CN110484202B - Energy-saving waterproof decorative adhesive plate and preparation method and application thereof - Google Patents
Energy-saving waterproof decorative adhesive plate and preparation method and application thereof Download PDFInfo
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- CN110484202B CN110484202B CN201910786607.XA CN201910786607A CN110484202B CN 110484202 B CN110484202 B CN 110484202B CN 201910786607 A CN201910786607 A CN 201910786607A CN 110484202 B CN110484202 B CN 110484202B
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- 239000000853 adhesive Substances 0.000 title claims abstract description 46
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 46
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 229920005989 resin Polymers 0.000 claims abstract description 68
- 239000011347 resin Substances 0.000 claims abstract description 68
- 239000000843 powder Substances 0.000 claims abstract description 52
- 239000000463 material Substances 0.000 claims abstract description 32
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 30
- 239000010426 asphalt Substances 0.000 claims abstract description 29
- 239000010692 aromatic oil Substances 0.000 claims abstract description 28
- 229920005549 butyl rubber Polymers 0.000 claims abstract description 24
- 229920001971 elastomer Polymers 0.000 claims abstract description 22
- 239000005060 rubber Substances 0.000 claims abstract description 22
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 15
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims abstract description 13
- 239000004810 polytetrafluoroethylene Substances 0.000 claims abstract description 13
- 239000011248 coating agent Substances 0.000 claims abstract description 10
- 238000000576 coating method Methods 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims description 58
- 238000003756 stirring Methods 0.000 claims description 28
- 238000001816 cooling Methods 0.000 claims description 16
- 238000010438 heat treatment Methods 0.000 claims description 16
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 10
- 229910052791 calcium Inorganic materials 0.000 claims description 10
- 239000011575 calcium Substances 0.000 claims description 10
- 239000003208 petroleum Substances 0.000 claims description 10
- 150000003505 terpenes Chemical class 0.000 claims description 10
- 235000007586 terpenes Nutrition 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 8
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 claims description 4
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 4
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 4
- 238000010276 construction Methods 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 4
- 229920006272 aromatic hydrocarbon resin Polymers 0.000 claims description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 2
- 239000002994 raw material Substances 0.000 abstract description 7
- 239000011241 protective layer Substances 0.000 abstract description 3
- 230000032683 aging Effects 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract 1
- 239000002861 polymer material Substances 0.000 description 7
- 238000005303 weighing Methods 0.000 description 6
- 238000005034 decoration Methods 0.000 description 3
- 239000010410 layer Substances 0.000 description 2
- 229920002401 polyacrylamide Polymers 0.000 description 2
- 241000276489 Merlangius merlangus Species 0.000 description 1
- 230000003679 aging effect Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- -1 polytetrafluoroethylene Polymers 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J195/00—Adhesives based on bituminous materials, e.g. asphalt, tar, pitch
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04D—ROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
- E04D13/00—Special arrangements or devices in connection with roof coverings; Protection against birds; Roof drainage ; Sky-lights
- E04D13/16—Insulating devices or arrangements in so far as the roof covering is concerned, e.g. characterised by the material or composition of the roof insulating material or its integration in the roof structure
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04D—ROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
- E04D3/00—Roof covering by making use of flat or curved slabs or stiff sheets
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/0885—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements specially adapted for being adhesively fixed to the wall; Fastening means therefor; Fixing by means of plastics materials hardening after application
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F2290/00—Specially adapted covering, lining or flooring elements not otherwise provided for
- E04F2290/04—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire
Landscapes
- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Chemical & Material Sciences (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention belongs to the technical field of waterproof decorative materials, and particularly provides an energy-saving waterproof decorative adhesive plate, a preparation method and application thereof, wherein the waterproof decorative adhesive plate is composed of the following structures: covering a PTFE sheet, coating a special high-temperature-resistant bonding material, and isolating a protective layer; the special bonding material is composed of the following raw materials: 30-40 parts of asphalt, 10-20 parts of aromatic oil, 10-15 parts of tackifying resin, 5-8 parts of SIS, 5-10 parts of modified rubber, 2-3 parts of KT resin, 3-7 parts of butyl rubber powder and 15-20 parts of heavy calcium carbonate powder. The performance of the bonding material of the energy-saving waterproof decorative adhesive plate provided by the invention meets the standard requirement of GB23441-2009 waterproof coiled materials, and the PTFE coating has good ageing resistance, so that the energy-saving waterproof decorative adhesive plate not only plays a role in water resistance, but also has an attractive decorative effect.
Description
Technical Field
The invention belongs to the technical field of waterproof decorative materials, and particularly provides an energy-saving waterproof decorative adhesive plate, and a preparation method and application thereof.
Background
In the field of waterproofing, the construction of roofs, vertical walls and kitchens and toilets is the most applied, the requirements on waterproof products are relatively low, and common products can meet the requirements, particularly roof and vertical walls, after waterproof is finished, meanwhile, a protective layer or a decorative layer is required to be arranged to protect the waterproof layer and beautify the appearance, so that manpower, material resources and funds are wasted, and therefore, the energy-saving waterproof decorative adhesive plate is developed, the bonding material has excellent bonding performance, is firmly bonded with a cement base surface, has high temperature resistance up to 110 ℃, has obvious waterproof and aging effects, the coated PTFE is a non-degradable material and has a self-cleaning function, the waterproof material can be used for leakage, can be made into different colors for decoration, saves resources, prolongs the service life of the waterproof material, and is a real energy-saving waterproof and decorative material.
Disclosure of Invention
The invention aims to provide an energy-saving waterproof decorative adhesive plate, a preparation method and application thereof, which aim to solve the problem that resources are wasted by making a protective layer after waterproof construction and solve the problems that the traditional waterproof product has poor heat resistance and is not suitable for external leakage use due to quick aging.
The invention is realized in such a way, and on one hand, the invention provides an energy-saving waterproof decorative adhesive plate which comprises an adhesive material, wherein the adhesive material comprises the following components in parts by weight: 30-40 parts of asphalt, 10-20 parts of aromatic oil, 10-15 parts of tackifying resin, 5-8 parts of SIS, 5-10 parts of modified rubber, 2-3 parts of KT resin, 3-7 parts of butyl rubber powder and 15-20 parts of heavy calcium carbonate powder.
Further, the asphalt is road petroleum asphalt with the model number of 90 or 70; the aromatic oil is transparent aromatic oil with pour point of-30 ℃ and flash point of more than 200 ℃.
Further, the tackifying resin is one or more of C9 resin, terpene resin, rosin resin and coumarone resin; the SIS melt index is 0.1-0.2.
Further, the butyl rubber powder is commercially available butyl rubber powder with the content of over 88 percent and the fineness of 160-200 meshes; the over-heavy calcium powder is white powder with the fineness of more than 200 meshes.
Further, the modified rubber is styrene butadiene rubber, and the KT resin is maleic anhydride grafted PE, which are all commercially available products.
On the other hand, the invention provides a preparation method of the energy-saving waterproof decorative adhesive plate, which comprises the following steps:
1) stirring and heating asphalt and aromatic oil to 155-165 ℃;
2) adding the SIS into the mixture obtained in the step 1) while stirring, heating to 170 ℃, and keeping the temperature until the SIS is completely melted;
3) adding the modified rubber, the butyl rubber powder and the KT resin into the mixture obtained in the step 2) in proportion while stirring until the modified rubber, the butyl rubber powder and the KT resin are uniformly dispersed;
4) cooling the mixture obtained in the step 3) to 150-160 ℃, and adding the tackifying resin and the polyacrylamide into the mixture obtained in the step 3) while stirring according to a certain proportion until the tackifying resin and the polyacrylamide are completely melted and uniformly dispersed;
5) cooling the mixture obtained in the step 4) to 130-140 ℃, and adding the heavy calcium powder into the mixture obtained in the step 4) while stirring according to a proportion until the mixture is uniformly dispersed;
6) keeping the temperature of the mixture prepared in the step 5) at 130-140 ℃ to form a bonding material with proper thickness.
7) Coating the bonding material prepared in the step 6) on a PTFE polymer sheet by production equipment to produce the energy-saving waterproof decorative bonding boards with different specifications.
The adhesive plate is used for waterproof decoration engineering of decorating roofs or wall erecting places.
The application method of the adhesive plate is that the overlapping edges are reserved for bonding in the cold bonding construction of the roof or the vertical wall, and the integral appearance is kept as a whole.
Compared with the prior art, the invention has the advantages that: the waterproof material meets various performance indexes required by GB23441-2009 and JC/T1075-2008 standards, simultaneously improves the problems of low heat resistance and unsuitability for leakage use of the traditional waterproof material, and is very suitable for waterproof decoration engineering of roofs or vertical wall places.
Detailed Description
The present invention is further illustrated by the following specific embodiments, but is not intended to limit the scope of the present invention. The present invention will be described in detail with reference to examples.
The asphalt, aromatic oil, tackifying resin, SIS, KT resin, modified rubber, butyl rubber powder and heavy calcium powder of the present invention are prepared by conventional techniques known to those skilled in the art, or are obtained by direct purchase. In the embodiment of the invention, PTFE (polytetrafluoroethylene) and the like are from commercial high polymer materials, and other various reagents mentioned in the implementation of the invention are from commercial manufacturers meeting index requirements.
Examples 1,
The embodiment provides an energy-saving waterproof decorative adhesive plate, which comprises the following raw materials in parts by weight: 90-36 parts of road petroleum asphalt, 15 parts of aromatic oil, 12 parts of tackifying resin, 7 parts of SIS, 8 parts of modified rubber, 5 parts of butyl rubber powder, 2 parts of KT resin and 15 parts of heavy calcium powder. The tackifying resin in this example is a terpene resin.
Weighing 36 parts of No. 90 asphalt and 15 parts of aromatic oil, stirring and heating to 160 ℃; in the embodiment, 36kg of No. 90 asphalt is added, and 15kg of aromatic oil is added;
adding 7 parts of SIS into the mixture, heating to 170 ℃, and stirring at constant temperature until the SIS is completely melted for 90 min;
adding 8 parts of modified rubber, 5 parts of butyl rubber powder and 2 parts of KT resin into the mixture stirred at the constant temperature, and uniformly dispersing for 60 min;
cooling the mixture to 155 ℃, adding 12 parts of tackifying resin until the terpene resin is melted and dispersed uniformly in the mixture for 30 min;
cooling the mixture to 135 ℃, adding 15 parts of heavy calcium carbonate powder, and stirring until the heavy calcium carbonate powder is uniformly dispersed in the mixture for 60 min;
and (3) keeping the prepared mixture at the constant temperature of 130 ℃ to form a bonding material with proper thickness, and coating the bonding material on the PTFE high polymer material by production equipment to produce the energy-saving waterproof decorative adhesive plate.
The energy-saving waterproof decorative adhesive plate provided by the example 1 is applied to the field of waterproof decorative engineering of roofs or other wall erecting places, and waterproof decorative adhesive plates with different thicknesses, lengths, widths and other specifications can be produced according to actual needs.
Examples 2,
The embodiment provides an energy-saving waterproof decorative adhesive plate, which comprises the following raw materials in parts by weight: the asphalt comprises, by weight, 70 parts of road petroleum asphalt, 15 parts of aromatic oil, 14 parts of tackifying resin, 8 parts of SIS, 6 parts of modified rubber, 5 parts of butyl rubber powder, 3 parts of KT resin and 15 parts of heavy calcium powder. The tackifying resin in this example is a C9 petroleum resin.
Weighing 34 parts of No. 70 asphalt and 15 parts of aromatic oil, stirring and heating to 165 ℃; in the embodiment, 34kg of No. 70 asphalt is added, and 15kg of aromatic oil is added;
adding 8 parts of SIS into the mixture, heating to 170 ℃, and stirring at constant temperature until the SIS is completely melted for 90 min;
adding 6 parts of modified rubber, 5 parts of butyl rubber powder and 3 parts of KT resin into the mixture stirred at the constant temperature, and uniformly dispersing for 60 min;
cooling the mixture to 160 ℃, and adding 14 parts of tackifying resin until the C9 petroleum resin is melted and dispersed uniformly in the mixture for 30 min;
cooling the mixture to 140 ℃, adding 15 parts of heavy calcium carbonate powder, and stirring until the heavy calcium carbonate powder is uniformly dispersed in the mixture for 60 min;
and (3) keeping the temperature of the prepared mixture at 135 ℃ to form a bonding material with proper thickness, and coating the bonding material on a PTFE high polymer material by production equipment to produce the energy-saving waterproof decorative adhesive plate.
The energy-saving waterproof decorative adhesive plate provided by the example 2 is applied to the field of waterproof decorative engineering of roofs or other vertical wall places, and waterproof decorative adhesive plates with different thicknesses, lengths, widths and other specifications can be produced according to actual needs.
Examples 3,
The energy-saving waterproof decorative adhesive board is characterized in that the adhesive comprises the following raw materials in parts by weight: 32 parts of road petroleum asphalt No. 70, 12 parts of aromatic oil, 11 parts of tackifying resin, 6 parts of SIS, 9 parts of modified rubber, 7 parts of butyl rubber powder, 3 parts of KT resin and 20 parts of heavy calcium powder. The tackifying resin in this example is a rosin resin.
Weighing 32 parts of No. 70 asphalt and 12 parts of aromatic oil, stirring and heating to 155 ℃; in the embodiment, 32kg of No. 70 asphalt is added, and 12kg of aromatic oil is added;
adding 6 parts of SIS into the mixture, heating to 170 ℃, and stirring at constant temperature until the SIS is completely melted for 90 min;
adding 9 parts of modified rubber, 7 parts of butyl rubber powder and 3 parts of KT resin into the mixture stirred at the constant temperature, and uniformly dispersing for 60 min;
cooling the mixture to 150 ℃, and adding 11 parts of tackifying resin until the rosin resin is melted and dispersed uniformly in the mixture for 30 min;
cooling the mixture to 130 ℃, adding 20 parts of heavy calcium carbonate powder, and stirring until the heavy calcium carbonate powder is uniformly dispersed in the mixture for 60 min;
and (3) keeping the temperature of the prepared mixture at 135 ℃ to form a bonding material with proper thickness, and coating the bonding material on a PTFE high polymer material by production equipment to produce the energy-saving waterproof decorative adhesive plate.
The energy-saving waterproof decorative adhesive plate provided by the example 3 is applied to the field of waterproof decorative engineering of roofs or other wall erecting places, and waterproof decorative adhesive plates with different thicknesses, lengths, widths and other specifications can be produced according to actual needs.
Examples 4,
The invention provides an energy-saving waterproof decorative adhesive board, which comprises the following raw materials in parts by weight: no. 90 road petroleum asphalt 38 parts, aromatic oil 18 parts, tackifying resin 15 parts, SIS 5 parts, modified rubber 6 parts, butyl rubber powder 5 parts, KT resin 2 parts and coarse whiting powder 17 parts. The tackifying resin in this example is a terpene resin.
Weighing 38 parts of No. 70 asphalt and 18 parts of aromatic oil, stirring and heating to 165 ℃; in the embodiment, 38kg of No. 70 asphalt is added, and 18kg of aromatic oil is added;
adding 5 parts of SIS into the mixture, heating to 170 ℃, and stirring at constant temperature until the SIS is completely melted for 90 min;
adding 6 parts of modified rubber, 5 parts of butyl rubber powder and 2 parts of KT resin into the mixture stirred at the constant temperature, and uniformly dispersing for 60 min;
cooling the mixture to 160 ℃, and adding 15 parts of tackifying resin until the terpene resin is melted and uniformly dispersed in the mixture for 30 min;
cooling the mixture to 140 ℃, adding 17 parts of heavy calcium carbonate powder, and stirring until the heavy calcium carbonate powder is uniformly dispersed in the mixture for 60 min;
and (3) keeping the prepared mixture at the constant temperature of 140 ℃ to form a bonding material with proper thickness, and coating the bonding material on the PTFE high polymer material by production equipment to produce the energy-saving waterproof decorative adhesive plate.
The energy-saving waterproof decorative adhesive plate provided by the example 4 is applied to the field of waterproof decorative engineering of roofs or other vertical wall places, and waterproof decorative adhesive plates with different thicknesses, lengths, widths and other specifications can be produced according to actual needs.
Examples 5,
The invention provides an energy-saving waterproof decorative adhesive board, which comprises the following raw materials in parts by weight: 30 parts of road petroleum asphalt No. 90, 20 parts of aromatic oil, 14 parts of tackifying resin, 6 parts of SIS, 10 parts of modified rubber, 2.5 parts of KT resin, 5 parts of butyl rubber powder and 18 parts of heavy calcium powder. The tackifying resin in this example is a terpene resin.
The preparation method comprises the following steps:
weighing 30 parts of No. 70 asphalt and 20 parts of aromatic oil, stirring and heating to 165 ℃; in the embodiment, 30kg of No. 70 asphalt is added, and 20kg of aromatic oil is added;
adding 6 parts of SIS into the mixture, heating to 170 ℃, and stirring at constant temperature until the SIS is completely melted for 90 min;
adding 10 parts of modified rubber, 5 parts of butyl rubber powder and 2.5 parts of KT resin into the mixture stirred at the constant temperature, and uniformly dispersing for 60 min;
cooling the mixture to 160 ℃, and adding 14 parts of tackifying resin until the terpene resin is melted and uniformly dispersed in the mixture for 30 min;
cooling the mixture to 140 ℃, adding 18 parts of heavy calcium carbonate powder, and stirring until the heavy calcium carbonate powder is uniformly dispersed in the mixture for 60 min;
and (3) keeping the prepared mixture at the constant temperature of 140 ℃ to form a bonding material with proper thickness, and coating the bonding material on the PTFE high polymer material by production equipment to produce the energy-saving waterproof decorative adhesive plate.
The energy-saving waterproof decorative adhesive plate provided by the example 5 is applied to the field of waterproof decorative engineering of roofs or other wall erecting places, and waterproof decorative adhesive plates with different thicknesses, lengths, widths and other specifications can be produced according to actual needs.
Examples 6,
The embodiment provides an energy-saving waterproof decorative adhesive plate, which comprises the following raw materials in parts by weight: no. 90 and 40 parts of road petroleum asphalt, 10 parts of aromatic oil, 10 parts of tackifying resin, 7 parts of SIS, 5 parts of modified rubber, 2 parts of KT resin, 3 parts of butyl rubber powder and 20 parts of heavy calcium powder. The tackifying resin in this example is a terpene resin.
The preparation method comprises the following steps:
weighing 40 parts of No. 70 asphalt and 10 parts of aromatic oil, stirring and heating to 165 ℃; in the embodiment, 40kg of No. 70 asphalt is added, and 10kg of aromatic oil is added;
adding 7 parts of SIS into the mixture, heating to 170 ℃, and stirring at constant temperature until the SIS is completely melted for 90 min;
adding 5 parts of modified rubber, 3 parts of butyl rubber powder and 2 parts of KT resin into the mixture stirred at the constant temperature, and uniformly dispersing for 60 min;
cooling the mixture to 160 ℃, and adding 10 parts of tackifying resin until the terpene resin is melted and uniformly dispersed in the mixture for about 30 min;
cooling the mixture to 140 ℃, adding 20 parts of heavy calcium carbonate powder, and stirring until the heavy calcium carbonate powder is uniformly dispersed in the mixture for about 60 min;
and (3) keeping the prepared mixture at the constant temperature of 140 ℃ to form a bonding material with proper thickness, and coating the bonding material on the PTFE high polymer material by production equipment to produce the energy-saving waterproof decorative adhesive plate.
The energy-saving waterproof decorative adhesive plate provided by the example 6 is applied to the field of waterproof decorative engineering of roofs or other vertical wall places, and waterproof decorative adhesive plates with different thicknesses, lengths, widths and other specifications can be produced according to actual needs.
The main detection data of the energy-saving waterproof decorative adhesive plate prepared by the embodiments are shown in table 1:
TABLE 1
| Serial number | Item | Requirement index | Detecting the index |
| 1 | Heat resistance | No sliding at 70 ℃ for 2h | No sliding at 110 ℃ for 2h |
| 2 | Low temperature flexibility | No crack at-20 ℃ for 1h | No crack at-22 ℃ for 1h |
| 3 | Is impervious to water | 0.3MPa for 30min | 0.5MPa for 120min |
| 4 | Tension force | ≥800N/50mm | 1100N/50mm |
| 5 | Peel strength of joint | ≥1.5N/mm | 4.0N/mm |
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents, improvements and the like that fall within the spirit and principle of the present invention are intended to be included therein.
Claims (5)
1. The preparation method of the energy-saving waterproof decorative adhesive plate comprises the following components in parts by weight: 30-40 parts of asphalt, 10-20 parts of aromatic oil, 10-15 parts of tackifying resin, 5-8 parts of SIS, 5-10 parts of modified rubber, 2-3 parts of KT resin, 3-7 parts of butyl rubber powder and 15-20 parts of heavy calcium carbonate powder; the butyl rubber powder is commercially available butyl rubber powder with the content of more than 88% and the fineness of 160-200 meshes; the heavy calcium powder is white powder with the fineness of more than 200 meshes; the modified rubber is styrene butadiene rubber, and the KT resin is maleic anhydride grafted PE; wherein the preparation method comprises the following steps: 1) Stirring and heating the asphalt and the aromatic oil to 155-165 ℃ according to the weight part ratio; 2) Adding the SIS into the mixture obtained in the step 1) while stirring, heating to 170 ℃, and keeping the temperature until the SIS is completely melted; 3) Adding the modified rubber, the butyl rubber powder and the KT resin into the mixture obtained in the step 2) in proportion while stirring until the modified rubber, the butyl rubber powder and the KT resin are uniformly dispersed; 4) Cooling the mixture obtained in the step 3) to 150-160 ℃, adding tackifying resin into the mixture obtained in the step 3) while stirring according to a proportion until the tackifying resin is completely melted and uniformly dispersed; 5) Cooling the mixture obtained in the step 4) to 130-140 ℃, and adding the heavy calcium powder into the mixture obtained in the step 4) while stirring according to a proportion until the mixture is uniformly dispersed; 6) Keeping the temperature of the mixture prepared in the step 5) at 130-140 ℃ to form a bonding material with proper thickness, and coating the bonding material on PTFE polymer sheets by production equipment to produce energy-saving waterproof decorative bonding plates with different specifications.
2. The method for preparing an energy-saving waterproof decorative adhesive plate according to claim 1, wherein the asphalt is road petroleum asphalt with a model number of 90 or 70; the aromatic oil is transparent aromatic oil with pour point of-30 ℃ and flash point of more than 200 ℃.
3. The method for preparing the energy-saving waterproof decorative adhesive plate according to claim 1, wherein the tackifying resin is one or more of C9 resin, terpene resin, rosin resin and coumarone resin; the SIS melt index is 0.1-0.2.
4. Use of the energy-saving waterproof decorative adhesive sheet according to claim 1, for waterproof decorative engineering for decorating roofing or wall-erecting sites.
5. The method for applying the energy-saving waterproof decorative adhesive plate as claimed in claim 1, wherein the overlapping edges are reserved for adhesion in cold adhesion construction of a roof or a vertical wall, so as to keep the integral appearance.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910786607.XA CN110484202B (en) | 2019-08-23 | 2019-08-23 | Energy-saving waterproof decorative adhesive plate and preparation method and application thereof |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2003127285A (en) * | 2001-10-19 | 2003-05-08 | Nisshin Steel Co Ltd | Coated material improved in slidability of material surface and cute of automatic vending machine using the same |
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| CN102408854B (en) * | 2011-08-26 | 2013-07-03 | 江苏达胜热缩材料有限公司 | High-temperature mastic cement for corrosion protection and preparation method thereof |
| CN105238292A (en) * | 2014-07-12 | 2016-01-13 | 卢桂才 | Reactive type modified emulsified asphalt and rubber waterproof sealant, and preparation method therefor |
| CN105298029A (en) * | 2015-09-29 | 2016-02-03 | 唐山德生防水股份有限公司 | Self-adhesive waterproof roll material for color steel roofs of buildings and method for manufacturing self-adhesive waterproof roll material |
| CN109294469B (en) * | 2018-09-27 | 2021-06-22 | 天津市禹红建筑防水材料有限公司 | Exposed flame-retardant strong cross-membrane self-adhesive waterproof roll and preparation method thereof |
| CN109401346A (en) * | 2018-10-24 | 2019-03-01 | 辽宁女娲防水建材科技集团有限公司 | A kind of cold roofing reflection and heat insulation adhesive waterproof coil and preparation method, application |
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2003127285A (en) * | 2001-10-19 | 2003-05-08 | Nisshin Steel Co Ltd | Coated material improved in slidability of material surface and cute of automatic vending machine using the same |
Non-Patent Citations (2)
| Title |
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| "Superhydrophobic Coatings on Asphalt Concrete Surfaces Toward Smart Solutions for Winter Pavement Maintenance";Ali Arabzadeh等;《TRANSPORTATION RESEARCH RECORD 》;20161231;第2551卷(第1期);第10-17页 * |
| 氯化聚乙烯-橡胶共混防水卷材用橡塑粉的改性及应用研究;杨旭等;《中国建筑防水》;20110920(第18期);第15-18页 * |
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Denomination of invention: An energy-saving waterproof decorative adhesive board and its preparation method and application Effective date of registration: 20231124 Granted publication date: 20211026 Pledgee: Panjin science and technology Financing Guarantee Co.,Ltd. Pledgor: LIAONING INNVWA WATERPROOF BUILDING MATERIALS TECHNOLOGY GROUP CO.,LTD. Registration number: Y2023210000303 |