CN107129185A - A kind of true mineral varnish and preparation method thereof - Google Patents
A kind of true mineral varnish and preparation method thereof Download PDFInfo
- Publication number
- CN107129185A CN107129185A CN201710258419.0A CN201710258419A CN107129185A CN 107129185 A CN107129185 A CN 107129185A CN 201710258419 A CN201710258419 A CN 201710258419A CN 107129185 A CN107129185 A CN 107129185A
- Authority
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- China
- Prior art keywords
- parts
- mineral varnish
- true mineral
- pure
- quartz sand
- Prior art date
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- Granted
Links
- 229910052500 inorganic mineral Inorganic materials 0.000 title claims abstract description 82
- 239000011707 mineral Substances 0.000 title claims abstract description 82
- 239000002966 varnish Substances 0.000 title claims abstract description 82
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 56
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 54
- 239000006004 Quartz sand Substances 0.000 claims abstract description 48
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 44
- 229920002678 cellulose Polymers 0.000 claims abstract description 42
- 235000010980 cellulose Nutrition 0.000 claims abstract description 42
- 239000000839 emulsion Substances 0.000 claims abstract description 41
- 239000002562 thickening agent Substances 0.000 claims abstract description 34
- 239000002002 slurry Substances 0.000 claims abstract description 31
- 235000012216 bentonite Nutrition 0.000 claims abstract description 28
- 239000003755 preservative agent Substances 0.000 claims abstract description 23
- 239000003002 pH adjusting agent Substances 0.000 claims abstract description 22
- 239000001913 cellulose Substances 0.000 claims description 27
- 239000000440 bentonite Substances 0.000 claims description 12
- 229910000278 bentonite Inorganic materials 0.000 claims description 12
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- -1 dioctyl ester Chemical class 0.000 claims description 7
- 230000004048 modification Effects 0.000 claims description 7
- 238000012986 modification Methods 0.000 claims description 7
- 230000002335 preservative effect Effects 0.000 claims description 7
- 239000003822 epoxy resin Substances 0.000 claims description 6
- 229920000647 polyepoxide Polymers 0.000 claims description 6
- 239000004576 sand Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 4
- 239000010453 quartz Substances 0.000 claims description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 125000005396 acrylic acid ester group Chemical group 0.000 claims 1
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 238000000576 coating method Methods 0.000 abstract description 15
- 239000011248 coating agent Substances 0.000 abstract description 10
- 238000002845 discoloration Methods 0.000 abstract description 5
- 230000002087 whitening effect Effects 0.000 abstract description 5
- 239000000470 constituent Substances 0.000 abstract description 3
- 238000005457 optimization Methods 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 3
- 239000004035 construction material Substances 0.000 abstract description 2
- 239000003973 paint Substances 0.000 description 30
- 230000000052 comparative effect Effects 0.000 description 23
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 17
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 10
- 150000002148 esters Chemical class 0.000 description 10
- 239000002245 particle Substances 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
- 239000007888 film coating Substances 0.000 description 8
- 238000009501 film coating Methods 0.000 description 8
- 238000003860 storage Methods 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 7
- 239000004579 marble Substances 0.000 description 7
- 239000004575 stone Substances 0.000 description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 5
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 5
- 235000011037 adipic acid Nutrition 0.000 description 5
- 239000001361 adipic acid Substances 0.000 description 5
- 239000003513 alkali Substances 0.000 description 5
- 235000011114 ammonium hydroxide Nutrition 0.000 description 5
- 230000002421 anti-septic effect Effects 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 238000004132 cross linking Methods 0.000 description 5
- 238000010586 diagram Methods 0.000 description 5
- 229920001519 homopolymer Polymers 0.000 description 5
- 230000032683 aging Effects 0.000 description 4
- 230000006866 deterioration Effects 0.000 description 4
- 230000007423 decrease Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 238000005562 fading Methods 0.000 description 3
- 229920000609 methyl cellulose Polymers 0.000 description 3
- 239000001923 methylcellulose Substances 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 230000008961 swelling Effects 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000000903 blocking effect Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- 239000004908 Emulsion polymer Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920003091 Methocel™ Polymers 0.000 description 1
- NEAPKZHDYMQZCB-UHFFFAOYSA-N N-[2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]ethyl]-2-oxo-3H-1,3-benzoxazole-6-carboxamide Chemical compound C1CN(CCN1CCNC(=O)C2=CC3=C(C=C2)NC(=O)O3)C4=CN=C(N=C4)NC5CC6=CC=CC=C6C5 NEAPKZHDYMQZCB-UHFFFAOYSA-N 0.000 description 1
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
- 239000007798 antifreeze agent Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000029219 regulation of pH Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000003442 weekly effect Effects 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/06—Acrylates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00241—Physical properties of the materials not provided for elsewhere in C04B2111/00
- C04B2111/00293—Materials impermeable to liquids
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/54—Substitutes for natural stone, artistic materials or the like
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/80—Optical properties, e.g. transparency or reflexibility
- C04B2111/82—Coloured materials
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to construction material, belong to wall building coating technical field.The invention provides a kind of true mineral varnish, according to the quartz sand and 20% ~ 28% slurry of mass percent meter, including 72% ~ 80%；Wherein, in parts by mass, the slurry includes 850 980 parts of pure water, 20 30 parts of modified celluloses, 20 50 parts of antifreezing agents, 40 75 parts of bentonites, 1,050 1300 parts of pure-acrylic emulsions, 60 80 parts of coalescents, 25 42 parts of thickeners, 10 28 parts of levelling agents, 5 10 parts of pH adjusting agents and 18 28 portions of preservatives.By the selection to raw material and constituent optimization, make product shape that there is preferable stability, frost resistance, water resistance and weatherability, preferable performance can be kept under low temperature, high humidity environment, non-whitening discoloration expands the traffic coverage of true mineral varnish and uses scope significantly.Present invention also offers the preparation method of the true mineral varnish simultaneously.
Description
Technical field
The present invention relates to construction material, belong to wall building coating technical field, and in particular to a kind of true mineral varnish and its
Preparation method.
Background technology
True mineral varnish is to develop very swift and violent product type in building coating industry in recent years, and it typically selects emulsion polymer
As binding agent, selection can constitute the color sand aggregate of stone texture, natural or compound sliver as color stuffing, outside finished product paint film
Such as natural stone general nature, steady, style are seen, product system has outstanding high durable, cracking resistance, hydrophobic ventilative and safety
The performance such as nontoxic, a large amount of applications for substituting ceramic tile and stone material in decoration of exterior wall in actual applications, oneself is through turning into decoration of exterior wall
Most popular product line in coating.In the market such product it is general after rainy day or when wetness is big will burst return
In vain, discolouration phenomena, easily forms hollowing, and service life is shorter.Its frost resistance, the ageing, feature of environmental protection of storage are bad, how to solve production
The problem of product are in frost resistance, the ageing, feature of environmental protection of storage, expands the application of product, as a great problem.
For this problem, there are some researches show by the way that true mineral varnish composition is transformed into powdered solid-state by liquid, to solve
Its frost resistance, the problem of storage is ageing, the feature of environmental protection is bad.As disclosed one kind in Chinese patent CN201310733947.9
" environment-friendlydry dry powder type real stone paint and preparation method ", it improves and deposited by the way that product is become into solid-state dry powder-shaped
Storage stability, expand transport and use scope, with progressive meaning.And for example disclosed in Chinese patent CN201210577169.4
" a kind of colored stone paint and preparation method thereof ", the acrylic latex powder of its 90%%~93% color sand and 6%-9% mainly included,
Be converted into solid-state dry powder-shaped again by by the component of true mineral varnish, to obtain preferably store it is ageing, transportability and
Frost resistance.
But true mineral varnish still needs addition water or solvent when using construction, is coated, forms it into Building wood
, it is necessary to the corrosion of the various external environments faced behind the top layer of material, particularly some low temperature, high humility area in use,
It is especially prominent.Although the studies above solves technical problem of the true mineral varnish in transport and preservation, but is not fully solved existing
Have true mineral varnish coating after rainy day or when wetness is big will burst return white, the phenomenon of colour fading.
The content of the invention
In view of the above-mentioned problems, the invention provides a kind of true mineral varnish, it has preferable stability, frost resistance, water resistance
With weatherability, preferable performance can be kept under low temperature, high humidity environment, non-whitening discoloration expands true mineral varnish significantly
Traffic coverage is with using scope.
In order to realize the technical purpose of the present invention, the present invention is adopted the following technical scheme that.
A kind of true mineral varnish, according to mass percent meter, the true mineral varnish include 72%~80% quartz sand and 20%~
28% slurry；Wherein, in parts by mass, the slurry includes 850-980 parts of pure water, 20-30 parts of modified celluloses, 20-50
Part antifreezing agent, 40-75 parts of bentonites, 1050-1300 parts of pure-acrylic emulsions, 60-80 parts of coalescents, 25-42 parts of thickeners, 10-
28 parts of levelling agents, 5-10 parts of pH adjusting agents and 18-28 portions of preservatives.
It is preferred that, the slurry include 876 parts of pure water, 22 parts of modified celluloses, 28 parts of antifreezing agents, 60 parts of bentonites,
1200 parts of pure-acrylic emulsions, 60 parts of coalescents, 35 parts of thickeners, 20 parts of levelling agents, 8 parts of pH adjusting agents and 22 portions of preservatives.
It is preferred that, the quartz sand is color sand, and color sand color is selected as needed.
It is preferred that, the antifreezing agent is DBS (SA dibutyl ester), DOS (SA dioctyl ester), (adipic acid two is pungent by DOA
At least one of ester).
It is preferred that, the modified cellulose is hydroxyethyl modified cellulose.The addition of cellulose can cause paint film water resistance
Decline, hydroxyethyl modified cellulose is used in the present invention, control is no more than 15 mass parts, with preferable water resistance.Its base
In the hydrophobic main chain on cellulose and surrounding water molecules through hydrogen bond association, the fluid volume of true mineral varnish particle in itself is improved, is subtracted
The space of Particle free activity is lacked, so as to improve the stability of system.When content of cellulose is relatively low or not added-time, institute completely
The true mineral varnish particle obtained is smaller, unstable, easily layering, is difficult long-term preservation.Using hydroxyethyl cellulose rather than use hydroxyl
Propyl methocel or methylcellulose are because it has colloid protective capability more more preferable than the latter and steady in the present invention
It is qualitative.
It is preferred that, the pure-acrylic emulsion is acrylate modified or epoxy resin modification pure-acrylic emulsion.Because this
Using pure-acrylic emulsion with there is more preferable paint film mildness using other kinds of emulsion (such as silicone acrylic emulsion) in invention, while
In the water resistance for testing true mineral varnish, it may have more excellent performance.
It is preferred that, the quartz sand is the quartz sand of 40-100 mesh.It is furthermore preferred that the color of the quartz sand can be white
Color, brown, black, yellow etc., are arranged in pairs or groups according to the requirement of basic true mineral varnish.Quartz sand selection the mesh of 40 mesh -100 reason be
The too small easy blocking spray gun of one side quartz sand mesh number, influences follow-up painting membrane process；If other quartz sand mesh number is too big, table
There is significant change in face glossiness etc., and the visual impression of imitation marble paint has larger decline.It is furthermore preferred that quartz sand in the present invention
Arrange in pairs or groups (quality)：90 mesh, which account for 14.8%, 80 mesh and account for 7.4%, 70 mesh, accounts for 7.8%, and remainder is 60 mesh quartz sands, with optimal table
Face glossiness and class marble vision sense of touch.
It is preferred that, the thickener is alkali swollen thickener, specifically refers to acrylic acid, the homopolymer of methacrylic acid or common
Copolymer emulsion thickener.Because such thickener is acid in itself, therefore need to adjust pH value to 8-9, ability when in use
There can be good thickening effect.
It is preferred that, the pH adjusting agent is one kind in ammoniacal liquor or saleratus.
It is preferred that, the bentonite is that average grain diameter is that between 0.5~2 μm, bentonite on the one hand can be with water combination shape
Into after pug, with higher plasticity, true mineral varnish particle is set to deform in the effect of external force, external force is deformed after removing to disappear
Characteristic, in the granular size for the true mineral varnish for increasing acquisition to a certain degree.In addition, swelling soil granularity is to its mud viscosity, mud
Ion exchange capacity, binding ability in slurry etc. all have a very big impact.In the present invention, bentonitic particle diameter is less than 2 μm can be with
Preferable plasticity and quartz sand associativity are obtained, selection is at 0.5 μm above is because the less bentonite of one side granularity exists
Improved a lot in cost and performance change is not obvious, still further aspect is in order at that swelling soil granularity is meticulous can also be due to than surface
Product is excessive when true mineral varnish coating is dried, and causes formed paint film to shrink excessive, discontinuous disconnected line occurs, influence product
Drastically deterioration that is attractive in appearance and causing water resistance.
It is preferred that, the LX-150 that preservative can be DOW Chemical is added, the antiseptic property of product is improved.
It is preferred that, the coalescents are Luo Diya or DOW Chemical DIB coalescents.
It is preferred that, the levelling agent is cross-linking type fluororesin levelling agent, can improve the weatherability of true mineral varnish, improves true stone
The rheological property of particle is painted, contributes to reinforcement to form monodisperse particles, flocculation is prevented, improves the stable storage of product
Property.
A kind of preparation method of true mineral varnish, comprises the following steps：Comprise the following steps：(1) by water, bentonite, antifreezing agent
It is added in reactor, stirring 2-5 minute is uniform to material, and continuation adds modified cellulose under stirring, continues stirring 5
Minute；(2) pure-acrylic emulsion, thickener are added, continues to stir 5 minutes to uniform；(3) coalescents, levelling agent, pH regulations are added
Disperse 2 minutes after agent；(4) preservative, quartz sand are added, continues to stir 5 minutes, stirring is shut down standby after 2 minutes.
It is preferred that, to be slowly added to during the addition of modified cellulose in the step (1), it is to avoid agglomerating caking.
The beneficial effects of the invention are as follows：
The invention provides a kind of true mineral varnish, by the selection to raw material and constituent optimization, there is product shape preferable stable
Property, frost resistance, water resistance and weatherability can keep preferable performance under low temperature, high humidity environment, non-whitening discoloration, greatly
The traffic coverage of true mineral varnish is expanded greatly and uses scope.Present invention also offers the preparation method of the true mineral varnish simultaneously.
Figure of description
In order that technical problem solved by the invention, technical scheme and beneficial effect are more clearly understood, below in conjunction with the accompanying drawings
The present invention will be described in further detail.
Fig. 1 is the schematic diagram of the true mineral varnish paint coatings of 1-4 of embodiment of the present invention formation (by water resistance test)；
Fig. 2 is comparative example 1 of the present invention, the schematic diagram of the true mineral varnish paint coatings of the formation of comparative example 2 (by water resistance test)；
Fig. 3 is the schematic diagram of the true mineral varnish paint coatings of the formation of comparative example 3 of the present invention (by water resistance test)；
Fig. 4 is the schematic diagram of the true mineral varnish paint coatings of the formation of comparative example 4 of the present invention (by water resistance test)；
Fig. 5 is the schematic diagram of the true mineral varnish paint coatings of comparative example 5-7 formation of the present invention (by water resistance test).
Wherein 1#-4# represents the picture of embodiment 1-4 paint film coatings successively, and 5#-11# represents comparative example 1-7 successively respectively
Paint film coating picture.
Embodiment
In order to be better understood from the present invention, invention is described in detail with reference to specific embodiment.It should be appreciated that this
The specific embodiment of place description does not limit the present invention only to explain the present invention.
Embodiment 1
A kind of true mineral varnish, according to mass percent meter, the true mineral varnish includes 72%~80% quartz sand and 20%~28%
Slurry；Wherein, in parts by mass, the slurry include 850-980 parts of pure water, 20-30 parts of modified celluloses, 20-50 parts it is antifreeze
Agent, 40-75 parts of bentonites, 1050-1300 parts of pure-acrylic emulsions, 60-80 parts of coalescents, 25-42 parts of thickeners, 10-28 parts of streams
Flat agent, 5-10 parts of pH adjusting agents and 18-28 portions of preservatives.
It is preferred that, the modified cellulose is hydroxyethyl modified cellulose.
It is preferred that, the pure-acrylic emulsion is acrylate modified or epoxy resin modification pure-acrylic emulsion.
It is preferred that, the bentonite is that average grain diameter is between 0.5~2 μm.
It is preferred that, the thickener is alkali swollen thickener, specifically refers to acrylic acid, the homopolymer of methacrylic acid or common
Any one in copolymer emulsion thickener.
It is preferred that, the quartz sand is the quartz sand of 40-100 mesh, and the color of the quartz sand can be carried out according to demand
Selection.Quartz sand collocation (quality) in the present invention：90 mesh, which account for 14.8%, 80 mesh and account for 7.4%, 70 mesh, accounts for 7.8%, and remainder is 60 mesh
Quartz sand, with optimal surface gloss and class marble vision sense of touch.
It is preferred that, the pH adjusting agent is one kind in ammoniacal liquor or saleratus.
It is preferred that, the LX-150 that preservative can be DOW Chemical is added, the antiseptic property of product is improved.
It is preferred that, the coalescents are Luo Diya or DOW Chemical DIB coalescents.
It is preferred that, the levelling agent is cross-linking type fluororesin levelling agent.
It is preferred that, the antifreezing agent is DBS (SA dibutyl ester), DOS (SA dioctyl ester), (adipic acid two is pungent by DOA
At least one of ester).
Embodiment 2
A kind of true mineral varnish, according to mass percent meter, the true mineral varnish includes 72% quartz sand and 28% slurry；Wherein, press
Mass parts meter, the slurry include 876 parts of pure water, 22 parts of modified celluloses, 28 parts of antifreezing agents, 60 parts of bentonites, 1200 parts it is pure
Acrylic emulsion, 60 parts of coalescents, 35 parts of thickeners, 20 parts of levelling agents, 8 parts of pH adjusting agents and 22 portions of preservatives.
It is preferred that, the modified cellulose is hydroxyethyl modified cellulose.
It is preferred that, the pure-acrylic emulsion is acrylate modified or epoxy resin modification pure-acrylic emulsion.
It is preferred that, the bentonite is that average grain diameter is between 0.5~2 μm.
It is preferred that, the thickener is alkali swollen thickener, specifically refers to acrylic acid, the homopolymer of methacrylic acid or common
Any one in copolymer emulsion thickener.
It is preferred that, the quartz sand is the quartz sand of 40-100 mesh, and the color of the quartz sand can be carried out according to demand
Selection.Quartz sand collocation (quality) in the present invention：90 mesh, which account for 14.8%, 80 mesh and account for 7.4%, 70 mesh, accounts for 7.8%, and remainder is 60 mesh
Quartz sand, with optimal surface gloss and class marble vision sense of touch.
It is preferred that, the pH adjusting agent is one kind in ammoniacal liquor or saleratus.
It is preferred that, the LX-150 that preservative can be DOW Chemical is added, the antiseptic property of product is improved.
It is preferred that, the coalescents are Luo Diya or DOW Chemical DIB coalescents.
It is preferred that, the levelling agent is cross-linking type fluororesin levelling agent.
It is preferred that, the antifreezing agent is DBS (SA dibutyl ester), DOS (SA dioctyl ester), (adipic acid two is pungent by DOA
At least one of ester).
Embodiment 3
A kind of true mineral varnish, according to mass percent meter, the true mineral varnish includes 80% quartz sand and 20% slurry；Wherein, press
Mass parts meter, the slurry include 850 parts of pure water, 20 parts of modified celluloses, 50 parts of antifreezing agents, 40 parts of bentonites, 1050 parts it is pure
Acrylic emulsion, 70 parts of coalescents, 25 parts of thickeners, 20 parts of levelling agents, 5 parts of pH adjusting agents and 18 portions of preservatives.
It is preferred that, the modified cellulose is hydroxyethyl modified cellulose.
It is preferred that, the pure-acrylic emulsion is acrylate modified or epoxy resin modification pure-acrylic emulsion.
It is preferred that, the bentonite is that average grain diameter is between 0.5~2 μm.
It is preferred that, the thickener is alkali swollen thickener, specifically refers to acrylic acid, the homopolymer of methacrylic acid or common
Any one in copolymer emulsion thickener.
It is preferred that, the quartz sand is the quartz sand of 40-100 mesh, and the color of the quartz sand can be carried out according to demand
Selection.Quartz sand collocation (quality) in the present invention：90 mesh, which account for 14.8%, 80 mesh and account for 7.4%, 70 mesh, accounts for 7.8%, and remainder is 60 mesh
Quartz sand, with optimal surface gloss and class marble vision sense of touch.
It is preferred that, the pH adjusting agent is one kind in ammoniacal liquor or saleratus.
It is preferred that, the LX-150 that preservative can be DOW Chemical is added, the antiseptic property of product is improved.
It is preferred that, the coalescents are Luo Diya or DOW Chemical DIB coalescents.
It is preferred that, the levelling agent is cross-linking type fluororesin levelling agent.
It is preferred that, the antifreezing agent is DBS (SA dibutyl ester), DOS (SA dioctyl ester), (adipic acid two is pungent by DOA
At least one of ester).
Embodiment 4
A kind of true mineral varnish, according to mass percent meter, the true mineral varnish includes 72% quartz sand and 28% slurry；Wherein, press
Mass parts meter, the slurry include 980 parts of pure water, 30 parts of modified celluloses, 20 parts of antifreezing agents, 75 parts of bentonites, 1300 parts it is pure
Acrylic emulsion, 80 parts of coalescents, 42 parts of thickeners, 10 parts of levelling agents, 10 parts of pH adjusting agents and 28 portions of preservatives.
It is preferred that, the modified cellulose is hydroxyethyl modified cellulose.
It is preferred that, the pure-acrylic emulsion is acrylate modified or epoxy resin modification pure-acrylic emulsion.
It is preferred that, the bentonite is that average grain diameter is between 0.5~2 μm.
It is preferred that, the thickener is alkali swollen thickener, specifically refers to acrylic acid, the homopolymer of methacrylic acid or common
Any one in copolymer emulsion thickener.
It is preferred that, the quartz sand is the quartz sand of 40-100 mesh, and the color of the quartz sand can be carried out according to demand
Selection.Quartz sand collocation (quality) in the present invention：90 mesh, which account for 14.8%, 80 mesh and account for 7.4%, 70 mesh, accounts for 7.8%, and remainder is 60 mesh
Quartz sand, with optimal surface gloss and class marble vision sense of touch.
It is preferred that, the pH adjusting agent is one kind in ammoniacal liquor or saleratus.
It is preferred that, the LX-150 that preservative can be DOW Chemical is added, the antiseptic property of product is improved.
It is preferred that, the coalescents are Luo Diya or DOW Chemical DIB coalescents.
It is preferred that, the levelling agent is cross-linking type fluororesin levelling agent.
It is preferred that, the antifreezing agent is DBS (SA dibutyl ester), DOS (SA dioctyl ester), (adipic acid two is pungent by DOA
At least one of ester).
Comparative example 1 (under conditions of content of cellulose is more than 40 parts)
A kind of true mineral varnish, according to mass percent meter, the true mineral varnish includes 72% quartz sand and 28% slurry；Wherein, press
Mass parts meter, the slurry include 876 parts of pure water, 40 parts of modified celluloses, 28 parts of antifreezing agents, 60 parts of bentonites, 1200 parts it is pure
Acrylic emulsion, 60 parts of coalescents, 35 parts of thickeners, 20 parts of levelling agents, 8 parts of pH adjusting agents and 22 portions of preservatives.
Comparative example 2 (content of cellulose is less than in the case of 15 parts)
A kind of true mineral varnish, according to mass percent meter, the true mineral varnish includes 72% quartz sand and 28% slurry；Wherein, press
Mass parts meter, the slurry include 876 parts of pure water, 15 parts of modified celluloses, 28 parts of antifreezing agents, 60 parts of bentonites, 1200 parts it is pure
Acrylic emulsion, 60 parts of coalescents, 35 parts of thickeners, 20 parts of levelling agents, 8 parts of pH adjusting agents and 22 portions of preservatives.
Comparative example 3 (uses silicone acrylic emulsion)
A kind of true mineral varnish, according to mass percent meter, the true mineral varnish includes 72% quartz sand and 28% slurry；Wherein, press
Mass parts meter, the slurry includes 876 parts of pure water, 22 parts of modified celluloses, 28 parts of antifreezing agents, 60 parts of bentonites, 1200 parts of silicon
Acrylic emulsion, 60 parts of coalescents, 35 parts of thickeners, 20 parts of levelling agents, 8 parts of pH adjusting agents and 22 portions of preservatives.
Comparative example 4 (influence of swelling soil granularity, average grain diameter is less than 0.3 μm of bentonite)
A kind of true mineral varnish, according to mass percent meter, the true mineral varnish includes 72% quartz sand and 28% slurry；Wherein, press
Mass parts meter, the slurry include 876 parts of pure water, 22 parts of modified celluloses, 28 parts of antifreezing agents, 60 parts of bentonites, 1200 parts it is pure
Acrylic emulsion, 60 parts of coalescents, 35 parts of thickeners, 20 parts of levelling agents, 8 parts of pH adjusting agents and 22 portions of preservatives.
Comparative example 5 (does not contain levelling agent)
A kind of true mineral varnish, according to mass percent meter, the true mineral varnish includes 72% quartz sand and 28% slurry；Wherein, press
Mass parts meter, the slurry include 876 parts of pure water, 22 parts of modified celluloses, 28 parts of antifreezing agents, 60 parts of bentonites, 1200 parts it is pure
Acrylic emulsion, 60 parts of coalescents, 35 parts of thickeners, 8 parts of pH adjusting agents and 22 portions of preservatives.
Comparative example 6 (does not contain antifreezing agent)
A kind of true mineral varnish, according to mass percent meter, the true mineral varnish includes 72% quartz sand and 28% slurry；Wherein, press
Mass parts meter, the slurry include 876 parts of pure water, 22 parts of modified celluloses, 60 parts of bentonites, 1200 parts of pure-acrylic emulsions, 60 parts
Coalescents, 35 parts of thickeners, 20 parts of levelling agents, 8 parts of pH adjusting agents and 22 portions of preservatives.
Comparative example 7 (uses methylcellulose)
A kind of true mineral varnish, according to mass percent meter, the true mineral varnish includes 72% quartz sand and 28% slurry；Wherein, press
Mass parts meter, the slurry include 876 parts of pure water, 22 parts of modified celluloses, 28 parts of antifreezing agents, 60 parts of bentonites, 1200 parts it is pure
Acrylic emulsion, 60 parts of coalescents, 35 parts of thickeners, 20 parts of levelling agents, 8 parts of pH adjusting agents and 22 portions of preservatives.
Coating paint film is made in the true mineral varnish obtained to above example and comparative example, and it is tested, as a result such as
Shown in table 1.
Performance test between each embodiment of table 1 and comparative example
Test condition：
Frost resistance：Paint film coating is made in product, temperature is placed in and whether occurs colour fading at 0-5 DEG C, to observe its surface and turn white
Situation changes, and every 30 days records are once.
Storage stability：Stood at 25 DEG C, observe whether it is layered, if the phenomenons such as muddiness occur, record weekly once.
Paint film application property：Blade coating or spray gun coating, observe it and whether there is the phenomenon for blocking spray gun or falling paint.
Paint film state：Paint film coating is made into, after natural drying, whether observation coating surface state is continuous, whether deposit
In the defect such as crackle and stomata, if there is marble visual impression.
Paint film water resistance：Paint film is applied to be placed at 15-20 DEG C in water and soaked, its situations such as turning white of whether fading is observed,
Record once within every 7 days, using the data result of 30 days as final water resistance test result.
Embodiment 1-4 result, product shape has preferable stability, frost resistance, water resistance and weatherability, can be low
Preferable performance is kept under temperature, high humidity environment, non-whitening discoloration expands the traffic coverage of true mineral varnish and uses model significantly
Enclose.
It is due to the modified fine of addition although the stability of the true mineral varnish of addition in comparative example 1 due to cellulose is more excellent
Cellulose content is tieed up more, so as to cause paint film water resistance to decline.The content of cellulose added in comparative example 2 is too low, although water-fast
Performance in property is not deteriorated, but the less stable of the true mineral varnish obtained, and the holding time is shorter, and is obtained
True mineral varnish be easily layered.Methylcellulose is used in comparative example 7, it can be seen that the true mineral varnish that it is obtained is on storage stability
It is weaker than using hydroxyethyl modified cellulose, and performance also has deterioration in frost resistance, there is slight blushing.
Silicone acrylic emulsion rather than pure-acrylic emulsion, the paint film coating mildness that the true mineral varnish obtained is made are used in comparative example 3
It is not high, the defect such as easily there is micropore, wrinkle, meanwhile, the paint film obtained is also deteriorated in water resistance, there is blushing.
Bentonitic granularity is smaller in comparative example 4, and the true mineral varnish product stability obtained preferably, but is made by true mineral varnish particle
During paint film coating, dried paint film is excessive due to shrinking, and discontinuous disconnected line easily occurs, influences the attractive in appearance of product, and
The water resistance of paint film, frost resistance deterioration, there is blushing.
Levelling agent is not contained in comparative example 5, the true mineral varnish obtained is more real in product storage stability, particle dispersion
Apply a 1-4 weak points.And the water resistance of its paint film coating finally obtained is also not as obtained in embodiment
Paint film coating, has the phenomenon turned white to occur.Due to not containing antifreezing agent in comparative example 6, it is substantially deteriorated in frost resistance,
And the water resistance in low temperature also occurs in that deterioration, on the one hand surface improves true mineral varnish using antifreeze in the present invention
Resistance to low temperature, still further aspect to true mineral varnish in terms of water resistance also have certain castering action.
According to above-described embodiment and comparative example data, it is apparent that the invention provides a kind of true mineral varnish, by right
The selection of raw material and constituent optimization, make product shape have preferable stability, frost resistance, water resistance and weatherability, can be low
Preferable performance is kept under temperature, high humidity environment, non-whitening discoloration expands the traffic coverage of true mineral varnish and uses model significantly
Enclose.Simultaneously present invention also offers the preparation method of the true mineral varnish, control adds speed during modified cellulose is added,
Conglomeration is avoided, the performance of true mineral varnish particle is influenceed.
The basic principles, principal features and advantages of the present invention have been shown and described above.The technical staff of the industry should
Understand, the invention is not limited in any way for above-described embodiment, it is all to be obtained by the way of equivalent substitution or equivalent transformation
Technical scheme, all falls within protection scope of the present invention.
Claims (10)
1. a kind of true mineral varnish, it is characterised in that according to mass percent meter, the true mineral varnish includes 72% ~ 80% quartz sand and 20%
~ 28% slurry；Wherein, in parts by mass, the slurry includes 850-980 parts of pure water, 20-30 parts of modified celluloses, 20-50
Part antifreezing agent, 40-75 parts of bentonites, 1050-1300 parts of pure-acrylic emulsions, 60-80 parts of coalescents, 25-42 parts of thickeners, 10-
28 parts of levelling agents, 5-10 parts of pH adjusting agents and 18-28 portions of preservatives.
2. a kind of true mineral varnish according to claim 1, it is characterised in that：The slurry includes 876 parts of pure water, 22 parts of modifications
Cellulose, 28 parts of antifreezing agents, 60 parts of bentonites, 1200 parts of pure-acrylic emulsions, 60 parts of coalescents, 35 parts of thickeners, 20 parts of levellings
Agent, 8 parts of pH adjusting agents and 22 portions of preservatives.
3. a kind of true mineral varnish according to claim 2, it is characterised in that：The quartz sand is the quartz sand of 40-100 mesh,
Wherein 90 mesh account for 14.8%, 80 mesh and account for 7.4%, 70 mesh and account for 7.8% by mass percentage, and remainder is 60 mesh quartz sands.
4. a kind of true mineral varnish according to claim 3, it is characterised in that：The quartz sand is color sand, color sand color according to
Need to be selected.
5. a kind of true mineral varnish according to claim 1 or 2 or 3 or 4, it is characterised in that：The modified cellulose is hydroxyl second
Base modified cellulose.
6. a kind of true mineral varnish according to claim 1 or 2 or 3 or 4, it is characterised in that：The pure-acrylic emulsion is acrylic acid
Ester modified or epoxy resin modification pure-acrylic emulsion.
7. a kind of true mineral varnish according to claim 1 or 2 or 3 or 4, it is characterised in that：The bentonite is modified for sodium base
Bentonite.
8. a kind of true mineral varnish according to claim 1 or 2 or 3 or 4, it is characterised in that：The antifreezing agent is DBS（Certain herbaceous plants with big flowers two
Dibutyl phthalate）、DOS（SA dioctyl ester）、DOA（Dioctyl adipate）At least one of.
9. the preparation method of a kind of true mineral varnish according to claim any one of 1-8, it is characterised in that including following step
Suddenly：（1）Water, bentonite, antifreezing agent are added in reactor, stirring 2-5 minute is uniform to material, and continuation is under stirring
Modified cellulose is added, continues to stir 5 minutes；（2）Pure-acrylic emulsion, thickener are added, continues to stir 5 minutes to uniform；（3）Plus
Enter and disperse 2 minutes after coalescents, levelling agent, pH adjusting agent；（4）Preservative, quartz sand are added, continues to stir 5 minutes, stirring
Shut down after 2 minutes standby.
10. a kind of preparation method of true mineral varnish according to claim 9, it is characterised in that：The step（1）It is middle modified fine
To be slowly added to during the addition for tieing up element, it is to avoid agglomerating caking.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108084750A (en) * | 2017-12-29 | 2018-05-29 | 平阳瑞丰新材料科技有限公司 | A kind of lacquer and its application |
| CN108191307A (en) * | 2017-12-25 | 2018-06-22 | 厦门市固力克节能科技有限公司 | A kind of anti-dropout graphene lacquer and preparation method thereof |
| CN108329744A (en) * | 2018-01-22 | 2018-07-27 | 河北晨阳工贸集团有限公司 | A kind of lacquer water-base resin sand and preparation method thereof |
| CN110066138A (en) * | 2019-03-23 | 2019-07-30 | 上海雷鸟涂料有限公司 | A kind of heat-resistance type lacquer and its preparation process |
| CN112480821A (en) * | 2020-11-25 | 2021-03-12 | 无锡乐华自动化科技有限公司 | Automatic real stone paint production method |
| CN115197620A (en) * | 2022-07-21 | 2022-10-18 | 亚士漆(上海)有限公司 | High-coating texture coating and preparation method and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104556831A (en) * | 2014-12-18 | 2015-04-29 | 沈阳富益通达商贸有限公司 | Really stone paint |
| CN105601166A (en) * | 2016-01-27 | 2016-05-25 | 广东施彩涂料有限公司 | Stone-like coating resisting temperature variation construction and preparation method thereof |
-
2017
- 2017-04-19 CN CN201710258419.0A patent/CN107129185B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104556831A (en) * | 2014-12-18 | 2015-04-29 | 沈阳富益通达商贸有限公司 | Really stone paint |
| CN105601166A (en) * | 2016-01-27 | 2016-05-25 | 广东施彩涂料有限公司 | Stone-like coating resisting temperature variation construction and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108191307A (en) * | 2017-12-25 | 2018-06-22 | 厦门市固力克节能科技有限公司 | A kind of anti-dropout graphene lacquer and preparation method thereof |
| CN108191307B (en) * | 2017-12-25 | 2020-10-09 | 厦门市固力克节能科技有限公司 | Anti-drop graphene stone-like paint and preparation method thereof |
| CN108084750A (en) * | 2017-12-29 | 2018-05-29 | 平阳瑞丰新材料科技有限公司 | A kind of lacquer and its application |
| CN108329744A (en) * | 2018-01-22 | 2018-07-27 | 河北晨阳工贸集团有限公司 | A kind of lacquer water-base resin sand and preparation method thereof |
| CN110066138A (en) * | 2019-03-23 | 2019-07-30 | 上海雷鸟涂料有限公司 | A kind of heat-resistance type lacquer and its preparation process |
| CN110066138B (en) * | 2019-03-23 | 2021-07-06 | 上海雷鸟涂料有限公司 | Temperature-resistant real stone paint and preparation process thereof |
| CN112480821A (en) * | 2020-11-25 | 2021-03-12 | 无锡乐华自动化科技有限公司 | Automatic real stone paint production method |
| CN115197620A (en) * | 2022-07-21 | 2022-10-18 | 亚士漆(上海)有限公司 | High-coating texture coating and preparation method and application thereof |
| CN115197620B (en) * | 2022-07-21 | 2023-10-20 | 亚士漆(上海)有限公司 | High-coating texture coating and preparation method and application thereof |
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Address after: No. 9, First Floor, Building B, No. 137 Weimin Road, Shenglong Village, Xiaolan Town, Zhongshan City, Guangdong Province, 528415 Patentee after: Guangdong Nantian New Material Technology Co.,Ltd. Country or region after: China Address before: No. 105 Zhuyuan Baoyuan Road, Xiaolan Town, Zhongshan City, Guangdong Province, 528415 Patentee before: GUANGDONG NANTIAN PAINT CO.,LTD. Country or region before: China |