CN108385437A - A kind of fire-retardant papermaking paint - Google Patents
A kind of fire-retardant papermaking paint Download PDFInfo
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- CN108385437A CN108385437A CN201711353510.7A CN201711353510A CN108385437A CN 108385437 A CN108385437 A CN 108385437A CN 201711353510 A CN201711353510 A CN 201711353510A CN 108385437 A CN108385437 A CN 108385437A
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- retardant
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/46—Non-macromolecular organic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/46—Non-macromolecular organic compounds
- D21H19/48—Diolefins, e.g. butadiene; Aromatic vinyl monomers, e.g. styrene; Polymerisable unsaturated acids or derivatives thereof, e.g. acrylic acid
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/52—Cellulose; Derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/62—Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/64—Inorganic compounds
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Paper (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention provides a kind of fire-retardant papermaking paint, which is characterized in that includes the component of following parts by weight：Waterborne polyurethane resin 25 36, methyl methacrylate 28 43, ethylene vinyl acetate 17 29, disodium ethylene diamine tetraacetate 18 25, polyethylene glycol 12 19, dispersant 11 19, thickener 7 13, antifoaming agent 6 13, pH adjusting agent 8 22, nanoscale silica hollow microspheres 45 62, Polyhaxemethylenguanidine Hydrochloride 13 24, distilled water 51 74, nano-graphene particle 22 35, silicon nitride ceramic 21 38,49 molecular sieves 34 55 of nanoscale MCM.By regulating and controlling the proportioning of ceramic powder and tiny balloon in the present invention, optimizes Compatibility of Coating Color, assign the functions such as paper anti-microbial property, flame retardant property, salt spray resistance；Improve the printability of coating paper simultaneously.
Description
Technical field
The invention belongs to functional material and pulp technology for making paper, and in particular to a kind of fire-retardant papermaking paint.
Background technology
Coating paper be at least one surface of body paper coating to be dried after pigment coating as main component and
It is formed.Coating paper can be used as the commercial prints objects such as poster, brochure, advertisement poster after polychrome printing or single color printing, or make
For publications such as books, magazines, it is widely used in routine work and life.
The property of coating directly affects ways and methods.A kind of existing common coating be based on starch,
When being produced applied to coating paper, the operability of coating operations is poor, coating weight is relatively low.Lower coating weight can not provide good
The problems such as good surface property, that there are surface roughnesses is larger for gained coating paper, anti-floating poor performance.The coating of coating simultaneously
Can be single, it cannot assign paper new function, be unfavorable for the development of coating paper.
Invention content
In view of this, the present invention provides a kind of fire-retardant papermaking paint, by regulating and controlling ceramic powder and tiny balloon in the present invention
Proportioning, optimize Compatibility of Coating Color, assign the functions such as paper anti-microbial property, flame retardant property, salt spray resistance；Improve coating simultaneously
The printability of paper.
The technical scheme is that：A kind of fire-retardant papermaking paint, which is characterized in that include the group of following parts by weight
Point：Waterborne polyurethane resin 25-36, methyl methacrylate 28-43, ethane-acetic acid ethyenyl ester 17-29, second two
Amine tetraacethyl disodium 18-25, polyethylene glycol 12-19, dispersant 11-19, thickener 7-13, antifoaming agent 6-13, pH are adjusted
Agent 8-22, nanoscale silica hollow microspheres 45-62, Polyhaxemethylenguanidine Hydrochloride 13-24, distilled water 115-160, nanometer
Graphene particles 22-35, silicon nitride ceramic 21-38, nanoscale MCM-49 molecular sieves 34-55.
Further, the grain diameter of the nanoscale silica hollow microspheres is 200-400nm.
Further, the grain diameter of the nanoscale MCM-49 molecular sieves is 100-200nm.
Further, the dispersant is lauryl sodium sulfate, methyl anyl alcohol, guar gum, fatty acid polyethylene glycol ester
In one kind.
Further, the thickener is hydroxypropyl methyl cellulose.
Further, the antifoaming agent is dimethyl silicone polymer.
Further, the pH adjusting agent is aminomethyl propanol.
In the present invention, pass through nanoscale silica hollow microspheres, Polyhaxemethylenguanidine Hydrochloride, nano-graphene particle, nitrogen
The synergistic complex role of SiClx ceramic powder, nanoscale MCM-49 molecular sieves, nanoscale silica hollow microspheres and nanoscale MCM-
There is unique three-dimensional netted space structure inside 49 molecular sieves, Polyhaxemethylenguanidine Hydrochloride, nano-graphene can be adsorbed
Particle achievees the effect that sustained release, significantly improves the antibacterial ability of coating of the present invention, while the silicon nitride ceramic added assigns this
Invention coating others functional characteristic；The effect of the helper components such as middle disodium ethylene diamine tetraacetate, polyethylene glycol through the invention,
Instant component can be made fully to merge, and there can be good adsorption capacity with paper.
Beneficial effects of the present invention：1. antibacterial paper paint preparation process of the present invention carries out at normal temperatures and pressures, it is not required to
New equipment is added, simple for process, production cost is low.After 2. coating of the present invention is coated on paper, assisted by each component
Effect acts on, and not only can effectively improve the functions such as anti-microbial property, flame retardant property, the salt spray resistance of paper, but also can assign paper
Good printability.3. being compared to antiseptic mode advantage is added in slurry：Retention rate is preferable, will not cause production process
In antiseptic waste, raw material can be saved；Its dosage added can be according to the requirement of the paper produced in wide range
It changes.
Preferably, preparation method of the invention is：Foundation is formulated aqueous polyurethane resin, metering system above
Sour methyl esters, ethane-acetic acid ethyenyl ester, disodium ethylene diamine tetraacetate, polyethylene glycol, dispersant are added in the water of coating dispersion bucket,
Rate of dispersion is maintained at 5000r/min, and jitter time reduces rotating speed to 2000r/min, antifoaming agent is added and continues to mix after being 15min
10min is closed, nanoscale silica hollow microspheres, Polyhaxemethylenguanidine Hydrochloride, nano-graphene particle, silicon nitride ceramics are added
Powder, nanoscale MCM-49 molecular sieves are gradually increased rotating speed to 8000r/min, after persistently disperseing 25min, then reduce rotating speed extremely
Thickener, pH adjusting agent is added in 2000r/min, disperses 10min, and the fire-retardant papermaking paint that solid content is 30-45% is made.
The present invention application method be：It is placed on body paper is smooth as required on coating machine, pressure tensioning volume, then coating
Volume it is pressed in top of form, puts down fixed-wing, take a certain amount of fire-retardant papermaking paint, is evenly distributed on top of form, start button,
Paper Coating is completed, and the paper after coating speed 30m/min coatings is put into pattern flash dryer, and 105 DEG C of drying temperature is dry
Time is 45s, according to paper made from the above paint formulation and coating process, through shaking the detection of flask standard measure, the results showed that,
Coating coating paper has reached 97% or more to staphylococcus aureus antimicrobial efficiency；Meanwhile after the coating of the above paint formulation,
The printability of paper is obviously improved.
Specific implementation mode
Technical scheme of the present invention is clearly and completely described below in conjunction with embodiment, it is clear that described reality
It is only a part of the embodiment of the present invention to apply example, instead of all the embodiments.
Embodiment 1
A kind of fire-retardant papermaking paint, which is characterized in that include the component of following parts by weight：Waterborne polyurethane resin
27, methyl methacrylate 32, ethane-acetic acid ethyenyl ester 21, disodium ethylene diamine tetraacetate 22, polyethylene glycol 15, dispersant
13, thickener 10, antifoaming agent 9, pH adjusting agent 14, nanoscale silica hollow microspheres 53, Polyhaxemethylenguanidine Hydrochloride
19, distilled water 130, nano-graphene particle 26, silicon nitride ceramic 27, nanoscale MCM-49 molecular sieves 45.
Further, the grain diameter of the nanoscale silica hollow microspheres is 300nm.
Further, the grain diameter of the nanoscale MCM-49 molecular sieves is 180nm.
Further, the dispersant is lauryl sodium sulfate.
Further, the thickener is hydroxypropyl methyl cellulose.
Further, the antifoaming agent is dimethyl silicone polymer.
Further, the pH adjusting agent is aminomethyl propanol.
In the present invention, pass through nanoscale silica hollow microspheres, Polyhaxemethylenguanidine Hydrochloride, nano-graphene particle, nitrogen
The synergistic complex role of SiClx ceramic powder, nanoscale MCM-49 molecular sieves, nanoscale silica hollow microspheres and nanoscale MCM-
There is unique three-dimensional netted space structure inside 49 molecular sieves, Polyhaxemethylenguanidine Hydrochloride, nano-graphene can be adsorbed
Particle achievees the effect that sustained release, significantly improves the antibacterial ability of coating of the present invention, while the silicon nitride ceramic added assigns this
Invention coating others functional characteristic；The effect of the helper components such as middle disodium ethylene diamine tetraacetate, polyethylene glycol through the invention,
Instant component can be made fully to merge, and there can be good adsorption capacity with paper.
Beneficial effects of the present invention：1. antibacterial paper paint preparation process of the present invention carries out at normal temperatures and pressures, it is not required to
New equipment is added, simple for process, production cost is low.After 2. coating of the present invention is coated on paper, assisted by each component
Effect acts on, and not only can effectively improve the functions such as anti-microbial property, flame retardant property, the salt spray resistance of paper, but also can assign paper
Good printability.3. being compared to antiseptic mode advantage is added in slurry：Retention rate is preferable, will not cause production process
In antiseptic waste, raw material can be saved；Its dosage added can be according to the requirement of the paper produced in wide range
It changes.
Preferably, preparation method of the invention is：Foundation is formulated aqueous polyurethane resin, metering system above
Sour methyl esters, ethane-acetic acid ethyenyl ester, disodium ethylene diamine tetraacetate, polyethylene glycol, dispersant are added in the water of coating dispersion bucket,
Rate of dispersion is maintained at 5000r/min, and jitter time reduces rotating speed to 2000r/min, antifoaming agent is added and continues to mix after being 15min
10min is closed, nanoscale silica hollow microspheres, Polyhaxemethylenguanidine Hydrochloride, nano-graphene particle, silicon nitride ceramics are added
Powder, nanoscale MCM-49 molecular sieves are gradually increased rotating speed to 8000r/min, after persistently disperseing 25min, then reduce rotating speed extremely
Thickener, pH adjusting agent is added in 2000r/min, disperses 10min, and the fire-retardant papermaking paint of the present invention is made.
Embodiment 2
A kind of fire-retardant papermaking paint, which is characterized in that include the component of following parts by weight：Waterborne polyurethane resin
25, methyl methacrylate 28, ethane-acetic acid ethyenyl ester 17, disodium ethylene diamine tetraacetate 18, polyethylene glycol 12, dispersant
11, thickener 7, antifoaming agent 6, pH adjusting agent 8, nanoscale silica hollow microspheres 45, Polyhaxemethylenguanidine Hydrochloride 13,
Distilled water 115, nano-graphene particle 22, silicon nitride ceramic 21, nanoscale MCM-49 molecular sieves 34.
Further, the grain diameter of the nanoscale silica hollow microspheres is 200nm.
Further, the grain diameter of the nanoscale MCM-49 molecular sieves is 100nm.
Further, the dispersant is methyl anyl alcohol.
Further, the thickener is hydroxypropyl methyl cellulose.
Further, the antifoaming agent is dimethyl silicone polymer.
Further, the pH adjusting agent is aminomethyl propanol.
Embodiment 3
A kind of fire-retardant papermaking paint, which is characterized in that include the component of following parts by weight：Waterborne polyurethane resin
36, methyl methacrylate 43, ethane-acetic acid ethyenyl ester 29, disodium ethylene diamine tetraacetate 25, polyethylene glycol 19, dispersant
19, thickener 13, antifoaming agent 13, pH adjusting agent 22, nanoscale silica hollow microspheres 62, Polyhaxemethylenguanidine Hydrochloride
24, distilled water 160, nano-graphene particle 35, silicon nitride ceramic 38, nanoscale MCM-49 molecular sieves 55.
Further, the grain diameter of the nanoscale silica hollow microspheres is 400nm.
Further, the grain diameter of the nanoscale MCM-49 molecular sieves is 200nm.
Further, the dispersant is guar gum.
Further, the thickener is hydroxypropyl methyl cellulose.
Further, the antifoaming agent is dimethyl silicone polymer.
Further, the pH adjusting agent is aminomethyl propanol.
Embodiment 4
A kind of fire-retardant papermaking paint, which is characterized in that include the component of following parts by weight：Waterborne polyurethane resin
28, methyl methacrylate 35, ethane-acetic acid ethyenyl ester 20, disodium ethylene diamine tetraacetate 22, polyethylene glycol 14, dispersant
13, thickener 10, antifoaming agent 9, pH adjusting agent 16, nanoscale silica hollow microspheres 52, Polyhaxemethylenguanidine Hydrochloride
18, distilled water 138, nano-graphene particle 27, silicon nitride ceramic 26, nanoscale MCM-49 molecular sieves 41.
Further, the grain diameter of the nanoscale silica hollow microspheres is 250nm.
Further, the grain diameter of the nanoscale MCM-49 molecular sieves is 150nm.
Further, the dispersant is fatty acid polyethylene glycol ester.
Further, the thickener is hydroxypropyl methyl cellulose.
Further, the antifoaming agent is dimethyl silicone polymer.
Further, the pH adjusting agent is aminomethyl propanol.
Embodiment 5
A kind of fire-retardant papermaking paint, which is characterized in that include the component of following parts by weight：Waterborne polyurethane resin
34, methyl methacrylate 38, ethane-acetic acid ethyenyl ester 25, disodium ethylene diamine tetraacetate 23, polyethylene glycol 17, dispersant
16, thickener 11, antifoaming agent 10, pH adjusting agent 19, nanoscale silica hollow microspheres 58, Polyhaxemethylenguanidine Hydrochloride
22, distilled water 150, nano-graphene particle 32, silicon nitride ceramic 35, nanoscale MCM-49 molecular sieves 53.
Further, the grain diameter of the nanoscale silica hollow microspheres is 350nm.
Further, the grain diameter of the nanoscale MCM-49 molecular sieves is 130nm.
Further, the dispersant is lauryl sodium sulfate.
Further, the thickener is hydroxypropyl methyl cellulose.
Further, the antifoaming agent is dimethyl silicone polymer.
Further, the pH adjusting agent is aminomethyl propanol.
Embodiment 6
A kind of fire-retardant papermaking paint, which is characterized in that include the component of following parts by weight：Waterborne polyurethane resin
32, methyl methacrylate 37, ethane-acetic acid ethyenyl ester 24, disodium ethylene diamine tetraacetate 21, polyethylene glycol 16, dispersant
17, thickener 9, antifoaming agent 11, pH adjusting agent 18, nanoscale silica hollow microspheres 54, Polyhaxemethylenguanidine Hydrochloride
17, distilled water 146, nano-graphene particle 29, silicon nitride ceramic 27, nanoscale MCM-49 molecular sieves 39.
Further, the grain diameter of the nanoscale silica hollow microspheres is 250nm.
Further, the grain diameter of the nanoscale MCM-49 molecular sieves is 160nm.
Further, the dispersant is methyl anyl alcohol.
Further, the thickener is hydroxypropyl methyl cellulose.
Further, the antifoaming agent is dimethyl silicone polymer.
Further, the pH adjusting agent is aminomethyl propanol.
Comparative example 1
A kind of fire-retardant papermaking paint, which is characterized in that include the component of following parts by weight：Waterborne polyurethane resin
32, methyl methacrylate 37, ethane-acetic acid ethyenyl ester 24, disodium ethylene diamine tetraacetate 21, polyethylene glycol 16, dispersant
17, thickener 9, antifoaming agent 11, pH adjusting agent 18, Polyhaxemethylenguanidine Hydrochloride 17, distilled water 146, silicon nitride ceramic
27, nanoscale MCM-49 molecular sieves 39.
Further, the grain diameter of the nanoscale MCM-49 molecular sieves is 160nm.
Further, the dispersant is methyl anyl alcohol.
Further, the thickener is hydroxypropyl methyl cellulose.
Further, the antifoaming agent is dimethyl silicone polymer.
Further, the pH adjusting agent is aminomethyl propanol.
Comparative example 2
A kind of fire-retardant papermaking paint, which is characterized in that include the component of following parts by weight：Waterborne polyurethane resin
32, methyl methacrylate 37, ethane-acetic acid ethyenyl ester 24, dispersant 17, thickener 9, antifoaming agent 11, pH adjusting agent
18, nanoscale silica hollow microspheres 54, Polyhaxemethylenguanidine Hydrochloride 17, distilled water 146, nano-graphene particle 29,
Silicon nitride ceramic 27, nanoscale MCM-49 molecular sieves 39.
Further, the grain diameter of the nanoscale silica hollow microspheres is 250nm.
Further, the grain diameter of the nanoscale MCM-49 molecular sieves is 160nm.
Further, the dispersant is methyl anyl alcohol.
Further, the thickener is hydroxypropyl methyl cellulose.
Further, the antifoaming agent is dimethyl silicone polymer.
Further, the pH adjusting agent is aminomethyl propanol.
Comparative example 3
A kind of fire-retardant papermaking paint, which is characterized in that include the component of following parts by weight：Waterborne polyurethane resin
32, methyl methacrylate 37, ethane-acetic acid ethyenyl ester 24, disodium ethylene diamine tetraacetate 21, polyethylene glycol 16, dispersant
17, thickener 9, antifoaming agent 11, pH adjusting agent 18, nanoscale silica hollow microspheres 54, Polyhaxemethylenguanidine Hydrochloride
17, distilled water 146, nano-graphene particle 29.
Further, the grain diameter of the nanoscale silica hollow microspheres is 250nm.
Further, the dispersant is methyl anyl alcohol.
Further, the thickener is hydroxypropyl methyl cellulose.
Further, the antifoaming agent is dimethyl silicone polymer.
Further, the pH adjusting agent is aminomethyl propanol.
Coating property is tested
Salt spray resistance
By the paint spraying in embodiment and comparative example in wooden test piece.After paint spraying, stands 48 hours and wait for that coating is completely solid
It is tested after chemical conversion film.Adhesive force test, neutral salt spray test carried out to above-mentioned coating, test method according to《GB/T
1720-1979 paint film adhesion measuring methods》、《GB/T 10125-2012 artificial atmosphere corrosion test salt spray tests》It carries out, surveys
Test result such as following table.
Anti-microbial property and flame retardant property
Anti-microbial property test is carried out according to GB/T 21866-2008；According to GB1244-2005 using cell combustion method to above-mentioned
The coating of embodiment carries out flame retardant property test, and the results are shown in table below.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, and do not carrying on the back
In the case of spirit or essential attributes from the present invention, the present invention can be realized in other specific forms.Therefore, no matter from which
From the point of view of a bit, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is wanted by appended right
Ask rather than above description limit, it is intended that by all changes that come within the meaning and range of equivalency of the claims
It is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiment being appreciated that.It is noted that the technical characteristic not being described in detail in the present invention, can pass through this
Field any prior art is realized.
Claims (7)
1. a kind of fire-retardant papermaking paint, which is characterized in that include the component of following parts by weight：Waterborne polyurethane resin
25-36, methyl methacrylate 28-43, ethane-acetic acid ethyenyl ester 17-29, disodium ethylene diamine tetraacetate 18-25, poly- second two
Alcohol 12-19, dispersant 11-19, thickener 7-13, antifoaming agent 6-13, pH adjusting agent 8-22, nano silicon dioxide are hollow
Microballoon 45-62, Polyhaxemethylenguanidine Hydrochloride 13-24, distilled water 115-160, nano-graphene particle 22-35, silicon nitride
Ceramic powder 21-38, nanoscale MCM-49 molecular sieves 34-55.
2. fire-retardant papermaking paint according to claim 1, which is characterized in that of the nanoscale silica hollow microspheres
Grain grain size is 200-400nm.
3. fire-retardant papermaking paint according to claim 1, which is characterized in that the particle of the nanoscale MCM-49 molecular sieves
Grain size is 100-200nm.
4. fire-retardant papermaking paint according to claim 1, which is characterized in that the dispersant be lauryl sodium sulfate,
One kind in methyl anyl alcohol, guar gum, fatty acid polyethylene glycol ester.
5. fire-retardant papermaking paint according to claim 1, which is characterized in that the thickener is hydroxypropyl methyl fiber
Element.
6. fire-retardant papermaking paint according to claim 1, which is characterized in that the antifoaming agent is dimethyl silicone polymer.
7. fire-retardant papermaking paint according to claim 1, which is characterized in that the pH adjusting agent is aminomethyl propanol.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711353510.7A CN108385437A (en) | 2017-12-15 | 2017-12-15 | A kind of fire-retardant papermaking paint |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711353510.7A CN108385437A (en) | 2017-12-15 | 2017-12-15 | A kind of fire-retardant papermaking paint |
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| CN108385437A true CN108385437A (en) | 2018-08-10 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109988469A (en) * | 2019-03-25 | 2019-07-09 | 惠州左右家私有限公司 | A kind of water-based paint compositions for Furniture manufacturing |
| CN112080962A (en) * | 2020-09-04 | 2020-12-15 | 中国制浆造纸研究院有限公司 | Flame-retardant coating for cigarette paper, low-ignition-tendency cigarette paper and preparation method thereof |
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| CN101512070A (en) * | 2006-09-26 | 2009-08-19 | 赢创德固赛公司 | Multi-functional paper for enhanced printing performance |
| CN105419438A (en) * | 2015-12-30 | 2016-03-23 | 李栋军 | Novel paint auxiliary agent |
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Application publication date: 20180810 |