CN110483846A - 一种阻燃生物质基抗菌膜的制备工艺 - Google Patents
一种阻燃生物质基抗菌膜的制备工艺 Download PDFInfo
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- CN110483846A CN110483846A CN201910767403.1A CN201910767403A CN110483846A CN 110483846 A CN110483846 A CN 110483846A CN 201910767403 A CN201910767403 A CN 201910767403A CN 110483846 A CN110483846 A CN 110483846A
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- polyethylene glycol
- chitosan
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- chitin
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- 238000002360 preparation method Methods 0.000 title claims abstract description 25
- 239000003063 flame retardant Substances 0.000 title claims abstract description 24
- 239000002028 Biomass Substances 0.000 title claims abstract description 22
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 14
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 52
- 229920001661 Chitosan Polymers 0.000 claims abstract description 46
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 39
- 229920002101 Chitin Polymers 0.000 claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims abstract description 14
- 239000004254 Ammonium phosphate Substances 0.000 claims abstract description 13
- 229920000877 Melamine resin Polymers 0.000 claims abstract description 13
- DKRWGRQBYLWNKR-UHFFFAOYSA-N OC(O)(O)[PH2]=O Chemical compound OC(O)(O)[PH2]=O DKRWGRQBYLWNKR-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims abstract description 13
- 235000019289 ammonium phosphates Nutrition 0.000 claims abstract description 13
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims abstract description 13
- TVHALOSDPLTTSR-UHFFFAOYSA-H hexasodium;[oxido-[oxido(phosphonatooxy)phosphoryl]oxyphosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O TVHALOSDPLTTSR-UHFFFAOYSA-H 0.000 claims abstract description 13
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229940068917 polyethylene glycols Drugs 0.000 claims abstract description 13
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical class N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000007788 liquid Substances 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 239000000243 solution Substances 0.000 claims description 60
- 239000000463 material Substances 0.000 claims description 30
- 238000003756 stirring Methods 0.000 claims description 22
- 239000007864 aqueous solution Substances 0.000 claims description 14
- 238000006467 substitution reaction Methods 0.000 claims description 10
- 238000010792 warming Methods 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 7
- 238000004321 preservation Methods 0.000 claims description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 4
- 239000004202 carbamide Substances 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 239000008367 deionised water Substances 0.000 claims description 4
- 229910021641 deionized water Inorganic materials 0.000 claims description 4
- 238000004090 dissolution Methods 0.000 claims description 4
- 238000000465 moulding Methods 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- 238000010257 thawing Methods 0.000 claims description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
- 238000000746 purification Methods 0.000 claims description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 3
- 230000003115 biocidal effect Effects 0.000 abstract description 4
- 238000004806 packaging method and process Methods 0.000 abstract 1
- 239000012528 membrane Substances 0.000 description 18
- -1 but simultaneously Substances 0.000 description 12
- 239000000047 product Substances 0.000 description 9
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N hydrochloric acid Substances Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 3
- 239000007987 MES buffer Substances 0.000 description 3
- NQTADLQHYWFPDB-UHFFFAOYSA-N N-Hydroxysuccinimide Chemical compound ON1C(=O)CCC1=O NQTADLQHYWFPDB-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 150000001733 carboxylic acid esters Chemical class 0.000 description 3
- 239000013065 commercial product Substances 0.000 description 3
- 238000010931 ester hydrolysis Methods 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 229960002317 succinimide Drugs 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 238000012424 Freeze-thaw process Methods 0.000 description 2
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920000747 poly(lactic acid) Polymers 0.000 description 1
- 229920001896 polybutyrate Polymers 0.000 description 1
- 239000004626 polylactic acid Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2305/00—Characterised by the use of polysaccharides or of their derivatives not provided for in groups C08J2301/00 or C08J2303/00
- C08J2305/08—Chitin; Chondroitin sulfate; Hyaluronic acid; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2405/00—Characterised by the use of polysaccharides or of their derivatives not provided for in groups C08J2401/00 or C08J2403/00
- C08J2405/08—Chitin; Chondroitin sulfate; Hyaluronic acid; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2483/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
- C08J2483/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2487/00—Characterised by the use of unspecified macromolecular compounds, obtained otherwise than by polymerisation reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34928—Salts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5397—Phosphine oxides
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
膜性能 | 实施例1 | 实施例2 |
断裂延伸率(%) | 32.7±3.6 | 35.6±4.2 |
拉伸强度(Kpa) | 489.4±23.7 | 545.7±31.2 |
横向撕裂强度(kN/m) | 136.5±9.1 | 144.7±7.4 |
纵向撕裂强度(kN/m) | 186.5±8.5 | 197.8±9.2 |
氧指数 | 30.6 | 31.2 |
垂直燃烧等级 | V-0 | V-0 |
Claims (4)
Priority Applications (1)
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CN201910767403.1A CN110483846B (zh) | 2019-08-20 | 2019-08-20 | 一种阻燃生物质基抗菌膜的制备工艺 |
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CN201910767403.1A CN110483846B (zh) | 2019-08-20 | 2019-08-20 | 一种阻燃生物质基抗菌膜的制备工艺 |
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Publication Number | Publication Date |
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CN110483846A true CN110483846A (zh) | 2019-11-22 |
CN110483846B CN110483846B (zh) | 2021-04-06 |
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Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103157410A (zh) * | 2013-03-13 | 2013-06-19 | 中国科学院化学研究所 | 一种气凝胶的制备方法 |
CN103739862A (zh) * | 2013-07-25 | 2014-04-23 | 天津大学 | 明胶/羧甲基壳聚糖/poss光交联水凝胶及制备方法 |
CN104128602A (zh) * | 2014-08-06 | 2014-11-05 | 四川大学 | 一种改性壳聚糖修饰的纳米银抗菌复合材料、制备方法及应用 |
CN105459536A (zh) * | 2015-05-03 | 2016-04-06 | 湖南工业大学 | 一种五层共挤高强度阻隔抗菌环保复合膜 |
CN105585795A (zh) * | 2015-11-09 | 2016-05-18 | 南通蛇类治疗研究所 | 废木材塑料秸秆废渣制备阻燃功能性板材 |
CN106700108A (zh) * | 2016-12-05 | 2017-05-24 | 深圳职业技术学院 | 一种可降解抗菌保鲜膜及其制备方法 |
CN108404221A (zh) * | 2018-04-09 | 2018-08-17 | 郑州轻工业学院 | 一种可注射性有机硅/壳聚糖纳米复合水凝胶及其制备方法与应用 |
CN109485747A (zh) * | 2017-09-12 | 2019-03-19 | 中国科学院理化技术研究所 | 一种水溶性壳聚糖抗菌衍生物及其制备方法 |
-
2019
- 2019-08-20 CN CN201910767403.1A patent/CN110483846B/zh active Active
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103157410A (zh) * | 2013-03-13 | 2013-06-19 | 中国科学院化学研究所 | 一种气凝胶的制备方法 |
CN103739862A (zh) * | 2013-07-25 | 2014-04-23 | 天津大学 | 明胶/羧甲基壳聚糖/poss光交联水凝胶及制备方法 |
CN104128602A (zh) * | 2014-08-06 | 2014-11-05 | 四川大学 | 一种改性壳聚糖修饰的纳米银抗菌复合材料、制备方法及应用 |
CN105459536A (zh) * | 2015-05-03 | 2016-04-06 | 湖南工业大学 | 一种五层共挤高强度阻隔抗菌环保复合膜 |
CN105585795A (zh) * | 2015-11-09 | 2016-05-18 | 南通蛇类治疗研究所 | 废木材塑料秸秆废渣制备阻燃功能性板材 |
CN106700108A (zh) * | 2016-12-05 | 2017-05-24 | 深圳职业技术学院 | 一种可降解抗菌保鲜膜及其制备方法 |
CN109485747A (zh) * | 2017-09-12 | 2019-03-19 | 中国科学院理化技术研究所 | 一种水溶性壳聚糖抗菌衍生物及其制备方法 |
CN108404221A (zh) * | 2018-04-09 | 2018-08-17 | 郑州轻工业学院 | 一种可注射性有机硅/壳聚糖纳米复合水凝胶及其制备方法与应用 |
Non-Patent Citations (2)
Title |
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SHINSUKE IFUKU等: "Preparation of high-strength transparent chitosan film reinforced with surface-deacetylated chitin nanofibers", 《CARBOHYDRATE POLYMERS》 * |
刘琴等: "POSS对壳聚糖膜的阻湿与拉伸性能的影响 ", 《包装工程》 * |
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