CN110563386B

CN110563386B - Batch scraping calcined sand stone-like paint and preparation method and application thereof

Info

Publication number: CN110563386B
Application number: CN201910806925.8A
Authority: CN
Inventors: 张志炯; 乔磊; 叶华阳; 施越
Original assignee: Beijing Raines New Materials Technology Co ltd
Current assignee: Hebei Laines New Material Technology Co ltd
Priority date: 2019-08-28
Filing date: 2019-08-28
Publication date: 2020-11-03
Anticipated expiration: 2039-08-28
Also published as: CN110563386A

Abstract

The invention relates to the technical field of coatings for buildings, in particular to a batch scraping calcined sand stone-like paint which is prepared from the following components in parts by weight: 10-20 parts of deionized water, 0.1-0.3 part of preservative, 0.5-1 part of antifreezing agent, 0.1-0.3 part of defoaming agent, 0.5-1.5 parts of film-forming additive, 0.2-0.5 part of cellulose, 0.1-0.5 part of aluminum magnesium silicate thixotropic lubricant, 0.05-0.2 part of starch ether, 10-20 parts of pure acrylic emulsion, 60-75 parts of calcined sand and 0.1-0.5 part of thickening agent; the preparation method of the stone-like paint and the application of the stone-like paint as a decorative layer in batch scraping on buildings are also provided, the smoothness and the thickness consistency of the paint in batch scraping can be kept, the construction is easy, and the stone-like paint has excellent weather resistance and decorative effect.

Description

Batch scraping calcined sand stone-like paint and preparation method and application thereof

Technical Field

The invention relates to the technical field of coatings for buildings, in particular to a batch scraping calcined sand stone-like paint and a preparation method and application thereof.

Background

The water-in-water and sand-in-water stone-like paint is a single-component paint for building external wall, which is prepared by suspending two or more kinds of water-based colour particles in a water-based medium layer and spraying once to produce multiple colours.

The domestic existing stone-like coating is mainly products such as real stone paint, water-in-water, sand-in-water and the like; among them, the stone-like paint is a coating having a decorative effect exactly like marble and granite, is mainly prepared from natural stone powders of various colors, is applied to the stone-like effect of building walls, and is also called as liquid stone. The stone-like paint has the advantages of strong decoration, wide application range, water-based environmental protection, good pollution resistance, long service life, no potential safety hazard and the like, and is widely applied to decoration and protection of building walls.

However, the stone-like paint in the prior art is not uniform in particles, and if the stone-like paint is applied in a batch scraping manner, the stone-like paint is not uniform in thickness control, so that the coating effect is affected, and therefore, the spraying construction is frequently adopted. The spraying construction can cause that the construction thickness and the consumption can not be ensured, the coating effect has certain difference under the influence of human subjectivity, and people with different experiences have different coating effects; and the spraying construction process has serious environmental pollution.

Disclosure of Invention

Aiming at the defects in the prior art, the invention aims to provide a batch scraping calcined sand stone-like paint which can keep smoothness and thickness consistency during batch scraping of paint and is easy to construct.

The first purpose of the invention is realized by the following technical scheme:

the batch scraping calcined sand stone-like paint is prepared from the following components in parts by weight: 10-20 parts of deionized water, 0.1-0.3 part of preservative, 0.5-1 part of antifreezing agent, 0.1-0.3 part of defoaming agent, 0.5-1.5 parts of film-forming additive, 0.2-0.5 part of cellulose, 0.1-0.5 part of aluminum magnesium silicate thixotropic lubricant, 0.05-0.2 part of starch ether, 10-20 parts of pure acrylic emulsion, 60-75 parts of calcined sand and 0.1-0.5 part of thickening agent.

By adopting the technical scheme, the calcined sand is prepared by washing natural colored sand with weak acid, sintering at high temperature and glazing on the surface, has the advantages of fastness, no flowering, acid and alkali resistance, and has the service life 5-8 years longer than that of the natural sand; the calcined sand is applied to the stone-like paint, and the smoothness and thickness consistency of the paint during batch scraping can be kept by matching with the dispersing and lubricating action of the acrylic emulsion and the auxiliary agent. The basic material of the magnesium aluminum silicate thixotropic lubricant is sheet-shaped silicate mineral materials, in an aqueous system, the sheet-shaped silicate mineral materials can form a cabin-shaped structure, the mechanism can improve the basic viscosity in the system, but can be easily damaged when external shearing force exists, the additives are specially developed for dry powder and paste systems, the additives can produce special effects, and the viscosity, the yield point, the stability and the workability can be controlled; the aluminum magnesium silicate thixotropic lubricant is applied to the stone-like paint, so that the high thixotropy of the aluminum magnesium silicate thixotropic lubricant can be used for keeping the good storage stability and the excellent smoothness during construction of the stone-like paint product. The starch ether can be uniformly dispersed in a system after being dissolved in water, and the starch ether molecules are in a net structure and are negatively charged, so that the positively charged sand particles can be adsorbed and can be used as a transition bridge to connect all components, thereby endowing the slurry with a larger yield value, playing a role in improving the anti-sagging or anti-sliding property, being easy to push under the action of a small external force and being easier to construct. According to the invention, calcined sand obtained by high-temperature calcination is used as a stone-like material, pure acrylic emulsion with excellent weather resistance is used as a main bonding substance, and a magnesium aluminum silicate thixotropic lubricant and a starch ether rheological agent are added, so that the purposes of controlling batch scraping thickness and enhancing construction smoothness are achieved, and the stone-like paint disclosed by the invention has excellent weather resistance and decorative effect.

Preferably, the composition is prepared from the following components in parts by weight: 12.4 to 15.5 portions of deionized water, 0.15 to 0.25 portion of preservative, 0.6 to 0.9 portion of antifreeze, 0.15 to 0.25 portion of defoamer, 0.7 to 1.2 portions of film forming additive, 0.25 to 0.4 portion of cellulose, 0.2 to 0.4 portion of magnesium aluminum silicate thixotropic lubricant, 0.1 to 0.15 portion of starch ether, 13 to 19 portions of pure acrylic emulsion, 63 to 70 portions of calcined sand and 0.2 to 0.35 portion of thickener.

By adopting the technical scheme, the content of each component is optimized, and the comprehensive performance of the stone-like paint is further improved. Wherein, too little preservative has the risk of deterioration and decay, and too much causes the waste of materials and has poor effect. The real stone paint product can be frozen at the temperature of-5 ℃, the quality of the product is not influenced after the real stone paint product is slightly frozen and is thawed at normal temperature, and if the addition amount of the antifreezing agent is too small, freeze thawing damage can be generated, so that the quality of the thawed product is damaged due to the fact that the real stone paint product is seriously frozen. The system of the invention does not contain emulsifier and dispersoid, basically does not foam, can ensure that the state of the real stone paint product is better by adding a small amount of defoamer, and the paint film obtained after batch scraping has uniform appearance.

Preferably, the calcined sand is 25-35 mesh spherical sand.

By adopting the technical scheme, the spherical sand with narrow particle size distribution is selected, so that the dispersion uniformity of the calcined sand in the paint can be ensured, the surface roughening phenomenon of a sprayed paint film can not occur, and the smoothness and the thickness consistency of the paint when the paint is scraped can be maintained.

Preferably, the antifreeze agent is propylene glycol.

Preferably, the defoamer is a mineral oil.

Preferably, the film forming aid is 2,2, 4-trimethyl-1, 3-pentanediol monoisobutyrate, and the thickener is an associated acrylic thickener.

By adopting the technical scheme, the associative acrylic thickener has good water resistance and good matching property with the acrylic emulsion.

The second purpose of the invention is to provide a preparation method of the batch scraped calcined sand real stone paint, which is obtained by the following processing steps:

sequentially adding a preservative, an antifreezing agent, a defoaming agent and a film forming auxiliary agent into deionized water at the rotating speed of 500 plus 800r/min, and uniformly stirring and dispersing to obtain a mixture A;

sequentially adding cellulose, magnesium aluminum silicate thixotropic lubricant and starch ether into the mixture A at the rotating speed of 500-; adding the pure acrylic emulsion at the rotating speed of 500 plus materials at 800r/min, and uniformly stirring to obtain a mixture B;

and adding the calcined sand and the thickening agent into the mixture B at the rotating speed of 300-500r/min, and uniformly stirring and mixing to obtain the batch scraping calcined sand stone-like paint.

By adopting the technical scheme, the auxiliary agents are mainly mixed in the early stage, the low-viscosity materials are stirred and splashed to the wall of the tank at an overhigh speed, more water is needed for cleaning, and the cellulose is agglomerated at an overhigh speed, is more difficult to dissolve and wastes energy. And the medium speed (500-800r/min) can play a role of mixing so as to pre-disperse the cellulose. After the magnesium aluminum silicate thixotropic lubricant and the starch ether are added, the system has certain viscosity, higher speed can be tolerated, and the cellulose, the magnesium aluminum silicate thixotropic lubricant and the starch ether can be dissolved better under high-speed stirring. In the stage of adding the pure acrylic emulsion after dissolution, because the pure acrylic emulsion has mechanical stability and the pure acrylic emulsion is demulsified due to overhigh rotating speed and shearing speed, the pure acrylic emulsion is uniformly mixed at medium speed. After the calcined sand is added in the later period, the viscosity of the system is further increased, a high-power and low-speed paddle stirrer is needed to uniformly mix the materials, and the high rotation speed of the machine not only can cause high load, but also can reduce the stability of the acrylic emulsion and the calcined sand.

The third purpose of the invention is to provide the application of the batch scraped calcined sand stone paint in building surface decoration, wherein the batch scraped calcined sand stone paint is batch scraped on the surface of an inner wall, an outer wall or a building cement substrate of a building to form a decorative layer.

By adopting the technical scheme, the building surface can be decorated and beautified to achieve the desired stone imitation effect, and the building surface can be protected.

In conclusion, the invention has the following beneficial effects:

(1) the stone-like paint can be constructed by adopting a batch scraping process, and the problems that the traditional spraying process has great environmental pollution, the spraying thickness is difficult to control, and the spraying effect cannot be ensured are solved; the method has the advantages of easy construction, controllable thickness, no flowering and good scraping effect;

(2) the addition of the calcined sand ensures batch scraping thickness and smoothness; the aluminum magnesium silicate thixotropic lubricant and the starch ether further improve the workability and the storability of the product;

(3) by utilizing the stability of the high-temperature calcined sand and the excellent ultraviolet resistance of the acrylic emulsion, the durability of the product is ensured, the service time of building surface decoration is prolonged, the recoating times are reduced, the material is saved, and the labor consumption is reduced.

Detailed Description

The present invention will be further described with reference to the following specific examples.

The calcined sand in the invention is selected from Guangxi gold dragon ore products, and is spherical sand with 25-35 meshes; the preservative is a cason preservative, and the weight percentage of active substances is 1.5%; the antifreezing agent is propylene glycol; the defoaming agent is NXZ defoaming agent; the film-forming auxiliary agent is Texanol; the cellulose is hydroxyethyl methylcellulose 250HBR selected from Himalayan; the aluminum magnesium silicate thixotropic lubricant is selected from Terotree with the model number of KW; the starch ether is selected from AVEBE starch ether Casucol 301; the pure acrylic emulsion is selected from 706T pure acrylic emulsion from the company of Bade Fukui industries, Ltd; TT-615 is selected as the thickening agent.

Example 1

The batch scraped calcined sand real stone paint is obtained through the following processing steps:

adding deionized water into a stirring tank according to the data in the table 1, starting a stirrer, sequentially adding a preservative, an antifreezing agent, an NXZ defoaming agent and a film-forming auxiliary agent at the rotating speed of 500r/min, stirring and dispersing for 5min, and uniformly dispersing to obtain a mixture A;

sequentially adding hydroxyethyl cellulose, magnesium aluminum silicate thixotropic lubricant and starch ether into the mixture A at a rotating speed of 500r/min under medium-speed stirring, and stirring for pre-dispersing for 5 min; stirring at high speed at 1000r/min for 60min, dispersing uniformly, adding pure acrylic emulsion at 500r/min, and stirring for 10min to obtain mixture B;

and adding the mixture B into a paddle mixer, adding calcined sand under the slow stirring of 300r/min, uniformly mixing the calcined sand with the color, adding TT-615 thickening agent to adjust the viscosity, and obtaining the batch scraped calcined sand stone-like paint.

Example 2

adding deionized water into a stirring tank according to the data in the table 1, starting a stirrer, sequentially adding a preservative, an antifreezing agent, an NXZ defoaming agent and a film-forming auxiliary agent at a rotating speed of 650r/min, stirring and dispersing for 5min, and uniformly dispersing to obtain a mixture A;

sequentially adding hydroxyethyl cellulose, magnesium aluminum silicate thixotropic lubricant and starch ether into the mixture A at a rotation speed of 650r/min by medium-speed stirring, and stirring for pre-dispersing for 5 min; stirring at high speed at the rotation speed of 1100r/min for dispersing for 60min, adding pure acrylic emulsion at the rotation speed of 650r/min after uniform dispersion, and stirring for 10min to obtain a mixture B;

and adding the mixture B into a paddle mixer, adding calcined sand under the slow stirring of 400r/min, uniformly mixing the calcined sand with the color, adding TT-615 thickening agent to adjust the viscosity, and obtaining the batch scraped calcined sand stone-like paint.

Example 3

adding deionized water into a stirring tank according to the data in the table 1, starting a stirrer, sequentially adding a preservative, an antifreezing agent, an NXZ defoaming agent and a film-forming auxiliary agent at the rotating speed of 800r/min, stirring and dispersing for 5min, and uniformly dispersing to obtain a mixture A;

sequentially adding hydroxyethyl cellulose, magnesium aluminum silicate thixotropic lubricant and starch ether into the mixture A at the rotation speed of 800r/min by medium-speed stirring, and stirring for pre-dispersing for 5 min; stirring at high speed at the rotation speed of 1200r/min for dispersing for 60min, adding pure acrylic emulsion at the rotation speed of 800r/min after uniform dispersion, and stirring for 10min to obtain a mixture B;

and adding the mixture B into a paddle mixer, adding calcined sand under the slow stirring of 500r/min, uniformly mixing the calcined sand with the color, adding TT-615 thickening agent to adjust the viscosity, and obtaining the batch scraped calcined sand stone-like paint.

Example 4

The real stone paint of example 4 was processed in the same manner as in example 1 except that the contents of the respective raw materials were added as shown in Table 1.

Example 5

The stone-like paint of example 5 was processed in the same manner as in example 2 except that the contents of the respective raw materials were added as shown in Table 1.

Example 6

The stone-like paint of example 6 was processed in the same manner as in example 2 except that the contents of the respective raw materials were added as shown in Table 1.

Example 7

The stone-like paint of example 7 was processed in the same manner as in example 2 except that the contents of the respective raw materials were added as shown in Table 1, and CF-16 as an antifoaming agent was used as the antifoaming agent.

Example 8

The stone-like paint of example 8 was processed in the same manner as in example 2 except that the contents of the respective raw materials were added as shown in Table 1 and TT935 as a thickener was used.

Example 9

The stone-like paint of example 9 was processed in the same manner as in example 2 except that the contents of the respective raw materials were added as shown in Table 1, the antifoaming agent was CF-16 antifoaming agent, and the thickening agent was TT935 thickening agent.

Example 10

The stone-like paint of example 10 was processed in the same manner as in example 2 except that the contents of the respective raw materials were added as shown in Table 1, the antifoaming agent was CF-16 antifoaming agent, and the thickening agent was TT935 thickening agent.

Example 11

The stone-like paint of example 11 was processed in the same manner as in example 2 except that the contents of the respective raw materials were added as shown in Table 1, the antifoaming agent was CF-16 antifoaming agent, and the thickening agent was TT935 thickening agent.

TABLE 1 content of each raw material (unit kg) of real stone paint in examples 1-11

Comparative examples 1 to 6

The stone-like paints of comparative examples 1 to 6 were processed in the same manner as in example 2, with different raw material components and contents, as shown in Table 2, and the rest was identical to example 2.

TABLE 2 composition and content (unit kg) of real stone paint in comparative examples 1-6

Wherein the preservatives, antifreeze, antifoam agents, film forming aids, hydroxyethyl cellulose, magnesium aluminum silicate thixotropic lubricants, starch ethers, acrylic emulsions, and thickeners in table 2 are the same as the corresponding raw materials in example 1 in type or brand, respectively.

Comparative example 7

Comparative example 7 is the stone-like paint of example 4 of the invention patent application with application publication number CN 107286784 a.

Comparative examples 8 to 10

Comparative examples 8 to 10 are conventional spray type real stone paints using the raw materials as shown in table 3 below, and natural sands having three particle sizes as shown in table 3 were added in the step of adding calcined sand in example 2 according to the processing method of example 2.

TABLE 3 composition and content (unit kg) of real stone paint in comparative examples 8-10

	Comparative example 8	Comparative example 9	Comparative example 10
				Deionized water	9	12	13.8
Preservative	0.20	0.20	0.20
				Antifreezing agent	0.80	0.80	0.80
Defoaming agent	0.20	0.20	0.20
				Film forming aid	1.00	1.00	1.00
Hydroxyethyl fiberVegetable extract	0.30	0.30	0.30
				Aluminum magnesium silicate thixotropic lubricant	0.30	0.20	0.30
Pure acrylic emulsion	18.00	15.00	13.00
				Natural sand 40-80 mesh	30	20	15
Natural sand 80-120 mesh	30	50.00	55.00
				Natural sand 120-mesh and 180-mesh	10	0	5
Thickening agent	0.20	0.20	0.20

Wherein the preservatives, antifreeze, antifoam agents, film forming aids, hydroxyethyl cellulose, magnesium aluminum silicate thixotropic lubricants, acrylic emulsions, and thickeners in table 3 are the same as the corresponding raw materials in example 1 in type or brand, respectively.

Effect detection

The real stone paints of examples 1-11 and comparative examples 1-10 were tested for various properties according to the test methods in the JG/T24-2018 industry standard, and the test results are shown in tables 4-7, respectively.

TABLE 4 results of testing the properties of the stone-like paints of examples 1 to 7

TABLE 5 results of testing the properties of the stone-like paints of examples 8 to 11

TABLE 6 results of testing the Properties of the real stone paints in comparative examples 1 to 7

TABLE 7 results of testing the Properties of the real stone paints in comparative examples 8 to 10

As can be seen from the detection results in tables 4-7, in comparative example 1, the batch scraping thickness cannot be controlled by replacing the high-temperature calcined sand with natural sand, so that the thickness is not uniform and the hair is caused; comparative example 6 the high temperature calcined sand is changed to low temperature calcined sand, the scraping is difficult, the paint film is not compact and is slightly cracked; comparative example 2 no magnesium aluminium silicate addition, batch scraping sagging, storage water diversion; comparative example 3 no starch ether was added, and the workability of batch scraping was slightly inferior to that of example 5; comparative example 4 no magnesium aluminum silicate and starch ether are added, the workability is poor; comparative example 5 withCompared with example 5, the content of sand is increased, the relative proportion of each component is small, the batch scraping is smooth, the performance is close to that of example 5, but the stain resistance is poor; comparative example 7 the sand has uneven grain diameter, uneven distribution of coarse sand and fine sand during batch scraping, uneven color distribution, higher grain diameter of coarse sand after recovery and high consumption which reaches 3kg/m²。

Application example 1

The batch scraped calcined sand stone-like paint of the embodiment 4 of the invention is uniformly batch scraped on the surface of the building outer wall of the cement substrate to form a decorative protective layer. After a period of 7 days, the thickness of the coating was measured by a film thickness meter, the thickness of five different points was measured, and the apparent state of the paint film was further observed, and the results are shown in Table 8.

Application example 2

The batch-scraped calcined sand stone-like paint of the embodiment 5 of the invention is uniformly batch-scraped on the inner wall surface of a building to form a decorative protective layer. After a period of 7 days, the thickness of the coating was measured by a film thickness meter, the thickness of five different points was measured, and the apparent state of the paint film was further observed, and the results are shown in Table 8.

Comparative application examples 1 to 2 and comparative application examples 6 to 10

The stone-like paints of comparative examples 1-2 and comparative examples 6-10 were applied to the exterior wall surface of a building by the procedure of application example 1, and the performance thereof was measured, and the results are shown in table 8.

TABLE 8 thickness and apparent morphology of real mineral paints in application examples 1-2, application comparative examples 1-2, and application comparative examples 6-10

As can be seen from Table 8, the stone-like paint of the present invention, whether applied to interior walls or exterior walls, can be firmly bonded to walls, has uniform thickness, and does not generate any decoration. The application examples 1 and 2 are smooth in construction, the paint film is directly formed by a spatula once, the thickness of each part of the paint film is controllable and uniform, the surface of the paint film after construction is flat and uniform, and the effect is attractive. The application comparative example 1 is natural sand, the surface is irregular, the grain diameter is not uniform, the thickness is not controllable during batch scraping, the uneven thickness is easy to generate flowers, fine sand is easy to be partially accumulated during final collection and smearing, and the color is deeper than the whole body to generate flowers; the application comparative example 2 does not add thixotropic lubricant, and slight sagging phenomenon exists when the drying is slow; the low-temperature sintered sand of comparative example 6 is applied, the coating strength of the sand is insufficient, the surface is sticky and unsmooth, the batch scraping property is slightly insufficient, and the phenomena of sand walking and bottom leakage exist; the sintered sand with different grain diameters is applied in the comparative example 7, the consumption is too high due to too coarse, the fine and coarse sand move inconsistently along with the spatula, and the local accumulation phenomenon is caused; the application comparative examples 8, 9 and 10 are the spraying type real stone paint, the protection and the power connection are needed, the influence of manual level is large, the spraying thickness is uneven, the flowers can be generated, the worker can spray even and fly sand, the consumption is high, and the surface is rough.

Compared with the traditional real stone paint taking natural sand as a main material, the real stone paint of the invention has the differences shown in the following table 9.

TABLE 9 comparison of the Properties of the real stone paint of example 5 with that of comparative example 2

The results in table 9 show that the stone-like paint of the present invention is different from the conventional stone-like material, and the construction can be carried out without power connection by using a batch cutter in the actual construction. The stone-like paint is not affected by the operation mode, and the scaffold, the hanging basket and the sliding plate can be constructed and operated. The main material is scraped for one-step molding, so that manpower can be effectively saved, and the construction period is shortened. The construction thickness is uniform, no stubble is connected, no blunt mark is generated, the specific gravity and the particle size of the calcined sand are consistent, and the phenomenon that fine particle size is accumulated to cause the flowering and the stubble connection during batch scraping caused by inconsistent particle size and specific gravity of natural sand is avoided. The stone-like paint has low consumption of only 2-2.5kg/m²Compared with the traditional real stone paint (3-5 kg/m)²) 3/5 can be saved at most, the material is saved, and the cost is reduced.

The above-mentioned embodiments are merely illustrative and not restrictive, and those skilled in the art can modify the embodiments without inventive contribution as required after reading this specification, but only fall within the scope of the claims of the present invention.

Claims

1. The batch scraping calcined sand stone-like paint is characterized by being prepared from the following components in parts by weight: 10-20 parts of deionized water, 0.1-0.3 part of preservative, 0.5-1 part of antifreezing agent, 0.1-0.3 part of defoaming agent, 0.5-1.5 parts of film-forming additive, 0.2-0.5 part of cellulose, 0.1-0.5 part of aluminum magnesium silicate thixotropic lubricant, 0.05-0.2 part of starch ether, 10-20 parts of pure acrylic emulsion, 60-75 parts of calcined sand and 0.1-0.5 part of thickening agent, wherein the calcined sand is 25-35 meshes of spherical sand.

2. The batch-scraping calcined sand stone-like paint as claimed in claim 1, which is prepared from the following components in parts by weight: 12.4 to 15.5 portions of deionized water, 0.15 to 0.25 portion of preservative, 0.6 to 0.9 portion of antifreeze, 0.15 to 0.25 portion of defoamer, 0.7 to 1.2 portions of film forming additive, 0.25 to 0.4 portion of cellulose, 0.2 to 0.4 portion of magnesium aluminum silicate thixotropic lubricant, 0.1 to 0.15 portion of starch ether, 13 to 19 portions of pure acrylic emulsion, 63 to 70 portions of calcined sand and 0.2 to 0.35 portion of thickener.

3. The batch-scraped calcined sand stone-like paint according to claim 1, wherein: the antifreezing agent is propylene glycol.

4. The batch-scraped calcined sand stone-like paint according to claim 1, wherein: the defoaming agent is mineral oil.

5. The batch-scraped calcined sand stone-like paint according to claim 1, wherein: the film-forming additive is 2,2, 4-trimethyl-1, 3-pentanediol monoisobutyrate.

6. The batch-scraped calcined sand stone-like paint according to claim 1, wherein: the thickening agent is an associated acrylic thickening agent.

7. A method for preparing the batch-scraped calcined sand stone-like paint according to any one of claims 1 to 6, which is obtained by the following processing steps:

8. Use of the batch-scraped calcined sand stone paint according to any one of claims 1 to 6 for building surface decoration, wherein: and scraping the scraped calcined sand stone paint on the surfaces of the inner wall, the outer wall or the building cement substrate of the building to form a decorative layer.