CN110528322A - A kind of preparation method of the mirror surface pearly-lustre paper jam with three-dimensional pearl effect - Google Patents
A kind of preparation method of the mirror surface pearly-lustre paper jam with three-dimensional pearl effect Download PDFInfo
- Publication number
- CN110528322A CN110528322A CN201910901091.9A CN201910901091A CN110528322A CN 110528322 A CN110528322 A CN 110528322A CN 201910901091 A CN201910901091 A CN 201910901091A CN 110528322 A CN110528322 A CN 110528322A
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- Prior art keywords
- pearl
- pearly
- paper jam
- preparation
- mirror surface
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Classifications
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
- D21H23/22—Addition to the formed paper
- D21H23/52—Addition to the formed paper by contacting paper with a device carrying the material
- D21H23/56—Rolls
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
- D21H25/04—Physical treatment, e.g. heating, irradiating
- D21H25/06—Physical treatment, e.g. heating, irradiating of impregnated or coated paper
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- Laminated Bodies (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The preparation method of the present invention provides a kind of mirror surface pearly-lustre paper jam with three-dimensional pearl effect, this method are that the pearl layer with a thickness of 30-70 μm is formed in art post paperboard by way of transfer or being directly coated with；Compound transfer basement membrane while being inversely coated with a transparent resin layer on pearl layer again, transparent resin layer is made of following component and proportion: Shui Ju An Zhi ︰ waterborne organic silicon Xiao Pao Ji ︰ levelling Ji ︰ dehydrated alcohol=80-85 ︰ 0.5-1 ︰ 1-2 ︰ 12-16, the upper machine viscosity of transparent resin is 38-45s, and compounding machine speed is 50-70m/min；Then 24 hours are stood after the baking oven primary solidification for being 100-130 DEG C by temperature by composite base material, is finally peeled away transfer basement membrane, obtains the mirror surface pearly-lustre paper jam with three-dimensional pearl effect.The pearly-lustre paper jam that preparation method of the present invention receives, pearly-lustre stereoscopic effect is good, stereovision is strong, glitter is high, mirror surface sense is strong, has more novelty；In addition, being not easy to lose powder by viscous draw of external force, printing adaptability is better than common pearly-lustre paper jam, will not damage printing equipment since pearl powder dosage is few.
Description
Technical field
The present invention relates to the preparation processes of iridescent paper more particularly to a kind of pearly-lustre with three-dimensional pearl effect to be coated with paper jam
Preparation process, specifically relate to a kind of preparation method of pearly-lustre paper jam with three-dimensional pearl effect and mirror effect.
Background technique
Pearly-lustre paper jam namely pearly-lustre are coated with paper jam, it is directly to be coated with pearl on art post paperboard surface by printing coating equipment
Light coating realizes full version pearl effect.Natural gloss as pearicoat has pearl inside the body of a freshwater mussel, can be such that package printed matter shows
In riotous profusion color like as bedecked with jewels, therefore some high-grade cigarettes, wine, cosmetics are used as packet frequently with this pearly-lustre coating paper jam
Package material increases the dicoration of packaging with this, improves the class of commodity.Existing pearly-lustre coating paper jam is in technique and final product quality
On there are the following drawbacks: (1) because pearl powder partial size be greater than dry-coated film thickness, there is part pearl powder and be exposed to outside coating,
Lead to picking phenomenon occurred by viscous draw easily of external force, and will cause the damage of equipment in printing process；(2) due to using solvent type
Pearicoat, the VOC that will cause finished product is exceeded, and use water-soluble pearlescent coating, paper page pearl effect is poor, and brightness
It is low；(3) pearly-lustre powder content is high but pearl effect is weak, pearly-lustre flicker degree is poor, this is because the pearly-lustre powder content of existing pearly-lustre paper jam
Generally between 18-30%, what is had is even higher, but coating is again relatively thin, causes pearl powder to be similar to as scale and accumulates, angle of visibility
Degree reduces, so it is poor in visual effect.
Summary of the invention
To solve the problems, such as present on, the object of the present invention is to provide a kind of mirror surface pearly-lustres with three-dimensional pearl effect
The preparation method of paper jam.
In order to achieve the above object, the preparation method of the mirror surface pearly-lustre paper jam with three-dimensional pearl effect of the invention, successively
Include the following steps:
(1) pearl layer with a thickness of 30-70 μm is formed by way of being coated with transfer or directly in art post paperboard, which is
It is inversely coated with to be formed using 45 ° of twill rollers, the line number of anilox roll is 23-35 line, the component and proportion of pearl layer are as follows: synthesis applies
Liao ︰ Zhu Guang Fen ︰ is Wu Shui Yi Chun ︰ water=90-92 ︰ 2-3 ︰ 15-17 ︰ 15-17；
(2) compound transfer basement membrane while being inversely coated with a transparent resin layer on pearl layer, transparent resin layer is by such as the following group
Divide and proportion is constituted: Shui Ju An Zhi ︰ waterborne organic silicon Xiao Pao Ji ︰ levelling Ji ︰ dehydrated alcohol=80-85 ︰ 0.5-1 ︰ 1-2 ︰ 12-
16, the upper machine viscosity of transparent resin is 38-45s, and compounding machine speed is 50-70m/min；
(3) baking oven for being 100-130 DEG C by temperature by composite base material, makes transparent resin layer primary solidification；
(4) transfer basement membrane is removed after the composite base material of primary solidification being stood 24 hours, obtains the mirror with three-dimensional pearl effect
Face pearly-lustre paper jam.
Preferably, in above-mentioned preparation method, the component and proportion of synthetic paint in the pearl layer are as follows: water soluble acrylic acid tree
Zhi ︰ waterborne organic silicon Xiao Pao Ji ︰ levelling Ji ︰ dehydrated alcohol=50-55 ︰ 0.2-0.8 ︰ 0.1-0.3 ︰ 14-16, the solidification of pearl layer
Temperature is 80-130 DEG C.
Preferably, in above-mentioned preparation method, the water-based acrylic resin in the synthetic paint is by butyl acrylate, third
The copolymer that two or more copolymerization in olefin(e) acid ethyl ester, methyl methacrylate or n propyl methacrylate is formed；
Partial size≤80 μm of the pearl powder.
Preferably, in above-mentioned preparation method, the transparent resin layer with a thickness of 6-10 μm, transfer basement membrane is PET film.
Preferably, in above-mentioned preparation method, the pearl layer in the art post paperboard is obtained by branch mode, pearl layer
The upper machine viscosity of pearly coating is 20-30s when coating, and wet coating amount is 35-50g/m2, and coating machine speed is 70-90m/min.
Preferably, in above-mentioned preparation method, it is added with glue that the pearl layer, which is transferred to the glue used in art post paperboard,
The glue of weight 0.2-2% pearl powder.
Preferably, in above-mentioned preparation method, the glue is made of following component and proportion: methyl methacrylate
Zhi ︰ acrylic Ding Zhi ︰ An Shui ︰ water=22-25 ︰ 24-26 ︰ 0.5-1.5 ︰ 45-55.
Preferably, in above-mentioned preparation method, the pearl layer in the art post paperboard is that direct coating obtains, pearl layer coating
When pearly coating upper machine viscosity be 24-40s, wet coating amount be 35-75g/m2, coating machine speed be 60-80m/min.
Component proportion described in the present patent application file each means weight ratio, and viscosity, which refers to use, examines 2# glasss of grace cup, In
The data measured under conditions of 28 DEG C of room temperature, humidity 40%.
The preparation method of the mirror surface pearly-lustre paper jam with three-dimensional pearl effect of the invention, using the twill roller of specific line number
Inverse to apply to form pearl layer of the thickness at 30-70 μm, which can be significantly in the case where pearly-lustre powder content is extremely low
Promotion pearl effect and pearly-lustre flicker degree, and pass through pearly-lustre layer surface coat transparent resin layer while it is compound one transfer base
Film forms a high photosphere, the mirror surface sense of pearl layer can not only be made to enhance, and can promote the flatness of paper, prints for rear process
Swiped through journey provides safeguard.The pearly-lustre paper jam received by preparation method of the present invention has the advantage that 1, pearly-lustre stereoscopic effect
Well, stereovision is strong, glitter is high, mirror surface sense is strong, has more novelty；2, pearl powder dosage is few, is not easy to lose powder by viscous draw of external force, be printed
Brush adaptability is better than common pearly-lustre paper jam, will not damage printing equipment.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of the twill roller roll surface used when pearl layer coating.
Fig. 2 is the structural schematic diagram for the pearly-lustre paper jam that transfer method is prepared.
Fig. 3 is the structural schematic diagram for the pearly-lustre paper jam that straight coating is prepared.
Specific embodiment
Here is the several specific embodiments of mirror surface pearly-lustre paper jam preparation method that the present invention has three-dimensional pearl effect, these
Embodiment only prepares mirror surface pearly-lustre paper jam to the present invention and illustrates, the protection scope being not intended to limit the invention.
Embodiment 1
As shown in Fig. 2, the present invention has the mirror surface pearly-lustre paper jam of three-dimensional pearl effect as made from transfer method, from bottom to up according to
Secondary includes art post paperboard 1, pearl layer 2, release layer 3 and high photosphere 4；Preparation method includes the following steps:
1, the preparation of pearly coating: disappearing by weight ratio for water the third alkene acid resin ︰ waterborne organic silicon, it is anhydrous to steep agent ︰ levelling agent ︰
Ethyl alcohol=50 ︰, 0.5 ︰, 0.2 ︰ 15 first prepares synthetic paint, then by weight ratio for synthesis Tu Liao ︰ Zhu Guang Fen ︰ Wu Shui Yi Chun ︰ water=
90 ︰, 2 ︰, 16 ︰ 16 carries out pearl powder and synthetic paint to be sufficiently mixed stirring 30min, adjusts its viscosity with dehydrated alcohol and water and exists
Between 20-30s, for use；
2, the preparation of pearly-lustre coating transfer membrane: using the production technology of notch board coating on coating machine, use line number for 23-35's
Above-mentioned pearly coating is uniformly inversely coated on the transfer class film by processing by 45 ° of twill rollers (to be turned coated with release layer
Move film), pearl layer 2 is formed, wet coating amount is controlled in 30-50g/ ㎡, and equipment drying box temperature setting is between 80-130 DEG C
(being arranged using staged), equipment manufacturing machine speed controls between 70-90m/min, obtains the transfer membrane of pearl layer semi-solid preparation；
3,12-24 hours will be stood under the transfer membrane of pearl layer semi-solid preparation indoors environment, obtains bottom pearl powder freely compacted
Dynamic, the pearly-lustre for obtaining pearl layer thickness at 30-70 μm is coated with transfer membrane；
4, the transfer of pearl layer: the pearl layer that pearly-lustre is coated on transfer membrane is transferred in art post paperboard 1 on compounding machine, this process
Glue type can be selected according to the performance requirement of client to improve the requirement such as folding resistance, if it is desired to which pearl effect stereovision is more
By force, the pearl powder for adding glue weight 0.2-2.0% in glue can be taken to carry out improvement effect；The formula of glue are as follows: metering system
Suan Jia Zhi ︰ acrylic Ding Zhi ︰ An Shui ︰ water=23 ︰, 25 ︰, 1 ︰ 50, transfer membrane and art post paperboard it is compound after at 100-130 DEG C
Removing transfer film, obtains after drying box (temperature is arranged using staged), the control of machine speed solidify under conditions of 90-100m/min
To semi-finished product pearly-lustre paper jam；
5, the preparation of transparent resin: being by weight ratio Shui Ju An Zhi ︰ waterborne organic silicon Xiao Pao Ji ︰ levelling Ji ︰ solvent=80-
85 ︰ 1-0.5 ︰ 1-2 ︰ 12-16 prepare transparent resin, modulate its viscosity between 38-50s, for use, add if viscosity is not high enough
Thickener improves viscosity；
6, above-mentioned transparent resin is inversely coated on semi-finished product pearly-lustre paper jam on compounding machine, preferred 6-10 μm of coating layer thickness,
Compound one layer of transfer basement membrane simultaneously guarantees that the roughness for solidify rear surface is lower with this, and raising mirror surface sense, composite base material exists
100-130 DEG C of drying box (temperature using staged be arranged), machine speed control primary solidification under conditions of 50-70m/min, put
It sets and removes PET basement membrane afterwards for 24 hours, obtain the mirror surface pearly-lustre paper jam with three-dimensional pearl effect.
Embodiment 2
As shown in figure 3, the present invention has the mirror surface pearly-lustre paper jam of three-dimensional pearl effect as made from straight coating, from bottom to up according to
Secondary includes art post paperboard 1, pearl layer 2 and high photosphere 4；Preparation method includes the following steps:
1, the preparation of pearly coating: disappearing by weight ratio for water the third alkene acid resin ︰ waterborne organic silicon, it is anhydrous to steep agent ︰ levelling agent ︰
Ethyl alcohol=50 ︰, 0.5 ︰, 0.2 ︰ 15 first prepares synthetic paint, then by weight ratio for synthesis Tu Liao ︰ Zhu Guang Fen ︰ Wu Shui Yi Chun ︰ water=
90 ︰, 2 ︰, 16 ︰ 16 carries out pearl powder and synthetic paint to be sufficiently mixed stirring 30min, adjusts its viscosity with dehydrated alcohol and water and exists
Between 24-40s, for use；
2, the preparation of semi-finished product pearly-lustre paper jam: using the production technology of notch board coating on coating machine, use line number for 23-35
45 ° of twill rollers above-mentioned pearly coating is uniformly inversely coated in art post paperboard 1, formed pearl layer 2, wet coating amount control exists
35-75g/ ㎡, equipment drying box temperature setting (are arranged) between 80-130 DEG C using staged, and the control of equipment manufacturing machine speed exists
Between 60-80m/min, semi-finished product pearly-lustre paper jam of the pearl layer thickness at 30-70 μm is obtained；
3, the preparation of transparent resin: being by weight ratio Shui Ju An Zhi ︰ waterborne organic silicon Xiao Pao Ji ︰ levelling Ji ︰ solvent=80-
85 ︰ 1-0.5 ︰ 1-2 ︰ 12-16 prepare transparent resin, modulate its viscosity between 38-50s, for use；
4, above-mentioned transparent resin is inversely coated on semi-finished product pearly-lustre paper jam on compounding machine, preferred 6-10 μm of coating layer thickness,
Compound one layer of PET basement membrane simultaneously guarantees that the roughness for solidify rear surface is lower with this, and raising mirror surface sense, composite base material exists
100-130 DEG C of drying box (temperature using staged be arranged), machine speed control primary solidification under conditions of 50-70m/min, put
It sets and removes PET basement membrane afterwards for 24 hours, obtain the mirror surface pearly-lustre paper jam with three-dimensional pearl effect.
Claims (8)
1. a kind of preparation method of the mirror surface pearly-lustre paper jam with three-dimensional pearl effect, in turn includes the following steps:
(1) pearl layer with a thickness of 30-70 μm is formed by way of being coated with transfer or directly in art post paperboard, which is
It is inversely coated with to be formed using 45 ° of twill rollers, the line number of anilox roll is 23-35 line, the component and proportion of pearl layer are as follows: synthesis applies
Liao ︰ Zhu Guang Fen ︰ is Wu Shui Yi Chun ︰ water=90-92 ︰ 2-3 ︰ 15-17 ︰ 15-17；
(2) compound transfer basement membrane while being inversely coated with a transparent resin layer on pearl layer, transparent resin layer is by such as the following group
Divide and proportion is constituted: Shui Ju An Zhi ︰ waterborne organic silicon Xiao Pao Ji ︰ levelling Ji ︰ dehydrated alcohol=80-85 ︰ 0.5-1 ︰ 1-2 ︰ 12-
16, the upper machine viscosity of transparent resin is 38-45s, and compounding machine speed is 50-70m/min；
(3) baking oven for being 100-130 DEG C by temperature by composite base material, makes transparent resin layer primary solidification；
(4) transfer basement membrane is removed after the composite base material of primary solidification being stood 24 hours, obtains the mirror with three-dimensional pearl effect
Face pearly-lustre paper jam.
2. the preparation method of the mirror surface pearly-lustre paper jam with three-dimensional pearl effect according to claim 1, it is characterised in that:
Synthetic paint component and proportion in the pearl layer are as follows: water the third alkene acid resin ︰ waterborne organic silicon disappear steep agent ︰ levelling agent ︰ without
Water-ethanol=50-55 ︰ 0.2-0.8 ︰ 0.1-0.3 ︰ 14-16, the solidification temperature of pearl layer are 80-130 DEG C.
3. the preparation method of the mirror surface pearly-lustre paper jam with three-dimensional pearl effect according to claim 2, it is characterised in that:
Water-based acrylic resin in the synthetic paint is by butyl acrylate, ethyl acrylate, methyl methacrylate or methyl
The copolymer that two or more copolymerization in n-propyl is formed；Partial size≤80 μm of the pearl powder.
4. the preparation method of the mirror surface pearly-lustre paper jam with three-dimensional pearl effect according to claim 2 or 3, feature exist
In: the transparent resin layer with a thickness of 6-10 μm, transfer basement membrane is PET film.
5. the preparation method of the mirror surface pearly-lustre paper jam with three-dimensional pearl effect according to claim 4, it is characterised in that:
Pearl layer in the art post paperboard is obtained by branch mode, and the upper machine viscosity of pearly coating is 20- when pearl layer is coated with
30s, wet coating amount are 35-50g/m2, and coating machine speed is 70-90m/min.
6. the preparation method of the mirror surface pearly-lustre paper jam with three-dimensional pearl effect according to claim 5, it is characterised in that:
It is the glue added with glue weight 0.2-2% pearl powder that the pearl layer, which is transferred to the glue used in art post paperboard,.
7. the preparation method of the mirror surface pearly-lustre paper jam with three-dimensional pearl effect according to claim 6, it is characterised in that:
The glue is made of following component and proportion: Jia base Bing olefin(e) acid Jia Zhi ︰ acrylic Ding Zhi ︰ An Shui ︰ water=22-
25 ︰ 24-26 ︰ 0.5-1.5 ︰ 45-55.
8. the preparation method of the mirror surface pearly-lustre paper jam with three-dimensional pearl effect according to claim 4, it is characterised in that:
Pearl layer in the art post paperboard is that direct coating obtains, and the upper machine viscosity of pearly coating is 24-40s when pearl layer is coated with,
Wet coating amount is 35-75g/m2, and coating machine speed is 60-80m/min.
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| CN201910901091.9A CN110528322A (en) | 2019-09-23 | 2019-09-23 | A kind of preparation method of the mirror surface pearly-lustre paper jam with three-dimensional pearl effect |
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| CN201910901091.9A CN110528322A (en) | 2019-09-23 | 2019-09-23 | A kind of preparation method of the mirror surface pearly-lustre paper jam with three-dimensional pearl effect |
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Cited By (1)
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| CN114960272A (en) * | 2022-04-26 | 2022-08-30 | 江苏膜可光学材料有限公司 | High-gloss porcelain-like paperboard with special glaze effect and process flow thereof |
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| US4436377A (en) * | 1980-11-06 | 1984-03-13 | Morgan Adhesives Company | Transmissive reflector including nacreous, pressure sensitive adhesive layer |
| CN101407656A (en) * | 2008-11-14 | 2009-04-15 | 上海维凯化学品有限公司 | Environment-friendly type moldable aqueous transfer coating, preparation and use thereof |
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Application publication date: 20191203 |