CN110699193A - Efficient hand-protecting liquid detergent - Google Patents
Efficient hand-protecting liquid detergent Download PDFInfo
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- CN110699193A CN110699193A CN201910990042.7A CN201910990042A CN110699193A CN 110699193 A CN110699193 A CN 110699193A CN 201910990042 A CN201910990042 A CN 201910990042A CN 110699193 A CN110699193 A CN 110699193A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B11/00—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
- B05B11/01—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use characterised by the means producing the flow
- B05B11/10—Pump arrangements for transferring the contents from the container to a pump chamber by a sucking effect and forcing the contents out through the dispensing nozzle
- B05B11/1042—Components or details
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3418—Toluene -, xylene -, cumene -, benzene - or naphthalene sulfonates or sulfates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
Abstract
The invention belongs to the technical field of washing products, and particularly relates to a high-efficiency hand-protecting liquid detergent which comprises a liquid detergent bottle for storing the liquid detergent; according to the invention, the citrus essential oil and the green tea extract are added into the liquid detergent, and the citrus essential oil is utilized to calm the central nerve of a human body, relieve the irritability, diminish inflammation and resist bacteria, and improve the mildness of the liquid detergent in use, so that the skin is effectively protected; the effects of antioxidation, free radical removal, antibiosis, detoxification and the like of the green tea extract are utilized, so that the cleaning quality and effect of the liquid detergent are improved; in addition, the containing pipe is arranged on the liquid detergent bottle, and the liquid detergent sprayed by the pressing nozzle is collected through the containing pipe, so that the collected liquid detergent flows downstream into the shell through the pipe wall of the containing pipe under the action of self gravity, unnecessary waste is reduced, and the storage and use effects of the liquid detergent are enhanced.
Description
Technical Field
The invention belongs to the technical field of washing products, and particularly relates to a high-efficiency hand-protecting liquid detergent.
Background
With the development of society, the pace of life of people is faster and faster, and people always seek higher efficiency in the time of dropping. In the aspect of tableware washing, the detergent is a necessary washing article for kitchens, the demand of people is not limited to the common detergent for a long time, along with the continuous improvement of the living standard of people, more and more families for cleaning tableware, fruits and vegetables by adopting the detergent are provided, in addition, most of the tableware detergent contains linear alkyl sodium benzenesulfonate, the irritation is larger, the degreasing capability is stronger, and the skin can be roughened after long-term contact.
And traditional liquid detergent bottle is after using, because press shower nozzle department not have the protection, when liquid detergent bottle drops or other external forces lead to pressing shower nozzle atress extrusion, the liquid detergent in the bottle spout from inside under uncontrollable exogenic action this moment, has not only caused liquid detergent unnecessary extravagant, still makes the inconvenient clearance of spun liquid detergent or child's mistake to eat.
In view of the above, the invention provides the efficient hand-protecting liquid detergent which can effectively enhance the cleaning and skin-protecting effects of the liquid detergent and can be reasonably taken and stored through the liquid detergent bottle.
Disclosure of Invention
In order to make up for the defects of the prior art, the invention provides the efficient hand-protecting liquid detergent which can effectively enhance the cleaning and skin-protecting effects of the liquid detergent and can be reasonably taken and stored through the liquid detergent bottle.
The technical scheme adopted by the invention for solving the technical problems is as follows: the efficient hand-protecting detergent comprises, by mass, 10-20 parts of fatty alcohol-polyoxyethylene ether sodium sulfate, 10-20 parts of alkyl glycoside, 10-20 parts of dodecyl dimethyl betaine, 5-10 parts of coconut diethanol amine fatty acid, 5-10 parts of fatty alcohol-polyoxyethylene ether, 0.1-1.5 parts of sodium dimethyl benzene sulfonate, 1-10 parts of propylene glycol, 0.1-1 part of citrus essential oil, 5-10 parts of particle plastic balls, 0.1-1 part of disodium ethylene diamine tetraacetate, 0.1-1 part of citric acid and 50-58 parts of deionized water; the preparation method of the efficient hand-protecting liquid detergent comprises the following steps:
s1: adding 50-58 parts of metered deionized water, adding 0.1-1 part of disodium ethylene diamine tetraacetate, and starting stirring until the materials are completely dissolved; the disodium ethylene diamine tetraacetate chelates the metal ions in the deionized water, so that the cleaning effect of the detergent is improved;
s2: after the material is completely dissolved in S1; adding 0.1-1.5 parts of sodium dimethyl benzene sulfonate and 1-10 parts of propylene glycol, and continuously stirring until the materials are completely dissolved; mixing the above components;
s3: stirring the added components in S2 until the components are completely dissolved, heating to 40-50 ℃, adding 10-20 parts of fatty alcohol-polyoxyethylene ether sodium sulfate, 10-20 parts of alkyl glycoside, 10-20 parts of dodecyl dimethyl betaine, 5-10 parts of coconut fatty acid diethanol amine, 5-10 parts of fatty alcohol-polyoxyethylene ether, 0.1-1 part of citrus essential oil and 5-10 parts of particle plastic balls, and continuously stirring until the materials are transparent; by adding the citrus essential oil into the liquid detergent, the liquid detergent can calm the central nerve of a human body, relieve the irritability, diminish inflammation and resist bacteria, and improve the mildness of the liquid detergent during use, so that the skin is effectively protected; the friction effect of the detergent with the granular plastic balls during use is utilized, so that the high efficiency and the cleaning quality of the detergent during cleaning are improved;
s4: stirring the added components in S3 until the components are transparent, adjusting the pH value to be approximately equal to 7 by 0.1-1 part of citric acid, continuously stirring to dissolve the components, filtering by a 300-mesh filter screen, and storing in a detergent bottle; by storing the liquid detergent in the liquid detergent bottle, the contact pollution of the liquid detergent and the outside air is reduced, and unnecessary overflow waste can be reduced;
the components of the high-efficiency hand-protecting detergent are described as follows:
sodium fatty alcohol polyoxyethylene ether sulfate: is easy to dissolve in water, has excellent decontamination, wetting, emulsifying, dispersing and foaming performances, good biological interpretation performance and low irritation to skin and eyes.
Alkyl glycoside: can be compounded with various ionic and nonionic surfactants to generate synergistic action, has good foamability, rich, fine and good solubility of foam, good thickening capability and good skin compatibility, obviously improves the mildness of the formula, and is non-toxic, non-irritant and easy to biodegrade.
Dodecyl dimethyl betaine: colorless to light yellow transparent liquid, has excellent stability under acidic and alkaline conditions and good compatibility; has low irritation to skin, good biodegradability, and excellent decontamination, sterilization, softness, antistatic property, hard water resistance and rust resistance.
Coconut oil fatty acid diethanolamine: the foam is a yellowish to amber viscous liquid, is easy to dissolve in water, and has good functions of foaming, foam stabilization, penetration decontamination, hard water resistance and the like.
Fatty alcohol polyoxyethylene ether: the colorless transparent liquid is white paste, and is used as a nonionic surfactant to play roles in emulsifying, foaming and decontaminating.
Sodium dimethyl benzenesulfonate: white crystalline powder, which can be used in liquid detergents, as coupling agent, hydrotrope, leveling agent, dispersant, and to lower cloud point and viscosity.
Propylene glycol: colorless viscous liquid, nearly tasteless, and slightly sweet, can be used for organic synthesis, and can be used as solvent, dehydrating agent, plasticizer, antifreeze, gas chromatography stationary liquid, etc.
Citrus essential oil: the main component is limonene, which has effects of eliminating phlegm, relieving cough, promoting gastrointestinal peristalsis, tranquilizing central nerve, relieving stress, diminishing inflammation and resisting bacteria.
Granular plastic balls: the granular plastic balls with the diameter of 0.1mm-0.5mm can increase the friction effect of solvent flow.
Disodium ethylene diamine tetraacetate: is white crystal particle or powder, odorless and tasteless, and is an important chelating agent capable of chelating metal ions in solution.
Citric acid: the colorless crystal contains crystal water, has no odor, strong sour taste, and is easy to dissolve in water, and can be used as sour agent, solubilizer, buffer, and antioxidant.
Deionized water: the purified water from which the impurities in the form of ions have been removed, a colorless clear liquid, odorless, tasteless, and of higher purity than distilled water.
Preferably, the preparation process of the citrus essential oil is as follows:
s1: crushing a citrus peel raw material into fine particles with the particle size of 3-5mm by using a crusher, adding a NaCl solution with the mass fraction of 3%, and soaking for 1-3 h; the extraction rate of the essential oil of the orange peel raw material is improved by soaking the raw materials in a NaCl solution;
s2: crushing the raw materials in S1, putting the raw materials mixed with NaCl solution into a distillation device for extracting essential oil, and collecting fractions;
s3: extracting and collecting the essential oil in S2, placing the essential oil in a high-speed centrifuge for centrifugal separation to remove most impurities in the essential oil, adding absolute ethyl alcohol and sodium sulfate water into the centrifuged essential oil, placing the essential oil in a refrigerator for 24 hours, and performing deep purification to obtain the citrus essential oil; and other impurities in the deeply purified citrus essential oil are reduced, so that the damage or reaction of the impurities to the components of the liquid detergent, which results in the failure of the components of the liquid detergent, is reduced.
Preferably, the high-efficiency hand-protecting liquid detergent also comprises 10-20 parts of green tea extract, wherein the green tea extract mainly comprises tea polyphenol; the tea polyphenol has the effects of resisting oxidation, scavenging free radicals, resisting bacteria, clearing away toxic materials, etc.; the green tea extract can be combined with other components of the liquid detergent, so that the damage to the skin of a human hand caused by the liquid detergent is reduced while the cleaning effect of the liquid detergent is enhanced, meanwhile, the green tea extract is added, so that the liquid detergent has bitter taste, the mistaken eating of children is reduced, and the safety of the liquid detergent is enhanced.
Preferably, the liquid detergent bottle comprises a shell, a bottle cap and a pressing nozzle, the bottle cap is positioned at the top end of the shell, and the pressing nozzle is installed on the bottle cap; the top end of the shell is connected with an elastic containing pipe, the bottom end of the containing pipe is communicated with the inside of the shell, the top end of the containing pipe is connected to the top surface of the shell in an upward bending shape through an elastic connecting rope, and the top end of the containing pipe is lower than the top end of the pressing spray head; the inner wall of the top end of the containing pipe is provided with elastic membranes which are uniformly distributed in a ring shape; when the bottle is in operation, after the traditional liquid detergent bottle is used, because the pressing nozzle is not protected, when the liquid detergent bottle drops or other external forces cause the pressing nozzle to be extruded under stress, the liquid detergent in the bottle is sprayed out from the inside under the action of uncontrollable external force, which not only causes unnecessary waste of the liquid detergent, but also causes inconvenience in cleaning the sprayed liquid detergent or children to eat by mistake, when the liquid detergent is not used for a long time and the pressing nozzle is locked, when the pressing nozzle is rotated and extruded, because the residual liquid detergent exists in the tube at the bottom of the pressing nozzle, the pressing nozzle can spray out a part of liquid detergent in the locking process, unnecessary waste is caused, time and labor are wasted when the pressing nozzle is locked and unscrewed for a long time, and the pressing nozzle is damaged, so that the storage and the use of the liquid detergent are influenced; the liquid detergent bottle is characterized in that a containing pipe is arranged at the top end of a shell, a pressing nozzle is rotated to enable a liquid outlet of the pressing nozzle to be sleeved at the top end of the containing pipe after the pressing nozzle is used, when the pressing nozzle is extruded due to uncontrollable force or locked by pressing and rotating the pressing nozzle artificially, liquid detergent sprayed out of the pressing nozzle flows downstream into the containing pipe and then flows back to the shell with the communicated bottom end from the inner wall of the containing pipe, so that the sprayed liquid detergent is recycled and utilized, unnecessary waste of the liquid detergent is reduced, and before the pressing nozzle is locked, the pressing nozzle is connected with the containing pipe, so that the liquid detergent in a bottom pipe is recycled to the interior of the shell when the pressing nozzle is locked; accomodate the connection rope of managing top connection simultaneously and make to accomodate the pipe top and be in the state of kickup, conveniently spout into to accomodate the detergent liquid on pipe top and through the pipe wall following current to the casing under the effect of self gravity, and accomodate the elastic membrane that the pipe top set up and can effectually seal to accomodating intraduct, thereby reduce external impurity and dust and get into to accomodating intraduct and cause pollution and destruction to the detergent, improved the save quality and the result of use of detergent.
Preferably, the middle part of the containing pipe is composed of a corrugated pipe, the corrugated pipe can stretch along the extending direction of the outer wall folds, and the folds on the inner wall of the corrugated pipe are in smooth arc transition; the during operation, when accomodating the pipe not when user state, make through the ripple fold of extrusion bellows this moment and accomodate a pipe length and shorten, reduce the bellows because of the influence that the use of length overlength caused to the liquid detergent, and when the compression of the smooth circular arc transition's of extrusion bellows inner wall fold department, the inside liquid detergent of fold can be extruded to the bellows fold inner wall that contracts to make things convenient for the liquid detergent to flow back to in the casing, the convenience when having strengthened the liquid detergent and using.
Preferably, the top end of the pressing nozzle and the inner wall of the top end of the containing pipe are respectively provided with a magnet, and the two groups of magnets are opposite in magnetism; the during operation will press the shower nozzle top and when accomodating the pipe top and link to each other, the magnet inter attraction of both inner walls that set up this moment has strengthened the fastening effect of pressing the shower nozzle and accomodating the pipe top, reduces to press the shower nozzle from accomodating the inside drop of pipe under the uncontrollable external force condition to strengthened the stability that the liquid detergent bottle used, further improved the save quality and the result of use of liquid detergent.
The invention has the following beneficial effects:
1. according to the invention, the citrus essential oil and the green tea extract are added into the liquid detergent, and the citrus essential oil is utilized to calm the central nerve of a human body, relieve the irritability, diminish inflammation and resist bacteria, and improve the mildness of the liquid detergent in use, so that the skin is effectively protected; and the effects of antioxidation, free radical removal, antibiosis, detoxification and the like of the green tea extract are utilized, so that the cleaning quality and effect of the liquid detergent are improved.
2. According to the invention, the containing pipe is arranged on the liquid detergent bottle, and the liquid detergent sprayed by the pressing nozzle is collected through the containing pipe, so that the collected liquid detergent flows downstream into the shell through the pipe wall of the containing pipe under the action of self gravity, unnecessary waste is reduced, and the storage and use effects of the liquid detergent are enhanced.
Drawings
The invention will be further explained with reference to the drawings.
FIG. 1 is a diagram of the steps of the preparation method of the present invention;
FIG. 2 is a schematic perspective view of the present invention;
FIG. 3 is a schematic structural view of the present invention;
FIG. 4 is an enlarged view at A in FIG. 3;
FIG. 5 is an enlarged view at B in FIG. 3;
in the figure: the bottle comprises a shell 1, a bottle cap 2, a pressing nozzle 3, a containing pipe 4, an elastic membrane 41, a connecting rope 5, a corrugated pipe 6 and a magnet 7.
Detailed Description
In order to make the technical means, the creation features, the achievement purposes and the effects of the invention easy to understand, the invention is further described with the following embodiments.
As shown in figures 1-5, the efficient hand-protecting detergent disclosed by the invention comprises the main active components, by mass, 10-20 parts of fatty alcohol-polyoxyethylene ether sodium sulfate, 10-20 parts of alkyl glycoside, 10-20 parts of dodecyl dimethyl betaine, 5-10 parts of coconut fatty acid diethanolamine, 5-10 parts of fatty alcohol-polyoxyethylene ether, 0.1-1.5 parts of sodium dimethyl benzene sulfonate, 1-10 parts of propylene glycol, 0.1-1 part of citrus essential oil, 5-10 parts of particle plastic balls, 0.1-1 part of disodium ethylenediamine tetraacetic acid, 0.1-1 part of citric acid and 50-58 parts of deionized water; the preparation method of the efficient hand-protecting liquid detergent comprises the following steps:
s1: adding 50-58 parts of metered deionized water, adding 0.1-1 part of disodium ethylene diamine tetraacetate, and starting stirring until the materials are completely dissolved; the disodium ethylene diamine tetraacetate chelates the metal ions in the deionized water, so that the cleaning effect of the detergent is improved;
s2: after the material is completely dissolved in S1; adding 0.1-1.5 parts of sodium dimethyl benzene sulfonate and 1-10 parts of propylene glycol, and continuously stirring until the materials are completely dissolved; mixing the above components;
s3: stirring the added components in S2 until the components are completely dissolved, heating to 40-50 ℃, adding 10-20 parts of fatty alcohol-polyoxyethylene ether sodium sulfate, 10-20 parts of alkyl glycoside, 10-20 parts of dodecyl dimethyl betaine, 5-10 parts of coconut fatty acid diethanol amine, 5-10 parts of fatty alcohol-polyoxyethylene ether, 0.1-1 part of citrus essential oil and 5-10 parts of particle plastic balls, and continuously stirring until the materials are transparent; by adding the citrus essential oil into the liquid detergent, the liquid detergent can calm the central nerve of a human body, relieve the irritability, diminish inflammation and resist bacteria, and improve the mildness of the liquid detergent during use, so that the skin is effectively protected; the friction effect of the detergent with the granular plastic balls during use is utilized, so that the high efficiency and the cleaning quality of the detergent during cleaning are improved;
s4: stirring the added components in S3 until the components are transparent, adjusting the pH value to be approximately equal to 7 by 0.1-1 part of citric acid, continuously stirring to dissolve the components, filtering by a 300-mesh filter screen, and storing in a detergent bottle; by storing the liquid detergent in the liquid detergent bottle, the contact pollution of the liquid detergent and the outside air is reduced, and unnecessary overflow waste can be reduced;
the components of the high-efficiency hand-protecting detergent are described as follows:
sodium fatty alcohol polyoxyethylene ether sulfate: is easy to dissolve in water, has excellent decontamination, wetting, emulsifying, dispersing and foaming performances, good biological interpretation performance and low irritation to skin and eyes.
Alkyl glycoside: can be compounded with various ionic and nonionic surfactants to generate synergistic action, has good foamability, rich, fine and good solubility of foam, good thickening capability and good skin compatibility, obviously improves the mildness of the formula, and is non-toxic, non-irritant and easy to biodegrade.
Dodecyl dimethyl betaine: colorless to light yellow transparent liquid, has excellent stability under acidic and alkaline conditions and good compatibility; has low irritation to skin, good biodegradability, and excellent decontamination, sterilization, softness, antistatic property, hard water resistance and rust resistance.
Coconut oil fatty acid diethanolamine: the foam is a yellowish to amber viscous liquid, is easy to dissolve in water, and has good functions of foaming, foam stabilization, penetration decontamination, hard water resistance and the like.
Fatty alcohol polyoxyethylene ether: the colorless transparent liquid is white paste, and is used as a nonionic surfactant to play roles in emulsifying, foaming and decontaminating.
Sodium dimethyl benzenesulfonate: white crystalline powder, which can be used in liquid detergents, as coupling agent, hydrotrope, leveling agent, dispersant, and to lower cloud point and viscosity.
Propylene glycol: colorless viscous liquid, nearly tasteless, and slightly sweet, can be used for organic synthesis, and can be used as solvent, dehydrating agent, plasticizer, antifreeze, gas chromatography stationary liquid, etc.
Citrus essential oil: the main component is limonene, which has effects of eliminating phlegm, relieving cough, promoting gastrointestinal peristalsis, tranquilizing central nerve, relieving stress, diminishing inflammation and resisting bacteria.
Granular plastic balls: the granular plastic balls with the diameter of 0.1mm-0.5mm can increase the friction effect of solvent flow.
Disodium ethylene diamine tetraacetate: is white crystal particle or powder, odorless and tasteless, and is an important chelating agent capable of chelating metal ions in solution.
Citric acid: the colorless crystal contains crystal water, has no odor, strong sour taste, and is easy to dissolve in water, and can be used as sour agent, solubilizer, buffer, and antioxidant.
Deionized water: the purified water from which the impurities in the form of ions have been removed, a colorless clear liquid, odorless, tasteless, and of higher purity than distilled water.
As an embodiment of the present invention, the citrus essential oil is prepared by the following steps:
s1: crushing a citrus peel raw material into fine particles with the particle size of 3-5mm by using a crusher, adding a NaCl solution with the mass fraction of 3%, and soaking for 1-3 h; the extraction rate of the essential oil of the orange peel raw material is improved by soaking the raw materials in a NaCl solution;
s2: crushing the raw materials in S1, putting the raw materials mixed with NaCl solution into a distillation device for extracting essential oil, and collecting fractions;
s3: extracting and collecting the essential oil in S2, placing the essential oil in a high-speed centrifuge for centrifugal separation to remove most impurities in the essential oil, adding absolute ethyl alcohol and sodium sulfate water into the centrifuged essential oil, placing the essential oil in a refrigerator for 24 hours, and performing deep purification to obtain the citrus essential oil; and other impurities in the deeply purified citrus essential oil are reduced, so that the damage or reaction of the impurities to the components of the liquid detergent, which results in the failure of the components of the liquid detergent, is reduced.
As an embodiment of the invention, the high-efficiency hand-care detergent further comprises 10-20 parts of green tea extract, wherein the green tea extract mainly comprises tea polyphenol; the tea polyphenol has the effects of resisting oxidation, scavenging free radicals, resisting bacteria, clearing away toxic materials, etc.; the green tea extract can be combined with other components of the liquid detergent, so that the damage to the skin of a human hand caused by the liquid detergent is reduced while the cleaning effect of the liquid detergent is enhanced, meanwhile, the green tea extract is added, so that the liquid detergent has bitter taste, the mistaken eating of children is reduced, and the safety of the liquid detergent is enhanced.
As an embodiment of the invention, the liquid detergent bottle comprises a shell 1, a bottle cap 2 and a pressing nozzle 3, wherein the bottle cap 2 is positioned at the top end of the shell 1, and the pressing nozzle 3 is arranged on the bottle cap 2; the top end of the shell 1 is connected with an elastic containing pipe 4, the bottom end of the containing pipe 4 is communicated with the inside of the shell 1, the top end of the containing pipe 4 is connected to the top surface of the shell 1 in an upward bending shape through an elastic connecting rope 5, and the top end of the containing pipe 4 is lower than the top end of the pressing nozzle 3; the inner wall of the top end of the containing pipe 4 is provided with elastic membranes 41 which are uniformly distributed in a ring shape; when the bottle is in operation, after the traditional liquid detergent bottle is used, because the pressing nozzle 3 is not protected, when the liquid detergent bottle drops or other external forces cause the pressing nozzle 3 to be extruded under stress, the liquid detergent in the bottle is sprayed out from the inside under the action of uncontrollable external force, which not only causes unnecessary waste of the liquid detergent, but also causes inconvenience in cleaning the sprayed liquid detergent or children's mistaken eating, when the liquid detergent is not used for a long time and the pressing nozzle 3 is locked, when the pressing nozzle 3 is rotated and extruded, because the residual liquid detergent exists in the tube at the bottom of the pressing nozzle 3, a part of the liquid detergent is sprayed out by the pressing nozzle 3 in the locking process, unnecessary waste is caused, time and labor are wasted when the pressing nozzle 3 is locked and unscrewed for a long time, and the pressing nozzle 3 is damaged, so that the storage and the use of the liquid detergent are influenced; the containing pipe 4 is arranged at the top end of the shell 1, after the pressing nozzle 3 is used, the pressing nozzle 3 is rotated to enable a liquid outlet of the pressing nozzle 3 to be sleeved at the top end of the containing pipe 4, when the pressing nozzle 3 is extruded due to uncontrollable force or the pressing nozzle 3 is locked through pressing rotation manually, the detergent sprayed from the pressing nozzle 3 flows downstream into the containing pipe 4 at the moment, and then flows back to the shell 1 communicated with the bottom end from the inner wall of the containing pipe 4, so that the sprayed detergent is recycled and utilized, unnecessary waste of the detergent is reduced, and before the pressing nozzle 3 is locked, the pressing nozzle 3 is connected with the containing pipe 4, so that the detergent in the bottom pipe is recycled into the shell 1 when the pressing nozzle 3 is locked; accomodate simultaneously and manage 4 top connections of 4 connecting ropes 5 make and accomodate 4 tops of pipe and be in the state of kickup, conveniently spout into the detergent seminal fluid of accomodating 4 tops under the effect of self gravity through the pipe wall following current to casing 1 in, and accomodate the elastic membrane 41 that 4 tops of pipe set up and can effectually seal taking in 4 insides, thereby reduce external impurity and dust and get into to accomodating 4 insides and cause pollution and destruction to the detergent, thereby the quality of preservation and the result of use of detergent have been improved.
As an embodiment of the present invention, the middle of the storage tube 4 is composed of a corrugated tube 6, the corrugated tube 6 can be extended and retracted along the direction in which the outer wall folds extend, and the folds of the inner wall of the corrugated tube 6 are in smooth arc transition; the during operation, when accomodating pipe 4 not when user state, make through the ripple fold of extrusion bellows 6 this moment and accomodate 4 length shortens, reduce bellows 6 because of the influence that the use of length overlength to the liquid detergent led to the fact, and when the compression of the smooth circular arc transition's of extrusion bellows 6 inner wall fold department, 6 fold inner walls of bellows that tighten can extrude the inside liquid detergent of fold, thereby make things convenient for the liquid detergent to flow back to casing 1 in, the convenience when having strengthened the liquid detergent and using.
As an embodiment of the present invention, the top end of the pressing nozzle 3 and the inner wall of the top end of the accommodating tube 4 are respectively provided with a magnet 7, and the two sets of magnets 7 have opposite magnetism; the during operation is pressing 3 tops of shower nozzle and when accomodating 4 tops and linking to each other, and the magnet 7 inter attraction of both inner walls that set up this moment has strengthened the fastening effect of pressing shower nozzle 3 and accomodating 4 tops, reduces to press shower nozzle 3 from accomodating the inside drop of pipe 4 under the uncontrollable external force condition to the stability of liquid detergent bottle use has been strengthened, has further improved the save quality and the result of use of liquid detergent.
To verify the effect of adding the citrus essential oil and the green tea extract according to the present invention, the following experiments of examples 1 to 4 were carried out by the person skilled in the art.
Example 1
Adding 50 g of metered deionized water, adding 0.2 g of disodium ethylene diamine tetraacetate, and starting stirring until the materials are completely dissolved; adding 1 g of sodium dimethyl benzene sulfonate and 4 g of propylene glycol, and continuously stirring until the materials are completely dissolved; heating to 45 ℃, adding 10 g of fatty alcohol-polyoxyethylene ether sodium sulfate, 12 g of alkyl glycoside, 14 g of dodecyl dimethyl betaine, 6 g of coconut diethanol amine fatty acid, 8 g of fatty alcohol-polyoxyethylene ether and 6 g of particle plastic balls, and continuously stirring until the materials are transparent; adjusting the pH value to be approximately equal to 7 by 0.3 g of citric acid, and continuously stirring to dissolve; the washing liquid is stored in a washing liquid bottle after being filtered by a 300-mesh filter screen, the same amount of washing liquid is extruded by a pressing nozzle extruding the washing liquid bottle, the same amount of washing liquid is used for cleaning 100 dishes adhered with greasy dirt impurities, the time required when 100 dishes are cleaned is calculated, the time for cleaning the dishes is 58 minutes under the condition, the stimulation condition of hands is heavy, and other side effects and adverse reactions are avoided.
Example 2
Adding 50 g of metered deionized water, adding 0.2 g of disodium ethylene diamine tetraacetate, and starting stirring until the materials are completely dissolved; adding 1 g of sodium dimethyl benzene sulfonate and 4 g of propylene glycol, and continuously stirring until the materials are completely dissolved; heating to 45 ℃, adding 10 g of fatty alcohol-polyoxyethylene ether sodium sulfate, 12 g of alkyl glycoside, 14 g of dodecyl dimethyl betaine, 6 g of coconut diethanol amine fatty acid, 8 g of fatty alcohol-polyoxyethylene ether, 0.2 g of citrus essential oil, 10 g of green tea extract and 6 g of particle plastic balls, and continuously stirring until the materials are transparent; adjusting the pH value to be approximately equal to 7 by 0.3 g of citric acid, and continuously stirring to dissolve; the washing liquid is stored in a washing liquid bottle after being filtered by a 300-mesh filter screen, the same amount of washing liquid is extruded by a pressing nozzle extruding the washing liquid bottle, the same amount of washing liquid is used for cleaning 100 dishes adhered with greasy dirt impurities, the time required for cleaning 100 dishes is calculated, the time for cleaning the dishes is 42 minutes under the condition, the hand stimulation condition is light, and other side effects and adverse reactions are avoided.
Example 3
Adding 50 g of metered deionized water, adding 0.2 g of disodium ethylene diamine tetraacetate, and starting stirring until the materials are completely dissolved; adding 1 g of sodium dimethyl benzene sulfonate and 4 g of propylene glycol, and continuously stirring until the materials are completely dissolved; heating to 45 ℃, adding 10 g of fatty alcohol-polyoxyethylene ether sodium sulfate, 12 g of alkyl glycoside, 14 g of dodecyl dimethyl betaine, 6 g of coconut diethanol amine fatty acid, 8 g of fatty alcohol-polyoxyethylene ether, 0.4 g of citrus essential oil, 10 g of green tea extract and 6 g of particle plastic balls, and continuously stirring until the materials are transparent; adjusting the pH value to be approximately equal to 7 by 0.3 g of citric acid, and continuously stirring to dissolve; the washing liquid is stored in a washing liquid bottle after being filtered by a 300-mesh filter screen, the same amount of washing liquid is extruded by a pressing nozzle extruding the washing liquid bottle, the same amount of washing liquid is used for cleaning 100 dishes adhered with greasy dirt impurities, the time required when 100 dishes are cleaned is calculated, the time for cleaning the dishes is 40 minutes under the condition, the hand stimulation condition is good, and other side effects and adverse reactions are avoided.
Example 4
Adding 50 g of metered deionized water, adding 0.2 g of disodium ethylene diamine tetraacetate, and starting stirring until the materials are completely dissolved; adding 1 g of sodium dimethyl benzene sulfonate and 4 g of propylene glycol, and continuously stirring until the materials are completely dissolved; heating to 45 ℃, adding 10 g of fatty alcohol-polyoxyethylene ether sodium sulfate, 12 g of alkyl glycoside, 14 g of dodecyl dimethyl betaine, 6 g of coconut diethanol amine fatty acid, 8 g of fatty alcohol-polyoxyethylene ether, 0.2 g of citrus essential oil, 12 g of green tea extract and 6 g of particle plastic balls, and continuously stirring until the materials are transparent; adjusting the pH value to be approximately equal to 7 by 0.3 g of citric acid, and continuously stirring to dissolve; the washing liquid is stored in a washing liquid bottle after being filtered by a 300-mesh filter screen, the same amount of washing liquid is extruded by a pressing nozzle of the extrusion washing liquid bottle, the same amount of washing liquid is used for cleaning 100 dishes adhered with greasy dirt impurities, the time required for cleaning 100 dishes is calculated, the cleaning time of the dishes is 41 minutes under the condition, the hand stimulation condition is light, and other side effects and adverse reactions are avoided.
Table one
The table I shows that the addition of the citrus essential oil and the green tea extract into the components of the detergent can effectively improve the cleaning efficiency of the detergent, effectively reduce the hand irritation of the detergent in the cleaning process, and increase the cleaning efficiency and the hand protection effect of the detergent along with the increase of the components of the citrus essential oil and the green tea extract under the condition of ensuring that the dosages of disodium ethylene diamine tetraacetate, sodium dimethyl benzene sulfonate, propylene glycol, sodium fatty alcohol polyoxyethylene ether sulfate, alkyl glycoside, dodecyl dimethyl betaine, diethanol cocoanut fatty acid, fatty alcohol polyoxyethylene ether and particle plastic balls are not changed.
The foregoing illustrates and describes the principles, general features, and advantages of the present invention. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are given by way of illustration of the principles of the present invention, and that various changes and modifications may be made without departing from the spirit and scope of the invention as defined by the appended claims. The scope of the invention is defined by the appended claims and equivalents thereof.
Claims (6)
1. A high-efficiency hand-protecting liquid detergent is characterized in that: the main active components of the high-efficiency hand-protecting detergent comprise, by mass, 10-20 parts of fatty alcohol-polyoxyethylene ether sodium sulfate, 10-20 parts of alkyl glycoside, 10-20 parts of dodecyl dimethyl betaine, 5-10 parts of coconut diethanol amine fatty acid, 5-10 parts of fatty alcohol-polyoxyethylene ether, 0.1-1.5 parts of dimethyl benzene sulfonate, 1-10 parts of propylene glycol, 0.1-1 part of citrus essential oil, 5-10 parts of particle plastic balls, 0.1-1 part of disodium ethylene diamine tetraacetate, 0.1-1 part of citric acid and 50-58 parts of deionized water; the preparation method of the efficient hand-protecting liquid detergent comprises the following steps:
s1: adding 50-58 parts of metered deionized water, adding 0.1-1 part of disodium ethylene diamine tetraacetate, and starting stirring until the materials are completely dissolved;
s2: after the material is completely dissolved in S1; adding 0.1-1.5 parts of sodium dimethyl benzene sulfonate and 1-10 parts of propylene glycol, and continuously stirring until the materials are completely dissolved;
s3: stirring the added components in S2 until the components are completely dissolved, heating to 40-50 ℃, adding 10-20 parts of fatty alcohol-polyoxyethylene ether sodium sulfate, 10-20 parts of alkyl glycoside, 10-20 parts of dodecyl dimethyl betaine, 5-10 parts of coconut fatty acid diethanol amine, 5-10 parts of fatty alcohol-polyoxyethylene ether, 0.1-1 part of citrus essential oil and 5-10 parts of particle plastic balls, and continuously stirring until the materials are transparent;
s4: after the components added in S3 are stirred until the components are transparent, 0.1-1 part of citric acid is used for adjusting the pH value to be approximately equal to 7, the components are continuously stirred to be dissolved, and the components are filtered by a 300-mesh filter screen and stored in a detergent bottle.
2. The efficient hand-protecting detergent as claimed in claim 1, wherein the citrus essential oil is prepared by the following steps:
s1: crushing a citrus peel raw material into fine particles with the particle size of 3-5mm by using a crusher, adding a NaCl solution with the mass fraction of 3%, and soaking for 1-3 h;
s2: crushing the raw materials in S1, putting the raw materials mixed with NaCl solution into a distillation device for extracting essential oil, and collecting fractions;
s3: extracting and collecting the essential oil in S2, centrifuging the essential oil in a high-speed centrifuge to remove most impurities in the essential oil, adding anhydrous ethanol and sodium sulfate water into the centrifuged essential oil, placing in a refrigerator for 24h, and deeply purifying to obtain the citrus essential oil.
3. The efficient hand-protecting liquid detergent as claimed in claim 1, which is characterized in that: the efficient hand-protecting liquid detergent also comprises 10-20 parts of green tea extracts, wherein the green tea extracts mainly comprise tea polyphenol; the tea polyphenols have antioxidant, free radical scavenging, antibacterial, and toxic materials clearing away effects.
4. The efficient hand-protecting liquid detergent as claimed in claim 1, which is characterized in that: the liquid detergent bottle comprises a shell (1), a bottle cap (2) and a pressing spray head (3), wherein the bottle cap (2) is positioned at the top end of the shell (1), and the pressing spray head (3) is installed on the bottle cap (2); the top end of the shell (1) is connected with an elastic containing pipe (4), the bottom end of the containing pipe (4) is communicated with the inside of the shell (1), the top end of the containing pipe (4) is connected to the top surface of the shell (1) in an upward bending shape through an elastic connecting rope (5), and the top end of the containing pipe (4) is lower than the top end of the pressing nozzle (3); and the inner wall of the top end of the accommodating pipe (4) is provided with an annular and uniformly distributed elastic membrane (41).
5. The efficient hand-protecting liquid detergent as claimed in claim 4, which is characterized in that: accomodate pipe (4) middle part and constitute by bellows (6), bellows (6) can stretch out and draw back along the direction that the outer wall fold extends, the fold department of bellows (6) inner wall is smooth circular arc transition.
6. The efficient hand-protecting liquid detergent as claimed in claim 4, which is characterized in that: the inner walls of the top end of the pressing nozzle (3) and the top end of the containing pipe (4) are respectively provided with a magnet (7), and the two groups of magnets (7) are opposite in magnetism.
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