CN110483823A - A kind of environmental-protecting self makeup exterior material - Google Patents
A kind of environmental-protecting self makeup exterior material Download PDFInfo
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- CN110483823A CN110483823A CN201910798109.7A CN201910798109A CN110483823A CN 110483823 A CN110483823 A CN 110483823A CN 201910798109 A CN201910798109 A CN 201910798109A CN 110483823 A CN110483823 A CN 110483823A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/0866—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements composed of several layers, e.g. sandwich panels or layered panels
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/12—Polypropene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2369/00—Characterised by the use of polycarbonates; Derivatives of polycarbonates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2443/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium or a metal; Derivatives of such polymers
- C08J2443/04—Homopolymers or copolymers of monomers containing silicon
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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Abstract
The present invention provides a kind of environmental-protecting self makeup exterior material, including formica and environmental-protecting self coating, the formica is arranged using novel building decorative plates, the environmental-protecting self coating is arranged using interior wall modified aqueous paint, it is arranged between shown formica and environmental purification coating using plasma spraying, the formica is polycarbonate plate, polyvinyl chloride decorative board, one kind of polyethylene decorative panel or polypropylene decorative panel.The present invention prepares environmental-protecting self coating by using modified machine acrylate emulsion modified with organosiloxane and a variety of different fillers and auxiliary agent, the health that is effectively had according to environmental-protecting self coating, environmental protection, easy for construction, dried coating film is fast, good permeability, water-tolerant, has excellent performance and have many advantages, such as self-purging room air, and it is combined with formica, the multiple performances such as environmentally friendly auto purification are decorated to effectively realize, improve family life quality.
Description
Technical field
The present invention relates to ornament materials design fields more particularly to a kind of environmental-protecting self to disguise exterior material.
Background technique
With the further promotion of people's living standard, people require also constantly promoted for the finishing of building, furniture,
The spies such as associated decorative material is enriched with changing style, color multiplicity, pattern, visual appearance, decorative effect are good are not required nothing more than
Point, it is also desirable to have fire-proof and water-proof, wear-resisting scratch resistance, safety and environmental protection, it is easy for construction, the characteristics such as be easily changed, this is just to traditional
More stringent requirements are proposed for the enterprises such as wallpaper, wall paper, decoration panel.
With the industries such as China's wallpaper, wall paper, decoration panel ripe day by day and people's safety and environmental protection realize reinforcement,
While people pay close attention to wallpaper, wall paper, decoration panel color and style varied, the practical and safety and environmental protection of product is also focused more on
Etc. performances, usually the problems such as solving environmental protection is carried out in plaque surface sprayed coating, however, existing sprayed coating is mostly water
Property coating, and water paint is generally divided into three classes by the dispersity of resin in water: water soluble paint, the hydrosol (micella point
Dissipate) coating, latex paint (emulsion coatings, latex paint).Emulsion paint is one of latex paint also known as synthetic resin emulsion
Coating is one kind using synthetic resin emulsion as film forming matter, face is added, the water paint that filler and various auxiliary agents are formulated,
And these belong to more low-grade water soluble paint, function is more single, not comprehensive enough.
Therefore, it is necessary to solve the above problems to invent a kind of environmental-protecting self makeup exterior material
Summary of the invention
The purpose of the present invention is to provide a kind of environmental-protecting selfs to disguise exterior material, to solve the above technical problems.
The present invention using following technical scheme in order to solve the above technical problems, realized:
A kind of environmental-protecting self makeup exterior material, including formica and environmental-protecting self coating, the formica
It is arranged using novel building decorative plates, the environmental-protecting self coating is arranged using interior wall modified aqueous paint, shown modeling
Expect to be arranged between decorative panel and environmental purification coating using plasma spraying.
Preferably, the formica is polycarbonate plate, polyvinyl chloride decorative board, polyethylene decorative panel or polypropylene
One kind of decorative panel has the characteristics that lightweight, high-strength, sound insulation, light transmission, fire prevention, flexible, easy for installation, anti-aging, not only may be used
To replace the ornament materials such as the timber specially united and steel, building function can also be improved, beautified the environment, modem architectural ornament is met
Demand.
Preferably, the formula of the environmental-protecting self coating is in parts by weight organosilicon-modified acrylate emulsion 100
Part, 20 parts of pigment, 200 parts of filler and 80 parts of auxiliary agent.
Preferably, the organosilicon-modified acrylate emulsion the preparation method comprises the following steps:
The preparation of S1 monomer pre-emulsion: the distilled water of 100ml is added to the 500ml four-hole boiling flask equipped with electric mixer
In, then it is separately added into emulsifier and acrylic ester monomer, whole siloxanyl monomers are eventually adding, are stirred with certain revolving speed
It mixes, after carrying out pre-emulsification at room temperature for a period of time, is transferred completely into 250ml separatory funnel；
The preparation of S2 acrylate seed emulsion: add into the four-hole boiling flask that condenser, electric mixer, thermometer are housed
Enter 100ml distilled water, then be separately added into remaining emulsifier and acrylic ester monomer, carries out pre-emulsification after a certain period of time, according to
It is secondary that suitable initiator solution, hydrochloric acid is added, it is stirred with certain revolving speed and carries out warming-in-water heating, after answering 20-30min,
There is blue light in kettle liquid, shows that acrylate seed emulsion generates；
The synthesis of S3 organosilicon-modified acrylate emulsion: when there is the generation of acrylate seed emulsion, start to reaction
Pre-emulsion and remaining initiator are added dropwise in kettle, control drips off in 2h, and then the insulation reaction 30min time, after reaction, cold
But to room temperature, pH value is adjusted with ammonium hydroxide and obtains the milky organosilicon-modified acrylic of blue light with the screen to filtrate of 200 mesh to 7-8
Ester lotion.
Preferably, the pigment is arranged using white pigment, the white pigment be titanium dioxide, zinc oxide, vertical powder or
One of antimony oxide mainly selects titanium dioxide for white pigment, it is made to have high covering power, strong reducing power and excellent stabilization
The characteristics of.
Preferably, the filler is one of kaolin, talcum powder, coarse whiting, diatomite or montmorillonite powder, wherein kaolinite
Soil, talcum powder, coarse whiting, diatomite or montmorillonite powder density be followed successively by 2.6g/cm-3,2.85g/cm-3,2.71g/cm-3,
2g/cm-3 and 2.5g/cm-3 makes the environmental-protecting self coating to be formed have different performances using different fillers.
Preferably, the auxiliary agent is wetting dispersing agent, defoaming agent, coalescing agent, thickener, antimildew disinfectant and pH value tune
Agent is saved, the wetting dispersing agent, defoaming agent, coalescing agent, thickener, antimildew disinfectant and the deal of pH value adjustment agent ratio are
10:2:2:50:3:13。
Preferably, the wetting dispersing agent uses one kind of calgon and polyacrylate, and the defoaming agent is adopted
With lower alcohols, one kind of polar organic compounds, mineral oils and organic siliconresin class, the coalescing agent using alcohols,
One kind of alcohol ethers and lipid, the thickener use inorganic, one kind of cellulose family, esters of acrylic acid and polyurethanes,
The antimildew disinfectant using wide spectrum, efficiently and the preservative of hypotoxicity, the pH value adjustment agent is using ammonium hydroxide and AMP-95
It is a kind of.
Preferably, the environmental-protecting self coating production are as follows: by the organosilicon-modified acrylate being prepared cream
Liquid is divided into equal two parts, and thickener is added in wherein portion first, is then heating another organosilicon-modified acrylic
Ester lotion, finally sequentially adds pigment, filler and auxiliary agent, stirs evenly, and plastics dress is sprayed on by the way of plasma spraying
On plaque, drying forms environmental-protecting self coating.
The beneficial effects of the present invention are:
(1) present invention is by using modified machine acrylate emulsion modified with organosiloxane and a variety of different fillers and auxiliary agent system
Standby environmental-protecting self coating out, the health effectively being had according to environmental-protecting self coating, environmental protection, easy for construction, dried coating film
Fastly, good permeability, water-tolerant, have excellent performance and have many advantages, such as self-purging room air, and and formica
It is combined, lightweight, high-strength, sound insulation, light transmission, fire prevention, flexible, easy for installation, anti-aging is had according to formica
Feature decorates the multiple performances such as environmentally friendly auto purification to effectively realize, improves family life quality.
Detailed description of the invention
Fig. 1 is the organosilicon-modified acrylate emulsion synthesis process flow diagram of invention；
Fig. 2 is the performance characteristics schematic diagram using different fillers of invention；
Fig. 3 is the performance characteristics schematic diagram using different thickeners of invention.
Specific embodiment
In order to be easy to understand the technical means, the creative features, the aims and the efficiencies achieved by the present invention, tie below
Specific embodiment is closed, the present invention is further explained, and however, the following embodiments are merely preferred embodiments of the present invention, and not all.
Based on the implementation example in the implementation mode, those skilled in the art's obtained other realities without making creative work
Example is applied, protection scope of the present invention is belonged to.Experimental method in following embodiments is unless otherwise specified conventional method,
The materials, reagents and the like used in the following examples is commercially available unless otherwise specified.
Embodiment one:
The present invention provides a kind of environmental-protecting selfs to disguise exterior material, including formica and environmental-protecting self coating, institute
It states formica to be arranged using novel building decorative plates, the environmental-protecting self coating uses interior wall modified aqueous paint
Setting is arranged between shown formica and environmental purification coating using plasma spraying, and the formica is poly- carbon
Acid esters plate, polyvinyl chloride decorative board, one kind of polyethylene decorative panel or polypropylene decorative panel, the environmental-protecting self coating are matched
Side is in parts by weight 100 parts of organosilicon-modified acrylate emulsion, 20 parts of pigment, 200 parts of filler and 80 parts of auxiliary agent, described
Organosilicon-modified acrylate emulsion the preparation method comprises the following steps:
The preparation of S1 monomer pre-emulsion: the distilled water of 100ml is added to the 500ml four-hole boiling flask equipped with electric mixer
In, then it is separately added into emulsifier and acrylic ester monomer, whole siloxanyl monomers are eventually adding, are stirred with certain revolving speed
It mixes, after carrying out pre-emulsification at room temperature for a period of time, is transferred completely into 250ml separatory funnel；
The preparation of S2 acrylate seed emulsion: add into the four-hole boiling flask that condenser, electric mixer, thermometer are housed
Enter 100ml distilled water, then be separately added into remaining emulsifier and acrylic ester monomer, carries out pre-emulsification after a certain period of time, according to
It is secondary that suitable initiator solution, hydrochloric acid is added, it is stirred with certain revolving speed and carries out warming-in-water heating, after answering 20-30min,
There is blue light in kettle liquid, shows that acrylate seed emulsion generates；
The synthesis of S3 organosilicon-modified acrylate emulsion: when there is the generation of acrylate seed emulsion, start to reaction
Pre-emulsion and remaining initiator are added dropwise in kettle, control drips off in 2h, and then the insulation reaction 30min time, after reaction, cold
But to room temperature, pH value is adjusted with ammonium hydroxide and obtains the milky organosilicon-modified acrylic of blue light with the screen to filtrate of 200 mesh to 7-8
Ester lotion；The environmental-protecting self coating production are as follows: the organosilicon-modified acrylate emulsion being prepared is divided into phase
Deng two parts, first wherein portion in thickener is added, then heat another organosilicon-modified acrylate emulsion, most
After sequentially add pigment, filler and auxiliary agent, wherein pigment is titanium dioxide, and filler is kaolin, and thickener is inorganic, cellulose
One kind of class, esters of acrylic acid and polyurethanes, stirs evenly, and formica is sprayed on by the way of plasma spraying
On, drying forms environmental-protecting self coating.
Embodiment two:
The present invention provides a kind of environmental-protecting selfs to disguise exterior material, including formica and environmental-protecting self coating, institute
It states formica to be arranged using novel building decorative plates, the environmental-protecting self coating uses interior wall modified aqueous paint
Setting is arranged between shown formica and environmental purification coating using plasma spraying, and the formica is poly- carbon
Acid esters plate, polyvinyl chloride decorative board, one kind of polyethylene decorative panel or polypropylene decorative panel, the environmental-protecting self coating are matched
Side is in parts by weight 100 parts of organosilicon-modified acrylate emulsion, 20 parts of pigment, 200 parts of filler and 80 parts of auxiliary agent, described
Organosilicon-modified acrylate emulsion the preparation method comprises the following steps:
The preparation of S1 monomer pre-emulsion: the distilled water of 100ml is added to the 500ml four-hole boiling flask equipped with electric mixer
In, then it is separately added into emulsifier and acrylic ester monomer, whole siloxanyl monomers are eventually adding, are stirred with certain revolving speed
It mixes, after carrying out pre-emulsification at room temperature for a period of time, is transferred completely into 250ml separatory funnel；
The preparation of S2 acrylate seed emulsion: add into the four-hole boiling flask that condenser, electric mixer, thermometer are housed
Enter 100ml distilled water, then be separately added into remaining emulsifier and acrylic ester monomer, carries out pre-emulsification after a certain period of time, according to
It is secondary that suitable initiator solution, hydrochloric acid is added, it is stirred with certain revolving speed and carries out warming-in-water heating, after answering 20-30min,
There is blue light in kettle liquid, shows that acrylate seed emulsion generates；
The synthesis of S3 organosilicon-modified acrylate emulsion: when there is the generation of acrylate seed emulsion, start to reaction
Pre-emulsion and remaining initiator are added dropwise in kettle, control drips off in 2h, and then the insulation reaction 30min time, after reaction, cold
But to room temperature, pH value is adjusted with ammonium hydroxide and obtains the milky organosilicon-modified acrylic of blue light with the screen to filtrate of 200 mesh to 7-8
Ester lotion；The environmental-protecting self coating production are as follows: the organosilicon-modified acrylate emulsion being prepared is divided into phase
Deng two parts, first wherein portion in thickener is added, then heat another organosilicon-modified acrylate emulsion, most
After sequentially add pigment, filler and auxiliary agent, wherein pigment is titanium dioxide, and filler is talcum powder, and thickener is inorganic, cellulose
One kind of class, esters of acrylic acid and polyurethanes, stirs evenly, and formica is sprayed on by the way of plasma spraying
On, drying forms environmental-protecting self coating.
Embodiment three:
The present invention provides a kind of environmental-protecting selfs to disguise exterior material, including formica and environmental-protecting self coating, institute
It states formica to be arranged using novel building decorative plates, the environmental-protecting self coating uses interior wall modified aqueous paint
Setting is arranged between shown formica and environmental purification coating using plasma spraying, and the formica is poly- carbon
Acid esters plate, polyvinyl chloride decorative board, one kind of polyethylene decorative panel or polypropylene decorative panel, the environmental-protecting self coating are matched
Side is in parts by weight 100 parts of organosilicon-modified acrylate emulsion, 20 parts of pigment, 200 parts of filler and 80 parts of auxiliary agent, described
Organosilicon-modified acrylate emulsion the preparation method comprises the following steps:
The preparation of S1 monomer pre-emulsion: the distilled water of 100ml is added to the 500ml four-hole boiling flask equipped with electric mixer
In, then it is separately added into emulsifier and acrylic ester monomer, whole siloxanyl monomers are eventually adding, are stirred with certain revolving speed
It mixes, after carrying out pre-emulsification at room temperature for a period of time, is transferred completely into 250ml separatory funnel；
The preparation of S2 acrylate seed emulsion: add into the four-hole boiling flask that condenser, electric mixer, thermometer are housed
Enter 100ml distilled water, then be separately added into remaining emulsifier and acrylic ester monomer, carries out pre-emulsification after a certain period of time, according to
It is secondary that suitable initiator solution, hydrochloric acid is added, it is stirred with certain revolving speed and carries out warming-in-water heating, after answering 20-30min,
There is blue light in kettle liquid, shows that acrylate seed emulsion generates；
The synthesis of S3 organosilicon-modified acrylate emulsion: when there is the generation of acrylate seed emulsion, start to reaction
Pre-emulsion and remaining initiator are added dropwise in kettle, control drips off in 2h, and then the insulation reaction 30min time, after reaction, cold
But to room temperature, pH value is adjusted with ammonium hydroxide and obtains the milky organosilicon-modified acrylic of blue light with the screen to filtrate of 200 mesh to 7-8
Ester lotion；The environmental-protecting self coating production are as follows: the organosilicon-modified acrylate emulsion being prepared is divided into phase
Deng two parts, first wherein portion in thickener is added, then heat another organosilicon-modified acrylate emulsion, most
After sequentially add pigment, filler and auxiliary agent, wherein pigment is titanium dioxide, and filler is coarse whiting, and thickener is inorganic, cellulose
One kind of class, esters of acrylic acid and polyurethanes, stirs evenly, and formica is sprayed on by the way of plasma spraying
On, drying forms environmental-protecting self coating.
Example IV:
The present invention provides a kind of environmental-protecting selfs to disguise exterior material, including formica and environmental-protecting self coating, institute
It states formica to be arranged using novel building decorative plates, the environmental-protecting self coating uses interior wall modified aqueous paint
Setting is arranged between shown formica and environmental purification coating using plasma spraying, and the formica is poly- carbon
Acid esters plate, polyvinyl chloride decorative board, one kind of polyethylene decorative panel or polypropylene decorative panel, the environmental-protecting self coating are matched
Side is in parts by weight 100 parts of organosilicon-modified acrylate emulsion, 20 parts of pigment, 200 parts of filler and 80 parts of auxiliary agent, described
Organosilicon-modified acrylate emulsion the preparation method comprises the following steps:
The preparation of S1 monomer pre-emulsion: the distilled water of 100ml is added to the 500ml four-hole boiling flask equipped with electric mixer
In, then it is separately added into emulsifier and acrylic ester monomer, whole siloxanyl monomers are eventually adding, are stirred with certain revolving speed
It mixes, after carrying out pre-emulsification at room temperature for a period of time, is transferred completely into 250ml separatory funnel；
The preparation of S2 acrylate seed emulsion: add into the four-hole boiling flask that condenser, electric mixer, thermometer are housed
Enter 100ml distilled water, then be separately added into remaining emulsifier and acrylic ester monomer, carries out pre-emulsification after a certain period of time, according to
It is secondary that suitable initiator solution, hydrochloric acid is added, it is stirred with certain revolving speed and carries out warming-in-water heating, after answering 20-30min,
There is blue light in kettle liquid, shows that acrylate seed emulsion generates；
The synthesis of S3 organosilicon-modified acrylate emulsion: when there is the generation of acrylate seed emulsion, start to reaction
Pre-emulsion and remaining initiator are added dropwise in kettle, control drips off in 2h, and then the insulation reaction 30min time, after reaction, cold
But to room temperature, pH value is adjusted with ammonium hydroxide and obtains the milky organosilicon-modified acrylic of blue light with the screen to filtrate of 200 mesh to 7-8
Ester lotion；The environmental-protecting self coating production are as follows: the organosilicon-modified acrylate emulsion being prepared is divided into phase
Deng two parts, first wherein portion in thickener is added, then heat another organosilicon-modified acrylate emulsion, most
After sequentially add pigment, filler and auxiliary agent, wherein pigment is titanium dioxide, and filler is diatomite, and thickener is inorganic, cellulose
One kind of class, esters of acrylic acid and polyurethanes, stirs evenly, and formica is sprayed on by the way of plasma spraying
On, drying forms environmental-protecting self coating.
Embodiment five:
The present invention provides a kind of environmental-protecting selfs to disguise exterior material, including formica and environmental-protecting self coating, institute
It states formica to be arranged using novel building decorative plates, the environmental-protecting self coating uses interior wall modified aqueous paint
Setting is arranged between shown formica and environmental purification coating using plasma spraying, and the formica is poly- carbon
Acid esters plate, polyvinyl chloride decorative board, one kind of polyethylene decorative panel or polypropylene decorative panel, the environmental-protecting self coating are matched
Side is in parts by weight 100 parts of organosilicon-modified acrylate emulsion, 20 parts of pigment, 200 parts of filler and 80 parts of auxiliary agent, described
Organosilicon-modified acrylate emulsion the preparation method comprises the following steps:
The preparation of S1 monomer pre-emulsion: the distilled water of 100ml is added to the 500ml four-hole boiling flask equipped with electric mixer
In, then it is separately added into emulsifier and acrylic ester monomer, whole siloxanyl monomers are eventually adding, are stirred with certain revolving speed
It mixes, after carrying out pre-emulsification at room temperature for a period of time, is transferred completely into 250ml separatory funnel；
The preparation of S2 acrylate seed emulsion: add into the four-hole boiling flask that condenser, electric mixer, thermometer are housed
Enter 100ml distilled water, then be separately added into remaining emulsifier and acrylic ester monomer, carries out pre-emulsification after a certain period of time, according to
It is secondary that suitable initiator solution, hydrochloric acid is added, it is stirred with certain revolving speed and carries out warming-in-water heating, after answering 20-30min,
There is blue light in kettle liquid, shows that acrylate seed emulsion generates；
The synthesis of S3 organosilicon-modified acrylate emulsion: when there is the generation of acrylate seed emulsion, start to reaction
Pre-emulsion and remaining initiator are added dropwise in kettle, control drips off in 2h, and then the insulation reaction 30min time, after reaction, cold
But to room temperature, pH value is adjusted with ammonium hydroxide and obtains the milky organosilicon-modified acrylic of blue light with the screen to filtrate of 200 mesh to 7-8
Ester lotion；The environmental-protecting self coating production are as follows: the organosilicon-modified acrylate emulsion being prepared is divided into phase
Deng two parts, first wherein portion in thickener is added, then heat another organosilicon-modified acrylate emulsion, most
After sequentially add pigment, filler and auxiliary agent, wherein pigment is titanium dioxide, and filler is montmorillonite powder, and thickener is inorganic, fiber
One kind of plain class, esters of acrylic acid and polyurethanes, stirs evenly, and formica is sprayed on by the way of plasma spraying
On, drying forms environmental-protecting self coating.
The basic principles, main features and advantages of the present invention have been shown and described above.The technology of the industry
For personnel it should be appreciated that the present invention is not limited to the above embodiments, described in the above embodiment and specification is only the present invention
Preference, be not intended to limit the invention, without departing from the spirit and scope of the present invention, the present invention also has various
Changes and improvements, these changes and improvements all fall within the protetion scope of the claimed invention.The claimed scope of the invention is by institute
Attached claims and its equivalent thereof.
Claims (9)
1. a kind of environmental-protecting self disguises exterior material, including formica and environmental-protecting self coating, it is characterised in that: the modeling
Expect that decorative panel is arranged using novel building decorative plates, the environmental-protecting self coating is set using interior wall modified aqueous paint
It sets, is arranged between shown formica and environmental purification coating using plasma spraying.
2. a kind of environmental-protecting self according to claim 1 disguises exterior material, it is characterised in that: the formica is poly-
Carbonic ester plate, polyvinyl chloride decorative board, one kind of polyethylene decorative panel or polypropylene decorative panel.
3. a kind of environmental-protecting self according to claim 1 disguises exterior material, it is characterised in that: the environmental-protecting self coating
Formula, be in parts by weight 100 parts of organosilicon-modified acrylate emulsion, 20 parts of pigment, 200 parts of filler and 80 parts of auxiliary agent.
4. a kind of environmental-protecting self according to claim 3 disguises exterior material, it is characterised in that: the organic-silicon-modified propylene
Acid esters emulsion preparation method are as follows:
The preparation of S1 monomer pre-emulsion: the distilled water of 100ml is added in the 500ml four-hole boiling flask equipped with electric mixer,
It is separately added into emulsifier and acrylic ester monomer again, is eventually adding whole siloxanyl monomers, is stirred with certain revolving speed, In
After carrying out pre-emulsification at room temperature for a period of time, it is transferred completely into 250ml separatory funnel；
The preparation of S2 acrylate seed emulsion: it is added into the four-hole boiling flask that condenser, electric mixer, thermometer are housed
100ml distilled water, then it is separately added into remaining emulsifier and acrylic ester monomer, carry out pre-emulsification after a certain period of time, successively
Suitable initiator solution, hydrochloric acid is added, stirred with certain revolving speed and carries out warming-in-water heating, after answering 20-30min, kettle
There is blue light in liquid, shows that acrylate seed emulsion generates；
The synthesis of S3 organosilicon-modified acrylate emulsion: when there is the generation of acrylate seed emulsion, start into reaction kettle
Pre-emulsion and remaining initiator is added dropwise, control drips off in 2h, and then the insulation reaction 30min time is cooled to after reaction
Room temperature adjusts pH value with ammonium hydroxide and obtains the milky organosilicon-modified acrylate cream of blue light with the screen to filtrate of 200 mesh to 7-8
Liquid.
5. a kind of environmental-protecting self according to claim 3 disguises exterior material, it is characterised in that: the pigment is using white face
Material setting, the white pigment are titanium dioxide, zinc oxide, found to obtain one of powder or antimony oxide.
6. a kind of environmental-protecting self according to claim 3 disguises exterior material, it is characterised in that: the filler be kaolin,
One of talcum powder, coarse whiting, diatomite or montmorillonite powder, wherein kaolin, talcum powder, coarse whiting, diatomite or montmorillonite powder
Density be followed successively by 2.6g/cm-3,2.85g/cm-3,2.71g/cm-3,2g/cm-3 and 2.5g/cm-3.
7. a kind of environmental-protecting self according to claim 3 disguises exterior material, it is characterised in that: the auxiliary agent is wetting and dispersing
Agent, defoaming agent, coalescing agent, thickener, antimildew disinfectant and pH value adjustment agent, the wetting dispersing agent, defoaming agent, film forming help
Agent, thickener, antimildew disinfectant and pH value adjustment agent deal ratio be 10:2:2:50:3:13.
8. a kind of environmental-protecting self according to claim 7 disguises exterior material, it is characterised in that: the wetting dispersing agent uses
One kind of calgon and polyacrylate, the defoaming agent use lower alcohols, polar organic compounds, mineral oils
With one kind of organic siliconresin class, the coalescing agent uses nothing using alcohols, one kind of alcohol ethers and lipid, the thickener
One kind of machine class, cellulose family, esters of acrylic acid and polyurethanes, the antimildew disinfectant is using wide spectrum, efficient and hypotoxicity
Preservative, the pH value adjustment agent use ammonium hydroxide and AMP-95 one kind.
9. a kind of environmental-protecting self according to claim 1 disguises exterior material, it is characterised in that: the environmental-protecting self coating
The preparation method comprises the following steps: the organosilicon-modified acrylate emulsion being prepared is divided into equal two parts, first in wherein portion
Thickener is added, is then heating another organosilicon-modified acrylate emulsion, is finally sequentially adding pigment, filler and help
Agent stirs evenly, and is sprayed on formica by the way of plasma spraying, and drying forms environmental-protecting self coating.
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| CN201910798109.7A CN110483823A (en) | 2019-08-27 | 2019-08-27 | A kind of environmental-protecting self makeup exterior material |
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| CN201910798109.7A CN110483823A (en) | 2019-08-27 | 2019-08-27 | A kind of environmental-protecting self makeup exterior material |
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