CN110447655A - A kind of hygienic biocide composition - Google Patents
A kind of hygienic biocide composition Download PDFInfo
- Publication number
- CN110447655A CN110447655A CN201910762533.6A CN201910762533A CN110447655A CN 110447655 A CN110447655 A CN 110447655A CN 201910762533 A CN201910762533 A CN 201910762533A CN 110447655 A CN110447655 A CN 110447655A
- Authority
- CN
- China
- Prior art keywords
- bait
- parts
- bait formulation
- arprocarb
- acetamiprid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/002—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits
- A01N25/006—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits insecticidal
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/22—O-Aryl or S-Aryl esters thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Food Science & Technology (AREA)
- Toxicology (AREA)
- Insects & Arthropods (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention provides a kind of hygienic biocide composition, effective component is arprocarb and Acetamiprid；The mass ratio of the arprocarb and Acetamiprid is 10:1-1:10；The content of the effective component in the composition is 0.01-5wt%.The controlling object of the hygienic biocide composition is ant, blattaria and flies.The present invention also provides a kind of matrix that can be used for above-mentioned gel bait for killing insects.Bait formulation of the present invention uses the effective component of two kinds of different role mechanism, is mixed with suitable proportion, function and effect notable synergistic compared with single dose can effectively prevent resistant insect, delay the generation and development of drug resistance；And can be avoided skin irritation caused by pyrethroids class medicament, it is highly-safe.Bait formulation matrix provided by the invention, viscosity and hardness are suitble to, can be suitable for squash type product；Moistening effect is good, place for a long time it is not mouldy, will not be stiff, application interval can be increased, can be widely applied in the preparation of various bait formulation.
Description
Technical field
The invention belongs to hygienic insecticide fields, are related to a kind of hygienic biocide composition containing arprocarb and Acetamiprid.
Background technique
Acetamiprid belongs to chlorination nicotinic insecticide, have tag, stomach toxicity and stronger osmosis, act on insect mind
Nicotinic acetylcholine receptor through system synapses, the stimulation conduction of interference insect nervous system, causes nervous system access
Obstruction causes neurotransmitter acetylcholine in the accumulation of synapses, final dead so as to cause insect paralysis.Based on special
Mechanism of action, Acetamiprid can kill effectively to organochlorine class, organic phosphates, carbamates and pyrethroid
Generate the sanitary insect pest of resistance.
Arprocarb belongs to carbamate insecticides, inhibits acetylcholine in insect nerve center and peripheral nervous system
The activity of enzyme, have tag, stomach poison function, speed is fast, the lasting period is long is knocked down to pest.The effective component is answered in the form of bait formulation
For the prevention and treatment of fly, cockroach and ant, field application is quick, and will not generate residual and pollution to environment.
The effective component of overwhelming majority fly bait and cockroach bait formulation is all using single dose at present, and the mechanism of action is single, for a long time
Using metabolic resistance and target site mutation is also easy to produce, lead to field application prevention and treatment failure.It can compared with single dose using mixture
Resistant insect is effectively prevented, the generation and development of drug resistance are delayed.
Summary of the invention
For the problems of the prior art, the present invention provides a kind of hygienic biocide composition, and effect is good, toxicity is low.
To achieve the above object, the present invention adopts the following technical scheme that.
A kind of hygienic biocide composition, effective component are arprocarb and Acetamiprid；The quality of the arprocarb and Acetamiprid
Than for 10:1-1:10；Preferably 2:1-1:4.
The content of the effective component in the composition is 0.01-5wt %, preferably 0.5-2 wt %.
The controlling object of the hygienic biocide composition is ant, blattaria and flies.Such as, monomorium pharaonisMonomorium pharaonis, Groton bugBlattella germanica, American cockroachPeriplaneta americana, houseflyMusca domestica, lucilia sericataLucilia sericata, chrysomyia megacephalaChrysomya megacephala。
The dosage form of the hygienic biocide composition is in stock solution, thermal fog, aerosol, bait formulation or pulvis
It is any；Preferably bait formulation.
A kind of bait formulation containing above-mentioned hygienic biocide composition.The matrix of the bait formulation, the raw material including following parts by weight
It is made:
It 400-430 parts of carbomer gel, 5-15 parts of sodium alginate, 0.5-10.5 parts of calcium chloride, 240-250 parts of sorbierite, lures
15-20 parts of agent, 1-10 parts of preservative, 25-30 parts of isopropanol, 20-30 parts of ethyl alcohol, 50-60 parts of water.
The carbomer model 940 or 941.The concentration of the carbomer gel is 0.5-2%.
The viscosity of the sodium alginate is 300-500mPa.s, and M/G ratio is 2.5-3.2.
The mass ratio of the sodium alginate and calcium chloride is 10:1-1.4.
The attractant can be carbohydrate, animal and plant fat or essence.The preservative is antimycotic, bacterium fungicide
Or antioxidant.
The invention has the following advantages that
Bait formulation of the present invention uses the effective component of two kinds of different chemical structures, and the target site and enzyme of effect are different, with
Suitable proportion mixing, function and effect notable synergistic compared with single dose can effectively prevent resistant insect, delay the generation of drug resistance
With development；And can be avoided skin irritation caused by pyrethroids class medicament, it is highly-safe.Bait formulation matrix provided by the invention,
Viscosity and hardness are suitble to, can be suitable for squash type product；Moistening effect is good, for a long time place it is not mouldy, will not be stiff, energy
It is enough to increase application interval, it can be widely applied in various bait formulation preparations.
Specific embodiment
Below with reference to embodiment, the present invention will be further described, but the present invention is not limited by the following examples.
1 arprocarb of embodiment and Acetamiprid to housefly (Musca domestica) joint toxicity measuring
1. the malicious feed preparation of band
Weigh arprocarb (95%TC), Acetamiprid (96%TC) according to different quality than be configured to 0.1% acetone mother liquor, wherein containing
0.1% Tween-80；Then it is configured to the dilution of series of concentrations with 1% hydromel, is added drop-wise to rayon balls up to saturation, as
Test bait formulation.
2. testing equipment
Square box device, 70cm × 70cm × 70cm；
Culture dish (internal diameter 9cm).
3. test procedure
" the 7th part of agriculture chemical registration hygienic insecticide indoor pharmacodynamic test and evaluation: bait formulation (GB/T according to national standards
Related request 13917.7-2009) " carries out test, all tests the metastable space of temperature and humidity [temperature: (26 ±
1) it DEG C, relative humidity: 60% ± 10%] carries out.Test uses square box device, and test bait formulation is placed in central location in square chest, so
It is put into afterwards 50 emergence 3-4 days adult flies (female: hero=1:1), test checks test worm death toll afterwards for 24 hours, calculates the death rate.Every kind
Medicament or compounding set 5 series of concentrations, and each concentration sets 3 repetitions, and setting up immersion cotton balls is blank control test.
4. data processing
As a result the Probit program analytical calculation LC of 20.0 software of SPSS is used50Value, and calculate two kinds of drug combination virulence
CTC.The results are shown in Table 1:
The co-toxicity of 1 arprocarb of table and Acetamiprid to housefly
From the data in table 1, it can be seen that the mass ratio of arprocarb and Acetamiprid is in 4:1-1:10, to the CTC of housefly 120 or more,
There is apparent synergistic effect.
2 arprocarb of embodiment and Acetamiprid to American cockroach (Periplaneta americana) joint toxicity measuring
1. prepared by poison bait
Weigh arprocarb (95%TC), Acetamiprid (96%TC) according to different quality than be configured to 0.1% acetone mother liquor, with acetone
It is diluted to the dilution of series of concentrations, uniform stirring after the dilution of various concentration is added in man-made feeds (crumbs), to
Acetone is used as test bait formulation after volatilizing naturally.
2. testing equipment
Square box device, 70cm × 70cm × 70cm；
Culture dish (internal diameter 9cm).
3. test procedure
" the 7th part of agriculture chemical registration hygienic insecticide indoor pharmacodynamic test and evaluation: bait formulation (GB/T according to national standards
Related request 13917.7-2009) " carries out test, all tests the metastable space of temperature and humidity [temperature: (26 ±
1) it DEG C, relative humidity: 60% ± 10%] carries out.Test use square box device, by the American cockroach of 30-15 ages in days of 10 age in days at
Worm (every kind female: hero=1:1) is put into the square box device for being turned off door by putting worm channel, is stoppered and is put worm channel, restores normal living to test worm
After dynamic, test bait formulation is placed in central location in square chest, while placing and filling immersion cotton balls culture dish, and it is dead to observe test worm day by day
Situation simultaneously takes out dead worm in time, the 12nd day after being observed continuously to bait throwing in, records test worm death toll, calculates the death rate.Every kind of medicament
Or compounding sets 5 series of concentrations, each concentration sets 3 reprocessings, and the crumbs for setting up not dosing are tried as blank control
It tests.
4. data processing
Bioassay results use the Probit program analytical calculation LC of 20.0 software of SPSS50Value, and calculate two kinds of medicament connection
Close the CTC of virulence.The results are shown in Table 2:
The co-toxicity of 2 arprocarb of table and Acetamiprid to American cockroach
From the data in table 2, it can be seen that the mass ratio of arprocarb and Acetamiprid is in 10:1-1:10, to the CTC of American cockroach 120
More than, there is synergistic effect.For the especially mass ratio of the two in 1:1-1:4, CTC has stronger synergy to make about 200
With.
3 arprocarb of embodiment and Acetamiprid to monomorium pharaonis (Monomorium pharaonis) joint toxicity measuring
1. prepared by poison bait
Weigh arprocarb (95%TC), Acetamiprid (96%TC) according to different quality than be configured to 0.1% acetone mother liquor, with acetone
It is diluted to the dilution of series of concentrations, uniform stirring after the dilution of various concentration is added in man-made feeds (crumbs), to
Acetone is used as test bait formulation after volatilizing naturally.
2. testing equipment
Enamel square tray (white, 40cm × 30cm × 40cm).
3. test procedure
" the 7th part of agriculture chemical registration hygienic insecticide indoor pharmacodynamic test and evaluation: bait formulation (GB/T according to national standards
Related request 13917.7-2009) " carries out test, all tests the metastable space of temperature and humidity [temperature: (26 ±
1) it DEG C, relative humidity: 60% ± 10%] carries out.Test uses enamel square tray, applies all scholars of circle in the inner wall edge of enamel square tray mouth
Forest belt is put into the above monomorium pharaonis worker ant of 3 ages in days 100, after it restores normal activity, places in enamel square tray central location
Bait formulation is tested, observe test worm death condition day by day and takes out dead worm in time, the 7th day after being observed continuously to bait throwing in, record test worm is dead
Number is died, the death rate is calculated.Every kind of medicament or compounding set 5 series of concentrations, and each concentration is set to be reprocessed three times, and sets up blank
Check experiment.
4. data processing
As a result the Probit program analytical calculation LC of 20.0 software of SPSS is used50Value, and calculate two kinds of drug combination virulence
CTC.The results are shown in Table 3:
The co-toxicity of 3 arprocarb of table and Acetamiprid to small Paederus densipennis Bernh
From the data in table 3, it can be seen that the mass ratio of arprocarb and Acetamiprid is in 10:1-1:10, to the CTC of small Paederus densipennis Bernh 120
More than, there is synergistic effect.Especially for the mass ratio of the two in 2:1-1:4, for CTC 200 or more, synergistic effect is significant.
The preparation of 4 bait formulation matrix of embodiment
1. bait formulation is prepared according to the following steps:
(1) it weighs 4g Carbomer-940 and the dissolution of 400mL water is added, 8mL 10%NaOH is then added and stirs gelled carbomer；
(2) sorbierite 240g, butter essence 20g, sodium benzoate 10g is weighed isopropanol 28g and ethyl alcohol 24g is added and is uniformly mixed
Afterwards, the carbomer gel of step (1) is added, mixes to and is completely dissolved；
(3) 5g sodium alginate (350-410mPa.s, M/G=3) are weighed to be added in 40g water, are heated to 80 DEG C, stirring is delayed to dissolving
It is slow that 5% calcium chloride solution of 10mL is added dropwise, keep the temperature simultaneously quickly stirring to obtain mixed liquor；
(4) mixed liquor of step (3) is added in the gel of step (2) and obtains glue bait matrix S1 after mixing evenly.
Different component is weighed according to material rate described in step (1)-(4), prepares glue bait matrix according to the method described above
S2, difference are the M/G value of the sodium alginate used for 1.2.
Glue bait matrix S3 is prepared according to material rate described in step (1)-(4) and method, difference is in step (3)
The concentration of calcium chloride solution is 10%, additional amount 20mL.
2. compression properties
Above-mentioned matrix is sub-packed in 5mL syringe, 5g in each syringe, after standing for 24 hours, pushes cylinder piston to release a certain amount of
Matrix, observe substrate status: S1 is uniform spherical gel；The matrix of S2 is harder crisp, squeezes out fragmentation；The matrix of S3 squeezes tired
Difficulty is condensed into syringe than more complete g., jelly-like gel.This explanation only has the M/G value of suitable sodium alginate and suitable
Sodium alginate: calcium chloride mass ratio can make matrix have preferable viscosity and hardness, be suitable for squash type product.
3. water retention property
Above-mentioned matrix is sub-packed in Trapping box, every box 2g is placed in 25 DEG C, the environment of 50% relative humidity, observation it is weightless and
Hardened condition, each 5 box of sample, the results are shown in Table 4 for weight-loss ratio:
4 different substrates weight-loss ratio of table compares (mean+SD)
Same column difference letter represents p < 0.05(Duncan inspection).
From the data in table 4, it can be seen that in addition to placing 30 days S2 percentages of water loss and being higher than other two sample, three samples of remaining observation point
Weight-loss ratio have no significant difference.But when off-test, sample S2 and sample S3 are stiff, very tired with tweezers separation fritter
Difficulty is no longer appropriate for pests；And sample S1 is relatively soft, remains to enough tweezers clampings, explanation can be by pests.Thus may be used
Know, matrix formulations of the invention not only have good retentiveness, and can keep palatability for a long time, take suitable for pest
Food.
The preparation of 5 glue bait of embodiment
After 96% raw medicine of 5.21g Acetamiprid and 95% raw medicine of 10.53g arprocarb are weighed with a small amount of acetone solution, 10% tween-is added
80 solution are configured to the lotion of 200g, and the matrix S1 in 800g step embodiment 4 is added, stands, obtains after high-speed stirred 30min
Obtain 1.5% arprocarb Acetamiprid (1:2) glue bait.According to above-mentioned steps preparation 2% arprocarb Acetamiprid (1:2) glue bait,
0.03% arprocarb Acetamiprid (1:1) glue bait and 5% arprocarb Acetamiprid (1:4) glue bait.
It weighs each glue bait of 2.5g gel and is placed in 25 DEG C, placed in the environment of 50% relative humidity, observe dehydration and hardening shape
Condition, until each gel is without mildew and fully hardened phenomenon, and effective component 0.03%-5% is without medicament after test when off-test in 90 days
Phenomena such as precipitation, illustrates that the glue bait of preparation is qualified.
6 arprocarb Acetamiprid glue bait field experiment of embodiment
1. housefly
Bait formulation is carried out to housefly referring to WS/T 576-2017 " measurement of hygienic insecticide field efficacy and evaluation fly eradication bait formulation "
Field efficacy evaluation: it selects 4 restaurant units of housefly similar density as testing ground, tests and do not used in the last week
Insecticide fly eradication, Fly density are greater than 10/m2, wherein 2 families are test group, 1 family is that (1.5% arprocarb kills fly bait to comparison medicament group
Agent, registration card number WP20170005), 1 family is blank control group, is repeated 3 times in Different field.According to 5g/10m2Preparation use
Fly eradication bait formulation is placed in culture dish by dose, every 10m2If one group, being equidistantly placed in testing ground, check plot is not administered.It surveys
Surely bait formulation 4h and live Fly density rear for 24 hours are laid, calculates Relative density decline rate (%) according to the following formula:
Rd=(1-) × 100(%)
In formula:R d —Relative density decline rate；
T a Average density value after the processing of-applying area；
T b Average density value before-applying area is handled；
C a Average density value after the processing of-blank district；
C b Average density value before the processing of-blank district.
5 1.5% arprocarb Acetamiprid glue bait of table kills housefly field experiment
Referring to WS/T 576-2017 standard, 4h housefly Relative density decline rate is greater than 75% after two kinds of medicament applications, after application for 24 hours
Housefly Relative density decline rate is greater than 85%, and effect of killing flies is qualified.According to 5 data of table it is found that 1.5% cannibalisation prepared by the present invention
Prestige Acetamiprid glue bait 4h and is significantly better than comparison medicament to the killing effect of housefly for 24 hours after medicine.
2. blattaria
Bait formulation pair is carried out with reference to GB/T 27783-2011 " malicious (glue) bait of roach is killed in the measurement of hygienic insecticide field efficacy and evaluation "
The field efficacy of blattaria is evaluated: selecting cockroach to encroach on serious, similar density 4 restaurant units as testing ground, area is equal
About 100m2, Groton bug density is greater than 10/, wherein 2 families are test group, 1 family is comparison medicament group (2.15% imidacloprid
Cockroach-killing gel bait, registration card number WP20080052), 1 family is blank control group, is uniformly laid on cockroach and multiplies habitat, is tested
Group preparation dosage is 0.1g/ m2, comparison medicament group preparation dosage is 0.3g/m2, blank district not medication, in application 3
It, 7 days, 14 days, after 30 days, measure trial zone and blank district cockroach density respectively, calculated under relative density according to following formula
Drop rate (%):
Rd=(1-) × 100(%)
In formula:R d —Relative density decline rate；
T a Average density value after the processing of-applying area；
T b Average density value before-applying area is handled；
C a Average density value after the processing of-blank district；
C b Average density value before the processing of-blank district.
6 2% arprocarb Acetamiprid glue bait of table kills blattaria field experiment
With reference to the standard in GB/T 27783-2011, two medicaments 30 days after administration, the Relative density decline rate of blattaria was greater than
80% or more, significant effect.From the data in table 6, it can be seen that 2% arprocarb Acetamiprid glue bait prepared by the present invention is 3 days after medicine, 7 days,
Comparison medicament was significantly better than to the killing effect of blattaria in 14 days, 30 days.
3. small Paederus densipennis Bernh
The 4 family residential buildings for selecting monomorium pharaonis to endanger are as testing ground.Wherein 2 families are test group, and 1 family is comparison medicament
Group (0.03% imidacloprid kills ant glue bait, registration card number WP20120237), 1 family are blank control group.Test group preparation dosage is
0.1g/m2, comparison medicament group preparation dosage is 0.2g/m2, check plot not medication, after laying before poison bait 1 day and laying poison bait
3rd day, 7 days, 3 points of observation are selected on 14 roads Tian Junyi, and lay a small amount of biscuit on point of observation and make bait, lay bait
The ant number on bait is observed after 30 min, as density index, calculates Relative density decline rate (%) according to following formula:
Rd=(1-) × 100(%)
In formula:R d —Relative density decline rate；
T a Average density value after the processing of-applying area；
T b Average density value before-applying area is handled；
C a Average density value after the processing of-blank district；
C b Average density value before the processing of-blank district.
7 0.03% arprocarb Acetamiprid glue bait of table kills small Paederus densipennis Bernh field experiment
From the data in table 7, it can be seen that two medicaments 7 days after administration, the Relative density decline rate of small Paederus densipennis Bernh is greater than 85%, significant effect.
And 14 days preventive effects decline after comparison medicament application, needing to offer medicine again keeps preferable killing effect.And it is prepared by the present invention
0.03% arprocarb Acetamiprid glue bait 3 days after medicine, 7 days, it is 14 days higher always to the killing effect of small Paederus densipennis Bernh, at least can
Enough keep being not required to offer medicine again for 14 days.
According to the data of table 5-7 it is found that hygienic biocide composition of the invention can effectively kill housefly, cockroach and ant
Pest density is effectively reduced in ant, and dosage is few, the lasting period is long.
Claims (10)
1. a kind of hygienic biocide composition, which is characterized in that effective component is arprocarb and Acetamiprid；The arprocarb and pyridine worm
The mass ratio of amidine is 10:1-1:10.
2. hygienic biocide composition according to claim 1, which is characterized in that the mass ratio of the arprocarb and Acetamiprid
For 2:1-1:4.
3. hygienic biocide composition according to claim 1, which is characterized in that the effective component is in the composition
Content is 0.01-5wt%；Preferably 0.5-2 wt%.
4. hygienic biocide composition according to claim 1, which is characterized in that the dosage form of the hygienic biocide composition is selected
It is any in self-injection agent, aerosol, bait formulation or pulvis；Preferably bait formulation.
5. hygienic biocide composition according to claim 1 to 4, which is characterized in that the hygienic biocide composition
Controlling object is ant, blattaria and flies.
6. a kind of hygienic biocide bait formulation matrix, which is characterized in that the raw material including following parts by weight is made: carbomer gel
400-430 parts, 5-15 parts of sodium alginate, 1.4-2 parts of calcium chloride, 240-250 parts of sorbierite, 15-20 parts of attractant, preservative 1-
10 parts, 25-30 parts of isopropanol, 20-30 parts of ethyl alcohol, 50-70 parts of water.
7. bait formulation matrix according to claim 6, which is characterized in that carbomer model 940 or 941；The carbomer
The concentration of gel is 0.5-2%.
8. bait formulation matrix according to claim 6, which is characterized in that the viscosity of the sodium alginate is 300-
500mPa.s, M/G ratio are 2.5-3.2.
9. bait formulation matrix according to claim 6, which is characterized in that the mass ratio of the sodium alginate and calcium chloride is
10:1-1.4。
10. bait formulation matrix according to claim 6, which is characterized in that the attractant be selected from carbohydrate, animal and plant fat or
Essence；The preservative is antimycotic, bacterium fungicide or antioxidant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910762533.6A CN110447655B (en) | 2019-08-19 | 2019-08-19 | Sanitary insecticidal composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910762533.6A CN110447655B (en) | 2019-08-19 | 2019-08-19 | Sanitary insecticidal composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN110447655A true CN110447655A (en) | 2019-11-15 |
| CN110447655B CN110447655B (en) | 2021-04-20 |
Family
ID=68487420
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910762533.6A Active CN110447655B (en) | 2019-08-19 | 2019-08-19 | Sanitary insecticidal composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110447655B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1265269A (en) * | 1999-09-21 | 2000-09-06 | 马越 | Bendiocarb-fenpropathrin pesticide composition |
| CN1457637A (en) * | 2002-05-16 | 2003-11-26 | 李晔 | Contact killing type insecticide paste |
| CN109221227A (en) * | 2018-10-21 | 2019-01-18 | 江苏长青生物科技有限公司 | It is a kind of efficiently to kill cockroach gel bait formulation and preparation method thereof |
-
2019
- 2019-08-19 CN CN201910762533.6A patent/CN110447655B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1265269A (en) * | 1999-09-21 | 2000-09-06 | 马越 | Bendiocarb-fenpropathrin pesticide composition |
| CN1457637A (en) * | 2002-05-16 | 2003-11-26 | 李晔 | Contact killing type insecticide paste |
| CN109221227A (en) * | 2018-10-21 | 2019-01-18 | 江苏长青生物科技有限公司 | It is a kind of efficiently to kill cockroach gel bait formulation and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 罗梁锋: ""开发海藻酸水凝胶饵剂管理蚂蚁"", 《世界农药》 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN110447655B (en) | 2021-04-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102113516B (en) | Insect killing compound containing chlorantraniliprole | |
| CN111226955B (en) | Insecticidal and acaricidal composition containing macrolide insect/acarid | |
| CN103907634A (en) | Insect disinfestation composition containing tetrachlorantraniliprole and pyrethroid | |
| CN105724389A (en) | Dispersible oil suspension containing chlorantraniliprole | |
| CN101564038A (en) | Insecticidal composition containing metaflumizone | |
| CN111657281B (en) | Insecticidal and acaricidal composition | |
| CN105410013A (en) | Insecticide-pesticide mixture preparation | |
| CN102379308A (en) | Mixed insecticidal composition containing clothianidin and application of mixed insecticidal composition | |
| CN102007944B (en) | Plant source synergistic compound aphicide and acaricide containing rotenone and preparation method thereof | |
| CN110447655A (en) | A kind of hygienic biocide composition | |
| CN111296478A (en) | Boric acid-containing insecticidal composition and application thereof | |
| CN105557758A (en) | Locust micro-microsporidia spore water suspension and preparation method thereof | |
| CN112704070B (en) | Insecticidal and acaricidal composition containing pyrethroid insecticides/acaricides | |
| RU2628936C1 (en) | Method for fighting flies | |
| CN104996435B (en) | Insect disinfestation composition containing 9080TM and etoxazole, and uses thereof | |
| CN103931649A (en) | Insecticidal composition containing emamectin benzoate and chlorempenthrin | |
| CN105994336B (en) | A kind of Pesticidal combination | |
| CN107136078A (en) | Pesticidal combination containing chlorine fluorine cyanogen insect amide and thiocyclam | |
| CN104322560B (en) | Pesticide synergistic compositions containing Diacloden Yu humic acids | |
| CN105941423A (en) | Insecticide composition containing chlorfenapyr and cyromazine | |
| CN107494585A (en) | A kind of Pesticidal combination containing effective cypermethrin and Rynaxypyr | |
| CN107836460A (en) | A kind of Pesticidal combination and its application containing cartap and imidacloprid | |
| CN106212495A (en) | Composition pesticide and its preparation method and application | |
| CN101584343A (en) | Metaflumizone and chlorpyrifos mixture insecticide | |
| CN106577660B (en) | A kind of Pesticidal combination containing propylene glycol alginate and chlorine fluorine cyanogen insect amide |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |