CN110464686A - The preparation method and application of Akebia Fruit natural surfactant - Google Patents
The preparation method and application of Akebia Fruit natural surfactant Download PDFInfo
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- CN110464686A CN110464686A CN201910883338.9A CN201910883338A CN110464686A CN 110464686 A CN110464686 A CN 110464686A CN 201910883338 A CN201910883338 A CN 201910883338A CN 110464686 A CN110464686 A CN 110464686A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
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- A61K8/9789—Magnoliopsida [dicotyledons]
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
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Abstract
The invention discloses a kind of preparation method and applications of Akebia Fruit natural surfactant, this method comprises: Akebia Fruit fruit crushed after being dried is immersed in the distilled water of 15~30 times of quality, 0.1-0.3% biological enzyme is added, extracts, filtrate and filter residue is obtained by filtration；Gained filter residue is repeated aforesaid operations 2~3 times, merging filtrate obtains Akebia Fruit extract liquor；It is to obtain concentrate between 1.1 to 1.2 that gained Akebia Fruit extract liquor, which is concentrated under reduced pressure into relative density,；Obtained concentrate is discarded by macroporous resin column with eluting, with 60%-85% ethanol elution, collects eluent；Be recovered under reduced pressure ethyl alcohol, concentration, freeze-drying, obtain it is filbert to colorless solid powder be Akebia Fruit natural surfactant.The Akebia Fruit natural surfactant purity that this method obtains is higher, and foaming power is strong and lasting, is applied in personal-care supplies, mitigates injury of the synthetic surfactant to skin and the pollution to environment.
Description
Technical field
The present invention relates to natural plants processing technology field more particularly to a kind of preparations of Akebia Fruit natural surfactant
Method and application.
Background technique
Akebia Fruit alias fiveleaf akebia fruit, August be fried, short, bristly hair or beard in August, Stauntonia latifolia, fruit in August etc., is plants of Lardizabalaceae caulis akebiae
(Akebia quinata (Thunb.) Decne.), threeleaf akebia (Akebia trifoliate (Thunb.) Koidz.), whitewood
The nearly mellow fruit of drying of logical (Akebia trifoliate (Thunb.) Koidz.var.australis ((Diels)) Rehd.)
It is real.Modern times chemical constitution study shows Akebia Fruit saponin containing bioactive triterpene, has the hydrophilies poles such as sugared body, carboxylic acid in structure
Property group, and glucoside member molecular structure is big, and polarity is low, has lipophilicity, there is the structure of surfactant-like on molecular structure
Feature can generate the foam of persistently similar soap solution, be a kind of natural nonionic surface active agent after aqueous solution shaking,
With good dirt-removing power, can be used for cleaning in washing product.A kind of fiveleaf akebia fruit is elaborated in patent CN201710507576
The preparation method and applications of purification total saposins, but the method that this method uses alcohol extracting, and make in the subtractive process of back
It has used n-butanol as purified reagent, has been used in reagent upper not environmentally protective enough.
Summary of the invention
Shortcoming present in view of the above technology, the present invention provide a kind of preparation of Akebia Fruit natural surfactant
Method and application, the preparation process is simple, green, and obtained Akebia Fruit natural surfactant foaming effect is significant, can be independent
It uses, and is applied on personal care product as foaming agent, injury of the synthetic surfactant to skin can be mitigated
With the pollution to environment.
To achieve the above object, the present invention provides a kind of preparation method of Akebia Fruit natural surfactant, comprising:
(1) by Akebia Fruit fruit crushed after being dried, it is immersed in the distilled water of 15~30 times of quality, it is raw that 0.1-0.3% is added
Object enzyme extracts, filtrate and filter residue is obtained by filtration；
(2) gained filter residue is repeated to operation 2~3 times of step (1), merging filtrate obtains Akebia Fruit extract liquor；
(3) Akebia Fruit extract liquor obtained by step (2) is concentrated under reduced pressure into relative density is to be concentrated between 1.1 to 1.2
Liquid；
(4) concentrate for obtaining step (3) is discarded, is washed with 60%-85% ethyl alcohol by macroporous resin column to elute
It is de-, collect eluent；
(5) it is recovered under reduced pressure ethyl alcohol, concentration, freeze-drying obtain filbert to colorless solid powder being that Akebia Fruit is natural
Surfactant.
Wherein, in step (1), the mesh number of crushing is 60~120 mesh.
Wherein, in step (1), the amount that the biological enzyme is added is 0.2%.
Wherein, in step (1), the condition of extraction are as follows: extract 2~4h in 60~70 DEG C of stirrings.
Wherein, step (2) includes: by operation 3 times of gained filter residue repetition step (1), and merging filtrate obtains Akebia Fruit extraction
Take liquid.
Wherein, the step (2) includes: that Akebia Fruit extract liquor obtained by step (2) is concentrated under reduced pressure into relative density is 1.1
To between 1.2, decolourized to obtain concentrate by activated-charcoal column.
Wherein, the specific gravity being concentrated in step (5) is 1.2.
The present invention also provides a kind of applications of Akebia Fruit natural surfactant, including any of the above item preparation method to obtain
Akebia Fruit natural surfactant.
The beneficial effects of the present invention are: compared with prior art, Akebia Fruit natural surfactant provided by the invention
The permeability of plant cell wall can be changed using cellulase treatment in preparation method and application, is conducive to improve extraction efficiency, and
It is further purified by macroreticular resin, improves the content of Akebia Fruit total saposins, operation is simple and feasible, and experiment condition is mildly pacified
Entirely, environmental-friendly；And the Akebia Fruit surfactant purity being prepared is higher, color is shallower, no special odor, and foaming power is strong
And it is lasting, which is applied in personal nursing, Akebia Fruit natural surfactant class in the market is filled up
Product blank.
Specific embodiment
It is the preferred embodiment of the present invention below, it is noted that for those of ordinary skill in the art, not
Under the premise of being detached from the principle of the invention, several improvements and modifications can also be made, these improvements and modifications are also considered as of the invention
Protection scope.
The present invention provides a kind of preparation method of Akebia Fruit natural surfactant, comprising the following steps:
(1) by Akebia Fruit fruit crushed after being dried, it is immersed in the distilled water of 15~30 times of quality, it is raw that 0.1-0.3% is added
Object enzyme extracts, filtrate and filter residue is obtained by filtration；
(2) gained filter residue is repeated to operation 2~3 times of step (1), merging filtrate obtains Akebia Fruit extract liquor；
(3) Akebia Fruit extract liquor obtained by step (2) is concentrated under reduced pressure into relative density is to be concentrated between 1.1 to 1.2
Liquid；
(4) concentrate for obtaining step (3) is discarded, is washed with 60%-85% ethyl alcohol by macroporous resin column to elute
It is de-, collect eluent；
(5) it is recovered under reduced pressure ethyl alcohol, concentration, freeze-drying obtain filbert to colorless solid powder being that Akebia Fruit is natural
Surfactant.
The effective component of plant is wrapped up by cell wall mostly, and the ingredient of cell wall is mainly cellulose, hemicellulose, fruit
Colloid etc., the present invention in step (1) with distilled water extract can to avoid containing the impurity such as many greases of sauce in Akebia Fruit extract liquor,
Using cellulase treatment, the permeability of plant cell wall can be changed, be conducive to improve extraction efficiency；And pass through in step (4) big
Hole resin is further purified, and improves the content of Akebia Fruit total saposins.The present invention is extracted using biological enzyme combines macroreticular resin pure
Change method improves the recovery rate and purity of Akebia Fruit total saposins.Poisonous and harmful reagent, final products are not used in preparation process
Akebia Fruit surfactant purity is higher, and color is shallower, no special odor, and foaming power is strong and lasting.
In the present embodiment, the step of preparing compound extract in (1), wherein in step (1), the mesh number of crushing
For 60~120 mesh, the amount that the biological enzyme is added is 0.2%, the condition of extraction are as follows: extracts 2~4h in 60~70 DEG C of stirrings, makes
The effect that must be extracted is more preferable, and step (2) specifically includes: it is 3 times by the operation that gained filter residue repeats step (1), merging filtrate,
Obtain Akebia Fruit extract liquor.When number of operations is 3 times, the effect of extraction is best, and step (3) specifically includes: by step (2)
It is to be decolourized to be concentrated by activated-charcoal column between 1.1 to 1.2 that gained Akebia Fruit extract liquor, which is concentrated under reduced pressure into relative density,
Liquid, the technique for increasing decoloration, so that can be convenient after finished product in daily chemical products；The specific gravity of concentration is in step (5)
1.2, improve the purity of Akebia Fruit natural surfactant.
It is classified into that the present invention is further detailed in multiple embodiments and simple Akebia Fruit self-faced is living below
Property agent application test, the wherein test mainly test to frothing capacity of the application of Akebia Fruit natural surfactant,
Frothing capacity test evaluation method is Waring-Blender method: being specially to carry out under certain revolving speed to certain bubbling system
Stirring generates foam and measures frothing capacity.This method specific steps are as follows: into Waring-Blender stirring cup
The Akebia Fruit surfactant solution that 100Ml mass concentration is 0.3% is added, 60s is stirred with 4000r/min when experiment, will be produced
Raw foam pours into rapidly in 1000mL graduated cylinder, records initial foam value.Passage at any time, due to the defoaming of foam and poly-
And liquid is constantly precipitated, and records and the time required for 50mL liquid is discharged in foam, partly declines to measure the analysis liquid of foam stability
Phase, experimental temperature are room temperature.
Embodiment 1
(1) by Akebia Fruit fruit crushed after being dried to 80 mesh, it is immersed in the distilled water of 20 times of quality, by total volume
0.1% is added cellulase, and 60 DEG C of stirrings extract 3h, filtrate and filter residue is obtained by filtration；
(2) gained filter residue is repeated step (1) operation for 2 times, merging filtrate is to get arriving Akebia Fruit extract liquor；
(3) it is between 1.1 to 1.2 being concentrated under reduced pressure into relative density at 50 DEG C by Akebia Fruit extract liquor obtained by step (2),
It first passes through the activated-charcoal column handled well to decolourize, collects eluent；
(2) it is discarded by the macroporous resin column handled well respectively with three column volume distilled water and 30% ethanol elution,
Then with 60% ethanol elution, eluent is collected, ethyl alcohol is recovered under reduced pressure, is concentrated into specific gravity 1.2, be freeze-dried, obtain filbert
It is Akebia Fruit natural surfactant 1 to colorless solid powder, the purity of Akebia Fruit total saposins is 82.5%.
The Akebia Fruit Natural surfactant that 100Ml mass concentration is 0.5% is added into Waring-Blender stirring cup
Agent 1 stirs 60s with 4000r/min when experiment, the foam of generation is poured into rapidly in 1000mL graduated cylinder, records initial foam body
Product is 785.3mL, and analysis liquid half-life period is 262s.
Implement 2
(1) by Akebia Fruit fruit crushed after being dried to 80 mesh, it is immersed in the distilled water of 20 times of quality, by total volume
0.2% is added pectase, and 60 DEG C of stirrings extract 3h, filtrate and filter residue is obtained by filtration；
(2) gained filter residue is repeated step (1) operation for 2 times, merging filtrate is to get arriving Akebia Fruit extract liquor；
(3) it is between 1.1 to 1.2 being concentrated under reduced pressure into relative density at 50 DEG C by Akebia Fruit extract liquor obtained by step (2),
It first passes through the activated-charcoal column handled well to decolourize, collects eluent；
(4) it then by the macroporous resin column handled well, respectively with three column volume distilled water and 30% ethanol elution, abandons
It goes, then with 60% ethanol elution, collects eluent, ethyl alcohol is recovered under reduced pressure, is concentrated into specific gravity 1.2, be freeze-dried, obtain light brown
Color to colorless solid powder is Akebia Fruit natural surfactant 2, and the purity of Akebia Fruit total saposins is 83.1%.
The Akebia Fruit surfactant 2 that 100Ml mass concentration is 0.5% is added into Waring-Blender stirring cup,
60s is stirred with 4000r/min when experiment, the foam of generation is poured into rapidly in 1000mL graduated cylinder, record initial foam value is
795.5mL, analysis liquid half-life period are 268s.
Embodiment 3
(1) by Akebia Fruit fruit crushed after being dried to 80 mesh, it is immersed in the distilled water of 20 times of quality, by total volume
0.2% is added papain, and 60 DEG C of stirrings extract 3h, filtrate and filter residue is obtained by filtration；
(2) gained filter residue is repeated step (1) operation for 2~3 times, merging filtrate is to get arriving Akebia Fruit extract liquor；
(3) it is between 1.1 to 1.2 being concentrated under reduced pressure into relative density at 50 DEG C by Akebia Fruit extract liquor obtained by step (2),
It first passes through the activated-charcoal column handled well to decolourize, collects eluent；
(4) it then by the macroporous resin column handled well, respectively with three column volume distilled water and 30% ethanol elution, abandons
It goes, then with 60% ethanol elution, collects eluent, ethyl alcohol is recovered under reduced pressure, is concentrated into specific gravity 1.2, be freeze-dried, obtain light brown
Color to colorless solid powder is Akebia Fruit natural surfactant, and the purity of Akebia Fruit total saposins is 72.1%.
It is molten that the Akebia Fruit surfactant that 100Ml mass concentration is 0.5% is added into Waring-Blender stirring cup
Liquid 3 stirs 60s with 4000r/min when experiment, the foam of generation is poured into rapidly in 1000mL graduated cylinder, records initial foam body
Product is 642.6mL, and analysis liquid half-life period is 194s.
Embodiment 4
(1) by Akebia Fruit fruit crushed after being dried to 80 mesh, it is immersed in the distilled water of 20 times of quality, by total volume
0.2% is added cellulase and pectase (1:1), and 60 DEG C of stirrings extract 3h, filtrate and filter residue is obtained by filtration；
(2) gained filter residue is repeated step (1) operation for 3 times, merging filtrate is to get arriving Akebia Fruit extract liquor；
(3) Akebia Fruit extract liquor obtained by step (2) is being concentrated under reduced pressure between relative density 1.2 at 50 DEG C, is being first passed through
The activated-charcoal column handled well decolourizes, and collects eluent；
(4) it then by the macroporous resin column handled well, respectively with three column volume distilled water and 30% ethanol elution, abandons
It goes, then with 60% ethanol elution, collects eluent, ethyl alcohol is recovered under reduced pressure, is concentrated into specific gravity 1.2, be freeze-dried, obtain light brown
Color to colorless solid powder is Akebia Fruit natural surfactant 4, and the purity of Akebia Fruit total saposins is 85.1%.
The Akebia Fruit surfactant 4 that 100Ml mass concentration is 0.5% is added into Waring-Blender stirring cup,
60s is stirred with 4000r/min when experiment, the foam of generation is poured into rapidly in 1000mL graduated cylinder, record initial foam value is
798.8mL, analysis liquid half-life period are 272s.
The invention also discloses applying Akebia Fruit natural surfactant in personal care product, specifically, such as
Toothpaste, hand cleanser, mildy wash etc., wherein the toothpaste comprises the following components in parts by weight when the personal care product is toothpaste:
Akebia Fruit natural surfactant 1.0%, titanium dioxide 5.0%, aluminium hydroxide 25%, pyrophosphate 3.5%, edible glycerol
30%, sodium bicarbonate 10%, propylene glycol 5.5%, peppermint oil 1.0%, 1.5% sorbierite 5.0% of sodium chloride, deionized water
12.5%.Wherein, above-described various raw materials are technical grade, and 5-10 is confirmed by the following examples:
Embodiment 5
(1) 60 DEG C of deionized waters are added in material kettle, silica, aluminium hydroxide, the resulting precognition of embodiment 1 is added
Sub- natural surfactant, deionized water are mixed evenly；
(2) it is cooled to temperature lower than 50 DEG C, is added with stirring sorbierite, edible glycerol, sodium bicarbonate, sodium chloride, the third two
Alcohol is stirred until homogeneous sticky lotion state, this step process time is 60min；
(3) when temperature is down to 305 DEG C, peppermint oil is added, and stir evenly；
(4) it is aged 300min；
(5) after being cooled to room temperature, detection, canned and packaging.
The test of the present embodiment properties of product: it is 10% that 100Ml mass concentration is added into Waring-Blender stirring cup
Embodiment 5 prepared by toothpaste, 60s is stirred with 4000r/min when experiment, the foam of generation is poured into rapidly 1000mL graduated cylinder
In, record initial foam value is 285.6mL, and analysis liquid half-life period is 156s.
Embodiment 6
(1) 60 DEG C of deionized waters are added in material kettle, silica, aluminium hydroxide, the resulting precognition of embodiment 2 is added
Sub- natural surfactant, deionized water are mixed evenly；
(2) it is cooled to temperature lower than 50 DEG C, is added with stirring sorbierite, edible glycerol, sodium bicarbonate, sodium chloride, the third two
Alcohol is stirred until homogeneous sticky lotion state, this step process time is 60min；
(3) when temperature is down to 30 DEG C, peppermint oil is added, and stir evenly；
(4) it is aged 300min；
(5) after being cooled to room temperature, detection, canned and packaging.
The test of the present embodiment properties of product: it is 10% that 100Ml mass concentration is added into Waring-Blender stirring cup
Embodiment 6 prepared by toothpaste, 60s is stirred with 4000r/min when experiment, the foam of generation is poured into rapidly 1000mL graduated cylinder
In, record initial foam value is 296.6mL, and analysis liquid half-life period is 176s.
Embodiment 7
(1) 60 DEG C of deionized waters are added in material kettle, silica, aluminium hydroxide, the resulting precognition of embodiment 3 is added
Sub- natural surfactant, deionized water are mixed evenly；
(2) it is cooled to temperature lower than 50 DEG C, is added with stirring sorbierite, edible glycerol, sodium bicarbonate, sodium chloride, the third two
Alcohol is stirred until homogeneous sticky lotion state, this step process time is 60min；
(3) when temperature is down to 30 DEG C, peppermint oil is added, and stir evenly；
(4) it is aged 300min；
(5) after being cooled to room temperature, detection, canned and packaging.
The test of the present embodiment properties of product: it is 10% that 100Ml mass concentration is added into Waring-Blender stirring cup
Embodiment 6 prepared by toothpaste, 60s is stirred with 4000r/min when experiment, the foam of generation is poured into rapidly 1000mL graduated cylinder
In, record initial foam value is 182.1mL, and analysis liquid half-life period is 108s.
Embodiment 8
(1) 60 DEG C of deionized waters are added in material kettle, silica, aluminium hydroxide, the resulting precognition of embodiment 4 is added
Sub- natural surfactant, deionized water are mixed evenly；
(2) it is cooled to temperature lower than 50 DEG C, is added with stirring sorbierite, edible glycerol, sodium bicarbonate, sodium chloride, the third two
Alcohol is stirred until homogeneous sticky lotion state, this step process time is 60min；
(3) when temperature is down to 30 DEG C, peppermint oil is added, and stir evenly；
(4) it is aged 300min；
(5) after being cooled to room temperature, detection, canned and packaging.
The test of the present embodiment properties of product: it is 10% that 100Ml mass concentration is added into Waring-Blender stirring cup
Embodiment 6 prepared by toothpaste, 60s is stirred with 4000r/min when experiment, the foam of generation is poured into rapidly 1000mL graduated cylinder
In, record initial foam value is 196.2mL, and analysis liquid half-life period is 165s.
Embodiment 9
Akebia Fruit natural surfactant is applied in hand cleanser, specifically includes the group that the hand cleanser includes following parts by weight
Point: Akebia Fruit natural surfactant 2.0%, fatty acid methyl ester sulfonate 5.0%, alkyl-glucoside 3.0%, edible glycerol
3.0%, citric acid 1.0%, Kathon CG 0.1%, sodium chloride 0.3%, orange flavor 0.2%, deionized water 85.4%.Wherein, with
The upper various raw materials are technical grade, are prepared by the following method to obtain and detect:
(1) deionized water is added in material kettle, fatty acid methyl ester sulfonate, alkyl-glucoside, 2 institute of embodiment is added
The Akebia Fruit natural surfactant obtained is mixed evenly；
(2) it is added with stirring edible glycerol, citric acid, sodium chloride, Kathon CG, is stirred until homogeneous sticky lotion state；
(3) orange flavor and remaining deionized water is added and stirs evenly；
(4) it is aged 200min；
(5) it detects, canned and packaging.
The test of the present embodiment properties of product: it is 2.0% that 100Ml mass concentration is added into Waring-Blender stirring cup
Embodiment 2 prepared by hand cleanser, 60s is stirred with 4000r/min when experiment, the foam of generation is poured into rapidly 1000mL amount
In cylinder, record initial foam value is 391.6mL, and analysis liquid half-life period is 276s.
Embodiment 10
Akebia Fruit natural surfactant is applied in mildy wash, specifically includes the group that the mildy wash includes following parts by weight
Point: Akebia Fruit natural surfactant 2.0%, olive oil 10.0%, hexadecanol 4.0%, olive oil emulsifying wax 5.0%, the third two
Alcohol 3.0%, glycerol 5.0%, citric acid 1.0%, EDTA-2NA 0.08%, sodium chloride 0.3%, essence 0.5%, deionized water
69.12%.Wherein, above-described various raw materials are technical grade, are prepared by the following method to obtain and detect:
(1) 70 ± 5 DEG C of deionized waters are added in material kettle, olive oil, hexadecanol, olive oil emulsifying wax, the third two are added
Alcohol, glycerol and the resulting Akebia Fruit natural surfactant of embodiment 4, deionized water are mixed evenly；
(2) it is cooled to temperature lower than 40 DEG C, is added with stirring citric acid, EDTA-2NA, sodium chloride, essence, stirring is extremely
Uniform sticky lotion state；
(3) it is aged 300min；
(4) after being cooled to room temperature, detection, canned and packaging.
The test of the present embodiment properties of product: it is 10% that 100Ml mass concentration is added into Waring-Blender stirring cup
Embodiment 7 prepared by mildy wash, 60s is stirred with 4000r/min when experiment, the foam of generation is poured into rapidly 1000mL amount
In cylinder, record initial foam value is 172.2mL, and analysis liquid half-life period is 95s.
Analysis: the Akebia Fruit natural surfactant obtained by this preparation method can be seen that by embodiment 1-4
Purity is high, and simple foaming effect when using is obvious, and has good stability, wherein the biological enzyme of embodiment 4 practical 0.2% and
When repeating step (2) 3 times, purity is best, and foaming effect is obvious and stability is very good；And obtain embodiment 1-4
When Akebia Fruit natural surfactant is applied in personal care product respectively, such as embodiment 5-10, embodiment 1-4 is obtained
Akebia Fruit natural surfactant is applied respectively in personal care product's toothpaste, hand cleanser and facial cleanser, has been similarly obtained good
Good foaming effect and good stability illustrate the Akebia Fruit Natural surfactant of the not only available purity is high of the present invention
The environment of agent, preparation method is good, and the Akebia Fruit natural surfactant being prepared can be used separately as foaming agent,
It can be applied in personal care product, filled up the blank that Akebia Fruit is applied in personal care product.
Present invention has an advantage that
(1) practical biological enzyme and macroporous resin treatment, operation is simple and feasible, and experiment condition is mildly safe, environmental-friendly；
(2) biological enzyme is added, extraction conditions is relatively mild, and Akebia Fruit total saponin content is high；
(3) pass through decolorization, can be convenient in daily chemical products；
(4) the Akebia Fruit natural surfactant obtained can be used separately as foaming agent, can be applied in individual
In care product, the blank that Akebia Fruit is applied in personal care product has been filled up.
Disclosed above is only one or several specific embodiments of the invention, but the present invention is not limited to this, is appointed
What what those skilled in the art can think variation should all fall into protection scope of the present invention.
Claims (10)
1. a kind of preparation method of Akebia Fruit natural surfactant characterized by comprising
(1) by Akebia Fruit fruit crushed after being dried, it is immersed in the distilled water of 15~30 times of quality, 0.1-0.3% biological enzyme is added,
It extracts, filtrate and filter residue is obtained by filtration；
(2) gained filter residue is repeated to operation 2~3 times of step (1), merging filtrate obtains Akebia Fruit extract liquor；
(3) Akebia Fruit extract liquor obtained by step (2) is concentrated under reduced pressure into relative density is to obtain concentrate between 1.1 to 1.2；
(4) concentrate for obtaining step (3) is discarded by macroporous resin column to elute, and with 60%-85% ethanol elution, is received
Collect eluent；
(5) be recovered under reduced pressure ethyl alcohol, concentration, freeze-drying, obtain it is filbert to colorless solid powder be Akebia Fruit self-faced
Activating agent.
2. the preparation method of Akebia Fruit natural surfactant according to claim 1, which is characterized in that in step (1)
In, the mesh number of crushing is 60~120 mesh.
3. the preparation method of Akebia Fruit natural surfactant according to claim 1, which is characterized in that in step (1)
In, the amount that the biological enzyme is added is 0.2%.
4. the preparation method of Akebia Fruit natural surfactant according to claim 1, which is characterized in that in step (1)
In, the condition of extraction are as follows: extract 2~4h in 60~70 DEG C of stirrings.
5. the preparation method of Akebia Fruit natural surfactant according to claim 1, which is characterized in that step (2) packet
It includes: gained filter residue being repeated operation 3 times of step (1), merging filtrate obtains Akebia Fruit extract liquor.
6. the preparation method of Akebia Fruit natural surfactant according to claim 1, which is characterized in that the step
It (2) include: that Akebia Fruit extract liquor obtained by step (2) is concentrated under reduced pressure into relative density is to pass through active carbon between 1.1 to 1.2
Column is decolourized to obtain concentrate.
7. the preparation method of Akebia Fruit natural surfactant according to claim 1, which is characterized in that in step (5)
The specific gravity of middle concentration is 1.2.
8. a kind of application of Akebia Fruit natural surfactant in preparation personal care product, which is characterized in that including right
It is required that Akebia Fruit natural surfactant and auxiliary material that the preparation method of any one of 1-7 obtains.
9. a kind of toothpaste, which is characterized in that comprise the following components in parts by weight: the preparation side including any one of claim 1-7
Akebia Fruit natural surfactant 1.0% that method obtains, titanium dioxide 5.0%, aluminium hydroxide 25%, pyrophosphate 3.5%, food
With glycerol 30%, sodium bicarbonate 10%, propylene glycol 5.5%, peppermint oil 1.0%, 1.5% sorbierite 5.0% of sodium chloride, deionized water
12.5%.
10. the preparation method of toothpaste according to claim 9 characterized by comprising
(1) 60 ± 5 DEG C of deionized waters are added in material kettle, any one of silica, aluminium hydroxide, claim 1-7 is added
Resulting Akebia Fruit natural surfactant, deionized water are mixed evenly；
(2) it is cooled to temperature lower than 50 DEG C, is added with stirring sorbierite, edible glycerol, sodium bicarbonate, sodium chloride, propylene glycol, stirs
It mixes to uniform sticky lotion state, this step process time is 60min；
(3) when temperature is down to 30 ± 5 DEG C, peppermint oil is added, and stir evenly；
(4) it is aged 200-300min；
(5) after being cooled to room temperature, detection, canned and packaging.
Priority Applications (1)
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| CN113214913A (en) * | 2021-04-29 | 2021-08-06 | 浙江吉叶生物科技有限公司 | Natural surfactant and preparation method thereof |
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