CN110484160A - A kind of stereo multi-colour waterproof roll and preparation method thereof with self-adhesive - Google Patents
A kind of stereo multi-colour waterproof roll and preparation method thereof with self-adhesive Download PDFInfo
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- CN110484160A CN110484160A CN201910785658.0A CN201910785658A CN110484160A CN 110484160 A CN110484160 A CN 110484160A CN 201910785658 A CN201910785658 A CN 201910785658A CN 110484160 A CN110484160 A CN 110484160A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J195/00—Adhesives based on bituminous materials, e.g. asphalt, tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/21—Paper; Textile fabrics
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
- C09J7/25—Plastics; Metallised plastics based on macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/255—Polyesters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04D—ROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
- E04D5/00—Roof covering by making use of flexible material, e.g. supplied in roll form
- E04D5/10—Roof covering by making use of flexible material, e.g. supplied in roll form by making use of compounded or laminated materials, e.g. metal foils or plastic films coated with bitumen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
- C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
- C09J2301/124—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present on both sides of the carrier, e.g. double-sided adhesive tape
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2467/00—Presence of polyester
- C09J2467/006—Presence of polyester in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2495/00—Presence of bitume
Abstract
This application involves be a kind of self-adhesion stereo multi-colour waterproof roll resistant to high temperature, it specifically provides a kind of stereo multi-colour waterproof roll with self-adhesive and preparation method and application, waterproof material is made of following raw material: 35-45 parts of pitch, 5-10 parts of aromatic naphtha, 3-5 parts of high temperature tackifier, 2-5 parts of KT resin, 3-7 parts of SBR, 8-12 parts of BR butadiene rubber, 2-5 parts of antiaging agent, 2-5 parts of ultraviolet absorbing agent, 5-9 parts of kaolin, 15-20 parts of talcum powder.The stereo multi-colour waterproof roll with self-adhesive of the application, on the basis of conventionally produced, using state-of-the-art laser printing colouring technology, the pattern of vertical coloured silk is printed upon above coiled material, three-dimensional sense is stronger, and the paint of selection is automobile specified paint vehicle, and color is more longlasting.When coiled material construction other than fixed using fixing piece, itself possess the self-adhesive of special formulation production, stronger, raising wind resistance is bonded with base.
Description
Technical field
The invention belongs to the exposed waterproof material technical fields of building roof, and it is more to specifically provide a kind of solid with self-adhesive
Color waterproof roll and preparation method.
Background technique
With the development of construction industry, it is logical that the waterproof problem of roofing perplexs always design, construction, the construction engineering quality of owner
Disease, decorative strong although existing stereo multi-colour coiled material waterproof effect is fine, various colors are colorful, can arbitrarily with exterior wall color
Collocation, easy to maintenance suitable for the roofing of various moulding, reducing engineering overall cost and maintenance cost, still coiled material needs heat
Molten construction, environmental pollution is big, and there are fire hazards.And common self-adhesive coiled material, high temperature are easy to appear at 70 DEG C for roofing
High temperature trickling phenomenon.In recent years, country increasingly supported to develop the waterproof material of environmental protection and energy saving, limited use to environment shadow
Ring biggish heat molten type coiled material.Therefore, it researchs and develops a stereo multi-colour waterproof roll with self-adhesive and has become China's waterproof
The task of top priority of materials industry.
Summary of the invention
The present invention is intended to provide a kind of stereo multi-colour waterproof roll, ageing-resistant to solve the waterproof material that exposed roofing uses
Effect is poor, and hot melt application pollutes environment and there are fire hazard, and hot melt application cannot reach the problems such as 100% full bonding.
The present invention provides a kind of stereo multi-colour waterproof roll with self-adhesive, including a kind of self-adhesive, and the self-adhesive is by weight
It measures part to count, including 35-45 parts of pitch, 5-10 parts of aromatic naphtha, 3-5 parts of high temperature tackifier, 2-5 parts of KT resin, 3-7 parts of SBR, BR
8-12 parts of butadiene rubber, 2-5 parts of antiaging agent, 2-5 parts of ultraviolet absorbing agent, 5-9 parts of kaolin, 15-20 parts of talcum powder.
Further, the pitch be bi tumenf orr oad, model No. 90 or No. 130;The aromatic naphtha is pour point -30
DEG C, the aromatic naphtha of 200 DEG C of flash-point or more of transparent or micro- Huang.
Further, the BR butadiene rubber is cis--Isosorbide-5-Nitrae-polybutadiene rubber powder, and butadiene rubber can be divided into low suitable again
Formula (cis- Isosorbide-5-Nitrae content be 35%~40%), in cis- (90% or so) and high-cis (96%~99%) three classes, BR is along fourth rubber
The low cis rubber powder that glue content is 35%~40%.The SBR is butadiene-styrene rubber powder, content 52%.
Further, the high temperature tackifier be C9 resin, the dilute resin of terpene, rosin resin it is one or more;It is described
KT resin is maleic anhydride graft copolymer resin, melt index 0.4-0.8.
Further, the antiaging agent is benzene di-isooctyl.
Further, the ultraviolet absorbing agent is toluic acid resorcinol.The kaolin is that fineness exists
Commercially available kaolin more than 1250 mesh;The talcum powder is white powder of the fineness more than 800 mesh.
On the other hand, the present invention provides a kind of method for preparing the above-mentioned stereo multi-colour waterproof roll with self-adhesive, including
Following steps:
1) according to above-mentioned weight, pitch and aromatic naphtha heating stirring are warming up to 155-165 DEG C;
2) KT resin is added to while stirring in the mixture in step 1), is warming up to 170 DEG C, constant temperature is complete to KT resin
Running down;Fusing time are as follows: 100-150min.
3) mixture obtained in step 2) is warming up to 180 DEG C, side is stirred together by BR butadiene rubber and SBR in proportion
Side is added in the obtained mixture of step 2), is uniformly dispersed to being completely melt;Fusing time are as follows: 100-150min.
4) high temperature tackifier are added in the mixture of step 3) while stirring in proportion, are warming up to 200 DEG C, constant temperature is extremely
It is completely melt;Fusing time are as follows: 90-120min.
5) kaolin and talcum powder are added in mixture made from step 4) while stirring according to a certain percentage, until point
It dissipates uniform;Mixing time are as follows: 100-120min.
6) mixture temperature made from step 5) is adjusted to 170-180 DEG C, sequentially adds antiaging agent, ultraviolet radiation absorption
Agent is added to while stirring in the mixture in step 5);Mixing time are as follows: 50-70min.
7) by mixture constant temperature made from step 6) at 170-180 DEG C, dilute consistency self-adhesive suitably resistant to high temperature is formed,
It is two-sided coated with self-adhesive using enhanced polyester felt as carcass using enhanced polyester felt as carcass again by production line, then with pure
Smalt is facing material, and pattern is printed upon on coiled material using 3D laser printing colouring technology, produces different size, different figures
The stereo multi-colour waterproof roll with self-adhesive of case.Above-mentioned waterproof roll is used for the roofing for industrial, civilian, military building
Waterproof and decoration are particularly suitable for the water-proof decorative of the pitched roofs such as communal facility, all kinds of villas.
The method of administration of above-mentioned waterproof roll is to construct in roofing self-adhesion, reserves overlap edge, and long side and short side overlap joint are
The form of glue and gluing knot.
Compared with the prior art, the advantages of the present invention are as follows: meet the peel strength requirement of GB23441-2009, while resistance to
Hot to have reached 120 DEG C or more, using in pitched roof, will not trickle sliding because of high temperature, and heat ageing significant effect is cold to apply
Work, the waterproofing work for being highly suitable for the exposed place of roofing use.
Specific embodiment
Below with reference to specific embodiment, explanation is further explained to the present invention, but is not limited to this
The protection scope of invention.Below with reference to embodiment, the present invention will be described in detail.
Embodiment 1
The present invention provides a kind of stereo multi-colour waterproof roll with self-adhesive, including a kind of self-adhesive, and the self-adhesive is by weight
Number meter is measured, is made of following raw material: No. 90 38 parts of bi tumenf orr oad, 6 parts of aromatic naphtha, 4 parts of high temperature tackifier, KT resin 3
Part, 5 parts of SBR, 9 parts of butadiene rubber, 3 parts of antiaging agent, 3 parts of ultraviolet absorbing agent, 6 parts of kaolin, 16 parts of talcum powder.This reality
Example high temperature tackifier are C9 hydrotreated petroleum resin.
38 parts of No. 90 pitches and 6 parts of aromatic naphtha are weighed, are heated with stirring to 160 DEG C;No. 90 pitches are added in the present embodiment
Quality 38kg, the quality of aromatic naphtha are 6kg;
3 parts of KT resin are added in above-mentioned mixture, is heated up 170 DEG C, constant temperature is stirred to KT resin and is completely melt, the time
100min;
9 parts of 5 parts of SBR and BR butadiene rubber powder are added in above-mentioned mixture, are warming up to 180 DEG C, constant temperature is to complete
Fusing, time 150min;
C9 hydrotreated petroleum resin is added in above-mentioned mixture for 4 parts, until the fusing dispersion of C9 hydrotreated petroleum resin is equal
It is even in mixture, time 90min;
6 parts and 16 parts of talcum powder of kaolin are added in above-mentioned mixture, is dispersed in kaolin and talcum powder mixed
It closes in material, time 100min;
Mixture temperature obtained is adjusted to 170-180 DEG C, sequentially adds 3 parts of antiaging agent, ultraviolet absorbing agent 3
Part, it is added in above-mentioned mixture while stirring, time 50min;
By mixture constant temperature obtained above at 170-180 DEG C, dilute consistency self-adhesive suitably resistant to high temperature is formed, then lead to
Production line is crossed, it is two-sided coated with self-adhesive using enhanced polyester felt as carcass using enhanced polyester felt as carcass, then with pure color sand
For facing material, pattern is printed upon on coiled material using 3D laser printing colouring technology, produces different size, different pattern
Stereo multi-colour waterproof roll with self-adhesive.
Embodiment 2
The present invention provides a kind of stereo multi-colour waterproof roll with self-adhesive, self-adhesive according to parts by weight, by following
Raw material composition: No. 90 45 parts of bi tumenf orr oad, 6 parts of aromatic naphtha, 4 parts of high temperature tackifier, 3 parts of KT resin, 5 parts of SBR, along fourth
9 parts of rubber, 3 parts of antiaging agent, 3 parts of ultraviolet absorbing agent, 6 parts of kaolin, 18 parts of talcum powder.This example high temperature tackifier are
The dilute resin of terpene.
The preparation method is as follows:
45 parts of No. 90 pitches and 6 parts of aromatic naphtha are weighed, are heated with stirring to 160 DEG C;No. 90 pitches are added in the present embodiment
Quality 45kg, the quality of aromatic naphtha are 6kg;
3 parts of KT resin are added in above-mentioned mixture, is heated up 170 DEG C, constant temperature is stirred to KT resin and is completely melt, the time
100min;
9 parts of 5 parts of SBR and BR butadiene rubber powder are added in above-mentioned mixture, are warming up to 180 DEG C, constant temperature is to complete
Fusing, time 150min;
The dilute resin of terpene is added in above-mentioned mixture for 4 parts, until the dilute resin fusing of terpene is uniformly dispersed in mixture,
Time 90min;
6 parts and 18 parts of talcum powder of kaolin are added in above-mentioned mixture, is dispersed in kaolin and talcum powder mixed
It closes in material, time 100min;
Mixture temperature obtained is adjusted to 170-180 DEG C, sequentially adds 3 parts of antiaging agent, ultraviolet absorbing agent 3
Part, it is added in above-mentioned mixture while stirring, time 50min;
By mixture constant temperature obtained above at 180 DEG C, dilute consistency self-adhesive suitably resistant to high temperature is formed, then pass through life
Producing line, it is two-sided coated with self-adhesive using enhanced polyester felt as carcass using enhanced polyester felt as carcass, then with pure color sand be cover
Pattern is printed upon on coiled material by plane materiel material using 3D laser printing colouring technology, produce different size, different pattern band from
The stereo multi-colour waterproof roll of viscose glue.
Embodiment 3
The present invention provides a kind of stereo multi-colour waterproof roll with self-adhesive, self-adhesive according to parts by weight, by following
Raw material composition: No. 90 45 parts of bi tumenf orr oad, 6 parts of aromatic naphtha, 5 parts of high temperature tackifier, 3 parts of KT resin, 5 parts of SBR, along fourth
9 parts of rubber, 3 parts of antiaging agent, 3 parts of ultraviolet absorbing agent, 6 parts of kaolin, 20 parts of talcum powder.This example high temperature tackifier are
Rosin resin.
The preparation method is as follows:
45 parts of No. 90 pitches and 6 parts of aromatic naphtha are weighed, are heated with stirring to 160 DEG C;No. 90 pitches are added in the present embodiment
Quality 45kg, the quality of aromatic naphtha are 6kg;
3 parts of KT resin are added in above-mentioned mixture, is heated up 170 DEG C, constant temperature is stirred to KT resin and is completely melt, the time
100min;
9 parts of 5 parts of SBR and BR butadiene rubber powder are added in above-mentioned mixture, are warming up to 180 DEG C, constant temperature is to complete
Fusing, time 150min;
5 parts of rosin resin are added in above-mentioned mixture, until the fusing of rosin resin is uniformly dispersed in mixture,
Time 90min;
6 parts and 20 parts of talcum powder of kaolin are added in above-mentioned mixture, is dispersed in kaolin and talcum powder mixed
It closes in material, time 100min;
Mixture temperature obtained is adjusted to 170-180 DEG C, sequentially adds 3 parts of antiaging agent, ultraviolet absorbing agent 3
Part, it is added in above-mentioned mixture while stirring, time 50min;
By mixture constant temperature obtained above at 180 DEG C, dilute consistency self-adhesive suitably resistant to high temperature is formed, then pass through life
Producing line, it is two-sided coated with self-adhesive using enhanced polyester felt as carcass using enhanced polyester felt as carcass, then with pure color sand be cover
Pattern is printed upon on coiled material by plane materiel material using 3D laser printing colouring technology, produce different size, different pattern band from
The stereo multi-colour waterproof roll of viscose glue.
Embodiment 4
The present invention provides a kind of stereo multi-colour waterproof roll with self-adhesive, self-adhesive according to parts by weight, by following
Raw material composition: No. 130 38 parts of bi tumenf orr oad, 6 parts of aromatic naphtha, 4 parts of high temperature tackifier, 3 parts of KT resin, 5 parts of SBR, along fourth
10 parts of rubber, 3 parts of antiaging agent, 3 parts of ultraviolet absorbing agent, 6 parts of kaolin, 20 parts of talcum powder.This example high temperature tackifier
For rosin resin.
The preparation method is as follows:
38 parts of No. 130 pitches and 6 parts of aromatic naphtha are weighed, are heated with stirring to 160 DEG C;No. 130 pitches are added in the present embodiment
Quality 38kg, the quality of aromatic naphtha is 6kg;
3 parts of KT resin are added in above-mentioned mixtures, is heated up 170 DEG C, constant temperature is stirred to KT resin and is completely melt, when fusing
Between 110min;
10 parts of 5 parts of SBR and BR butadiene rubber powder are added in above-mentioned mixture, are warming up to 180 DEG C, constant temperature is to complete
Running down, fusing time 150min;
4 parts of rosin resin are added in above-mentioned mixture, until the fusing of rosin resin is uniformly dispersed in mixture,
Time 100min;
6 parts and 20 parts of talcum powder of kaolin are added in above-mentioned mixture, is dispersed in kaolin and talcum powder mixed
It closes in material, time 100min;
Mixture temperature obtained is adjusted to 170-180 DEG C, sequentially adds 3 parts of antiaging agent, ultraviolet absorbing agent 3
Part, it is added in above-mentioned mixture while stirring, mixing time 50min;
By mixture constant temperature obtained above at 180 DEG C, dilute consistency self-adhesive suitably resistant to high temperature is formed, then pass through life
Producing line, it is two-sided coated with self-adhesive using enhanced polyester felt as carcass using enhanced polyester felt as carcass, then with pure color sand be cover
Pattern is printed upon on coiled material by plane materiel material using 3D laser printing colouring technology, produce different size, different pattern band from
The stereo multi-colour waterproof roll of viscose glue.
Embodiment 5
The present invention provides a kind of stereo multi-colour waterproof roll with self-adhesive, self-adhesive according to parts by weight, by following
Raw material composition: No. 130 35 parts of bi tumenf orr oad, 5 parts of aromatic naphtha, 3 parts of high temperature tackifier, 5 parts of KT resin, 7 parts of SBR, along fourth
8 parts of rubber, 5 parts of antiaging agent, 2 parts of ultraviolet absorbing agent, 5 parts of kaolin, 15 parts of talcum powder.This example high temperature tackifier are
C9 hydrotreated petroleum resin.
The preparation method is as follows:
35 parts of No. 130 pitches and 5 parts of aromatic naphtha are weighed, are heated with stirring to 160 DEG C;No. 130 pitches are added in the present embodiment
Quality 35kg, the quality of aromatic naphtha is 5kg;
5 parts of KT resin are added in above-mentioned mixtures, is heated up 170 DEG C, constant temperature is stirred to KT resin and is completely melt, when fusing
Between 100min;
8 parts of 7 parts of SBR and BR butadiene rubber powder are added in above-mentioned mixture, are warming up to 180 DEG C, constant temperature is to complete
Fusing, fusing time 150min;
C9 hydrotreated petroleum resin is added in above-mentioned mixture for 3 parts, until the fusing dispersion of C9 hydrotreated petroleum resin is equal
It is even in mixture, fusing time 90min;
5 parts and 15 parts of talcum powder of kaolin are added in above-mentioned mixture, is dispersed in kaolin and talcum powder mixed
It closes in material, time 100min;
Mixture temperature obtained is adjusted to 170-180 DEG C, sequentially adds 5 parts of antiaging agent, ultraviolet absorbing agent 2
Part, it is added in above-mentioned mixture while stirring, mixing time 50min;
By mixture constant temperature obtained above at 180 DEG C, dilute consistency self-adhesive suitably resistant to high temperature is formed, then pass through life
Producing line, it is two-sided coated with self-adhesive using enhanced polyester felt as carcass using enhanced polyester felt as carcass, then with pure color sand be cover
Pattern is printed upon on coiled material by plane materiel material using 3D laser printing colouring technology, produce different size, different pattern band from
The stereo multi-colour waterproof roll of viscose glue.
Embodiment 6
The present invention provides a kind of stereo multi-colour waterproof roll with self-adhesive, self-adhesive according to parts by weight, by following
Raw material composition: No. 130 40 parts of bi tumenf orr oad, 10 parts of aromatic naphtha, 4 parts of high temperature tackifier, 2 parts of KT resin, 3 parts of SBR, suitable
12 parts of buna, 2 parts of antiaging agent, 5 parts of ultraviolet absorbing agent, 9 parts of kaolin, 18 parts of talcum powder.This example high temperature thickening
Agent is the dilute resin of terpene.
The preparation method is as follows:
According to above-mentioned raw materials weight ratio, 40 parts of No. 130 pitches and 10 parts of aromatic naphtha are weighed, are heated with stirring to 160 DEG C;This reality
The quality 40kg that No. 130 pitch is added in example is applied, the quality of aromatic naphtha is 10kg;
2 parts of KT resin are added in above-mentioned mixture, is heated up 170 DEG C, constant temperature is stirred to KT resin and is completely melt, the time
100min;
12 parts of 3 parts of SBR and BR butadiene rubber powder are added in above-mentioned mixture, are warming up to 180 DEG C, constant temperature is to complete
Running down, time 140min;
The dilute resin of terpene is added in above-mentioned mixture for 4 parts, until the dilute resin fusing of terpene is uniformly dispersed in mixture,
Time 90min;
9 parts and 18 parts of talcum powder of kaolin are added in above-mentioned mixture, is dispersed in kaolin and talcum powder mixed
It closes in material, time 110min;
Mixture temperature obtained is adjusted to 170-180 DEG C, sequentially adds 2 parts of antiaging agent, ultraviolet absorbing agent 5
Part, it is added in above-mentioned mixture while stirring, time 50min;
By mixture constant temperature obtained above at 180 DEG C, dilute consistency self-adhesive suitably resistant to high temperature is formed, then pass through life
Producing line, it is two-sided coated with self-adhesive using enhanced polyester felt as carcass using enhanced polyester felt as carcass, then with pure color sand be cover
Pattern is printed upon on coiled material by plane materiel material using 3D laser printing colouring technology, produce different size, different pattern band from
The stereo multi-colour waterproof roll of viscose glue.
Stereo multi-colour waterproof roll provided by the above embodiment with self-adhesive is used for industrial, civilian, military building
Roof waterproof and decoration are particularly suitable for the water-proof decorative of the pitched roofs such as communal facility, all kinds of villas.And the stereo multi-colour waterproof
Coiled material predominantly detects data such as table 1:
Table 1
Enhanced polyester felt carcass is in commercially available special polyester felt carcass, present invention implementation in the embodiment of the present invention
Antiaging agent, the ultraviolet absorbing agent referred to is all from the commercially available producer for meeting index request.Pitch of the invention, aromatic naphtha,
High temperature tackifier, SBR, kaolin, talcum powder, are that direct purchase obtains at KT resin.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (6)
1. a kind of stereo multi-colour waterproof roll with self-adhesive, which is characterized in that the self-adhesive by weight, including pitch
35-45 parts, 5-10 parts of aromatic naphtha, 3-5 parts of high temperature tackifier, 2-5 parts of KT resin, 3-7 parts of SBR, 8-12 parts of BR butadiene rubber,
2-5 parts of antiaging agent, 2-5 parts of ultraviolet absorbing agent, 5-9 parts of kaolin, 15-20 parts of talcum powder.
2. a kind of stereo multi-colour waterproof roll with self-adhesive as described in claim 1, which is characterized in that the pitch is road
Road asphalt, model No. 90 or No. 130;The aromatic naphtha is the transparent or micro- Huang of -30 DEG C of pour point, 200 DEG C of flash-point or more
Aromatic naphtha.
3. a kind of stereo multi-colour waterproof roll with self-adhesive as described in claim 1, which is characterized in that the BR is along fourth
Rubber is cis--Isosorbide-5-Nitrae-polybutadiene rubber powder, and the BR butadiene rubber is the low cis rubber that content is 35%~40%
Powder;The SBR is butadiene-styrene rubber powder, and butadiene-styrene rubber content is 52%.
4. a kind of stereo multi-colour waterproof roll with self-adhesive as described in claim 1, which is characterized in that the high temperature increases
Stick be the dilute resin of terpene, C9 resin, rosin resin it is one or more;The KT resin is maleic anhydride graft copolymer tree
Ester, melt index 0.4-0.8;Antiaging agent is benzene di-isooctyl;Ultraviolet absorbing agent is toluic acid resorcinol.
5. a kind of stereo multi-colour waterproof roll with self-adhesive as described in claim 1, which is characterized in that the kaolin
For kaolin of the fineness more than 1250 mesh;The talcum powder is white powder of the fineness more than 800 mesh.
6. preparation as power 1 to power 5 it is any as described in the stereo multi-colour waterproof roll with self-adhesive method, which is characterized in that wrap
Include following steps:
1) according to above-mentioned weight, pitch and aromatic naphtha heating stirring are warming up to 155-165 DEG C;
2) KT resin is added to while stirring in the mixture in step 1), is warming up to 170 DEG C, until KT resin is completely melt;
3) mixture obtained in step 2) is warming up to 180 DEG C, in proportion adds BR butadiene rubber and SBR while stirring together
Enter in the mixture that step 2) obtains, is uniformly dispersed to being completely melt;
4) high temperature tackifier are added in the mixture of step 3) while stirring in proportion, are warming up to 200 DEG C, constant temperature is to complete
Fusing;
5) kaolin and talc in proportion are added to while stirring in mixture made from step 4), until being uniformly dispersed;
6) mixture temperature made from step 5) is adjusted to 170-180 DEG C, sequentially adds antiaging agent, ultraviolet absorbing agent,
It is added in the mixture in step 5) while stirring;
7) by mixture constant temperature made from step 6) at 170-180 DEG C, dilute consistency self-adhesive suitably resistant to high temperature is formed;Lead to again
Production line is crossed, it is two-sided coated with above-mentioned self-adhesive using enhanced polyester felt as carcass, then using pure color sand as facing material, utilize 3D
Pattern is printed upon on coiled material by laser printing colouring technology.
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Cited By (1)
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JP2004352892A (en) * | 2003-05-29 | 2004-12-16 | Mitsubishi Paper Mills Ltd | Removable pressure-sensitive adhesive composition and self-sealing postcard paper produced by using the same |
CN1662623A (en) * | 2002-06-25 | 2005-08-31 | 3M创新有限公司 | Linerless printable adhesive tape |
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CN109401346A (en) * | 2018-10-24 | 2019-03-01 | 辽宁女娲防水建材科技集团有限公司 | A kind of cold roofing reflection and heat insulation adhesive waterproof coil and preparation method, application |
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CN1399669A (en) * | 1999-10-29 | 2003-02-26 | 艾弗里·丹尼森公司 | Multilayer composite PSA constructions |
CN1662623A (en) * | 2002-06-25 | 2005-08-31 | 3M创新有限公司 | Linerless printable adhesive tape |
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