CN104099041B - A kind of aqueous two-in-one colorful covering membrane glue and preparation method thereof - Google Patents
A kind of aqueous two-in-one colorful covering membrane glue and preparation method thereof Download PDFInfo
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- CN104099041B CN104099041B CN201310119062.XA CN201310119062A CN104099041B CN 104099041 B CN104099041 B CN 104099041B CN 201310119062 A CN201310119062 A CN 201310119062A CN 104099041 B CN104099041 B CN 104099041B
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Abstract
The present invention is about a kind of aqueous two-in-one colorful covering membrane glue and preparation method thereof, this aqueous two-in-one colorful covering membrane glue is made up of following part by weight composition: acrylicacidandesters and cinnamic co-polymer emulsion 70% 95%, aliphatic polycarboxylic acid's salt and block copolymer and organic silicon solution 0.70% or polyether-modified polysiloxane and polyether polyester modification by copolymerization polysiloxane 0.80%, high shear auxiliary rheological agents 0 1%, aqueous color paste 4% 25%, defoamer 0 0.1%.Product adaptation of the present invention is in printing processing dry type coating technique, for completing the lamination bonding between paper and film, can synchronize to replace traditional big spot color printing operation on the spot and traditional dry method coating processes, two procedures are integrated and are reduced to one procedure and complete, have saving of labor, save time, environmental protection, energy-saving and cost-reducing, reduce processing cost, improve the characteristics such as production efficiency；Meanwhile, the finished product after processing has that cohesive force is strong, lid powder power is good, coloring good, brightness is high, without shrinkage cavity, without performance advantages such as Snow Mark cloud points.
Description
Technical field
The present invention relates to a kind of aqueous two-in-one colorful covering membrane glue and preparation method thereof.
Background technology
This century nearly ten years, traditional aqueous dry method laminated adhesive, by dry method laminating machine gluing, be dried, laminating technique,
The lamination bonding operation between film and paper can be completed, but the big spot ink printer on the spot of paper cannot be synchronously completed with machine
Sequence；Equally, traditional printer can complete the big spot ink printing process the most on the spot of paper, can not with machine synchronously complete paper with
Lamination bonding operation between film.With a product of the present invention, replace printing-ink and two kinds of materials of laminated adhesive, by dry simultaneously
Method laminating machine and coating technique thereof, can synchronize to be integrated into big spot ink printing on the spot with dry method overlay film two procedure with machine
One procedure completes.The innovation point of the present invention is, applies the technology of the present invention, has started big spot ink and dry method on the spot
The two kinds of materials covering glue unite two into one, have saving of labor, save time, environmental protection, energy-saving and cost-reducing, reduce processing cost, improve production efficiency
Etc. characteristic；Meanwhile, the finished product after processing has that cohesive force is strong, lid powder power is good, coloring good, brightness is high, without shrinkage cavity, without Snow Mark
The performance advantages such as cloud point.
Summary of the invention
The technical problem to be solved in the present invention is to provide one and has that cohesive force is strong, lid powder power is good, coloring good, brightness
High, without shrinkage cavity, without Snow Mark cloud point, the simple aqueous of operation two-in-one colorful covering membrane glue and preparation method thereof.The present invention is logical
Cross what techniques below scheme realized:
A kind of aqueous two-in-one colorful covering membrane glue, is made up of following part by weight composition: acrylicacidandesters and styrene
Co-polymer emulsion 93.70%, the aqueous carbon black color slurry 5.00% of solid content 50%, aliphatic polycarboxylic acid's salt and block copolymerization
Thing and organic silicon solution 0.70%, association type polyurethanes high shear auxiliary rheological agents 0.50%, non-silicon class froth breaking foam inhibitor
0.10%.
Described acrylicacidandesters and cinnamic co-polymer emulsion are anionic, and pH value is 7～8, solid content
46% ± 2%, viscosity is 18 seconds/25 DEG C, is coated with 4# cup, and Tg value is-8 DEG C, particle diameter 0.2 micron.
The manufacture method of this aqueous two-in-one colorful covering membrane glue is:
(1) start blender, under the stirring of 40-50r/min speed, the raw material in above-mentioned weight proportion is put into not successively
In rust steel container, feed intake complete.
(2) after blender continues dispersed with stirring 30min under 400-500r/min speed stirs, through 400 mesh double medium filtrations
Produce.
Further, a kind of aqueous two-in-one colorful covering membrane glue, it is made up of following part by weight composition: acrylicacidandesters
With cinnamic co-polymer emulsion 86. 60%, the organic red slurry of aqueous azo 12.00% of solid content 55%, polyethers changes
Property polysiloxane and polyether polyester modification by copolymerization polysiloxane 0.80%, association type polyurethanes high shear rheology helps
Agent 0.50%, non-silicon class froth breaking foam inhibitor 0.10%.
Described acrylicacidandesters and cinnamic co-polymer emulsion are anionic, and pH value is 7～8, solid content
46% ± 2%, viscosity is 18 seconds/25 DEG C, is coated with 4# cup, and Tg value is-8 DEG C, particle diameter 0.2 micron.
The manufacture method of this aqueous two-in-one colorful covering membrane glue is: (1) starts blender, and 40-50r/min speed stirs
Under, the raw material in above-mentioned weight proportion is put in rustless steel container successively, feeds intake complete.
(2) after blender continues dispersed with stirring 30min under 400-500r/min speed stirs, through 400 mesh double medium filtrations
Produce.
Further, a kind of aqueous two-in-one colorful covering membrane glue, be made up of following part by weight composition: acrylic acid and
Ester and cinnamic co-polymer emulsion 82. 60%, the aqueous azo organic yellow mill base 16.00% of solid content 55%, polyethers
Modified polyorganosiloxanes and polyether polyester modification by copolymerization polysiloxane 0.40%, aliphatic polycarboxylic acid's salt and block copolymerization
Thing and organic silicon solution 0.40%, association type polyurethanes high shear auxiliary rheological agents 0.50%, non-silicon class froth breaking foam inhibitor
0.10%.
Described acrylicacidandesters and cinnamic co-polymer emulsion are anionic, and pH value is 7～8, solid content 46%
± 2%, viscosity is 18 seconds/25 DEG C, is coated with 4# cup, and Tg value is-8 DEG C, particle diameter 0.2 micron.
The manufacture method of this aqueous two-in-one colorful covering membrane glue is: (1) starts blender, and 40-50r/min speed stirs
Under, the raw material in above-mentioned weight proportion is put in rustless steel container successively, feeds intake complete.
(2) after blender continues dispersed with stirring 30min under 400-500r/min speed stirs, through 400 mesh double medium filtrations
Produce.
Further, a kind of aqueous two-in-one colorful covering membrane glue, be made up of following part by weight composition: acrylic acid and
Ester and cinnamic co-polymer emulsion 86. 60%, the aqueous phthalocyanine class green organic slurry 12.00% of solid content 58%, polyethers
Modified polyorganosiloxanes and polyether polyester modification by copolymerization polysiloxane 0.50%, aliphatic polycarboxylic acid's salt and block copolymerization
Thing and organic silicon solution 0.30%, association type polyurethanes high shear auxiliary rheological agents 0.50%, non-silicon class froth breaking foam inhibitor
0.10%.
Described acrylicacidandesters and cinnamic co-polymer emulsion are anionic, and pH value is 7～8, solid content 46%
± 2%, viscosity is 18 seconds/25 DEG C, is coated with 4# cup, and Tg value is-8 DEG C, particle diameter 0.2 micron.
The manufacture method of this aqueous two-in-one colorful covering membrane glue is: (1) starts blender, and 40-50r/min speed stirs
Under, the raw material in above-mentioned weight proportion is put in rustless steel container successively, feeds intake complete.
(2) after blender continues dispersed with stirring 30min under 400-500r/min speed stirs, through 400 mesh double medium filtrations
Produce.
Further, a kind of aqueous two-in-one colorful covering membrane glue, be made up of following part by weight composition: acrylic acid and
Ester and cinnamic co-polymer emulsion 88. 60%, the organic blue slurry 10.00% of aqueous phthalocyanine class of solid content 60%, polyethers
Modified polyorganosiloxanes and polyether polyester modification by copolymerization polysiloxane 0.50%, aliphatic polycarboxylic acid's salt and block copolymerization
Thing and organic silicon solution 0.30%, association type polyurethanes high shear auxiliary rheological agents 0.50%, non-silicon class froth breaking foam inhibitor
0.10%.
Described acrylicacidandesters and cinnamic co-polymer emulsion are anionic, and pH value is 7～8, solid content 46%
± 2%, viscosity is 18 seconds/25 DEG C, is coated with 4# cup, and Tg value is-8 DEG C, particle diameter 0.2 micron.
The manufacture method of this aqueous two-in-one colorful covering membrane glue is: (1) starts blender, and 40-50r/min speed stirs
Under, the raw material in above-mentioned weight proportion is put in rustless steel container successively, feeds intake complete.
(2) after blender continues dispersed with stirring 30min under 400-500r/min speed stirs, through 400 mesh double medium filtrations
Produce.
A kind of aqueous two-in-one colorful covering membrane glue of the present invention and preparation method thereof, by acrylicacidandesters with cinnamic
Co-polymer emulsion, wetting dispersing agent, high shear auxiliary rheological agents, aqueous color paste, defoamer are prepared from through mechanical dispersion, adapt to
In printing processing dry type coating technique, the lamination be used between paper and film bonds, can synchronize to replace traditional the most on the spot
Two procedures integration are reduced to one procedure and complete, have saving of labor, province by spot color printing operation and traditional dry method coating processes
Time, environmental protection, energy-saving and cost-reducing, reduce processing cost, improve the characteristics such as production efficiency；Meanwhile, the finished product after processing has cohesive force
By force, lid powder power is good, coloring good, brightness is high, without shrinkage cavity, without performance advantages such as Snow Mark cloud points.
Detailed description of the invention
Following example are used for illustrating the present invention, but are not limited to the scope of the present invention.
Embodiment one
A kind of aqueous two-in-one colorful covering membrane glue, is made up of following part by weight composition: acrylicacidandesters and styrene
Co-polymer emulsion 93.70%, aqueous carbon black color slurry (solid content 50%) 5.00%, aliphatic polycarboxylic acid's salt and block copolymerization
Thing and organic silicon solution 0.70%, high shear auxiliary rheological agents (association type polyurethanes high shear auxiliary rheological agents) 0.50%, non-silicon
Class froth breaking foam inhibitor 0.10 %.
Wherein, acrylicacidandesters with the technical specification of cinnamic co-polymer emulsion is: anionic, solid content
(%) 46 ± 2, pH value 7-8, viscosity (being coated with 4# cup/25 DEG C) 18 seconds, Tg value-8 DEG C, particle diameter 0.2 micron.
The manufacture method of described a kind of aqueous two-in-one colorful covering membrane glue is as follows:
(1) start blender, under the stirring of 40-50r/min speed, the raw material in above-mentioned weight proportion is put into not successively
In rust steel container, feed intake complete；
(2) after blender continues dispersed with stirring 30min under 400-500r/min speed stirs, through 400 mesh double medium filtrations
Produce.
Wherein, the product technology performance of preparation is: fineness (scraper plate method) is less than 15 μ, viscosity (being coated with 4# cup/25 DEG C) 20
Second, pH value 7, solid content (%) 46.50.
Embodiment two
A kind of aqueous two-in-one colorful covering membrane glue, is made up of following part by weight composition: acrylicacidandesters and styrene
Co-polymer emulsion 86. 60%, the organic red slurry of aqueous azo (solid content 55%) 12.00%, polyether-modified poly-organic
Siloxanes and polyether polyester modification by copolymerization polysiloxane 0.80%, high shear auxiliary rheological agents (cut by association type polyurethanes height
Cut auxiliary rheological agents) 0.50%, defoamer (non-silicon class froth breaking foam inhibitor) 0.10%.
Wherein, acrylicacidandesters with the technical specification of cinnamic co-polymer emulsion is: anionic, solid content
(%) 46 ± 2, pH value 7-8, viscosity (being coated with 4# cup/25 DEG C) 18 seconds, Tg value-8 DEG C, particle diameter 0.2 micron.
The manufacture method of described a kind of aqueous two-in-one colorful covering membrane glue is as follows:
(1) start blender, under the stirring of 40-50r/min speed, the raw material in above-mentioned weight proportion is put into not successively
In rust steel container, feed intake complete；
(2) after blender continues dispersed with stirring 30min under 400-500r/min speed stirs, through 400 mesh double medium filtrations
Produce.
Wherein, the product technology performance of preparation is: fineness (scraper plate method) is less than 15 μ, viscosity (being coated with 4# cup/25 DEG C) 22
Second, pH value 7, solid content (%) 47.30.
Embodiment three
A kind of aqueous two-in-one colorful covering membrane glue, is made up of following part by weight composition: acrylicacidandesters and styrene
Co-polymer emulsion 82. 60%, aqueous azo organic yellow mill base (solid content 55%) 16.00%, polyether-modified poly-organic
Siloxanes and polyether polyester modification by copolymerization polysiloxane 0.40%, aliphatic polycarboxylic acid's salt and block copolymer and organosilicon
Solution 0.40%, high shear auxiliary rheological agents (association type polyurethanes high shear auxiliary rheological agents) 0.50%, (non-silicon class disappears defoamer
Bubble foam inhibitor) 0.10%.
Wherein, acrylicacidandesters with the technical specification of cinnamic co-polymer emulsion is: anionic, solid content
(%) 46 ± 2, pH value 7-8, viscosity (being coated with 4# cup/25 DEG C) 18 seconds, Tg value-8 DEG C, particle diameter 0.2 micron.
The manufacture method of described a kind of aqueous two-in-one colorful covering membrane glue is as follows:
(1) start blender, under the stirring of 40-50r/min speed, the raw material in above-mentioned weight proportion is put into not successively
In rust steel container, feed intake complete；
(2) after blender continues dispersed with stirring 30min under 400-500r/min speed stirs, through 400 mesh double medium filtrations
Produce.
Wherein, the product technology performance of preparation is: fineness (scraper plate method) is less than 15 μ, viscosity (being coated with 4# cup/25 DEG C) 21
Second, pH value 7, solid content (%) 47.60.
Embodiment four
A kind of aqueous two-in-one colorful covering membrane glue, is made up of following part by weight composition: acrylicacidandesters and styrene
Co-polymer emulsion 86. 60%, aqueous phthalocyanine class green organic slurry (solid content 58%) 12.00%, polyether-modified poly-organic
Siloxanes and polyether polyester modification by copolymerization polysiloxane 0.50%, aliphatic polycarboxylic acid's salt and block copolymer and organosilicon
Solution 0.30%, high shear auxiliary rheological agents (association type polyurethanes high shear auxiliary rheological agents) 0.50%, (non-silicon class disappears defoamer
Bubble foam inhibitor) 0.10%.
Wherein, acrylicacidandesters with the technical specification of cinnamic co-polymer emulsion is: anionic, solid content
(%) 46 ± 2, pH value 7-8, viscosity (being coated with 4# cup/25 DEG C) 18 seconds, Tg value-8 DEG C, particle diameter 0.2 micron.
The manufacture method of described a kind of aqueous two-in-one colorful covering membrane glue is as follows:
(1) start blender, under the stirring of 40-50r/min speed, the raw material in above-mentioned weight proportion is put into not successively
In rust steel container, feed intake complete；
(2) after blender continues dispersed with stirring 30min under 400-500r/min speed stirs, through 400 mesh double medium filtrations
Produce.
Wherein, the product technology performance of preparation is: fineness (scraper plate method) is less than 15 μ, viscosity (being coated with 4# cup/25 DEG C) 22
Second, pH value 7, solid content (%) 47.70.
Embodiment five
A kind of aqueous two-in-one colorful covering membrane glue, is made up of following part by weight composition: acrylicacidandesters and styrene
Co-polymer emulsion 88. 60%, organic blue slurry (solid content 60%) 10.00% of aqueous phthalocyanine class, polyether-modified poly-organic
Siloxanes and polyether polyester modification by copolymerization polysiloxane 0.50%, aliphatic polycarboxylic acid's salt and block copolymer and organosilicon
Solution 0.30%, high shear auxiliary rheological agents (association type polyurethanes high shear auxiliary rheological agents) 0.50%, (non-silicon class disappears defoamer
Bubble foam inhibitor) 0.10%.
Wherein, acrylicacidandesters with the technical specification of cinnamic co-polymer emulsion is: anionic, solid content
(%) 46 ± 2, pH value 7-8, viscosity (being coated with 4# cup/25 DEG C) 18 seconds, Tg value-8 DEG C, particle diameter 0.2 micron.
The manufacture method of described a kind of aqueous two-in-one colorful covering membrane glue is as follows:
(1) start blender, under the stirring of 40-50r/min speed, the raw material in above-mentioned weight proportion is put into not successively
In rust steel container, feed intake complete；
(2) after blender continues dispersed with stirring 30min under 400-500r/min speed stirs, through 400 mesh double medium filtrations
Produce.
Wherein, the product technology performance of preparation is: fineness (scraper plate method) is less than 15 μ, viscosity (being coated with 4# cup/25 DEG C) 21
Second, pH value 7, solid content (%) 47.60.
A kind of aqueous two-in-one colorful covering membrane glue of the present invention and preparation method thereof, by acrylicacidandesters with cinnamic
Co-polymer emulsion, wetting dispersing agent, high shear auxiliary rheological agents, aqueous color paste, defoamer are prepared from through mechanical dispersion, adapt to
In printing processing dry type coating technique, the lamination be used between paper and film bonds, can synchronize to replace traditional the most on the spot
Two procedures integration are reduced to one procedure and complete, have saving of labor, province by spot color printing operation and traditional dry method coating processes
Time, environmental protection, energy-saving and cost-reducing, reduce processing cost, improve the characteristics such as production efficiency；Meanwhile, the finished product after processing has cohesive force
By force, lid powder power is good, coloring good, brightness is high, without shrinkage cavity, without performance advantages such as Snow Mark cloud points.
The present invention is not limited to above-mentioned preferred forms, anyone draw under the enlightenment of the present invention other any with
Product as the present invention is same or like, within all falling within protection scope of the present invention.
Claims (5)
1. an aqueous two-in-one colorful covering membrane glue, it is characterised in that: it is made up of following part by weight composition: acrylicacidandesters
With cinnamic co-polymer emulsion 93.70%, the aqueous carbon black color slurry 5.00% of solid content 50%, aliphatic polycarboxylic acid's salt and
Block copolymer and organic silicon solution 0.70%, association type polyurethanes high shear auxiliary rheological agents 0.50%, non-silicon class froth breaking presses down
Infusion 0.10 %；
Described acrylicacidandesters and cinnamic co-polymer emulsion are anionic, and pH value is 7～8, solid content 46% ±
2%, viscosity is 18 seconds/25 DEG C, is coated with 4# cup, and Tg value is-8 DEG C, particle diameter 0.2 micron；
The manufacture method of this aqueous two-in-one colorful covering membrane glue is:
(1) start blender, under the stirring of 40-50r/min speed, the raw material in above-mentioned weight proportion is put into rustless steel successively
In container, feed intake complete；
(2), after blender continues dispersed with stirring 30min under 400-500r/min speed stirs, produce through 400 mesh double medium filtrations.
2. an aqueous two-in-one colorful covering membrane glue, it is characterised in that: it is made up of following part by weight composition: acrylicacidandesters
With cinnamic co-polymer emulsion 86. 60%, the organic red slurry of aqueous azo 12.00% of solid content 55%, polyethers changes
Property polysiloxane and polyether polyester modification by copolymerization polysiloxane 0.80%, association type polyurethanes high shear rheology helps
Agent 0.50%, non-silicon class froth breaking foam inhibitor 0.10%；
Described acrylicacidandesters and cinnamic co-polymer emulsion are anionic, and pH value is 7～8, solid content 46% ±
2%, viscosity is 18 seconds/25 DEG C, is coated with 4# cup, and Tg value is-8 DEG C, particle diameter 0.2 micron；
The manufacture method of this aqueous two-in-one colorful covering membrane glue is:
(1) start blender, under the stirring of 40-50r/min speed, the raw material in above-mentioned weight proportion is put into rustless steel successively
In container, feed intake complete；
(2), after blender continues dispersed with stirring 30min under 400-500r/min speed stirs, produce through 400 mesh double medium filtrations.
3. an aqueous two-in-one colorful covering membrane glue, it is characterised in that: it is made up of following part by weight composition: acrylicacidandesters
With cinnamic co-polymer emulsion 82. 60%, the aqueous azo organic yellow mill base 16.00% of solid content 55%, polyethers changes
Property polysiloxane and polyether polyester modification by copolymerization polysiloxane 0.40%, aliphatic polycarboxylic acid's salt and block copolymer
With organic silicon solution 0.40%, association type polyurethanes high shear auxiliary rheological agents 0.50%, non-silicon class froth breaking foam inhibitor 0.10%；
Described acrylicacidandesters and cinnamic co-polymer emulsion are anionic, and pH value is 7～8, solid content 46% ±
2%, viscosity is 18 seconds/25 DEG C, is coated with 4# cup, and Tg value is-8 DEG C, particle diameter 0.2 micron；
The manufacture method of this aqueous two-in-one colorful covering membrane glue is:
(1) start blender, under the stirring of 40-50r/min speed, the raw material in above-mentioned weight proportion is put into rustless steel successively
In container, feed intake complete；
(2), after blender continues dispersed with stirring 30min under 400-500r/min speed stirs, produce through 400 mesh double medium filtrations.
4. an aqueous two-in-one colorful covering membrane glue, it is characterised in that: it is made up of following part by weight composition: acrylicacidandesters
With cinnamic co-polymer emulsion 86. 60%, the aqueous phthalocyanine class green organic slurry 12.00% of solid content 58%, polyethers changes
Property polysiloxane and polyether polyester modification by copolymerization polysiloxane 0.50%, aliphatic polycarboxylic acid's salt and block copolymer
With organic silicon solution 0.30%, association type polyurethanes high shear auxiliary rheological agents 0.50%, non-silicon class froth breaking foam inhibitor 0.10%；
Described acrylicacidandesters and cinnamic co-polymer emulsion are anionic, and pH value is 7～8, solid content 46% ±
2%, viscosity is 18 seconds/25 DEG C, is coated with 4# cup, and Tg value is-8 DEG C, particle diameter 0.2 micron；
The manufacture method of this aqueous two-in-one colorful covering membrane glue is:
(1) start blender, under the stirring of 40-50r/min speed, the raw material in above-mentioned weight proportion is put into rustless steel successively
In container, feed intake complete；
(2), after blender continues dispersed with stirring 30min under 400-500r/min speed stirs, produce through 400 mesh double medium filtrations.
5. an aqueous two-in-one colorful covering membrane glue, it is characterised in that: it is made up of following part by weight composition: acrylicacidandesters
With cinnamic co-polymer emulsion 88. 60%, the organic blue slurry 10.00% of aqueous phthalocyanine class of solid content 60%, polyethers changes
Property polysiloxane and polyether polyester modification by copolymerization polysiloxane 0.50%, aliphatic polycarboxylic acid's salt and block copolymer
With organic silicon solution 0.30%, association type polyurethanes high shear auxiliary rheological agents 0.50%, non-silicon class froth breaking foam inhibitor 0.10%；
Described acrylicacidandesters and cinnamic co-polymer emulsion are anionic, and pH value is 7～8, solid content 46% ±
2%, viscosity is 18 seconds/25 DEG C, is coated with 4# cup, and Tg value is-8 DEG C, particle diameter 0.2 micron；
The manufacture method of this aqueous two-in-one colorful covering membrane glue is:
(1) start blender, under the stirring of 40-50r/min speed, the raw material in above-mentioned weight proportion is put into rustless steel successively
In container, feed intake complete；
(2), after blender continues dispersed with stirring 30min under 400-500r/min speed stirs, produce through 400 mesh double medium filtrations.
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| CN201310119062.XA CN104099041B (en) | 2013-04-08 | 2013-04-08 | A kind of aqueous two-in-one colorful covering membrane glue and preparation method thereof |
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| CN104449487B (en) * | 2014-12-25 | 2016-05-11 | 上海奇想青晨新材料科技股份有限公司 | A kind of colored multiple film glue and preparation method thereof |
| CN105820788A (en) * | 2015-01-04 | 2016-08-03 | 辽宁天麒科技有限公司 | Colored glue |
| CN105820789A (en) * | 2015-01-04 | 2016-08-03 | 辽宁天麒科技有限公司 | Preparation method of glue |
| CN112172366A (en) * | 2020-09-30 | 2021-01-05 | 襄阳和顺发彩色印刷有限公司 | Printing process of green environment-friendly color box |
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| CN101676349A (en) * | 2008-09-19 | 2010-03-24 | 上海奇想青晨化工科技股份有限公司 | Water soluble cardboard composite adhesive and preparation method thereof |
| CN102140320B (en) * | 2010-08-19 | 2012-12-12 | 北京高盟新材料股份有限公司 | Water-based polyacrylic emulsion laminating adhesive and preparation method thereof |
| CN102134463B (en) * | 2010-08-19 | 2012-07-25 | 北京高盟新材料股份有限公司 | Water-based dry-type complex film adhesive and preparation method thereof |
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