CN110670362A - Green nontoxic mosquito-proof fabric and preparation method thereof - Google Patents

Green nontoxic mosquito-proof fabric and preparation method thereof Download PDF

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Publication number
CN110670362A
CN110670362A CN201910971698.4A CN201910971698A CN110670362A CN 110670362 A CN110670362 A CN 110670362A CN 201910971698 A CN201910971698 A CN 201910971698A CN 110670362 A CN110670362 A CN 110670362A
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Prior art keywords
mosquito
fabric
oil extract
essential oil
finishing agent
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CN201910971698.4A
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Inventor
蔡燕霖
刘茜
张璐
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Suzhou Weipu Worsted Technology Co Ltd
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Suzhou Weipu Worsted Technology Co Ltd
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144Alcohols; Metal alcoholates
    • D06M13/148Polyalcohols, e.g. glycerol or glucose
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224Esters of carboxylic acids; Esters of carbonic acid
    • D06M13/2246Esters of unsaturated carboxylic acids
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03Polysaccharides or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32Polyesters

Abstract

The invention relates to a green nontoxic anti-mosquito fabric and a preparation method thereof, the anti-mosquito fabric comprises a fabric body and an anti-mosquito thin film layer formed on the surface of the fabric body, and the anti-mosquito thin film layer is a porous thin film layer formed by spraying an anti-mosquito finishing agent onto the surface of the fabric body through atomization and then drying. The anti-mosquito fabric comprises a fabric body and an anti-mosquito thin film layer formed on the surface of the fabric body, wherein the anti-mosquito thin film layer is formed by spraying an anti-mosquito finishing agent onto the surface of the fabric body in an atomizing mode and then drying the fabric body, and the anti-mosquito thin film layer formed in the atomizing mode is a porous thin film layer, so that the fabric has a quick killing effect on mosquitoes and has a good anti-mosquito effect.

Description

Green nontoxic mosquito-proof fabric and preparation method thereof
Technical Field
The invention belongs to the technical field of textiles, and particularly relates to a green nontoxic mosquito-proof fabric and a preparation method thereof.
Background
In hot summer, the phenomenon of mosquito bite is very annoying to people. When a mosquito bites, some saliva is injected into the wound to prevent blood from coagulating, and pathogens are transmitted. Skin is red and swollen slightly after being bitten by mosquitoes, and diseases are infected seriously. Common mosquito-borne diseases in China include malaria, filariasis, dengue fever and epidemic encephalitis B. Mosquito-borne diseases such as yellow fever, West Nile fever, eastern equine encephalitis, Western equine encephalitis, Venezuelan equine encephalitis, St.Louis encephalitis, and Kikungunya fever are also prevalent abroad. In asia, africa and america, more than 100 million deaths are infected annually with malaria due to mosquito bites. Therefore, the mosquito control work has very important significance.
The conventional method for preventing mosquitoes comprises the following steps: mosquito nets, fly traps, smoking, and applying mosquito repellent liquid or toilet water, and the mosquito repellent effect of the mosquito nets and the fly traps obviously has certain operational troubles and risks. Some liquids are directly in contact with the skin and cause certain irritation and irritation, especially to children. Therefore, the research on the anti-mosquito finishing of the textile is of great significance, and the current domestic method for developing the anti-mosquito fabric is to design a complex structural fabric, or to use the processes of dipping, padding and the like to carry out after-finishing, or to use microcapsule water suspension to soak the fabric and the like.
For example, the mosquito-proof antibacterial textile fabric and the preparation method thereof disclosed in chinese patent CN109594333A, the preparation method of the mosquito-proof antibacterial textile fabric mentioned in the patent includes: weaving to obtain cloth, soaking the cloth in an anti-ultraviolet finishing agent and a mosquito-repellent finishing agent for 30-70 min, then baking at 70-80 ℃, and finally performing sizing treatment to obtain the mosquito-repellent antibacterial textile fabric.
The fabric treatment mentioned in the patent adopts the steps of adding water into the microcapsule finishing agent and uniformly stirring to form mosquito-proof microcapsule finishing liquid, and then placing the fabric into the finishing liquid at the temperature of 50-80 ℃ to be soaked for 40-80 min to prepare the mosquito-proof fabric.
However, the fabric prepared by the method has weak mosquito repelling durability and poor air permeability, the complex structural fabric is not resistant to water washing, and the insect prevention effect of the fabric is poor after the fabric is washed for many times. And the mosquito-proof fabric is originally used in summer and summer with hot weather, if the fabric with poor ventilation is used for preventing mosquitoes, although the mosquito-proof effect is achieved, the mosquito-proof fabric can cause the user to be extremely uncomfortable.
On the other hand, a large amount of water is used in the process of fabric impregnation, so that the waste of water resources is caused, and the wearability of the fabric after impregnation finishing is greatly influenced.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provide an anti-mosquito fabric with good anti-mosquito effect and high air permeability and a preparation method thereof.
In order to achieve the purpose, the technical scheme adopted by the invention is as follows:
the utility model provides a mosquito-proof worm fabric, mosquito-proof worm fabric includes that fabric body and formation are in the mosquito-proof worm thin layer on fabric body surface, mosquito-proof worm thin layer is through spouting mosquito-proof worm finishing agent extremely through atomizing the surface of fabric body, then the porous thin layer that the stoving formed.
According to some embodiments of the invention, the raw materials of the anti-mosquito finishing agent comprise pyrethroid compounds or beta-cyclodextrin, p-menthane-3, 8-diol and plant essential oil extracts, and the mass ratio of the pyrethroid compounds or the beta-cyclodextrin, the p-menthane-3, 8-diol, the plant essential oil extracts and polyurethane is 5-20: 20-40: 10-70: 5 to 40.
According to some embodiments of the invention, the plant essential oil extract is one or a combination of lemon eucalyptus oil extract, lavender essential oil extract and aloe essential oil extract.
According to some embodiments of the invention, the pyrethroid is permethrin (also known as permethrin).
According to some embodiments of the invention, the anti-mosquito finishing agent is prepared by the following steps: firstly, dissolving polyurethane in an acetone aqueous solution, then adding p-menthane-3, 8-diol, a pyrethroid compound or beta-cyclodextrin into the mixed solution, uniformly stirring, and finally adding a plant essential oil extract to obtain the anti-mosquito finishing agent.
According to some embodiments of the invention, the concentration of the acetone aqueous solution is 40-60%, and the adding mass ratio of the polyurethane to the acetone aqueous solution is 1: 8 to 20.
The polyurethane is a thermoplastic polyurethane elastomer (TPU).
According to some embodiments of the invention, the drying temperature is 80-120 ℃.
According to some embodiments of the invention, the fabric body is made of natural and/or chemical fibers, either woven or non-woven.
According to some embodiments of the present invention, the two side surfaces of the fabric body are respectively formed with the anti-mosquito thin film layers.
The invention adopts another technical scheme that: the preparation method of the anti-mosquito fabric comprises the following steps:
(1) preparing an anti-mosquito finishing agent:
firstly, dissolving polyurethane in an acetone aqueous solution, then adding p-menthane-3, 8-diol, a pyrethroid compound or beta-cyclodextrin into the mixed solution, uniformly stirring, and finally adding a plant essential oil extract to obtain the anti-mosquito finishing agent;
(2) preparing the anti-mosquito fabric:
the natural fiber and the chemical fiber are made into a fabric body through weaving or non-weaving, then the anti-mosquito finishing agent is sprayed to the surface of the fabric body through atomization and is dried, an anti-mosquito thin film layer is formed on the surface of the fabric body, and therefore the anti-mosquito fabric is obtained.
The atomization technique used in the present invention includes, but is not limited to, high pressure gas flow liquid atomization technique, steam atomization technique, etc.
The spraying amount of the atomized spraying can be determined according to the thickness of the fabric and the gram weight of square meters, and is generally 0.04-0.08 kg/m2
Due to the application of the technical scheme, compared with the prior art, the invention has the following advantages:
the anti-mosquito fabric comprises a fabric body and an anti-mosquito thin film layer formed on the surface of the fabric body, wherein the anti-mosquito thin film layer is formed by spraying an anti-mosquito finishing agent onto the surface of the fabric body in an atomizing mode and then drying the fabric body, and the anti-mosquito thin film layer formed in the atomizing mode is a porous thin film layer, so that the fabric has a quick mosquito killing effect and a good anti-mosquito effect.
Meanwhile, the anti-mosquito fabric has no stimulation and allergy to skin, is safe and nontoxic to human bodies, and can be widely applied to the fields of outdoor textiles such as tents, sportswear and the like, and textiles for protection functions such as home textiles and pets.
Detailed Description
Specific embodiments of the present invention will be described in further detail with reference to specific examples, but the scope of the present invention is not limited thereto.
Example 1
The green nontoxic mosquito-proof fabric provided by the embodiment is prepared by the following method:
(1) preparing anti-mosquito finishing agent
Dissolving 15 parts of polyurethane particles into 120 parts of acetone aqueous solution (water temperature is 30 ℃, and the concentration of acetone is 50%), sequentially adding 30 parts of p-menthane-3, 8-diol and 10 parts of permethrin into the mixed solution, uniformly stirring, and then adding 45 parts of plant essential oil extract into the mixed solution to obtain the anti-mosquito finishing agent, wherein the plant essential oil extract is a eucalyptus citriodora leaf essential oil extract, a lavender essential oil extract and an aloe essential oil extract according to the mass ratio of 15: 15: 15 in combination.
(2) Preparation of mosquito-proof fabric
Weaving cotton fibers and polyester fibers into a fabric body according to the mass ratio of 2:3, and then quickly and uniformly spraying the anti-mosquito finishing agent prepared in the step (1) onto the surface of the fabric body through a spray head by using a high-pressure airflow auxiliary liquid atomization technology with the pressure value of 0.5MPa (single-side spraying is adopted), wherein the spraying amount is 0.05kg/m2And then drying the fabric body for 20min at the temperature of 80 ℃ by using an oven to form a firm anti-mosquito porous film layer on the surface of the fabric body, thereby obtaining the green, nontoxic and highly breathable anti-mosquito fabric.
Example 2
The preparation method of the green nontoxic anti-mosquito fabric provided by the embodiment is the same as that of the embodiment 1, and the difference is that: beta-cyclodextrin is used instead of pyrethroid compounds.
Comparative example 1
The anti-mosquito fabric provided by the comparative example has the following difference that the anti-mosquito finishing agent and the fabric body adopted by the anti-mosquito fabric are the same as those in embodiment 1: and (3) soaking the fabric body in the anti-mosquito finishing agent for 60min, and then drying at 80 ℃.
The mosquito-repellent fabrics of example 1 and comparative example 1 were subjected to mosquito-repellent effect and air permeability tests, the results of which are shown in tables 1 and 2, wherein,
the mosquito prevention effect test method comprises the following steps:
the fabric that will prevent mosquito fabric and not prevent mosquito arrangement makes the ribbon respectively and wears ankle department, wrist department, the neck at 2 testers (in this experiment the tester is bitten by the mosquito, and the skin can be red swelling and itch), lets 20 mosquitoes and 2 testers locate one room (length 24 hours) altogether, later calculates the mosquito-proof effect: s ═ 100% (1-mosquito bite trace a on the tester wearing the mosquito repellent fabric/mosquito bite trace B on the tester wearing the fabric without mosquito repellent finish).
The air permeability test method comprises the following steps: and (4) directly testing by using a digital fabric air permeability tester.
Table 1 shows the mosquito repellent effect test results of example 1 and comparative example 1
Table 2 shows the results of the permeability test of example 1 and comparative example 1
Figure BDA0002232306180000042
Samples No. 1-6 in the examples were taken from different positions of the same fabric, and samples No. 1-6 in comparative example 1 were taken from different positions of the same fabric.
The above embodiments are merely illustrative of the technical ideas and features of the present invention, and the purpose thereof is to enable those skilled in the art to understand the contents of the present invention and implement the present invention, and not to limit the protection scope of the present invention. All equivalent changes and modifications made according to the spirit of the present invention should be covered within the protection scope of the present invention.

Claims (10)

1. A mosquito-proof worm fabric which characterized in that: mosquito-proof worm fabric includes the fabric body and forms the mosquito-proof worm thin layer on fabric body surface, mosquito-proof worm thin layer is through spouting mosquito-proof worm finish agent extremely through atomizing the surface of fabric body, then the porous thin layer that the stoving formed.
2. The anti-mosquito fabric according to claim 1, wherein the raw materials of the anti-mosquito finishing agent comprise pyrethroid compounds or beta-cyclodextrin, p-menthane-3, 8-diol, plant essential oil extract and polyurethane, and the mass ratio of the pyrethroid compounds or beta-cyclodextrin, p-menthane-3, 8-diol, plant essential oil extract and polyurethane is 5 ~ 20: 20 ~ 40: 10 ~ 70: 5 ~ 40.
3. A mosquito repellent fabric according to claim 2, characterized in that: the plant essential oil extract is one or more of a lemon eucalyptus oil extract, a lavender essential oil extract and an aloe essential oil extract.
4. A mosquito repellent fabric according to claim 2, characterized in that: the pyrethroid is permethrin.
5. The anti-mosquito fabric according to claim 2, wherein the preparation method of the anti-mosquito finishing agent is as follows: firstly, polyurethane is dissolved in acetone aqueous solution, then p-menthane-3, 8-diol, pyrethroid compound or beta-cyclodextrin are added into the mixed solution, the mixture is stirred uniformly, and then plant essential oil extract is added to obtain the anti-mosquito finishing agent.
6. An anti-mosquito fabric as claimed in claim 5, wherein the concentration of the acetone aqueous solution is 40 ~ 60%, and the adding mass ratio of the polyurethane to the acetone aqueous solution is 1: 8 ~ 20.
7. The mosquito repellent fabric according to claim 2 or 5, characterized in that: the polyurethane is a thermoplastic polyurethane elastomer.
8. The mosquito-proof fabric according to claim 1, wherein the drying temperature is 80 ~ 120 ℃.
9. A mosquito repellent fabric according to claim 1, characterized in that: the fabric body is made of natural fibers and/or chemical fibers by weaving or non-weaving.
10. A method of preparing a mosquito repellent fabric according to any one of claims 1 ~ 9, comprising the steps of:
(1) preparing an anti-mosquito finishing agent:
firstly, dissolving polyurethane in an acetone aqueous solution, then adding p-menthane-3, 8-diol, a pyrethroid compound or beta-cyclodextrin into the mixed solution, uniformly stirring, and finally adding a plant essential oil extract to obtain the anti-mosquito finishing agent;
(2) preparing the anti-mosquito fabric:
the method comprises the steps of preparing a fabric body from natural fibers and/or chemical fibers through weaving or non-weaving, spraying an anti-mosquito finishing agent to the surface of the fabric body through atomization, drying, and forming an anti-mosquito thin film layer on the surface of the fabric body, so that the anti-mosquito fabric is obtained.
CN201910971698.4A 2019-10-14 2019-10-14 Green nontoxic mosquito-proof fabric and preparation method thereof Pending CN110670362A (en)

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