CN110499068A - A kind of water-based ink carbon ribbon film and preparation method thereof - Google Patents
A kind of water-based ink carbon ribbon film and preparation method thereof Download PDFInfo
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- CN110499068A CN110499068A CN201910624254.3A CN201910624254A CN110499068A CN 110499068 A CN110499068 A CN 110499068A CN 201910624254 A CN201910624254 A CN 201910624254A CN 110499068 A CN110499068 A CN 110499068A
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- carbon ribbon
- based ink
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- ribbon film
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/08—Printing inks based on natural resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of water-based ink carbon ribbon films, are formulated by the raw material of following parts by weight: 32-38 parts of rosin modified phenolic resin, 34-40 parts of rosin maleic anhydride polyol ester, 12-16 parts of colouring matter, 1-3 parts of calcium carbonate, 2-4 parts of barium sulfate, 0.4-0.6 parts of smog silicon, 5-9 parts of starch, 0.7-0.9 parts of plasticizer, 0.3-0.5 parts of white oil, 1-3 parts of fragrance, 70-80 parts of graphene oxide dispersion.Using the technical program, by calcium carbonate, barium sulfate as filler material, is conducive to the thickness for increasing carbon ribbon film, improves its wearability；Smog silicon, the starch of addition change the mobility of system, reduce solids sedimentation rate；The white oil of addition advantageously reduces the color intensity of colouring matter；The fragrance of addition is conducive to improve the smell of carbon ribbon film；Prepared water-based ink carbon ribbon film organic solvent-free release, safer, environmentally friendly, preparation is convenient, at low cost, superior performance.
Description
Technical field
The present invention relates to the technical field of ink preparation more particularly to a kind of water-based ink carbon ribbon films and preparation method thereof.
Background technique
Water-based ink is referred to as ink, and flexographic plate aqueous ink is also referred to as liquid ink, it is mainly by water-soluble resin, You Jiyan
Material, solvent and related auxiliaries are formed through abrasive machining, and water-based ink is especially suitable for cigarette, wine, food, beverage, drug, youngster
The sanitary conditions such as virgin toy require stringent Packaging Printing Product.
Stage now, water-based ink become gradually instead of traditional solvent-based ink and print becoming greatly for ink now
Gesture.Water-based ink is with water and alcohol instead of organic solvents such as original benzene classes, therefore it is excellent to have an environmental-protecting performance, VOC content
Low advantage；The water-based ink of existing preparation remains the disadvantages of poor adhesive force, poor water resistance, high cost of material.Therefore,
Need to develop the better water-based ink of performance, to meet the application demand of people, therefore, we design a kind of water-based ink carbon
Band film and preparation method thereof.
Summary of the invention
For the defect for solving prior art, the invention discloses a kind of water-based ink carbon ribbon films and preparation method thereof.
The invention discloses a kind of water-based ink carbon ribbon films, are formulated by the raw material of following parts by weight: Abietyl modified phenol
32-38 parts of urea formaldehyde, 34-40 parts of rosin maleic anhydride polyol ester, 12-16 parts of colouring matter, 1-3 parts of calcium carbonate, 2-4 parts of barium sulfate,
0.4-0.6 parts of smog silicon, 5-9 parts of starch, 0.7-0.9 parts of plasticizer, 0.3-0.5 parts of white oil, 1-3 parts of fragrance, graphene oxide
70-80 parts of dispersion liquid.
Preferably, a kind of water-based ink carbon ribbon film, is formulated: rosin modified phenolic resin by the raw material of following parts by weight
32 parts, 34 parts of rosin maleic anhydride polyol ester, 12 parts of colouring matter, 1 part of calcium carbonate, 2 parts of barium sulfate, 0.4 part of smog silicon, 5 parts of starch,
0.7 part of plasticizer, 0.3 part of white oil, 1 part of fragrance, 70 parts of graphene oxide dispersion.
Preferably, a kind of water-based ink carbon ribbon film, is formulated: rosin modified phenolic resin by the raw material of following parts by weight
35 parts, 37 parts of rosin maleic anhydride polyol ester, 14 parts of colouring matter, 2 parts of calcium carbonate, 3 parts of barium sulfate, 0.5 part of smog silicon, 7 parts of starch,
0.8 part of plasticizer, 0.4 part of white oil, 2 parts of fragrance, 75 parts of graphene oxide dispersion.
Preferably, a kind of water-based ink carbon ribbon film, is formulated: rosin modified phenolic resin by the raw material of following parts by weight
38 parts, 40 parts of rosin maleic anhydride polyol ester, 16 parts of colouring matter, 3 parts of calcium carbonate, 4 parts of barium sulfate, 0.6 part of smog silicon, 9 parts of starch,
0.9 part of plasticizer, 0.5 part of white oil, 3 parts of fragrance, 80 parts of graphene oxide dispersion.
Preferably, the colouring matter is azo system or phthalein blueness is organic pigment.
Preferably, the plasticizer is dibatyl phithalate.
Preferably, a kind of preparation method of water-based ink carbon ribbon film, by weight component weigh rosin modified phenolic resin, pine
Fragrant cis-butenedioic anhydride polyol ester, colouring matter, calcium carbonate, barium sulfate, smog silicon, starch, plasticizer, white oil, fragrance, graphene oxide point
Dispersion liquid is added in reaction kettle, and temperature of reaction kettle is at 30-40 DEG C, and 2000-3000 revs/min of speed of agitator, stir process 1-
Water-based ink carbon ribbon film is made by vacuum filtration method after stirring in 2h.
Preferably, obtained water-based ink carbon ribbon film carries out sided corona treatment, and the surface tension of film layer is made to reach 44-
48dyn/cm。
Beneficial effect is: by calcium carbonate, barium sulfate as filler material, being conducive to the thickness for increasing carbon ribbon film, improves it
Wearability；Smog silicon, the starch of addition change the mobility of system, reduce solids sedimentation rate；The white oil of addition is conducive to
Reduce the color intensity of colouring matter；The fragrance of addition is conducive to improve the smell of carbon ribbon film；Prepared water-based ink carbon ribbon film
Organic solvent-free release, safer, environmentally friendly, preparation is convenient, at low cost, superior performance.
Specific embodiment
Embodiment 1
The invention discloses a kind of water-based ink carbon ribbon films, are formulated by the raw material of following parts by weight: rosin modified phenolic tree
32 parts of rouge, 34 parts of rosin maleic anhydride polyol ester, 12 parts of colouring matter, 1 part of calcium carbonate, 2 parts of barium sulfate, 0.4 part of smog silicon, starch 5
Part, 0.7 part of plasticizer, 0.3 part of white oil, 1 part of fragrance, 70 parts of graphene oxide dispersion.
The colouring matter is azo system or phthalein blueness is organic pigment.
The plasticizer is dibatyl phithalate.
A kind of preparation method of water-based ink carbon ribbon film, by weight component weigh rosin modified phenolic resin, Rosin Maleic
Polyol ester, colouring matter, calcium carbonate, barium sulfate, smog silicon, starch, plasticizer, white oil, fragrance, graphene oxide dispersion add
Enter into reaction kettle, temperature of reaction kettle is at 30 DEG C, and 2000 revs/min of speed of agitator, stir process 1h passes through vacuum after stirring
Water-based ink carbon ribbon film is made in suction filtration method.
Obtained water-based ink carbon ribbon film carries out sided corona treatment, and the surface tension of film layer is made to reach 44dyn/cm.
Embodiment 2
The invention discloses a kind of water-based ink carbon ribbon films, are formulated by the raw material of following parts by weight: rosin modified phenolic tree
35 parts of rouge, 37 parts of rosin maleic anhydride polyol ester, 14 parts of colouring matter, 2 parts of calcium carbonate, 3 parts of barium sulfate, 0.5 part of smog silicon, starch 7
Part, 0.8 part of plasticizer, 0.4 part of white oil, 2 parts of fragrance, 75 parts of graphene oxide dispersion.
The colouring matter is azo system or phthalein blueness is organic pigment.
The plasticizer is dibatyl phithalate.
A kind of preparation method of water-based ink carbon ribbon film, by weight component weigh rosin modified phenolic resin, Rosin Maleic
Polyol ester, colouring matter, calcium carbonate, barium sulfate, smog silicon, starch, plasticizer, white oil, fragrance, graphene oxide dispersion add
Entering into reaction kettle, temperature of reaction kettle is at 35 DEG C, and 2500 revs/min of speed of agitator, stir process 1.5h, by true after stirring
Water-based ink carbon ribbon film is made in empty pump filtering method.
Obtained water-based ink carbon ribbon film carries out sided corona treatment, and the surface tension of film layer is made to reach 46dyn/cm.
Embodiment 3
The invention discloses a kind of water-based ink carbon ribbon films, are formulated by the raw material of following parts by weight: rosin modified phenolic tree
38 parts of rouge, 40 parts of rosin maleic anhydride polyol ester, 16 parts of colouring matter, 3 parts of calcium carbonate, 4 parts of barium sulfate, 0.6 part of smog silicon, starch 9
Part, 0.9 part of plasticizer, 0.5 part of white oil, 3 parts of fragrance, 80 parts of graphene oxide dispersion.
The colouring matter is azo system or phthalein blueness is organic pigment.
The plasticizer is dibatyl phithalate.
A kind of preparation method of water-based ink carbon ribbon film, by weight component weigh rosin modified phenolic resin, Rosin Maleic
Polyol ester, colouring matter, calcium carbonate, barium sulfate, smog silicon, starch, plasticizer, white oil, fragrance, graphene oxide dispersion add
Enter into reaction kettle, temperature of reaction kettle is at 40 DEG C, and 3000 revs/min of speed of agitator, stir process 2h passes through vacuum after stirring
Water-based ink carbon ribbon film is made in suction filtration method.
Obtained water-based ink carbon ribbon film carries out sided corona treatment, and the surface tension of film layer is made to reach 48dyn/cm.
Finally, it should be noted that above embodiments are only to illustrate the present invention and not limit technology described in the invention
Scheme；Therefore, although this specification is referring to above-mentioned each embodiment, the present invention has been described in detail, this
Field it is to be appreciated by one skilled in the art that still can modify to the present invention or equivalent replacement；And all do not depart from this
The technical solution and its improvement of the spirit and scope of invention, should all cover within the scope of the claims of the present invention.
Claims (8)
1. a kind of water-based ink carbon ribbon film, it is characterised in that: be formulated by the raw material of following parts by weight: rosin modified phenolic tree
32-38 parts of rouge, 34-40 parts of rosin maleic anhydride polyol ester, 12-16 parts of colouring matter, 1-3 parts of calcium carbonate, 2-4 parts of barium sulfate, smog
0.4-0.6 parts of silicon, 5-9 parts of starch, 0.7-0.9 parts of plasticizer, 0.3-0.5 parts of white oil, 1-3 parts of fragrance, graphene oxide dispersion
70-80 parts of liquid.
2. a kind of water-based ink carbon ribbon film according to claim 1, it is characterised in that: prepared by the raw material of following parts by weight
It forms: 32 parts of rosin modified phenolic resin, 34 parts of rosin maleic anhydride polyol ester, 12 parts of colouring matter, 1 part of calcium carbonate, barium sulfate 2
Part, 0.4 part of smog silicon, 5 parts of starch, 0.7 part of plasticizer, 0.3 part of white oil, 1 part of fragrance, 70 parts of graphene oxide dispersion.
3. a kind of water-based ink carbon ribbon film according to claim 1, it is characterised in that: prepared by the raw material of following parts by weight
It forms: 35 parts of rosin modified phenolic resin, 37 parts of rosin maleic anhydride polyol ester, 14 parts of colouring matter, 2 parts of calcium carbonate, barium sulfate 3
Part, 0.5 part of smog silicon, 7 parts of starch, 0.8 part of plasticizer, 0.4 part of white oil, 2 parts of fragrance, 75 parts of graphene oxide dispersion.
4. a kind of water-based ink carbon ribbon film according to claim 1, it is characterised in that: prepared by the raw material of following parts by weight
It forms: 38 parts of rosin modified phenolic resin, 40 parts of rosin maleic anhydride polyol ester, 16 parts of colouring matter, 3 parts of calcium carbonate, barium sulfate 4
Part, 0.6 part of smog silicon, 9 parts of starch, 0.9 part of plasticizer, 0.5 part of white oil, 3 parts of fragrance, 80 parts of graphene oxide dispersion.
5. a kind of water-based ink carbon ribbon film according to claim 1, it is characterised in that: the colouring matter is azo system or phthalein
Blueness is organic pigment.
6. a kind of water-based ink carbon ribbon film according to claim 1, it is characterised in that: the plasticizer is phthalic acid two
Butyl ester.
7. a kind of preparation method of water-based ink carbon ribbon film, it is characterised in that: by weight component weigh rosin modified phenolic resin,
Rosin maleic anhydride polyol ester, colouring matter, calcium carbonate, barium sulfate, smog silicon, starch, plasticizer, white oil, fragrance, graphene oxide
Dispersion liquid is added in reaction kettle, and temperature of reaction kettle is at 30-40 DEG C, and 2000-3000 revs/min of speed of agitator, stir process
Water-based ink carbon ribbon film is made by vacuum filtration method after stirring in 1-2h.
8. a kind of preparation method of water-based ink carbon ribbon film according to claim 7, it is characterised in that: obtained is aqueous
Ink carbon ribbon film carries out sided corona treatment, and the surface tension of film layer is made to reach 44-48dyn/cm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910624254.3A CN110499068A (en) | 2019-07-11 | 2019-07-11 | A kind of water-based ink carbon ribbon film and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910624254.3A CN110499068A (en) | 2019-07-11 | 2019-07-11 | A kind of water-based ink carbon ribbon film and preparation method thereof |
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| Publication Number | Publication Date |
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| CN110499068A true CN110499068A (en) | 2019-11-26 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910624254.3A Pending CN110499068A (en) | 2019-07-11 | 2019-07-11 | A kind of water-based ink carbon ribbon film and preparation method thereof |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB943401A (en) * | 1959-02-11 | |||
| CN102936438A (en) * | 2012-11-29 | 2013-02-20 | 天津市赢事达办公用品厂 | Water-based ink type food date label |
| CN106189544A (en) * | 2016-07-11 | 2016-12-07 | 鹏码实业(上海)有限公司 | A kind of heat transfer colour ribbon based on water-base resin and preparation method thereof |
-
2019
- 2019-07-11 CN CN201910624254.3A patent/CN110499068A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB943401A (en) * | 1959-02-11 | |||
| CN102936438A (en) * | 2012-11-29 | 2013-02-20 | 天津市赢事达办公用品厂 | Water-based ink type food date label |
| CN106189544A (en) * | 2016-07-11 | 2016-12-07 | 鹏码实业(上海)有限公司 | A kind of heat transfer colour ribbon based on water-base resin and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 张光华编著: "《精细化学品配方技术》", 30 November 1991 * |
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| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information | ||
| CB02 | Change of applicant information |
Address after: 236000 Xinhua office, Yingdong District, Fuyang City, Anhui Province Applicant after: Anhui Mengniu Packaging Technology Co.,Ltd. Address before: 236000 Xinhua office, Yingdong District, Fuyang City, Anhui Province Applicant before: ANHUI MENGNIU COLOR PRINTING PACKAGING Co.,Ltd. Address after: 236000 Xinhua office, Yingdong District, Fuyang City, Anhui Province Applicant after: Anhui Fuhe Packaging Technology Co.,Ltd. Address before: 236000 Xinhua office, Yingdong District, Fuyang City, Anhui Province Applicant before: Anhui Mengniu Packaging Technology Co.,Ltd. |
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Application publication date: 20191126 |