CN111892834A - Real stone paint and preparation method thereof - Google Patents

Real stone paint and preparation method thereof Download PDF

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Publication number
CN111892834A
CN111892834A CN202010828861.4A CN202010828861A CN111892834A CN 111892834 A CN111892834 A CN 111892834A CN 202010828861 A CN202010828861 A CN 202010828861A CN 111892834 A CN111892834 A CN 111892834A
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CN
China
Prior art keywords
stone
paint
agent
water
emulsion
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Pending
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CN202010828861.4A
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Chinese (zh)
Inventor
王辉
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Individual
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Individual
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Priority to CN202010828861.4A priority Critical patent/CN111892834A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a stone-like paint and a preparation method thereof, relating to the technical field of agricultural improvement and specifically comprising the following steps: the stone-like paint comprises the following components in percentage by mass: 1.4-2% of water, 12-15% of emulsion, 8-10% of cellulose, 0.3-0.5% of antifreezing agent, 0.03-0.07% of defoaming agent, 0.01-0.05% of wetting agent, 0.2-0.7% of regulator, 1-4% of thickening agent and 70-80% of stone powder. The prepared stone-like paint has simple preparation method, can be used on a plurality of base surfaces, such as cement brick walls, foams, gypsum boards or glass, belongs to an environment-friendly water-based emulsion, does not cause any damage to human bodies, has more selected colors and longer service life, can be used for 15 years at least if the maintenance is good, has very high safety factor, can be constructed according to a normal construction process, does not fall off integrally in the later period, is difficult to attach 90 percent of dirt, is bright as new after being washed by rainwater, and is easier to clean manually.

Description

Real stone paint and preparation method thereof
Technical Field
The invention relates to the technical field of agricultural improvement, in particular to a stone-like paint and a preparation method thereof.
Background
With the rapid development of economy, the building exterior wall coating industry is also greatly developed. The stone-like paint as an important kind of water-based building coating can be used for decorating external walls and is an important component for protecting the external walls, and the stone-like paint is mainly used for decorating the external walls and comprises the following components: decorate stone material, glass curtain wall, outer wall facing brick, plastic-aluminum board, exterior wall coating (contain real mineral varnish) etc. and what exists in four kinds of facing material before there are various problems: and (3) stone material decoration: the paint is easy to be vibrated by the outside to form bright lines, easy to break, strong in water and oil absorption, poor in fire resistance, difficult to construct, high in manufacturing cost, radiated and the like. Glass curtain wall: the glass curtain wall causes changeable images, causes visual fatigue of pedestrians and drivers, easily causes accidents and causes 'light pollution'. Exterior wall facing brick: large production energy consumption, land resource consumption, easy hollowing and dropping, and unsafe use. An aluminum-plastic composite board: are relatively expensive and thus have limited applications.
In recent years, with the deepening of people's understanding of environmental problems, sustainable development has become a basic requirement of building material industry, and the existing real stone paint has the disadvantages of tedious configuration process, single color and troublesome use.
Disclosure of Invention
The invention aims to provide a stone-like paint and a preparation method thereof, which aim to solve the existing problems: the existing stone-like paint has complicated preparation process.
In order to achieve the purpose, the invention provides the following technical scheme: the stone-like paint comprises the following components in percentage by mass: 1.4-2% of water, 12-15% of emulsion, 8-10% of cellulose, 0.3-0.5% of antifreezing agent, 0.03-0.07% of defoaming agent, 0.01-0.05% of wetting agent, 0.2-0.7% of regulator, 1-4% of thickening agent and 70-80% of stone powder.
Preferably, the stone-like paint comprises the following components in percentage by mass: 2% of water, 15% of emulsion, 8% of cellulose, 0.4% of antifreezing agent, 0.05% of defoaming agent, 0.05% of wetting agent, 0.5% of regulator, 4% of thickening agent and 70% of stone powder.
Preferably, a color piece is further included for adding color.
Preferably, the stone-like paint comprises the following components in percentage by mass: 1.4-2% of water, 12-15% of emulsion, 8-10% of cellulose, 0.3-0.5% of antifreezing agent, 0.03-0.07% of defoaming agent, 0.01-0.05% of wetting agent, 0.2-0.7% of regulator, 1-4% of thickening agent, 65-75% of stone powder and 1-5% of color piece.
Preferably, the stone-like paint comprises the following components in percentage by mass: 2% of water, 12% of emulsion, 10% of cellulose, 0.5% of antifreezing agent, 0.07% of defoaming agent, 0.03% of wetting agent, 0.4% of regulator, 4% of thickening agent, 67% of stone powder and 4% of color piece.
A preparation method of a real stone paint comprises the following steps:
s1, preparing water, cellulose, an antifreezing agent, a defoaming agent, a wetting agent and a regulator in proportion, and mixing and stirring uniformly;
s2, adding the emulsion and the thickening agent, and further stirring uniformly;
s3, adding stone powder into the processed mixed solution to mix paint
Preferably, in step S3, a color piece is added to make the obtained stone-like paint have various colors.
Compared with the prior art, the invention has the beneficial effects that:
the prepared stone-like paint has simple preparation method, can be used on a plurality of base surfaces, such as cement brick walls, foams, gypsum boards or glass, belongs to an environment-friendly water-based emulsion, does not cause any damage to human bodies, has more selected colors and longer service life, can be used for 15 years at least if the maintenance is good, has very high safety factor, can be constructed according to a normal construction process, does not fall off integrally in the later period, is difficult to attach 90 percent of dirt, is bright as new after being washed by rainwater, and is easier to clean manually.
Detailed Description
The technical solutions in the embodiments of the present invention are clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments.
The first embodiment is as follows:
the stone-like paint comprises the following components in percentage by mass: 2% of water, 15% of emulsion, 8% of cellulose, 0.4% of antifreezing agent, 0.05% of defoaming agent, 0.05% of wetting agent, 0.5% of regulator, 4% of thickening agent and 70% of stone powder.
The preparation method of the stone-like paint comprises the following steps:
preparing water, cellulose, an antifreezing agent, a defoaming agent, a wetting agent and a regulator in proportion, and mixing and stirring uniformly; then adding the emulsion and the thickening agent, and further stirring uniformly; and after the mixture is stirred uniformly, adding stone powder into the processed mixed solution for paint mixing to obtain the real stone paint.
Example two:
the stone-like paint comprises the following components in percentage by mass: 2% of water, 12% of emulsion, 10% of cellulose, 0.5% of antifreezing agent, 0.07% of defoaming agent, 0.03% of wetting agent, 0.4% of regulator, 4% of thickening agent, 67% of stone powder and 4% of color piece.
The preparation method of the stone-like paint comprises the following steps:
preparing water, cellulose, an antifreezing agent, a defoaming agent, a wetting agent and a regulator in proportion, and mixing and stirring uniformly; then adding the emulsion and the thickening agent, and further stirring uniformly; after the mixture is stirred evenly, stone powder and color pieces are added into the processed mixed liquid for paint mixing, and the real stone paint can be obtained.
In the embodiment, the cellulose is specifically hydroxyethyl cellulose, transitional scattering of the real stone paint powder can be prevented by adding the hydroxyethyl cellulose, the effective construction area is increased, loss and environmental pollution are reduced, the real stone paint product made of the hydroxyethyl cellulose has a tight structure, the color and luster are uniform and cannot be bloomed during finish paint construction, and the using amount of the finish paint is relatively reduced. After the traditional thickening (such as alkali swelling and the like) is made into the stone-like paint, the structure is relatively loose after the stone-like paint is constructed and molded, the paint consumption is increased when the finish is coated due to the fact that the stone-like paint is thick and thin during construction and different in shape, the absorption difference of the finish is large, the stone-like paint made of hydroxyethyl cellulose is strong in product bonding force and good in emulsion compatibility, and a formed film of the stone-like paint is compact and compact, so that the water resistance of the stone-like paint is improved, the phenomenon of whitening in rainy seasons is effectively prevented, the stone-like paint made of the hydroxyethyl cellulose has a special net-shaped structure, powder sinking can be effectively prevented, the product is stable in the transportation and storage processes, and a good can opening effect is obtained.
The antifreezing agent is propylene glycol, plays a role in water retention and moisture retention in summer and slow drying, enables water to volatilize slowly, plays an antifreezing role in winter, and reduces the freezing temperature of water, and the freeze-thaw stability of the real stone paint is improved by adding 3-4 kg of the antifreezing agent per ton in winter. If the amount of the cellulose in the summer really stone paint formula is larger (for example, 1.5-2 kilograms of the cellulose is added), the propylene glycol can be not added, because the cellulose also has strong water retention and moisture retention effects, and if the amount of the cellulose is less, the propylene glycol needs to be added to prevent too fast drying. The natural stone paint is dried at high temperature in summer, and the problems of film formation on the surface of the emulsion, shade and sun surfaces, temperature difference and color difference and the like can be prevented by slightly drying the natural stone paint
The defoaming agent is composed of organic polyether ester, mineral oil and alcohol in a composite mode, and can be used as a chemical auxiliary agent for defoaming and inhibiting foam in production and application of stone paint.
Wetting agents are agents that reduce the surface tension of the liquid and the interfacial tension between solid and liquid, allowing the liquid to spread easily over the solid surface.
The emulsion is a new generation of stable styrene-acrylic emulsion developed by selecting imported special auxiliary agents and functional monomers, has good water whitening resistance, water resistance and weather resistance, good comprehensive stability, good color development property, toughness and stronger yellowing resistance. It has strong alkali resistance, calcium ion stability, dilution stability and freeze-thaw stability.
The regulator can be selected from ammonia water or AMP-95 which are water-soluble substances, the ammonia water is relatively fast to volatilize, the AMP-95 is completely volatilized for about 1 week, and the AMP-95 is added to have some influence on the initial water resistance of the real stone paint.
The thickener is specifically TRM-380 associated type alkali swelling thickener, which can provide double high thickening efficiency of association thickening and water phase thickening, rapid and excellent thickening efficiency of medium shear (KU) viscosity and low shear viscosity (Brookfield), extremely high pseudoplastic rheological characteristic and excellent anti-sagging and anti-settling performance.
The stone powder is sand grains which are processed by a plurality of procedures of selection, crushing, grading, packaging and the like of marble or granite and the like, has various colors, is prepared by selection and processing, has natural color, does not contain any dye, and has the advantages of no toxicity, no odor, no pollution, corrosion resistance, acid and alkali resistance, insolation resistance and no color change.
The color piece can be added for adding colors to the stone paint and decorating, and different colors can be selected according to personal preference of consumers.
The real mineral varnish that finishes of modulation can use on many basal planes, for example cement brick wall, foam, gypsum board or glass, belong to the aqueous emulsion of a very environmental protection, can not produce any injury to the human body, the life-span of use is longer, if good maintenance, can use 15 years's time at least, factor of safety is very high, as long as can be under construction according to normal construction process, the condition that wholly drops can not appear in the later stage, and 90% filth are difficult to adhere to, the back is washed to the rainwater, it is bright as new, the manual cleaning is easier.
When the real stone paint is prepared, the construction temperature must be ensured not to be lower than 5 ℃ during construction, and if the temperature is too low, the real stone paint is solidified. Secondly be exactly the wall of guaranteeing the construction very dry, if the wall has water, the phenomenon that later stage can appear droing or whitely flower. In addition, the real stone paint can not be stirred too hard, if the real stone paint is stirred too hard, particles of the real stone paint can be ground, and water can not be added into the real stone paint to dilute the real stone paint.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.

Claims (7)

1. The stone-like paint is characterized by comprising the following components in percentage by mass: 1.4-2% of water, 12-15% of emulsion, 8-10% of cellulose, 0.3-0.5% of antifreezing agent, 0.03-0.07% of defoaming agent, 0.01-0.05% of wetting agent, 0.2-0.7% of regulator, 1-4% of thickening agent and 70-80% of stone powder.
2. The stone-like paint as claimed in claim 1, wherein: the stone-like paint comprises the following components in percentage by mass: 2% of water, 15% of emulsion, 8% of cellulose, 0.4% of antifreezing agent, 0.05% of defoaming agent, 0.05% of wetting agent, 0.5% of regulator, 4% of thickening agent and 70% of stone powder.
3. The stone-like paint as claimed in claim 1, wherein: also comprises a color piece for adding color.
4. The stone-like paint as claimed in claim 1, wherein: the stone-like paint comprises the following components in percentage by mass: 1.4-2% of water, 12-15% of emulsion, 8-10% of cellulose, 0.3-0.5% of antifreezing agent, 0.03-0.07% of defoaming agent, 0.01-0.05% of wetting agent, 0.2-0.7% of regulator, 1-4% of thickening agent, 65-75% of stone powder and 1-5% of color piece.
5. The stone-like paint as claimed in claim 1, wherein: the stone-like paint comprises the following components in percentage by mass: 2% of water, 12% of emulsion, 10% of cellulose, 0.5% of antifreezing agent, 0.07% of defoaming agent, 0.03% of wetting agent, 0.4% of regulator, 4% of thickening agent, 67% of stone powder and 4% of color piece.
6. A preparation method of a stone-like paint is characterized by comprising the following steps: the method comprises the following steps:
s1, preparing water, cellulose, an antifreezing agent, a defoaming agent, a wetting agent and a regulator in proportion, and mixing and stirring uniformly;
s2, adding the emulsion and the thickening agent, and further stirring uniformly;
s3, adding stone powder into the processed mixed solution to mix paint.
7. The manufacturing method of the preparation method of the real stone paint as claimed in claim 5, wherein: in step S3, color chips are added to make the obtained stone-like paint have various colors.
CN202010828861.4A 2020-08-17 2020-08-17 Real stone paint and preparation method thereof Pending CN111892834A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010828861.4A CN111892834A (en) 2020-08-17 2020-08-17 Real stone paint and preparation method thereof

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Application Number Priority Date Filing Date Title
CN202010828861.4A CN111892834A (en) 2020-08-17 2020-08-17 Real stone paint and preparation method thereof

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CN111892834A true CN111892834A (en) 2020-11-06

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113912324A (en) * 2021-11-02 2022-01-11 河南三棵树新材料科技有限公司 Low-consumption real stone paint and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10109425A1 (en) * 2001-02-27 2002-09-05 Andreas Schultze-Kraft Thin granite type synthetic stone coating production, comprises spraying reaction resin onto plate-shaped member, blowing ground glass into spray, compressing glass granules, and hardening
CN104591598A (en) * 2013-10-31 2015-05-06 北新集团建材股份有限公司 Real stone paint, and preparation method and construction method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10109425A1 (en) * 2001-02-27 2002-09-05 Andreas Schultze-Kraft Thin granite type synthetic stone coating production, comprises spraying reaction resin onto plate-shaped member, blowing ground glass into spray, compressing glass granules, and hardening
CN104591598A (en) * 2013-10-31 2015-05-06 北新集团建材股份有限公司 Real stone paint, and preparation method and construction method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113912324A (en) * 2021-11-02 2022-01-11 河南三棵树新材料科技有限公司 Low-consumption real stone paint and preparation method thereof

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