CN1105046A - 颜料组合物 - Google Patents
颜料组合物 Download PDFInfo
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- CN1105046A CN1105046A CN94113777A CN94113777A CN1105046A CN 1105046 A CN1105046 A CN 1105046A CN 94113777 A CN94113777 A CN 94113777A CN 94113777 A CN94113777 A CN 94113777A CN 1105046 A CN1105046 A CN 1105046A
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- primary amine
- pigment
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- 239000000049 pigment Substances 0.000 title claims abstract description 35
- 239000000203 mixture Substances 0.000 title claims abstract description 34
- 150000001412 amines Chemical class 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims abstract description 6
- 150000003141 primary amines Chemical class 0.000 claims description 26
- 150000001875 compounds Chemical class 0.000 claims description 16
- YCWSUKQGVSGXJO-NTUHNPAUSA-N nifuroxazide Chemical group C1=CC(O)=CC=C1C(=O)N\N=C\C1=CC=C([N+]([O-])=O)O1 YCWSUKQGVSGXJO-NTUHNPAUSA-N 0.000 claims description 13
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 10
- 239000011707 mineral Substances 0.000 claims description 10
- 230000003213 activating effect Effects 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 claims 1
- 150000002484 inorganic compounds Chemical class 0.000 abstract 1
- 229910010272 inorganic material Inorganic materials 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 239000000243 solution Substances 0.000 description 8
- 238000005859 coupling reaction Methods 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 230000008878 coupling Effects 0.000 description 6
- 238000010168 coupling process Methods 0.000 description 6
- 229920000768 polyamine Polymers 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 4
- 239000004408 titanium dioxide Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- 125000003831 tetrazolyl group Chemical group 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 235000011054 acetic acid Nutrition 0.000 description 2
- 150000001243 acetic acids Chemical class 0.000 description 2
- DYRDKSSFIWVSNM-UHFFFAOYSA-N acetoacetanilide Chemical compound CC(=O)CC(=O)NC1=CC=CC=C1 DYRDKSSFIWVSNM-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000004985 diamines Chemical class 0.000 description 2
- XXUJMEYKYHETBZ-UHFFFAOYSA-N ethyl 4-nitrophenyl ethylphosphonate Chemical compound CCOP(=O)(CC)OC1=CC=C([N+]([O-])=O)C=C1 XXUJMEYKYHETBZ-UHFFFAOYSA-N 0.000 description 2
- 235000012907 honey Nutrition 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000012764 mineral filler Substances 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- OSFBJERFMQCEQY-UHFFFAOYSA-N propylidene Chemical group [CH]CC OSFBJERFMQCEQY-UHFFFAOYSA-N 0.000 description 2
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- PWGJDPKCLMLPJW-UHFFFAOYSA-N 1,8-diaminooctane Chemical compound NCCCCCCCCN PWGJDPKCLMLPJW-UHFFFAOYSA-N 0.000 description 1
- FZZMTSNZRBFGGU-UHFFFAOYSA-N 2-chloro-7-fluoroquinazolin-4-amine Chemical compound FC1=CC=C2C(N)=NC(Cl)=NC2=C1 FZZMTSNZRBFGGU-UHFFFAOYSA-N 0.000 description 1
- YXVIXWDTSCFZHY-UHFFFAOYSA-N 3-imino-N-methyl-N-propylpropan-1-amine Chemical compound CN(CCC=N)CCC YXVIXWDTSCFZHY-UHFFFAOYSA-N 0.000 description 1
- LPDSNGAFAJYVKH-UHFFFAOYSA-N 4-(4-aminophenyl)-2,3-dichloroaniline Chemical compound C1=CC(N)=CC=C1C1=CC=C(N)C(Cl)=C1Cl LPDSNGAFAJYVKH-UHFFFAOYSA-N 0.000 description 1
- LHECBTWFKAHFAS-UHFFFAOYSA-N 4-(4-aminophenyl)-6,6-dichlorocyclohexa-1,3-dien-1-amine Chemical compound C1C(Cl)(Cl)C(N)=CC=C1C1=CC=C(N)C=C1 LHECBTWFKAHFAS-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 101100247531 Arabidopsis thaliana RBOHC gene Proteins 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical group [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical class Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- 229940124913 IPOL Drugs 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 1
- 239000005700 Putrescine Substances 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 125000001118 alkylidene group Chemical group 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 239000000549 coloured material Substances 0.000 description 1
- 229940125782 compound 2 Drugs 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- -1 hydrocarbon primary amine Chemical class 0.000 description 1
- 235000011167 hydrochloric acid Nutrition 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- BFVHBHKMLIBQNN-UHFFFAOYSA-N n-(2-chlorophenyl)-3-oxobutanamide Chemical compound CC(=O)CC(=O)NC1=CC=CC=C1Cl BFVHBHKMLIBQNN-UHFFFAOYSA-N 0.000 description 1
- TVZIWRMELPWPPR-UHFFFAOYSA-N n-(2-methylphenyl)-3-oxobutanamide Chemical compound CC(=O)CC(=O)NC1=CC=CC=C1C TVZIWRMELPWPPR-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 229940001516 sodium nitrate Drugs 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- 150000003456 sulfonamides Chemical class 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000012756 surface treatment agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical class NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000001052 yellow pigment Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0001—Post-treatment of organic pigments or dyes
- C09B67/002—Influencing the physical properties by treatment with an amine
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/08—Treatment with low-molecular-weight non-polymer organic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Paints Or Removers (AREA)
Abstract
本发明公开了一种颜料组合物，它包括二芳基颜
料、一元伯胺、二元伯胺和具有活性氧化物或氢氧化
物表面的无机化合物。
Description
本发明涉及二芳基颜料组合物以及由该二芳基颜料组合物制得的印刷油墨，尤其是书刊凹印油墨。
二芳基颜料在印刷墨的制造中是常用的一类重要的着色材料。颜料黄12是一种广泛使用的溶剂基书刊凹印油墨，而且这时通常进行表面处理以赋予某些所需的应用特性。其中典型的表面处理剂是长链烃胺。GB 1085835指出，可使用脂肪族伯胺来处理颜料黄12以赋予良好的着色强度、光泽、透明度和改进的流变性能。在US 4515639中，也使用二胺来处理二芳基颜料，以减少油墨从中渗到质量较差的裸露纸料中。还有其它许多专利描述了用胺处理得到改性的颜料黄12，用来制备书刊凹印油墨，例如：US4643770，4462833，4220473，3905825，3827902，3655641和3607861。在GB1472781中，也描述了结合使用白色无机填料与烃伯胺处理的二芳基颜料在不损害光泽和强度的情况下改善渗透性的方法，所述无机填料是沉淀碳酸钙、瓷土、钡白或滑石。
本发明描述的是：用具有活性氧化物或氢氧化物表面的特定的无机化合物来处理已经过胺处理的二芳基颜料尤其是颜料黄12，使得凹印油墨的光泽和着色值大大改善。
因此，本发明提供一种颜料组合物，它包括二芳基黄色颜料、一元伯胺、二元伯胺和具有活性氧化物或氢氧物表面的无机化合物。
本发明的二芳基颜料组合物可以是例如颜料黄12，13，14，17，83，114，126，127，176，颜料橙16或颜料橙34或它们的组合物或混合物。
优选的颜料是颜料黄12，因为它广泛地用在溶剂基书刊凹印油墨中。
用于对本发明颜料组合物表面处理的一元伯胺可以是具有10-24个碳原子、优选12-18个碳原子的长链烷基的伯胺。适宜的一元伯胺的例子包括硬脂胺、松香胺如木树脂的胺衍生物（
Rosin Amine D）、N-长链烷基亚烷基二胺类（
Duomeens）、多胺类如N-coco丙二胺-N′-丙胺、聚酰胺/多胺衍生物（
Merginamide）、β胺类（
Armeen Lll）。特别优选的是N-烷基多亚丙基多胺（
In-ipol PS），其中烷基链的碳原子数主要落在C16-C18的范围内。
所述二元伯胺可以是如下通式I的化合物：
式中A是具有2-8个碳原子的亚烷基，n是0-8。
上述化合物的例子是1，3-二氨基丙烷、1，4-二氨基丁烷、1，8-二氨基辛烷、甲基亚氨基二丙基胺、二亚乙基三胺和五亚乙基六胺。特别优选的是四亚乙基五胺（TEPA）。
与上述胺一并添加以完整形成二芳基颜料组合物并提供活性氧化物或氢氧化物表面的无机化合物是金属例如钛、铝、镁、锌、锡、铁和镍/锑混合物的化合物。特别有价值的是市售级的二氧化钛（2
Tioxide R-CR，RCR6，RHD2，RCR90，RCR92和
Tiona 472和
Kro-nos 2063）。
所述具有活性氧化物或氢氧化物表面的化合物可直接加入或就地生成。例如：可以使用金属的盐类，使混合物呈碱性以沉淀出氧化物或氢氧化物。适宜的盐包括硫酸镁和硫酸铝。如果需要，可以使用化合物的混合物。
这些有机化合物可以在颜料合成之前、合成过程中或完成后加入，但优选在加完二胺（例如TEPA）之后和颜料组合物的分离之前加入。
本发明的二芳基颜料组合物可按下述方法制备：使3，3-二氯联苯胺四氮化，然后在水中用一种或多种成分如N-乙酰乙酰苯胺、乙酰乙酰-2-甲苯胺、乙酰乙酰-2-氯苯胺、乙酰乙酰-2，4-二甲苯胺和乙酰乙酰-2，5-二甲氧基-4-氯苯胺使其偶合。
一元伯胺和/或二元伯胺的添加可以在颜料合成之前、合成期间或之后时行。合成偶合优选在二元伯胺（例如TEPA）的存在下进行，而一元伯胺可以在合成完毕后加入。任何所需的遮光剂都可与一元伯胺一道加入，例如：颜料橙34。然后可加入无机化合物以完成组合。
一元伯胺的用量可以是二芳基颜料的5-30%（重量），优选15-25%（重量）。二元伯胺的用量可以是颜料重量的1-15%（重量），优选1.5-8%（重量）。有机化合物的用量可以是颜料重量的0.1-10%（重量），优选2.5-10%（重量）。
用这些组合物制成的书刊凹印油墨在光泽和着色强度方面显示出显著的改善。
实施例1
将32.6份3，3′-二氧联苯胺二盐酸盐在250份含40份浓盐酸（36%）的水中形成的均匀糊状物搅拌，然后用13.8份硝酸钠溶于25份水的溶液四氮化制得四唑鎓盐溶液。同时于0-5℃保温。加入1份活性炭使四唑鎓盐溶液澄清，随后过滤。在0-5℃下、用水将四唑翁盐溶液调至800份的最终重量。
将47.5份N-乙酰乙酰苯胺和22.6份氢氧化钠（47%）溶于465份水中，然后在剧烈搅拌下缓慢加入18.5份冰乙酸在135份水中的溶液制得偶合组分悬浮液。再向该偶合组分悬浮液中缓慢加入4.5份四亚乙基五胺在180份水中的溶液。
通过向沉淀的偶合组分悬浮液中逐渐加入四氮化的二氯联苯胺来进行偶合反应，反应过程中保持pH在4.5-5.5之间并通过添加冰块将温度控制在15-25℃之间。
将13.1份N-烷基多亚丙基多胺（
Inipol PS）和3份冰乙酸在290份水中的混合物搅拌加热至80℃而制成溶液，向其中加入1.2份颜料橙34和4.5份二氧化钛，用SILVERSON搅拌机搅拌5分钟后，加到偶合浆液中。
将浆液升温于90-95℃，保温10分钟，然后加入15%氢氧化钠溶液使pH值增至11.0。加冷水使浆液冷却至70℃。吸滤，用水洗至滤液的电导率小于500μS。
产物于80℃干燥20小时，然后碾碎，通过250μm筛。
实施例2-4
重复实施例1，只是用等量的下列化合物替代二氧化钛：
| 实施例 | 化合物 |
| 234 | 硫酸镁钛酸丁酯硫酸铝 |
实施例5-7
用实施例1，2和3的颜料组合物制成的油墨，用实施例1的颜料但不加二氧化钛制成对比油墨。
往蜜罐（honey jar）中装200g 10mm滑石瓷球、56.7g金属树脂酸盐与甲苯的混合物。26.6g甲苯和16.7g颜料制得油墨。将混合物以116转/分钟的转速球磨4小时。倒出研磨料用2号壳牌粘度杯测定流动性。用甲苯稀释至最终油墨通过2号壳牌粘度杯的时间为16秒。
然后用K-型刮板从油墨中刮样。用Gretag D152密度计测定强度，用Erichsen微型光泽计评定光泽。在下面给出的表中，对比油墨的强度和光泽设定为100%，所以任何超过100%的数字都表示有所改进。可以看出，在所有情况下，本发明的油墨都表现出较多的强度和改善的光泽。
结果列表
| 实施例 | 颜料 | 强度（％） | 光泽（％） |
| －567 | 对比实施例1实施例2实施例3 | 100105110105 | 100127125128 |
Claims (13)
1、一种颜料组合物，它包括二芳基颜料、一元伯胺、二元伯胺和具有活性氧化物或氢氧化物表面的无机化合物。
2、权利要求1所述的组合物，其中二芳基颜料黄12。
3、权利要求1或2所述的组合物，其中一元伯胺是具有10-24个碳原子的长链烷基的一元伯胺。
4、前述任意一项权利要求所述的组合物，其中二元伯胺是通式I的二元伯胺：
式中A是C2-8亚烷基，n是0-8。
5、权利要求4所述的组合物，其中二元伯胺是四乙亚乙基五胺。
6、前述任意一项权利要求所述的组合物，其中具有活性氧化物或氢氧化物表面的无机化合物直接加入或就地生成。
7、权利要求6所述的组合物，其中无机化合物是二氧化钠、硫酸镁、硫酸铝或钛酸丁酯或其衍生物。
8、前述任意一项权利要求所述的组合物，其中一元伯胺的用量为颜料的5-30%（重量）。
9、前述任意一项权利要求所述的组合物，其中二元伯胺的用量为颜料的1-15%（重量）。
10、前述任意一项权利要求所述的组合物，其中无机化合物的用量为颜料的0.1-10%（重量）。
11、制备前述任意一项权利要求所述的组合物的方法，它包括在颜料合成之前、期间或之后将一元伯胺、二元伯胺和无机化合物加到颜料中。
12、权利要求11所述的方法，其中颜料合成是这样进行的：在二元伯胺的存在下，合成完毕后加入一元伯胺，随后加入无机化合物。
13、一种油墨，它含有权利要求1-10任意一项所述的颜料组合物作为着色剂。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9322257.8 | 1993-10-28 | ||
| GB939322257A GB9322257D0 (en) | 1993-10-28 | 1993-10-28 | Pigment composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1105046A true CN1105046A (zh) | 1995-07-12 |
| CN1068363C CN1068363C (zh) | 2001-07-11 |
Family
ID=10744278
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN94113777A Expired - Fee Related CN1068363C (zh) | 1993-10-28 | 1994-10-28 | 颜料组合物 |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US5482548A (zh) |
| EP (1) | EP0651029B1 (zh) |
| KR (1) | KR100319497B1 (zh) |
| CN (1) | CN1068363C (zh) |
| AU (1) | AU674791B2 (zh) |
| CA (1) | CA2134412A1 (zh) |
| CZ (1) | CZ289373B6 (zh) |
| DE (1) | DE69423417T2 (zh) |
| DK (1) | DK0651029T3 (zh) |
| ES (1) | ES2144037T3 (zh) |
| GB (1) | GB9322257D0 (zh) |
| SK (1) | SK129594A3 (zh) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1942531B (zh) * | 2004-04-06 | 2010-09-01 | 西巴特殊化学品控股有限公司 | 流变学改善的油墨用颜料组合物 |
| CN101155885B (zh) * | 2005-03-14 | 2012-05-09 | 惠普开发有限公司 | 耐臭氧牢度更好的含胺和酞菁染料的喷墨墨水 |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9516929D0 (en) * | 1995-08-18 | 1995-10-18 | Ciba Geigy Ag | Pigment compositions |
| DE19710977A1 (de) * | 1997-03-17 | 1998-09-24 | Clariant Gmbh | Illustrationstiefdruckfarbe auf Basis von C.I.Pigment Yellow 139 |
| US5897695A (en) * | 1997-09-02 | 1999-04-27 | Xerox Corporation | Ink compositions |
| DE19751448A1 (de) * | 1997-11-20 | 1999-05-27 | Bayer Ag | Anorganische Pigmente enthaltende Pigmentpräparationen |
| US6136087A (en) * | 1998-11-04 | 2000-10-24 | Uhlich Color Company, Inc. | Crystal growth inhibitor |
| DE10342601A1 (de) | 2003-09-12 | 2005-04-21 | Clariant Gmbh | Pigmentzusammensetzungen aus organischen und anorganischen Pigmenten |
| WO2006111493A2 (en) * | 2005-04-21 | 2006-10-26 | Ciba Specialty Chemicals Holding Inc. | Pigment formulations |
| EP4174141A1 (de) * | 2021-10-26 | 2023-05-03 | SURTECO GmbH | Intensive homogene uniflächen |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1472781A (en) * | 1974-08-14 | 1977-05-04 | Koege Kemisk Vaerk | Preconditione d yellow pigment preparations |
| DE3104257A1 (de) * | 1981-02-07 | 1983-02-03 | Hoechst Ag, 6000 Frankfurt | Azopigmentpraeparationen, verfahren zu ihrer herstellung und ihre verwendung |
| DE3113882A1 (de) * | 1981-04-07 | 1982-10-21 | Hoechst Ag, 6000 Frankfurt | Azopigmentpraeparationen, verfahren zu ihrer herstellung und ihre verwendung |
| US4462833A (en) * | 1982-12-27 | 1984-07-31 | Inmont Corporation | Process for treating diarylide yellow pigment |
| DE3336030A1 (de) * | 1983-10-04 | 1985-04-11 | Bayer Ag, 5090 Leverkusen | Azopigmentpraeparationen |
| US4643770A (en) * | 1985-04-12 | 1987-02-17 | Basf Corporation, Inmont Division | Amine-free, easily dispersible diarylide yellow pigment compositions |
-
1993
- 1993-10-28 GB GB939322257A patent/GB9322257D0/en active Pending
-
1994
- 1994-10-21 EP EP94307777A patent/EP0651029B1/en not_active Expired - Lifetime
- 1994-10-21 DE DE69423417T patent/DE69423417T2/de not_active Expired - Fee Related
- 1994-10-21 DK DK94307777T patent/DK0651029T3/da active
- 1994-10-21 ES ES94307777T patent/ES2144037T3/es not_active Expired - Lifetime
- 1994-10-25 CZ CZ19942634A patent/CZ289373B6/cs not_active IP Right Cessation
- 1994-10-25 US US08/328,227 patent/US5482548A/en not_active Expired - Fee Related
- 1994-10-26 CA CA002134412A patent/CA2134412A1/en not_active Abandoned
- 1994-10-26 SK SK1295-94A patent/SK129594A3/sk unknown
- 1994-10-26 AU AU77499/94A patent/AU674791B2/en not_active Ceased
- 1994-10-27 KR KR1019940027605A patent/KR100319497B1/ko not_active IP Right Cessation
- 1994-10-28 CN CN94113777A patent/CN1068363C/zh not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1942531B (zh) * | 2004-04-06 | 2010-09-01 | 西巴特殊化学品控股有限公司 | 流变学改善的油墨用颜料组合物 |
| CN101155885B (zh) * | 2005-03-14 | 2012-05-09 | 惠普开发有限公司 | 耐臭氧牢度更好的含胺和酞菁染料的喷墨墨水 |
Also Published As
| Publication number | Publication date |
|---|---|
| US5482548A (en) | 1996-01-09 |
| KR100319497B1 (ko) | 2002-11-13 |
| DE69423417D1 (de) | 2000-04-20 |
| JP3795092B2 (ja) | 2006-07-12 |
| CA2134412A1 (en) | 1995-04-29 |
| CZ263494A3 (en) | 1995-10-18 |
| CN1068363C (zh) | 2001-07-11 |
| EP0651029A1 (en) | 1995-05-03 |
| DK0651029T3 (da) | 2000-08-14 |
| EP0651029B1 (en) | 2000-03-15 |
| ES2144037T3 (es) | 2000-06-01 |
| GB9322257D0 (en) | 1993-12-15 |
| AU7749994A (en) | 1995-05-18 |
| AU674791B2 (en) | 1997-01-09 |
| KR950011565A (ko) | 1995-05-15 |
| DE69423417T2 (de) | 2000-09-07 |
| CZ289373B6 (cs) | 2002-01-16 |
| JPH07179779A (ja) | 1995-07-18 |
| SK129594A3 (en) | 1995-05-10 |
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