CN107059486A - A kind of pearly-lustre holographic false proof paper and its preparation technology - Google Patents

A kind of pearly-lustre holographic false proof paper and its preparation technology Download PDF

Info

Publication number
CN107059486A
CN107059486A CN201710373934.3A CN201710373934A CN107059486A CN 107059486 A CN107059486 A CN 107059486A CN 201710373934 A CN201710373934 A CN 201710373934A CN 107059486 A CN107059486 A CN 107059486A
Authority
CN
China
Prior art keywords
layer
pearly
pearl
lustre
paper
Prior art date
Application number
CN201710373934.3A
Other languages
Chinese (zh)
Other versions
CN107059486B (en
Inventor
杨建青
Original Assignee
烟台博源科技材料股份有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 烟台博源科技材料股份有限公司 filed Critical 烟台博源科技材料股份有限公司
Priority to CN201710373934.3A priority Critical patent/CN107059486B/en
Publication of CN107059486A publication Critical patent/CN107059486A/en
Application granted granted Critical
Publication of CN107059486B publication Critical patent/CN107059486B/en

Links

Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/10—Packing paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/02—Metal coatings
    • D21H19/08—Metal coatings applied as vapour, e.g. in vacuum
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper

Abstract

The present invention relates to a kind of pearly-lustre holographic false proof paper and its preparation technology.The pearly-lustre holographic false proof paper, includes radium-shine layer, dielectric layer, pearl layer, glue layer, body paper successively from top to bottom.Preparation technology includes 1】Moldable coating is coated with transfer basement membrane；2】Molding laser information, obtains laser information layer on moldable coating；3】The spraying plating zinc sulphide on laser information layer, obtains dielectric layer；4】Pearl layer is coated with dielectric layer；5】Pearl layer and body paper are combined with glue；6】Transfer basement membrane is peeled off.Glue layer of the present invention does not interfere with the pearl effect of pearl layer below pearl layer.Medium is placed between pearl layer and radium-shine layer, laser information can be protected not disturbed by pearl layer well, laser information is clearly presented；The presence of dielectric layer also serves protective effect to pearl layer, pearl layer do not weakened, absorb or change incident ray because of the covering of radium-shine diffracting layer, anti-counterfeiting performance is stronger.

Description

A kind of pearly-lustre holographic false proof paper and its preparation technology
Technical field
The invention belongs to pack and decoration material field, it is related to a kind of pearly-lustre holographic false proof paper and its preparation technology.
Background technology
The packaging material of pearl effect plays an important role always in packaging field, in recent years radium-shine colorful bag Package material also increasingly receives an acclaim, and laser effect is in addition to itself can bring visual effect to consumer, moreover it is possible to enhancing production The anti-counterfeiting performance of product.With the improvement of living standards, requirement of the consumer to packaging material also more and more higher, simple iridescent paper Or laser paper can not meet the esthetic requirement of consumer as wrapping paper.There is the paper of pearly-lustre and laser effect simultaneously The attractive in appearance and class of wrapping paper can be lifted, meets the aesthetic requirement of present people.In the market temporarily also without a kind of product To integrate radium-shine with pearl effect, i.e. existing radium-shine distinctive diffracting effect on a sheet of paper, while there is pearlescent pigment again Distinctive change spar effect.
Patent is had at present discloses obtained pearly-lustre laser paper, patent of invention（CN 105525536 A ）Radium-shine pearly-lustre paperboard and its Preparation method, the preparation method of the invention is that pearl essence and glue are proportionally mixed to get into compo, and compound is applied Cloth is then combined with laser film, peeled off on paper.The patent is not aluminized or medium, is aluminized on laser film if do not increased Or plating medium effect, if being directly combined after molding with glue, that laser effect will disappear.Patent of invention（CN 104960353 A ）A kind of pearly-lustre laser paper and its preparation technology, preparation technology is：In the Bopp basement membranes with radium-shine layer Upper coating pearlescent pigment layer, medium is plated after carrying out surface tension reinforcement processing to pearly-lustre transfer layer in the above again, is being situated between afterwards One layer of transfer adhesive water layer is coated with matter layer；Former recto is combined with transfer adhesive water layer after the back of the body is applied again, and Bopp basement membranes are peeled off After obtain the invention product.The technique has plated one layer of medium on pearl layer, and pearl layer is protected using the transparency of medium. But, the invention is directly coated with pearl layer on laser information layer, does not have dielectric layer between radium-shine layer and pearl layer.Utility model Patent（CN 205188713 U）A kind of colorful pearly-lustre laser packing paper, is also that pearl layer is directly coated with laser information layer, There is no dielectric layer between radium-shine layer and pearl layer.The purpose of plating medium is pearly-lustre laser effect is kept transparent performance, can be obtained To more preferable pearly-lustre laser effect, while making the adhesion property of pearly-lustre transfer layer more preferable.
The content of the invention
Present invention mainly solves deficiency present in existing product, there is provided a kind of pearl effect is good, laser pattern is clear, peace The paper that loopful is protected, while providing a kind of preparation technology of pearly-lustre holographic false proof paper.
The present invention technical solution be：A kind of pearly-lustre holographic false proof paper, includes radium-shine layer, transparent successively from top to bottom Dielectric layer, pearl layer, glue layer, body paper.
The transparent dielectric layer is zinc sulphide transparent dielectric layer.
The pearl layer is not limited to full version, special edition or patterned pearl layer.
The radium-shine layer is not limited to the radium-shine layer of hollow out or the radium-shine layer of full version.
The preparation technology of above-mentioned pearly-lustre holographic false proof paper, including following process：
1】Transferable coating and heating, drying are coated with transfer basement membrane, moldable coating is obtained：, will be transferable on coating machine Coating is uniformly applied on PET basement membranes by anilox roll, and heating, drying obtains moldable coating；The cable roll can be The steel of 200~300 lines or ceramic cable roll；Coating speed is 100-150m/min speeds, and hot drying temperature is 80-150 DEG C； The PET film is reusable；Its thickness is 12 μm~18 μm；
2】Molding laser information, obtains laser information layer on moldable coating：The laser information layer is by vertical with three-dimensional The holographic Ni plate mould pressure of body pattern is formed, and moulding press molding speed is 40-60m/min, and molding temperature is 130-180 DEG C, molding Radium-shine thickness degree be 1.0 μm -1.5 μm；
3】The spraying plating zinc sulphide on laser information layer, obtains dielectric layer：By molybdenum boat by the zinc sulphide of high-purity on aluminum-spraying machine Spraying plating obtains dielectric layer on laser information layer；The % of the zinc sulphide purity >=99.0, the thickness of dielectric layers of spraying plating is in 0.15 μ M-0.25 μm, the vacuum of aluminum-spraying machine is 2 × 10-2 - 7×10 -2Pa；
4】Pearly coating is coated with dielectric layer by cable roll, pearl layer is obtained：The pearl essence of certain mass number is weighed, It is distributed under room temperature condition with mixer in aqueous polyurethane coating, stirring to pearl essence is completely dispersed uniformly.The pearl essence Particle diameter be 10 μm -80 μm, pearl essence weight/mass percentage composition is 10%-30%, preferably 15%-25%, and the pearl essence can be with It is white, gold, black, blueness etc.；
5】On compounding machine, the pearl layer and body paper on transfer basement membrane are combined with each other with glue, it is then solid through oven for drying Change；The glue requires it is transparent after drying, and obvious cover is not produced on the color on paper surface influences；It can use Commercially available specific complex glue；Paper can be 50~300g/m2Paper, paper be combined face color can be white, also can be in paper Open surface and be pre-coated with dyed layer, color can be the progressive coloured of various forms that are monochromatic or being produced by monochrome；
6】Transfer basement membrane is peeled off.
It is an advantage of the invention that：（1）The present invention paper good visual effect, it appear that be not merely radium-shine color Make oneself too remarkable, nor be only the gentle soft of pearly-lustre color and luster, but the combination of both visual effects.This combination is not only Conflict or contrast will not be constituted, a kind of deep graceful sense is given people on the contrary.Paper of the present invention has radium-shine and pearly-lustre antifalsification concurrently, Its antifalse effect is stronger, can be widely used in a variety of expensive goods packagings such as cosmetics, tobacco and wine, medicine, clothes.
（2）Due to aperture is distributed with radium-shine layer, laser effect is produced using the diffraction or reflection of light, pearlescent pigment contains There is particle, if being directly coated with pearl layer on radium-shine layer, pearlescent pigment can block aperture, weaken laser effect, therefore, this Shen Please transparent medium is placed between pearl layer and radium-shine layer, laser information can be protected not disturbed by pearl layer well, made Laser information is clearly presented；The presence of transparent dielectric layer also serves protective effect to pearl layer, moreover it is possible to make the pearly-lustre of pearl layer More preferably, pearl layer will not weaken, absorb or change incident ray to effect because of the covering of radium-shine diffracting layer, so that the color of pearly-lustre Pool can show that anti-counterfeiting performance is stronger completely.Pearl layer forms the background color of a floor height brightness below radium-shine layer, seemingly, to be upper The radium-shine color in face adds saturation degree, enriches visual experience.Product laser information complete display, the level finally obtained is rich Rich, pearl effect is preferable.Glue layer does not interfere with the pearl effect of pearl layer below pearl layer, yet.
（3）Present invention process is simple, and the PET film after stripping can be reused several times, cost-effective, is improving production efficiency While, also act the effect of energy-conserving and environment-protective；Aqueous polyurethane coating environmental pollution is small.
Brief description of the drawings
Fig. 1 is a kind of preparation technology route flow chart of pearly-lustre holographic false proof paper；
Fig. 2 is embodiment paper structure schematic diagram.
In figure：1st, radium-shine layer, 2, transparent dielectric layer, 3, pearl layer, 4, glue layer, 5, body paper.
Embodiment
The embodiment of the present invention is further illustrated by the following examples, but the invention is not restricted to institute in embodiment The specific embodiment of description.
Embodiment 1
1st, by moldable transfer coatings on coating machine with 100m/min speeds, be coated on 12 μm of PET films with 250 mesh cable rolls On surface, film after coating is 90 DEG C by temperature, 1000 DEG C, 130 DEG C, 120 DEG C of hot drying tunnels film forming is dried.
2. with moulding press with 40m/min speed, 20kg molding pressure, 130 DEG C of molding temperatures, by the horizontal net in nickel version Line light beam laser information stamp transfer is on moldable coating；The radium-shine thickness degree of molding is 1.0 μm, is obtained containing transverse web light The PET film of post laser pattern.
3rd, the PET film with laser information is sent into vacuum evaporating system, is 5 × 10 in vacuum-2 Spraying plating under the conditions of Pa The % of one 0.20 μm of thickness, purity >=99.0 ZnS dielectric layers.
4th, 25 parts are weighed, particle diameter is 15 μm of golden pearl essence, be distributed at ambient temperature with mixer 75 parts it is transparent In aqueous polyurethane coating, stirring to pearl essence is completely dispersed uniformly.Aqueous polyurethane coating is purchased from the U.S. macromolecule of Shandong Order Materials Co., Ltd.
5th, the pearlescent pigment obtained by step 4 is spread evenly across on dielectric layer with 250 lines ceramic rod on coating machine, be coated with Film afterwards by temperature be 100 DEG C, 120 DEG C, 110 DEG C, 100 DEG C of hot drying tunnels film forming is dried, obtain pearl layer.
6th, the PET film containing pearl layer is utilized into aqueous transparent glue and 300g/m2The white paperboard of grammes per square metre is combined, and is combined Machine speed is 110m/min, and composite pressure is 4.0kg/cm2, and oven temperature is set as 100 DEG C, 110 DEG C, 120 DEG C, 110 DEG C, Compound is 250 mesh ceramic rollers with cable roll.
7th, the paper after will be compound is peeled off PET film with 180m/min speed, all information on film on stripping machine Stay on paper, obtain radium-shine pearly-lustre without aluminium paper, the PET film rewinding after stripping is stand-by.
Above example has following beneficial effect：
The paper that present invention process is obtained gives people to bring a kind of soft, noble visual phenomenon, fine grain golden pearlescent pigment Formation can bring simple and elegant, fine and smooth silkiness gloss, after laser effect is combined, make the whole structure of whole more preferably excellent.I Observe gloss occur multiple refraction in pearicoat via incident ray after be compounded to form, so pearicoat Show the uncertainty of texture as a kind of similar pearl and position sense.Laser effect and pearl effect are independent of each other.
Embodiment 2
1st, by moldable transfer coatings on coating machine with 120m/min speeds, be coated on 15 μm of PET films with 200 mesh cable rolls On surface, film after coating is 90 DEG C by temperature, 130 DEG C, 140 DEG C, 120 DEG C of hot drying tunnels film forming is dried.
2. with moulding press with 50m/min speed, 22kg molding pressure, 150 DEG C of molding temperatures, by the vegetarian noodles in nickel version Laser information stamp transfer is on moldable coating；The radium-shine thickness degree of molding is 1.5 μm, is obtained containing fresh laser pattern PET film.
3rd, the PET film with laser information is sent into vacuum evaporating system, is 5 × 10 in vacuum-2 Spraying plating under the conditions of Pa The % of one 0.20 μm of thickness, purity >=99.0 ZnS dielectric layers.
4th, 15 parts are weighed, particle diameter is 40 μm of white pearlescent powder, is distributed to 85 parts of bluenesss with mixer at ambient temperature In aqueous polyurethane coating, stirring to pearl essence is completely dispersed uniformly.
5th, the pearlescent pigment obtained by step 4 is spread evenly across on dielectric layer with 300 lines ceramic rod on coating machine, be coated with Film afterwards by temperature be 90 DEG C, 110 DEG C, 110 DEG C, 100 DEG C of hot drying tunnels film forming is dried, obtain pearl layer.
6th, the PET film containing pearl layer is utilized into aqueous transparent glue and 175g/m2The white paperboard of grammes per square metre is combined, and is combined Machine speed is 120m/min, and composite pressure is 4.2kg/cm2, and oven temperature is set as 110 DEG C, 120 DEG C, 130 DEG C, 120 DEG C, Compound is 250 mesh ceramic rollers with cable roll.
7th, the paper after will be compound is peeled off PET film with 160m/min speed, all information on film on stripping machine Stay on paper, obtain radium-shine pearly-lustre without aluminium paper, the PET film rewinding after stripping is stand-by.
Above example has following beneficial effect：
The paper that present invention process is obtained gives people to bring a kind of visual phenomenon for having depth, being imbued with innervation.It is white in blue coating paper Pearly-lustre flashes light, after being combined together with fresh laser effect, just as a piece of sparkling sea, beautiful grand. It is can see during observation on same surface, different points of view has delicate difference, be not merely gloss, also color.By Scattering is produced at pigment edge in material, we are readily observed glistening starlight effect.The radium-shine perfect knot with pearly-lustre Close, our more rich visual effect.
Embodiment 3
1st, by moldable transfer coatings on coating machine with 150m/min speeds, be coated on 18 μm of PET films with 300 mesh cable rolls On surface, film after coating is 90 DEG C by temperature, 120 DEG C, 110 DEG C, 110 DEG C of hot drying tunnels film forming is dried.
2. with moulding press with 60m/min speed, 23kg molding pressure, 175 DEG C of molding temperatures, by the minute surface in nickel version Light beam laser information stamp transfer is on moldable coating；The radium-shine thickness degree of molding is 1.2 μm, is obtained containing the radium-shine figure of minute surface The PET film of case.
3rd, the PET film with laser information is sent into vacuum evaporating system, is 5 × 10 in vacuum-2 Spraying plating under the conditions of Pa The % of one 0.20 μm of thickness, purity >=99.0 ZnS dielectric layers.
4th, 20 parts are weighed, particle diameter is 80 μm of red pearl essence, be distributed at ambient temperature with mixer 80 parts it is transparent In aqueous polyurethane coating, stirring to pearl essence is completely dispersed uniformly.
5th, the local hollow out steel rod of 300 lines for being carved with maple leaf pattern is used on coating machine by the pearlescent pigment obtained by step 4 Be spread evenly across on dielectric layer, the film after coating is 100 DEG C by temperature, 110 DEG C, 110 DEG C, 100 DEG C of hot drying tunnels are done Dry film forming, obtains pearl layer.
6th, the PET film containing pearl layer is utilized into aqueous transparent glue and 70g/m2The white paperboard of grammes per square metre is combined, and is combined Machine speed is 110m/min, and composite pressure is 4.0kg/cm2, and oven temperature is set as 110 DEG C, 120 DEG C, 130 DEG C, 120 DEG C, Compound is 200 mesh ceramic rollers with cable roll.
7th, the paper after will be compound is peeled off PET film with 150m/min speed, all information on film on stripping machine Stay on paper, obtain radium-shine pearly-lustre without aluminium paper, the PET film rewinding after stripping is stand-by.
Above example has following beneficial effect：
The paper that present invention process is obtained is a kind of special edition hollow out paper, and it is not full width pearly-lustre, according to the coating steel rod of design, Only there is pearl effect on pattern maple leaf, and maple leaf pattern is red.The design of pierced pattern more highlights pattern colorful effect Really, while antifalse effect is stronger.
The above described is only a preferred embodiment of the present invention, not the structure to the present invention makees any formal limitation. Any simple modification, equivalent variations and modification that every technical spirit according to the present invention is made to above example, each fall within In protection scope of the present invention.

Claims (10)

1. a kind of pearly-lustre holographic false proof paper, it is characterised in that include successively from top to bottom radium-shine layer, transparent dielectric layer, pearl layer, Glue layer, body paper.
2. pearly-lustre holographic false proof paper according to claim 1, it is characterised in that the transparent dielectric layer is that zinc sulphide is transparent Dielectric layer.
3. pearly-lustre holographic false proof paper according to claim 1 or 2, it is characterised in that the radium-shine layer is the radium-shine layer of hollow out Or the radium-shine layer of full version.
4. pearly-lustre holographic false proof paper according to claim 3, it is characterised in that the pearl layer is full version, special edition or band The pearl layer of pattern.
5. the preparation technology of pearly-lustre holographic false proof paper according to claim 1, it is characterised in that including entering in chronological order Capable following process：
1】Transferable coating and heating, drying are coated with transfer basement membrane, moldable coating is obtained；
2】Molding laser information, obtains laser information layer on moldable coating；
3】The spraying plating medium on laser information layer, obtains transparent dielectric layer；
4】Pearly coating is coated with transparent dielectric layer, pearl layer is obtained；
5】Pearl layer and body paper are combined with each other with glue, then baking and curing；
6】Transfer basement membrane is peeled off.
6. the preparation technology of pearly-lustre holographic false proof paper according to claim 5, it is characterised in that the pearly coating is logical Cross the dispersed pearl essence in aqueous polyurethane coating and prepare.
7. the preparation technology of pearly-lustre holographic false proof paper according to claim 6, it is characterised in that the quality of the pearl essence Percentage composition is 10%-30%.
8. the preparation technology of pearly-lustre holographic false proof paper according to claim 7, it is characterised in that the pearl essence particle diameter is 5-100μm。
9. the preparation technology of pearly-lustre holographic false proof paper according to claim 7, it is characterised in that the body paper is 50~ 300g/m2Paper.
10. the preparation technology of pearly-lustre holographic false proof paper according to claim 9, it is characterised in that the transfer basement membrane is PET film；The transfer basement membrane thickness is 12~22 μm.
CN201710373934.3A 2017-05-24 2017-05-24 A kind of pearly-lustre holographic false proof paper and its preparation process CN107059486B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710373934.3A CN107059486B (en) 2017-05-24 2017-05-24 A kind of pearly-lustre holographic false proof paper and its preparation process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710373934.3A CN107059486B (en) 2017-05-24 2017-05-24 A kind of pearly-lustre holographic false proof paper and its preparation process

Publications (2)

Publication Number Publication Date
CN107059486A true CN107059486A (en) 2017-08-18
CN107059486B CN107059486B (en) 2019-01-11

Family

ID=59609714

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710373934.3A CN107059486B (en) 2017-05-24 2017-05-24 A kind of pearly-lustre holographic false proof paper and its preparation process

Country Status (1)

Country Link
CN (1) CN107059486B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108394157A (en) * 2017-10-13 2018-08-14 厦门富桂通科技有限公司 A kind of wear-resisting composite membrane of stretch-proof and preparation method thereof
CN109024074A (en) * 2018-08-09 2018-12-18 高阳 A kind of bloom pearly-lustre laser paper and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102896855A (en) * 2012-09-17 2013-01-30 西安工业大学 Glass bead type anti-counterfeiting film and preparation method thereof
CN103342064A (en) * 2013-07-12 2013-10-09 上海宏盾防伪材料有限公司 Positioning laser certificate anti-fake thin film for individually printing and preparation method thereof
CN205188713U (en) * 2015-11-09 2016-04-27 中山市金海包装科技有限公司 Radium -shine wrapping paper of colorful pearly -lustre
CN205416790U (en) * 2015-12-02 2016-08-03 广东壮丽彩印股份有限公司 Printing material structure with anti -fake function of paper money line

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102896855A (en) * 2012-09-17 2013-01-30 西安工业大学 Glass bead type anti-counterfeiting film and preparation method thereof
CN103342064A (en) * 2013-07-12 2013-10-09 上海宏盾防伪材料有限公司 Positioning laser certificate anti-fake thin film for individually printing and preparation method thereof
CN205188713U (en) * 2015-11-09 2016-04-27 中山市金海包装科技有限公司 Radium -shine wrapping paper of colorful pearly -lustre
CN205416790U (en) * 2015-12-02 2016-08-03 广东壮丽彩印股份有限公司 Printing material structure with anti -fake function of paper money line

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108394157A (en) * 2017-10-13 2018-08-14 厦门富桂通科技有限公司 A kind of wear-resisting composite membrane of stretch-proof and preparation method thereof
CN108394157B (en) * 2017-10-13 2020-03-17 厦门富桂通科技有限公司 Stretch-resistant wear-resistant composite film and preparation method thereof
CN109024074A (en) * 2018-08-09 2018-12-18 高阳 A kind of bloom pearly-lustre laser paper and preparation method thereof

Also Published As

Publication number Publication date
CN107059486B (en) 2019-01-11

Similar Documents

Publication Publication Date Title
CN103080992B (en) Safety label or adhesive tape with tamper-proofing
JP4878884B2 (en) Decorative sheet
US4797308A (en) Simulated mother-of-pearl
CN105659309B (en) For decorating the label, bottle and the method for processing this label of bottle
CN104960353B (en) A kind of pearly-lustre laser paper and its preparation technology
JP5598793B2 (en) Fabric seal, silk fabric seal, and manufacturing method thereof
JP5683495B2 (en) PRINTABLE MULTILAYER SHEET HAVING SOFT OR SILK FEEL AND METHOD FOR PRODUCING THE SHEET
CN201622859U (en) Portable product shell
CN101849067A (en) Sheet having at least one watermark or pseudo-watermark observable only on one side of the sheet
CN102634116A (en) Base paper of antiflaming environment-friendly rich mineral paper and manufacturing method of the base paper
US4256794A (en) Blocking foil
CN105286146B (en) A kind of fancy reflection cloth and preparation method thereof
CN105220580B (en) A kind of crisperding 3D embossment wallpapers and preparation method thereof
CN105587084A (en) Gypsum plaster board, preparation method and use method thereof
CN105002773B (en) A kind of citicall limited aluminium antifake lottery paper and its manufacture method
TWI472809B (en) Process for reflective products
JP6037371B2 (en) Powder-supported thin film
CN201254046Y (en) Stereoscopic paster
CN101670744B (en) Decorative film and manufacturing method thereof
CN103171351B (en) Preparation method of high-fidelity heat sublimation transfer paper base function material
CN202611157U (en) Art wall cloth
CA2641677A1 (en) Film material comprising at least one watermark having a coloured nuance
CN101815616B (en) Light-blocking decorative sheet
MXPA00003207A (en) Label adhesive with dispersed refractive particles.
CN103774493B (en) A kind of laser direct plating paper and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant