原料组成：表面活性剂助剂1～10份、表面活性剂5～15份、灰分清除剂5～15份、螯合剂1～10份、缓蚀剂0.05～0.15份、消泡剂0.05～0.15份、分散剂0.05～0.15份，余量为水；
所述表面活性剂按质量份数计由20～40份十二烷基硫酸钠、10～30份月桂醇硫酸钠、40～60份异丙醇酰胺C13复配而成；
所述灰分清除剂按质量份数计由5～15份羟基乙叉二膦酸、45～55份乙酸、15～25份酒石酸、10～20份乙二醇、0～10份十二烷基苯磺酸钠复配而成；
所述螯合剂按质量份数计由40～60份EDTA-2Na、15～35份乙二胺二邻苯基乙酸钠、15～35份马来酸丙烯酸共聚物复配而成；
所述表面活性剂助剂选自正丁醇或正戊醇。
2.根据权利要求1所述的柴油颗粒捕集器灰分清洗液，其特征在于：所述缓蚀剂选自膦羧酸、苯并三唑、磺化木质素、油酸二乙醇胺、聚环氧琥珀酸、三乙醇胺硼酸酯中的一种。
3.根据权利要求1所述的柴油颗粒捕集器灰分清洗液，其特征在于：所述消泡剂选自聚氧乙烯聚氧丙烯季戊四醇醚、聚氧乙烯聚氧丙醇胺醚、聚氧丙烯甘油醚或聚氧丙烯聚氧乙烯甘油醚中的一种。
4.根据权利要求1所述的柴油颗粒捕集器灰分清洗液，其特征在于：所述分散剂为水解聚马来酸酐。
5.一种权利要求1～4任一项所述的柴油颗粒捕集器灰分清洗液的制备方法，其特征在于：包括如下步骤：
1)按质量份数配比将表面活性剂助剂、表面活性剂、灰分清除剂、水加入反应器中加热至50℃～70℃；
2)向反应器中加入螯合剂，并搅拌均匀；
3)降温至20℃～25℃加入缓蚀剂、消泡剂、分散剂，并搅拌均匀，即可。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911100219.8A CN110846144B (zh) | 2019-11-12 | 2019-11-12 | 柴油颗粒捕集器灰分清洗液及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911100219.8A CN110846144B (zh) | 2019-11-12 | 2019-11-12 | 柴油颗粒捕集器灰分清洗液及其制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN110846144A CN110846144A (zh) | 2020-02-28 |
| CN110846144B true CN110846144B (zh) | 2021-07-06 |
Family
ID=69600085
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201911100219.8A Active CN110846144B (zh) | 2019-11-12 | 2019-11-12 | 柴油颗粒捕集器灰分清洗液及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110846144B (zh) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112048395A (zh) * | 2020-09-14 | 2020-12-08 | 英德市东顺精细化工实业有限公司 | 一种水性浓缩型柴油车dpf清洗剂及其制备方法 |
| CN113339107B (zh) * | 2021-05-27 | 2023-07-28 | 东风商用车有限公司 | 一种适用于再制造工厂的dpf灰分清洗装置及方法 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106398884A (zh) * | 2016-08-31 | 2017-02-15 | 江苏可兰素汽车环保科技有限公司 | 一种柴油机doc/poc清洗再生剂的制备方法 |
| CN108085169A (zh) * | 2017-12-28 | 2018-05-29 | 江苏可兰素汽车环保科技有限公司 | 一种柴油机dpf清洗再生剂及其应用 |
| CN108165379A (zh) * | 2017-12-28 | 2018-06-15 | 江苏可兰素汽车环保科技有限公司 | 一种柴油机dpf清洗再生剂及其制备方法 |
| CN108798833A (zh) * | 2018-05-25 | 2018-11-13 | 上海汽车集团股份有限公司 | 颗粒捕捉器灰分累积模型的建模方法 |
| CN109370787A (zh) * | 2018-10-23 | 2019-02-22 | 武汉布朗环境能源有限公司 | 一种机动车尾气处理系统柴油颗粒捕集器dpf清洗剂 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8619064D0 (en) * | 1986-08-05 | 1986-09-17 | Unilever Plc | Detergent compositions |
| EP1372950A2 (en) * | 2000-11-01 | 2004-01-02 | The Procter & Gamble Company | Multi-layer substrate for a premoistened wipe capable of controlled fluid release |
| CN103224841B (zh) * | 2013-05-15 | 2016-01-20 | 大唐淮北发电厂 | 一种脱硫烟气换热器清洗剂 |
| CN105368490A (zh) * | 2014-08-25 | 2016-03-02 | 中石化洛阳工程有限公司 | 一种脱除煤焦油中金属和灰分的复合剂及其使用方法 |
| CN109504542A (zh) * | 2018-12-17 | 2019-03-22 | 金丰宏润科技(广东)有限公司 | 一种高效发动机油泥清洗剂 |
-
2019
- 2019-11-12 CN CN201911100219.8A patent/CN110846144B/zh active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106398884A (zh) * | 2016-08-31 | 2017-02-15 | 江苏可兰素汽车环保科技有限公司 | 一种柴油机doc/poc清洗再生剂的制备方法 |
| CN108085169A (zh) * | 2017-12-28 | 2018-05-29 | 江苏可兰素汽车环保科技有限公司 | 一种柴油机dpf清洗再生剂及其应用 |
| CN108165379A (zh) * | 2017-12-28 | 2018-06-15 | 江苏可兰素汽车环保科技有限公司 | 一种柴油机dpf清洗再生剂及其制备方法 |
| CN108798833A (zh) * | 2018-05-25 | 2018-11-13 | 上海汽车集团股份有限公司 | 颗粒捕捉器灰分累积模型的建模方法 |
| CN109370787A (zh) * | 2018-10-23 | 2019-02-22 | 武汉布朗环境能源有限公司 | 一种机动车尾气处理系统柴油颗粒捕集器dpf清洗剂 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN110846144A (zh) | 2020-02-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108085169B (zh) | 一种柴油机dpf清洗再生剂及其应用 | |
| CN110846144B (zh) | 柴油颗粒捕集器灰分清洗液及其制备方法 | |
| CN101932803B (zh) | 执行scr和egr的排气系统 | |
| JP5372781B2 (ja) | シアヌール酸類に基づくデポジットの形成を抑える方法 | |
| CN103688033A (zh) | 用于减少内燃机排气中的氮氧化物和硫氧化物的方法 | |
| CN108165379A (zh) | 一种柴油机dpf清洗再生剂及其制备方法 | |
| CN101307705A (zh) | 一种分级式颗粒捕集装置及其再生方法 | |
| CN105586158B (zh) | 一种汽车三元催化水基清洗剂 | |
| CN106391143B (zh) | 一种柴油机doc/poc清洗再生剂及其应用 | |
| CN106398914A (zh) | 一种用于清除柴油机scr后处理系统沉积物的清洗再生剂 | |
| CN104128212A (zh) | Scr脱硝催化剂失活修复剂及其失活再生工艺 | |
| CN106398884A (zh) | 一种柴油机doc/poc清洗再生剂的制备方法 | |
| KR102360435B1 (ko) | 배기가스 정화 장치 및 배기가스 정화 방법 | |
| CN114317045B (zh) | 一种用于柴油车颗粒捕集器再生添加剂及其制备方法和应用 | |
| CN114478654B (zh) | 一种二茂铁-卟啉金属配合物的制备方法、二茂铁-卟啉金属配合物及含双金属燃油添加剂 | |
| CN103331140A (zh) | 脱汞吸附剂及其制备方法 | |
| CN107674767B (zh) | 汽车三元催化器清洗剂及其制备方法 | |
| CN110242393A (zh) | 一种免拆卸水洗颗粒捕集器 | |
| CN110043348B (zh) | 一种防汽车尾气扩散的尾气净化系统及其工作方法 | |
| CN209925064U (zh) | 一种防汽车尾气扩散的尾气净化装置 | |
| CN109731595B (zh) | 柴油车颗粒物捕集器用催化剂及其制备方法 | |
| CN103742233A (zh) | 一种颗粒捕集器的再生方法 | |
| CN209892299U (zh) | 一种甲醇为外加能源实现颗粒捕集器再生的系统 | |
| CN112210448A (zh) | 汽车三元催化器的清洗剂 | |
| CN115595216A (zh) | 一种柴油机高效且免损涂层dpf清洗剂及其制备方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |