CN108457122A - A kind of functional form Paper Coating coating - Google Patents

A kind of functional form Paper Coating coating Download PDF

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Publication number
CN108457122A
CN108457122A CN201711353489.0A CN201711353489A CN108457122A CN 108457122 A CN108457122 A CN 108457122A CN 201711353489 A CN201711353489 A CN 201711353489A CN 108457122 A CN108457122 A CN 108457122A
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CN
China
Prior art keywords
coating
functional form
form paper
paper
thickener
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Pending
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CN201711353489.0A
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Chinese (zh)
Inventor
谷文
刘莉莉
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Individual
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Individual
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Priority to CN201711353489.0A priority Critical patent/CN108457122A/en
Publication of CN108457122A publication Critical patent/CN108457122A/en
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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/62—Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/38—Coatings with pigments characterised by the pigments
    • D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/46—Non-macromolecular organic compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/46—Non-macromolecular organic compounds
    • D21H19/48—Diolefins, e.g. butadiene; Aromatic vinyl monomers, e.g. styrene; Polymerisable unsaturated acids or derivatives thereof, e.g. acrylic acid
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/52—Cellulose; Derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/64—Inorganic compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/34—Ignifugeants
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention provides a kind of functional form Paper Coating coating, which is characterized in that includes the component of following parts by weight：Waterborne polyurethane resin 25 36, methyl methacrylate 28 43, ethylene vinyl acetate 17 29, disodium ethylene diamine tetraacetate 18 25, polyethylene glycol 12 19, dispersant 11 19, thickener 7 13, antifoaming agent 6 13, pH adjusting agent 8 22, polyaniline graphene hollow microspheres 45 62, gluconic acid polyhexamethylene guanide 13 24, distilled water 51 74, kaolin 22 35, Ti3SiC ceramic powder 21 38,49 molecular sieves 34 55 of nanoscale MCM.By regulating and controlling the proportioning of ceramic powder and tiny balloon in the present invention, optimizes Compatibility of Coating Color, assign the functions such as paper anti-microbial property, flame retardant property, salt spray resistance；Improve the printability of coating paper simultaneously.

Description

A kind of functional form Paper Coating coating
Technical field
The invention belongs to functional material and pulp technology for making paper, and in particular to a kind of functional form Paper Coating coating.
Background technology
Coating paper be at least one surface of body paper coating to be dried after pigment coating as main component and It is formed.Coating paper can be used as the commercial prints objects such as poster, brochure, advertisement poster after polychrome printing or single color printing, or make For publications such as books, magazines, it is widely used in routine work and life.
The property of coating directly affects ways and methods.A kind of existing common coating be based on starch, When being produced applied to coating paper, the operability of coating operations is poor, coating weight is relatively low.Lower coating weight can not provide good The problems such as good surface property, that there are surface roughnesses is larger for gained coating paper, anti-floating poor performance.The coating of coating simultaneously Can be single, it cannot assign paper new function, be unfavorable for the development of coating paper.
Invention content
In view of this, the present invention provides a kind of functional form Paper Coating coating, by regulating and controlling ceramic powder and sky in the present invention The proportioning of heart microballoon optimizes Compatibility of Coating Color, assigns the functions such as paper anti-microbial property, flame retardant property, salt spray resistance；Change simultaneously The printability of kind coating paper.
The technical scheme is that：A kind of functional form Paper Coating coating, which is characterized in that including following parts by weight Component：Waterborne polyurethane resin 25-36, methyl methacrylate 28-43, ethane-acetic acid ethyenyl ester 17-29, Disodium ethylene diamine tetraacetate 18-25, polyethylene glycol 12-19, dispersant 11-19, thickener 7-13, antifoaming agent 6-13, pH Conditioning agent 8-22, polyaniline-graphite alkene tiny balloon 45-62, gluconic acid polyhexamethylene guanide 13-24, distilled water 115- 160, kaolin 22-35, Ti3SiC ceramic powder 21-38, nanoscale MCM-49 molecular sieves 34-55.
Further, the grain diameter of the polyaniline-graphite alkene tiny balloon is 200-400nm.
Further, the grain diameter of the nanoscale MCM-49 molecular sieves is 100-200nm.
Further, the dispersant is lauryl sodium sulfate, methyl anyl alcohol, guar gum, fatty acid polyethylene glycol ester In one kind.
Further, the thickener is hydroxypropyl methyl cellulose.
Further, the antifoaming agent is dimethyl silicone polymer.
Further, the pH adjusting agent is aminomethyl propanol.
In the present invention, by polyaniline-graphite alkene tiny balloon, polyhexamethylene guanidine propionate, nano-graphene particle, Ti3The synergistic complex role of SiC ceramic powder, nanoscale MCM-49 molecular sieves, polyaniline-graphite alkene tiny balloon and nanoscale There is unique three-dimensional netted space structure inside MCM-49 molecular sieves, polyhexamethylene guanidine propionate, nanometer stone can be adsorbed Black alkene particle, achievees the effect that sustained release, significantly improves the antibacterial ability of coating of the present invention, while the Ti added3SiC ceramic powder is assigned Give coating others functional characteristic of the present invention；The helper components such as middle disodium ethylene diamine tetraacetate, polyethylene glycol through the invention Effect, can be such that instant component fully merges, and can have good adsorption capacity with paper.
Beneficial effects of the present invention：1. antibacterial paper paint preparation process of the present invention carries out at normal temperatures and pressures, it is not required to New equipment is added, simple for process, production cost is low.After 2. coating of the present invention is coated on paper, assisted by each component Effect acts on, and not only can effectively improve the functions such as anti-microbial property, flame retardant property, the salt spray resistance of paper, but also can assign paper Good printability.3. being compared to antiseptic mode advantage is added in slurry：Retention rate is preferable, will not cause production process In antiseptic waste, raw material can be saved；Its dosage added can be according to the requirement of the paper produced in wide range It changes.
Preferably, preparation method of the invention is：Foundation is formulated aqueous polyurethane resin, metering system above Sour methyl esters, ethane-acetic acid ethyenyl ester, disodium ethylene diamine tetraacetate, polyethylene glycol, dispersant are added in the water of coating dispersion bucket, Rate of dispersion is maintained at 5000r/min, and jitter time reduces rotating speed to 2000r/min, antifoaming agent is added and continues to mix after being 15min 10min is closed, polyaniline-graphite alkene tiny balloon, polyhexamethylene guanidine propionate, nano-graphene particle, Ti are added3SiC makes pottery Porcelain powder, nanoscale MCM-49 molecular sieves are gradually increased rotating speed to 8000r/min, after persistently disperseing 25min, then reduce rotating speed extremely Thickener, pH adjusting agent is added in 2000r/min, disperses 10min, and the functional form Paper Coating that solid content is 30-45% is made and applies Material.
The present invention application method be：It is placed on body paper is smooth as required on coating machine, pressure tensioning volume, then coating It collects and is pressed in top of form, put down fixed-wing, take a certain amount of functional form Paper Coating coating, be evenly distributed on top of form, open Dynamic button, Paper Coating are completed, and the paper after coating speed 30m/min coatings is put into pattern flash dryer, drying temperature 105 DEG C, drying time 45s, according to paper made from the above paint formulation and coating process, through shaking the detection of flask standard measure, knot Fruit shows that coating coating paper has reached 97% or more to staphylococcus aureus antimicrobial efficiency；Meanwhile through the above paint formulation After coating, the printability of paper is obviously improved.
Specific implementation mode
Technical scheme of the present invention is clearly and completely described below in conjunction with embodiment, it is clear that described reality It is only a part of the embodiment of the present invention to apply example, instead of all the embodiments.
Embodiment 1
A kind of functional form Paper Coating coating, which is characterized in that include the component of following parts by weight：Waterborne polyurethane Resin 27, methyl methacrylate 32, ethane-acetic acid ethyenyl ester 21, disodium ethylene diamine tetraacetate 22, polyethylene glycol 15, Dispersant 13, thickener 10, antifoaming agent 9, pH adjusting agent 14, polyaniline-graphite alkene tiny balloon 53, gluconic acid are poly- Hexa-methylene guanidine 19, distilled water 130, kaolin 26, Ti3SiC ceramic powder 27, nanoscale MCM-49 molecular sieves 45.
Further, the grain diameter of the polyaniline-graphite alkene tiny balloon is 300nm.
Further, the grain diameter of the nanoscale MCM-49 molecular sieves is 180nm.
Further, the dispersant is lauryl sodium sulfate.
Further, the thickener is hydroxypropyl methyl cellulose.
Further, the antifoaming agent is dimethyl silicone polymer.
Further, the pH adjusting agent is aminomethyl propanol.
In the present invention, by polyaniline-graphite alkene tiny balloon, polyhexamethylene guanidine propionate, nano-graphene particle, Ti3The synergistic complex role of SiC ceramic powder, nanoscale MCM-49 molecular sieves, polyaniline-graphite alkene tiny balloon and nanoscale There is unique three-dimensional netted space structure inside MCM-49 molecular sieves, polyhexamethylene guanidine propionate, nanometer stone can be adsorbed Black alkene particle, achievees the effect that sustained release, significantly improves the antibacterial ability of coating of the present invention, while the Ti added3SiC ceramic powder is assigned Give coating others functional characteristic of the present invention；The helper components such as middle disodium ethylene diamine tetraacetate, polyethylene glycol through the invention Effect, can be such that instant component fully merges, and can have good adsorption capacity with paper.
Beneficial effects of the present invention：1. antibacterial paper paint preparation process of the present invention carries out at normal temperatures and pressures, it is not required to New equipment is added, simple for process, production cost is low.After 2. coating of the present invention is coated on paper, assisted by each component Effect acts on, and not only can effectively improve the functions such as anti-microbial property, flame retardant property, the salt spray resistance of paper, but also can assign paper Good printability.3. being compared to antiseptic mode advantage is added in slurry：Retention rate is preferable, will not cause production process In antiseptic waste, raw material can be saved；Its dosage added can be according to the requirement of the paper produced in wide range It changes.
Preferably, preparation method of the invention is：Foundation is formulated aqueous polyurethane resin, metering system above Sour methyl esters, ethane-acetic acid ethyenyl ester, disodium ethylene diamine tetraacetate, polyethylene glycol, dispersant are added in the water of coating dispersion bucket, Rate of dispersion is maintained at 5000r/min, and jitter time reduces rotating speed to 2000r/min, antifoaming agent is added and continues to mix after being 15min 10min is closed, polyaniline-graphite alkene tiny balloon, polyhexamethylene guanidine propionate, nano-graphene particle, Ti are added3SiC makes pottery Porcelain powder, nanoscale MCM-49 molecular sieves are gradually increased rotating speed to 8000r/min, after persistently disperseing 25min, then reduce rotating speed extremely Thickener, pH adjusting agent is added in 2000r/min, disperses 10min, and the functional form Paper Coating coating of the present invention is made.
Embodiment 2
A kind of functional form Paper Coating coating, which is characterized in that include the component of following parts by weight：Waterborne polyurethane Resin 25, methyl methacrylate 28, ethane-acetic acid ethyenyl ester 17, disodium ethylene diamine tetraacetate 18, polyethylene glycol 12, Dispersant 11, thickener 7, antifoaming agent 6, pH adjusting agent 8, polyaniline-graphite alkene tiny balloon 45, gluconic acid poly- six Methylene guanidine 13, distilled water 115, kaolin 22, Ti3SiC ceramic powder 21, nanoscale MCM-49 molecular sieves 34.
Further, the grain diameter of the polyaniline-graphite alkene tiny balloon is 200nm.
Further, the grain diameter of the nanoscale MCM-49 molecular sieves is 100nm.
Further, the dispersant is methyl anyl alcohol.
Further, the thickener is hydroxypropyl methyl cellulose.
Further, the antifoaming agent is dimethyl silicone polymer.
Further, the pH adjusting agent is aminomethyl propanol.
Embodiment 3
A kind of functional form Paper Coating coating, which is characterized in that include the component of following parts by weight：Waterborne polyurethane Resin 36, methyl methacrylate 43, ethane-acetic acid ethyenyl ester 29, disodium ethylene diamine tetraacetate 25, polyethylene glycol 19, Dispersant 19, thickener 13, antifoaming agent 13, pH adjusting agent 22, polyaniline-graphite alkene tiny balloon 62, gluconic acid are poly- Hexa-methylene guanidine 24, distilled water 160, kaolin 35, Ti3SiC ceramic powder 38, nanoscale MCM-49 molecular sieves 55.
Further, the grain diameter of the polyaniline-graphite alkene tiny balloon is 400nm.
Further, the grain diameter of the nanoscale MCM-49 molecular sieves is 200nm.
Further, the dispersant is guar gum.
Further, the thickener is hydroxypropyl methyl cellulose.
Further, the antifoaming agent is dimethyl silicone polymer.
Further, the pH adjusting agent is aminomethyl propanol.
Embodiment 4
A kind of functional form Paper Coating coating, which is characterized in that include the component of following parts by weight：Waterborne polyurethane Resin 28, methyl methacrylate 35, ethane-acetic acid ethyenyl ester 20, disodium ethylene diamine tetraacetate 22, polyethylene glycol 14, Dispersant 13, thickener 10, antifoaming agent 9, pH adjusting agent 16, polyaniline-graphite alkene tiny balloon 52, gluconic acid are poly- Hexa-methylene guanidine 18, distilled water 138, kaolin 27, Ti3SiC ceramic powder 26, nanoscale MCM-49 molecular sieves 41.
Further, the grain diameter of the polyaniline-graphite alkene tiny balloon is 250nm.
Further, the grain diameter of the nanoscale MCM-49 molecular sieves is 150nm.
Further, the dispersant is fatty acid polyethylene glycol ester.
Further, the thickener is hydroxypropyl methyl cellulose.
Further, the antifoaming agent is dimethyl silicone polymer.
Further, the pH adjusting agent is aminomethyl propanol.
Embodiment 5
A kind of functional form Paper Coating coating, which is characterized in that include the component of following parts by weight：Waterborne polyurethane Resin 34, methyl methacrylate 38, ethane-acetic acid ethyenyl ester 25, disodium ethylene diamine tetraacetate 23, polyethylene glycol 17, Dispersant 16, thickener 11, antifoaming agent 10, pH adjusting agent 19, polyaniline-graphite alkene tiny balloon 58, gluconic acid are poly- Hexa-methylene guanidine 22, distilled water 150, kaolin 32, Ti3SiC ceramic powder 35, nanoscale MCM-49 molecular sieves 53.
Further, the grain diameter of the polyaniline-graphite alkene tiny balloon is 350nm.
Further, the grain diameter of the nanoscale MCM-49 molecular sieves is 130nm.
Further, the dispersant is lauryl sodium sulfate.
Further, the thickener is hydroxypropyl methyl cellulose.
Further, the antifoaming agent is dimethyl silicone polymer.
Further, the pH adjusting agent is aminomethyl propanol.
Embodiment 6
A kind of functional form Paper Coating coating, which is characterized in that include the component of following parts by weight：Waterborne polyurethane Resin 32, methyl methacrylate 37, ethane-acetic acid ethyenyl ester 24, disodium ethylene diamine tetraacetate 21, polyethylene glycol 16, Dispersant 17, thickener 9, antifoaming agent 11, pH adjusting agent 18, polyaniline-graphite alkene tiny balloon 54, gluconic acid are poly- Hexa-methylene guanidine 17, distilled water 146, kaolin 29, Ti3SiC ceramic powder 27, nanoscale MCM-49 molecular sieves 39.
Further, the grain diameter of the polyaniline-graphite alkene tiny balloon is 250nm.
Further, the grain diameter of the nanoscale MCM-49 molecular sieves is 160nm.
Further, the dispersant is methyl anyl alcohol.
Further, the thickener is hydroxypropyl methyl cellulose.
Further, the antifoaming agent is dimethyl silicone polymer.
Further, the pH adjusting agent is aminomethyl propanol.
Comparative example 1
A kind of functional form Paper Coating coating, which is characterized in that include the component of following parts by weight：Waterborne polyurethane Resin 32, methyl methacrylate 37, ethane-acetic acid ethyenyl ester 24, disodium ethylene diamine tetraacetate 21, polyethylene glycol 16, Dispersant 17, thickener 9, antifoaming agent 11, pH adjusting agent 18, gluconic acid polyhexamethylene guanide 17, distilled water 146, Ti3SiC ceramic powder 27, nanoscale MCM-49 molecular sieves 39.
Further, the grain diameter of the nanoscale MCM-49 molecular sieves is 160nm.
Further, the dispersant is methyl anyl alcohol.
Further, the thickener is hydroxypropyl methyl cellulose.
Further, the antifoaming agent is dimethyl silicone polymer.
Further, the pH adjusting agent is aminomethyl propanol.
Comparative example 2
A kind of functional form Paper Coating coating, which is characterized in that include the component of following parts by weight：Waterborne polyurethane Resin 32, methyl methacrylate 37, ethane-acetic acid ethyenyl ester 24, dispersant 17, thickener 9, antifoaming agent 11, pH Conditioning agent 18, polyaniline-graphite alkene tiny balloon 54, gluconic acid polyhexamethylene guanide 17, distilled water 146, kaolin 29、Ti3SiC ceramic powder 27, nanoscale MCM-49 molecular sieves 39.
Further, the grain diameter of the polyaniline-graphite alkene tiny balloon is 250nm.
Further, the grain diameter of the nanoscale MCM-49 molecular sieves is 160nm.
Further, the dispersant is methyl anyl alcohol.
Further, the thickener is hydroxypropyl methyl cellulose.
Further, the antifoaming agent is dimethyl silicone polymer.
Further, the pH adjusting agent is aminomethyl propanol.
Comparative example 3
A kind of functional form Paper Coating coating, which is characterized in that include the component of following parts by weight：Waterborne polyurethane Resin 32, methyl methacrylate 37, ethane-acetic acid ethyenyl ester 24, disodium ethylene diamine tetraacetate 21, polyethylene glycol 16, Dispersant 17, thickener 9, antifoaming agent 11, pH adjusting agent 18, polyaniline-graphite alkene tiny balloon 54, gluconic acid are poly- Hexa-methylene guanidine 17, distilled water 146, kaolin 29.
Further, the grain diameter of the polyaniline-graphite alkene tiny balloon is 250nm.
Further, the dispersant is methyl anyl alcohol.
Further, the thickener is hydroxypropyl methyl cellulose.
Further, the antifoaming agent is dimethyl silicone polymer.
Further, the pH adjusting agent is aminomethyl propanol.
Coating property is tested
Salt spray resistance
By the paint spraying in embodiment and comparative example in wooden test piece.After paint spraying, stands 48 hours and wait for that coating is completely solid It is tested after chemical conversion film.Adhesive force test, neutral salt spray test carried out to above-mentioned coating, test method according to《GB/T 1720-1979 paint film adhesion measuring methods》、《GB/T 10125-2012 artificial atmosphere corrosion test salt spray tests》It carries out, surveys Test result such as following table.
Anti-microbial property and flame retardant property
Anti-microbial property test is carried out according to GB/T 21866-2008；According to GB1244-2005 using cell combustion method to above-mentioned The coating of embodiment carries out flame retardant property test, and the results are shown in table below.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, and do not carrying on the back In the case of spirit or essential attributes from the present invention, the present invention can be realized in other specific forms.Therefore, no matter from which From the point of view of a bit, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is wanted by appended right Ask rather than above description limit, it is intended that by all changes that come within the meaning and range of equivalency of the claims It is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art The other embodiment being appreciated that.It is noted that the technical characteristic not being described in detail in the present invention, can pass through this Field any prior art is realized.

Claims (7)

1. a kind of functional form Paper Coating coating, which is characterized in that include the component of following parts by weight：Aqueous polyamine group formic acid Ester resin 25-36, methyl methacrylate 28-43, ethane-acetic acid ethyenyl ester 17-29, disodium ethylene diamine tetraacetate 18- 25, polyethylene glycol 12-19, dispersant 11-19, thickener 7-13, antifoaming agent 6-13, pH adjusting agent 8-22, polyaniline- Graphene hollow microspheres 45-62, gluconic acid polyhexamethylene guanide 13-24, distilled water 115-160, kaolin 22-35, Ti3SiC ceramic powder 21-38, nanoscale MCM-49 molecular sieves 34-55.
2. functional form Paper Coating coating according to claim 1, which is characterized in that the polyaniline-graphite alkene is hollow The grain diameter of microballoon is 200-400nm.
3. functional form Paper Coating coating according to claim 1, which is characterized in that the nanoscale MCM-49 molecular sieves Grain diameter be 100-200nm.
4. functional form Paper Coating coating according to claim 1, which is characterized in that the dispersant is dodecyl sulphur One kind in sour sodium, methyl anyl alcohol, guar gum, fatty acid polyethylene glycol ester.
5. functional form Paper Coating coating according to claim 1, which is characterized in that the thickener is hydroxypropyl methyl Cellulose.
6. functional form Paper Coating coating according to claim 1, which is characterized in that the antifoaming agent is poly dimethyl silicon Oxygen alkane.
7. functional form Paper Coating coating according to claim 1, which is characterized in that the pH adjusting agent is aminomethyl third Alcohol.
CN201711353489.0A 2017-12-15 2017-12-15 A kind of functional form Paper Coating coating Pending CN108457122A (en)

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CN201711353489.0A CN108457122A (en) 2017-12-15 2017-12-15 A kind of functional form Paper Coating coating

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CN108457122A true CN108457122A (en) 2018-08-28

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101512070A (en) * 2006-09-26 2009-08-19 赢创德固赛公司 Multi-functional paper for enhanced printing performance
CN105419438A (en) * 2015-12-30 2016-03-23 李栋军 Novel paint auxiliary agent
CN106280829A (en) * 2016-08-08 2017-01-04 马晓洁 A kind of aqueous, environmental protective acrylate paint with low abnormal smells from the patient, Formaldehyde decomposition
CN107266984A (en) * 2017-08-04 2017-10-20 吴俊� A kind of multifunctional anticorrosive water-proof heat-insulating paint and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101512070A (en) * 2006-09-26 2009-08-19 赢创德固赛公司 Multi-functional paper for enhanced printing performance
CN105419438A (en) * 2015-12-30 2016-03-23 李栋军 Novel paint auxiliary agent
CN106280829A (en) * 2016-08-08 2017-01-04 马晓洁 A kind of aqueous, environmental protective acrylate paint with low abnormal smells from the patient, Formaldehyde decomposition
CN107266984A (en) * 2017-08-04 2017-10-20 吴俊� A kind of multifunctional anticorrosive water-proof heat-insulating paint and preparation method thereof

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Application publication date: 20180828