CN106973958A - A kind of special anti-mosquito agent of textile and preparation method thereof - Google Patents
A kind of special anti-mosquito agent of textile and preparation method thereof Download PDFInfo
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- CN106973958A CN106973958A CN201710199498.2A CN201710199498A CN106973958A CN 106973958 A CN106973958 A CN 106973958A CN 201710199498 A CN201710199498 A CN 201710199498A CN 106973958 A CN106973958 A CN 106973958A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
- A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/22—Lamiaceae or Labiatae [Mint family], e.g. thyme, rosemary, skullcap, selfheal, lavender, perilla, pennyroyal, peppermint or spearmint
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/36—Rutaceae [Rue family], e.g. lime, orange, lemon, corktree or pricklyash
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/40—Liliopsida [monocotyledons]
- A01N65/44—Poaceae or Gramineae [Grass family], e.g. bamboo, lemon grass or citronella grass
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/236—Esters of carboxylic acids; Esters of carbonic acid containing halogen atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/345—Nitriles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/352—Heterocyclic compounds having five-membered heterocyclic rings
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/395—Isocyanates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
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- Engineering & Computer Science (AREA)
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- General Health & Medical Sciences (AREA)
- Plant Pathology (AREA)
- Environmental Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Natural Medicines & Medicinal Plants (AREA)
- Zoology (AREA)
- Wood Science & Technology (AREA)
- Textile Engineering (AREA)
- Dentistry (AREA)
- Mycology (AREA)
- Microbiology (AREA)
- Biotechnology (AREA)
- Pest Control & Pesticides (AREA)
- Chemical & Material Sciences (AREA)
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Abstract
The invention discloses a kind of special anti-mosquito agent of textile, including the following component of fraction meter by weight：0.5 2.0% plants essential oil, 10 20% insecticides, 10 20% surfactants, 30 50% solvents, 5 10% fastness elevators, 10 20% deionized waters；The plants essential oil is at least one of oil of Cymbopogon winterianus, Lavender, tea tree ethereal oil, Geranium Essential, lemon, Peppermint essential oil；The insecticide is at least one of tetramethrin, fluorine chlorine ether chrysanthemum ester, valeric acid cyanogen ether fat, dichloro phenylate fat.The special anti-mosquito agent of textile of the present invention, the effect with more preferable mosquito dispersing all has preferable repellent action to hematophaguses such as mosquito, sand fly, ticks.
Description
Technical field
The present invention relates to anophelifuge preparation field, and in particular to a kind of special anti-mosquito agent of textile and its preparation side
Method.
Background technology
In actual life, especially in hot summer, people are often bitten by mosquito, and these mosquitoes are by connecing
Touch blood of human body and spread disease, influence health.For biting for mosquito, in the prior art, people are usually will be mosquito-proof
Worm agent is directly sprayed onto on skin, has developed some new mosquito-proof methods later, and the utilization anophelifuge such as also having enters to fiber, fabric
Row post processing, or the mosquito-proof medicine of microcapsule coated is used, then it is organized on fiber or fabric face.
At present, the anophelifuge of in the market is varied, but current anophelifuge have the shortcomings that it is more or less.Such as
Have that toxicity, insecticidal spectrum are narrower, the smell is awful.
Application No. 88105917.X, the Chinese invention patent of entitled " high-efficient healthy refined mosquito killer and its preparation method " is public
A kind of high-efficient healthy refined mosquito killer is opened, its main component is base-material agent, mosquito killing agent, mosquito-killing adjuvant, perfume agent etc.
Cooperation is made.The mosquito killer agent main component provided in the invention is the extract solution of fish-bone, tortoise bone and huge legendary turtle bone, safe nothing
Poison, but these materials are mouldy indoors, rot that niff can be distributed, and pollute air, and can only be used for mosquito,
The effect driven and killed is not had for other harmful insects.
CN101187158 discloses what a kind of antimosquito finishing agent was prepared with preparation method and using the mosquito proof finishing agent
Mosquito proof fabric, wherein mosquito proof finishing agent use the compound of class containing dextrin, culicifuge, surfactant, buffer, catalysis
Agent, crosslinking agent composition, by the cavity of dextrin class compound, then regarding culicifuge inclusion as crosslinking with imidazoles resinoid
Agent, adding other appropriate additives just can be made finishing agent.By the aqueous solution of antimosquito finishing agent through padding ,-preliminary drying-is baked
Technique, antimosquito finishing agent can be arranged into cloth, obtain anti-mosquito cloth by Chemical Crosslinking Methods.But this kind of mosquito proof is knitted
Thing is after washing, and anophelifuge is easy to depart from fabric, and mosquito-proof ability can be substantially reduced.
The content of the invention
It is an object of the invention to the problem above for overcoming prior art presence, there is provided a kind of special mosquito proof of textile
Agent, the anophelifuge is safe and environment-friendly, and can all have preferable repellent action to hematophaguses such as mosquito, sand fly, ticks, can be with
Effectively prevent from biting；And it is water-fastness when the anophelifuge handles textile, make processed material mosquito proof effect lasting.
Another object of the present invention is to provide the preparation method of above-mentioned anti-mosquito agent.
To realize above-mentioned technical purpose and the technique effect, the present invention is achieved through the following technical solutions：
A kind of special anti-mosquito agent of textile, including the following component of fraction meter by weight：0.5-2.0% plant essence
Oil, 10-20% insecticides, 10-20% surfactants, 30-50% solvents, 5-10% fastness elevators, 10-20% deionizations
Water；
The plants essential oil is oil of Cymbopogon winterianus, Lavender, tea tree ethereal oil, Geranium Essential, lemon, peppermint essence
At least one of oil.
Oil of Cymbopogon winterianus is extracted from nardgrass plant (Cymbopogon nardus), belongs to grass family lemongrass
Category.Oil of Cymbopogon winterianus is identified a kind of expelling parasite essential oil (especially effective to carrying the mosquito of malaria) very early.It is for pure and fresh
Brains, clean rooms, dermalaxia is set also to have very big benefit；Can be widely used for clean environment insect prevention sterilization, smell improves, can
It is sprayed on house, clothing, footgear or pet.
Lavender is a kind of rare and important natural perfume plant, the essential oil obtained through refining by its flower spike, fragrance delicate fragrance, fragrance
It is pleasant, it can be not only used in daily cosmetics industry, and because lavender has an insecticidal effect in itself, people are generally with smoked
Clothing grass, which is made sachet and is placed in cabinet, carrys out expelling parasite.The volatile oil being extract by lavender, can clean skin with clearing heat and detoxicating
Skin, control oil, freckle removing and whitening, the tender skin of anti-wrinkle, eye haustra -dsipelling livid ring around eye may additionally facilitate the skin care work(such as damaged tissues regeneration recovery
Energy.
Tea tree ethereal oil originates in Australia, is the extract of tea tree.With bactericidal antiphlogistic, convergence pore, treatment cold,
Cough, rhinitis, asthma, the effects such as improving dysmenorrhoea, irregular menstruation and genital infection.Suitable for oiliness and acne-prone skin, treatment
Suppurative wound and burn, tan severely, athlete's foot and dandruff.Clear the head, rejuvenate, anti-depression.
In Geranium Essential containing citronellol, citronellyl formate, loose alkene, gemic acid, Geraniol, terpinol, citral,
Menthones and lot of trace mineral element.Geranium Essential can relieve pain, restrains antibacterial, put in and knit scar, enhancing cytophylaxis function,
Its energy deep layer clean skin, balances sebum secretion, promotes Skin Cell newborn, repair scar, striae of pregnancy, be particularly suitable for use in oily skin
With small pox skin, have to small pox and acne print and alleviate well and eradicating efficacy.Although fish pelargonium is not the most Canon of mosquito repellent
Hand, but oil of Cymbopogon winterianus is together if you arrange in pairs or groups, not only can be with mosquito dispersing, and the phenomenon alleviated and itched can be helped.
Lemon can improve circulatory function, including stimulate circulation, to reduce blood pressure, only nosebleed.It can be with
Strengthen immune system, purify body, improve digestive system function, the group of reducing fat, treatment indigestion and constipation.Lemon
With consoling and alleviating headache and the effect of migraines, by the acidic materials in general physical, to treatment of arthritis and rheumatism
Disease is also helpful.Cleaning acne, cleaning Greasy Skin and hair are additionally aided, and removes dead skin cells.
Peppermint essential oil is the composition that peppermint is distilled by water or subcritical low-temperature extraction goes out.Mint flavored is clearly cooled off oneself, the mind
Rouse oneself, there is the effect of purification air, and this taste mosquito and do not like, it was reported that the repelling effect of Peppermint essential oil is general drives
As many as 10 times of mosquito product.
Preferred scheme is in the present invention, and the insecticide is tetramethrin, fluorine chlorine ether chrysanthemum ester, valeric acid cyanogen ether fat, dichloro
At least one of phenylate fat.
Preferred scheme is in the present invention, and the surfactant is AEO, polyvinyl chloride dehydration mountain
Pears alcohol fatty acid ester, sorbitan carboxylic esterses or phenyl phenol polyethenoxy ether.
Preferred scheme is in the present invention, and the fastness elevator is polyurethanes or toluene di-isocyanate(TDI).
Preferred scheme is in the present invention, and the solvent is diol, derivatives.
Preferred scheme is in the present invention, and the diol, derivatives are glycol monoethyl ether, ethylene glycol monoethyl ether or second two
Alcohol monobutyl ether.
The invention also discloses the preparation method of the special anti-mosquito agent of above-mentioned textile, including the steps：
1) solvent is added into reactor, setting mixing speed is 500-600r/min, stirring at normal temperature；It is subsequently added into desinsection
Agent, 20-30min；
2) surfactant is added into reactor, 30-40 degree is warming up to, 30-40min is stirred；Add plants essential oil,
Keeping temperature is 30-40 degree, stirs 25-50min；Fastness elevator is subsequently added into, 50-60 degree is warming up to, mixing speed is
1000-1200r/min, stirs 60-90min；
3) question response kettle temperature degree is down to 20-30 degree, and adjustment mixing speed to 400-500r/min adds deionized water, treated
Reactor temperature is down to normal temperature, and feeding produces the anti-mosquito agent of the present invention.
It is preferred that, step 2) be：Surfactant is added into reactor, 32-35 degree is warming up to, 35-38min is stirred；
Plants essential oil is added, keeping temperature is 32-35 degree, stirs 35-40min；Fastness elevator is subsequently added into, 55-58 is warming up to
Degree, mixing speed is 1100-1200r/min, stirs 75-80min.
The beneficial effects of the invention are as follows:
The special anti-mosquito agent of textile of the present invention, by introducing oil of Cymbopogon winterianus, Lavender, tea tree in formula
The plants essential oils such as essential oil, Geranium Essential, and define the proportioning of above-mentioned plants essential oil and insecticide so that plants essential oil is with killing
Worm agent produces synergy, adds the effect of mosquito dispersing, all has preferable repellent to hematophaguses such as mosquito, sand fly, ticks
Effect.
The special anti-mosquito agent of textile of the present invention, safety non-toxic environmental protection, the weaving of the anti-mosquito agent processing through the present invention
Product, meet ecological textile Oeko-Tex Standard 100 and Reach laws and regulations requirements.
Through the present invention anti-mosquito agent processing textile, with it is water-fastness the characteristics of, mosquito proof effect is more longlasting.
Described above is only the general introduction of technical solution of the present invention, in order to better understand the technological means of the present invention,
And can be practiced according to the content of specification, described in detail below with presently preferred embodiments of the present invention as after.The tool of the present invention
Body embodiment is shown in detail by following examples.
Embodiment
Below in conjunction with the embodiment of the present invention, technical scheme is clearly and completely described, it is clear that institute
The embodiment of description is only a part of embodiment of the invention, rather than whole embodiments.Based on the embodiment in the present invention,
The every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, belongs to this hair
The scope of bright protection.
In the specific embodiment of the invention, oil of Cymbopogon winterianus is purchased from Jishui County day into perfumery oil factory, and Lavender is purchased from her
The fragrant bio tech ltd of magnificent pure lavender is ploughed, tea tree ethereal oil is purchased from the grand perfumery oil Co., Ltd in Ji'an, fish pelargonium essence
Oil is purchased from Ding Cheng plant perfumes Co., Ltd of Shenzhen, and lemon is purchased from Guo Xin essence and flavoring agents Co., Ltd of Shenzhen, peppermint
Essential oil is purchased from Nantong Menthol Factory Co., Ltd..The essential oil being directed to use with this formula is extracted using the plant way of distillation.
The preparation method of the special anti-mosquito agent of textile in the specific embodiment of the invention, including the steps：
1) solvent is added into reactor, setting mixing speed is 500-600r/min, stirring at normal temperature；It is subsequently added into desinsection
Agent, 20-30min；
2) surfactant is added into reactor, 30-40 degree is warming up to, 30-40min is stirred；Add plants essential oil,
Keeping temperature is 30-40 degree, stirs 25-50min；Fastness elevator is subsequently added into, 50-60 degree is warming up to, mixing speed is
1000-1200r/min, stirs 60-90min；
3) question response kettle temperature degree is down to 20-30 degree, and adjustment mixing speed to 400-500r/min adds deionized water, treated
Reactor temperature is down to normal temperature, and feeding produces the anti-mosquito agent of the present invention.
In the specific embodiment of the invention, the anti-mosquito agent of comparative example is not added with plants essential oil.
Embodiment 1
A kind of special anti-mosquito agent of textile, including the following component of fraction meter by weight：0.80% oil of Cymbopogon winterianus,
6.80% fluorine chlorine ether chrysanthemum ester, 6.2% dichloro phenylate fat, 1.2% AEO, 3.4% polyvinyl chloride
Sorbitan fatty acid ester, 3.4% sorbitan carboxylic esterses, 4.5% phenyl phenol polyethenoxy ether, 45% second two
Alcohol monobutyl ether, 9% polyurethanes, 19.7% deionized water.
Embodiment 2
A kind of special anti-mosquito agent of textile, including the following component of fraction meter by weight：1.2% Lavender,
8% fluorine chlorine ether chrysanthemum ester, 7% tetramethrin, 3% AEO, 2.2% polyvinyl chloride anhydrous sorbitol
Fatty acid ester, 3.2% sorbitan carboxylic esterses, 9.2% phenyl phenol polyethenoxy ether, 45% ethylene glycol monobutyl ether,
8.5% toluene di-isocyanate(TDI), 12.7% deionized water.
Embodiment 3
A kind of special anti-mosquito agent of textile, including the following component of fraction meter by weight：1.5% tea tree ethereal oil,
14.6% tetramethrin, 3.3% AEO, 2.4% polyvinyl chloride sorbitan fatty acid ester,
2.6% sorbitan carboxylic esterses, 10.1% phenyl phenol polyethenoxy ether, 46% ethylene glycol monobutyl ether, 5.9% first
Phenylene diisocyanate, 13.6% deionized water.
Embodiment 4
A kind of special anti-mosquito agent of textile, including the following component of fraction meter by weight：0.8% Geranium Essential,
4% valeric acid cyanogen ether fat, 12% dichloro phenylate fat, 2.3% AEO, 2.9% polyvinyl chloride dehydration
Span, 3.3% sorbitan carboxylic esterses, 11.4% phenyl phenol polyethenoxy ether, 38% ethylene glycol
Monobutyl ether, 6.5% polyurethanes, 18.8% deionized water.
Embodiment 5
A kind of special anti-mosquito agent of textile, including the following component of fraction meter by weight：1.8% lemon,
15.3% fluorine chlorine ether chrysanthemum ester, 4.2% AEO, 2.3% polyvinyl chloride sorbitan fatty acid ester,
2.7% sorbitan carboxylic esterses, 8.4% phenyl phenol polyethenoxy ether, 40% ethylene glycol monobutyl ether, 8% poly- ammonia
Carbamate, 17.3% deionized water.
Embodiment 6
A kind of special anti-mosquito agent of textile, including the following component of fraction meter by weight：1.3% Peppermint essential oil,
14.5% dichloro phenylate fat, 3.6% AEO, 2.4% polyvinyl chloride sorbitan fatty acid ester,
2.4% sorbitan carboxylic esterses, 8.8% phenyl phenol polyethenoxy ether, 43% ethylene glycol monobutyl ether, 5.5% first
Phenylene diisocyanate, 18.5% deionized water.
Embodiment 7
A kind of special anti-mosquito agent of textile, including the following component of fraction meter by weight：0.65% Peppermint essential oil,
0.45% Lavender, 13.8% dichloro phenylate fat, 3.8% AEO, 2.8% polyvinyl chloride
Sorbitan fatty acid ester, 2.7% sorbitan carboxylic esterses, 7.8% phenyl phenol polyethenoxy ether, 45% second two
Alcohol monomethyl ether, 8.5% toluene di-isocyanate(TDI), 14.5% deionized water.
Embodiment 8
A kind of special anti-mosquito agent of textile, including the following component of fraction meter by weight：0.3% tea tree ethereal oil,
0.4% lemon, 16.8% valeric acid cyanogen ether fat, 4.1% AEO, 3.1% polyvinyl chloride lose
Water Span, 3.4% sorbitan carboxylic esterses, 5.8% phenyl phenol polyethenoxy ether, 38% ethylene glycol
Monobutyl ether, 9% polyurethanes, 19.1% deionized water.
Embodiment 9
A kind of special anti-mosquito agent of textile, including the following component of fraction meter by weight：0.1% Lavender,
0.2% Peppermint essential oil, 0.25% lemon, 15.6% fluorine chlorine ether chrysanthemum ester, 3.6% AEO,
3.2% polyvinyl chloride sorbitan fatty acid ester, 2.9% sorbitan carboxylic esterses, 6.2% phenyl phenol polyoxy second
Alkene ether, 45% ethylene glycol monobutyl ether, 8% toluene di-isocyanate(TDI), 14.95% deionized water.
Comparative example 1
A kind of special anti-mosquito agent of textile, including the following component of fraction meter by weight：18% dichloro phenylate fat,
4.1% AEO, 2.2% polyvinyl chloride sorbitan fatty acid ester, 2.5% sorbitan fatty
Acid esters, 7.3% phenyl phenol polyethenoxy ether, 48% ethylene glycol monobutyl ether, 8.5% polyurethanes, 9.4% goes
Ionized water.
Experimental example
Silk stocking are handled by Example 1-9 anti-mosquito agent respectively, obtain experimental group anophelifuge fabrics, are named as
1-9 groups；Using the silk stocking without any processing as blank group, the 10th group is named as；The anti-mosquito agent of comparative example 1 is taken to enter silk stocking
Row processing, obtains control group anophelifuge fabrics, is named as the 11st group.
Experimental subjects：- 55 years old 20 years old women, are divided into 11 groups, every group of 10 people are randomly assigned.
Experimental program：Experimental subjects wears corresponding silk stocking from 8:00-20:00 totally 12 hours, count every group of experimental subjects
By the average value of the number of times of bite by mosquitos and bitten number of times slip.
Bitten number of times slip=(experimental subjects for wearing blank sample is bitten the experiment pair of number of times-wear trials group
As being bitten number of times)/wear blank sample experimental subjects and bitten number of times.
Acquired results are as shown in table 1.
The repellent effect of the embodiment 1-10 of table 1 and the anophelifuge of comparative example 1 to mosquito
As can be seen from Table 1, in the 10th group (blank group), the average number of times of being bitten of experimental subjects is 32.3 times, and the
In 1-9 groups (experimental group), the average number of times bitten of experimental subjects is 4.6-5.8 times, and being bitten number of times slip is
82.04%-85.76%, the anti-mosquito agent of this explanation present invention for mosquito have it is good walk quickly and keep away effect, can significantly reduce by
Mosquito bites number of times.Compared with average 6.3 times of the 11st group (control group) bite number of times, 1-9 groups (experimental group) experiment pair
The average number of times bitten of elephant also has certain decline, and this shows, the compounding of plants essential oil and insecticide is also in certain journey
The mosquito-repelling effect of anti-mosquito agent is improved on degree.It is a kind of special that its main cause is that plants essential oil in the present invention all has
Smell, can walk quickly and keep away mosquito, therefore add it in anti-mosquito agent, and can reduce mosquito bites number of times.
In addition, as it can be seen from table 1 when restriction only adds a kind of plants essential oil, adding lemon-grass essential oil and peppermint essence
The anti-mosquito agent of oil has best repelling effect, and main cause is that the smell of both essential oils is heavier, for becoming for mosquito
Avoiding effect is preferable.But it is due to that smell is heavier, is not suitable for owner.Therefore, inventor is groped by substantial amounts of, is found
A variety of essential oils are compounded, are then added in the formula of anti-mosquito agent, can be reduced on the premise of anti-mosquito agent effect is not reduced
The smell of anti-mosquito agent.Secondly, by the compounding of a variety of essential oils, the anti-mosquito agent product with multiple fragrance can be obtained.From
Table 1 is as can be seen that embodiment 7-9 is the anti-mosquito agent for adding various plants essential oil, and its number of times bitten is 4.8-5.1,
Same level is in embodiment 1 and embodiment 6.And by the compounding of essential oil, obtain with multiple fragrance and smell
Than shallower anti-mosquito agent, it is adapted to requirement of the various people to anti-mosquito agent.
The foregoing description of the disclosed embodiments, enables professional and technical personnel in the field to realize or using the present invention.
A variety of modifications to these embodiments will be apparent for those skilled in the art, as defined herein
General Principle can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore, it is of the invention
The embodiments shown herein is not intended to be limited to, and is to fit to and principles disclosed herein and features of novelty phase one
The most wide scope caused.
Claims (7)
1. a kind of special anti-mosquito agent of textile, it is characterised in that include the following component of fraction meter by weight：0.5-2.0%
Plants essential oil, 10-20% insecticides, 10-20% surfactants, 30-50% solvents, 5-10% fastness elevators, 10-
20% deionized water；
The plants essential oil is in oil of Cymbopogon winterianus, Lavender, tea tree ethereal oil, Geranium Essential, lemon, Peppermint essential oil
At least one；The insecticide is at least one of tetramethrin, fluorine chlorine ether chrysanthemum ester, valeric acid cyanogen ether fat, dichloro phenylate fat.
2. the special anti-mosquito agent of textile as claimed in claim 1, it is characterised in that the surfactant is poly alkyl alcohol
Oxygen vinethene, polyvinyl chloride sorbitan fatty acid ester, sorbitan carboxylic esterses or phenyl phenol polyethenoxy ether.
3. the special anti-mosquito agent of textile as claimed in claim 1, it is characterised in that the fastness elevator is poly- amino first
Acid esters or toluene di-isocyanate(TDI).
4. the special anti-mosquito agent of textile as claimed in claim 1, it is characterised in that the solvent is diol, derivatives.
5. the special anti-mosquito agent of textile as claimed in claim 4, it is characterised in that the diol, derivatives are ethylene glycol list
Methyl ether, ethylene glycol monoethyl ether or ethylene glycol monobutyl ether.
6. a kind of preparation method of special anti-mosquito agent of textile as described in claim any one of 1-5, it is characterised in that bag
Include the steps：
1) solvent is added into reactor, setting mixing speed is 500-600r/min, stirring at normal temperature；It is subsequently added into insecticide,
20-30min；
2) surfactant is added into reactor, 30-40 degree is warming up to, 30-40min is stirred；Plants essential oil is added, is kept
Temperature is 30-40 degree, stirs 25-50min；Fastness elevator is subsequently added into, 50-60 degree is warming up to, mixing speed is 1000-
1200r/min, stirs 60-90min；
3) question response kettle temperature degree is down to 20-30 degree, and adjustment mixing speed to 400-500r/min adds deionized water, question response
Temperature in the kettle is down to normal temperature, and feeding produces the anti-mosquito agent of the present invention.
7. the preparation method of the special anti-mosquito agent of textile as claimed in claim 6, it is characterised in that step 2) be：To anti-
Answer and surfactant is added in kettle, be warming up to 32-35 degree, stir 35-38min；Plants essential oil is added, keeping temperature is 32-
35 degree, stir 35-40min；Fastness elevator is subsequently added into, 55-58 degree is warming up to, mixing speed is 1100-1200r/min,
Stir 75-80min.
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| CN110273305A (en) * | 2019-05-14 | 2019-09-24 | 苏州市奥彩纺织整理有限公司 | A kind of dyeing and finishing technology of complex function dacron |
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| CN110670362A (en) * | 2019-10-14 | 2020-01-10 | 苏州市韦普精纺科技有限公司 | Green nontoxic mosquito-proof fabric and preparation method thereof |
| CN111549525A (en) * | 2020-06-10 | 2020-08-18 | 临清三利纺织有限公司 | Anti-mosquito slurry and processing technology for printed fabric by using same |
| CN114982788A (en) * | 2022-05-05 | 2022-09-02 | 常州大学 | Preparation method, product and application of compound essential oil mosquito-repellent microcapsule |
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| CN108677529A (en) * | 2018-05-16 | 2018-10-19 | 丁爱军 | A kind of mould reagent of textile and preparation method thereof and application method |
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| CN111549525A (en) * | 2020-06-10 | 2020-08-18 | 临清三利纺织有限公司 | Anti-mosquito slurry and processing technology for printed fabric by using same |
| CN114982788A (en) * | 2022-05-05 | 2022-09-02 | 常州大学 | Preparation method, product and application of compound essential oil mosquito-repellent microcapsule |
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Application publication date: 20170725 |