CN110433767A - 一种陶质除磷颗粒滤料及其制备方法 - Google Patents

一种陶质除磷颗粒滤料及其制备方法 Download PDF

Info

Publication number
CN110433767A
CN110433767A CN201910818158.2A CN201910818158A CN110433767A CN 110433767 A CN110433767 A CN 110433767A CN 201910818158 A CN201910818158 A CN 201910818158A CN 110433767 A CN110433767 A CN 110433767A
Authority
CN
China
Prior art keywords
parts
filter material
ceramic
granule filter
green body
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910818158.2A
Other languages
English (en)
Inventor
汪智杰
杨伟煜
王光荣
严传洪
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hangzhou Qinlin Ecological Technology Co Ltd
Original Assignee
Hangzhou Qinlin Ecological Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hangzhou Qinlin Ecological Technology Co Ltd filed Critical Hangzhou Qinlin Ecological Technology Co Ltd
Priority to CN201910818158.2A priority Critical patent/CN110433767A/zh
Publication of CN110433767A publication Critical patent/CN110433767A/zh
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D39/00—Filtering material for liquid or gaseous fluids
    • B01D39/02—Loose filtering material, e.g. loose fibres
    • B01D39/06—Inorganic material, e.g. asbestos fibres, glass beads or fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0225—Compounds of Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt
    • B01J20/0229—Compounds of Fe
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0248—Compounds of B, Al, Ga, In, Tl
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/041—Oxides or hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/103—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/12—Naturally occurring clays or bleaching earth
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/04—Clay; Kaolin
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
    • C04B35/6303—Inorganic additives
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/06—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances
    • C04B38/063—Preparing or treating the raw materials individually or as batches
    • C04B38/0635—Compounding ingredients
    • C04B38/0645—Burnable, meltable, sublimable materials
    • C04B38/0665—Waste material; Refuse other than vegetable refuse
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/10—Filtering material manufacturing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/48—Sorbents characterised by the starting material used for their preparation
    • B01J2220/4806—Sorbents characterised by the starting material used for their preparation the starting material being of inorganic character
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/48—Sorbents characterised by the starting material used for their preparation
    • B01J2220/4875—Sorbents characterised by the starting material used for their preparation the starting material being a waste, residue or of undefined composition
    • B01J2220/4887—Residues, wastes, e.g. garbage, municipal or industrial sludges, compost, animal manure; fly-ashes
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/105—Phosphorus compounds
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
    • C04B2235/602—Making the green bodies or pre-forms by moulding
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
    • C04B2235/606—Drying
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6562—Heating rate
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6567—Treatment time
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/95—Products characterised by their size, e.g. microceramics

Abstract

本发明公开了一种陶质除磷颗粒滤料及其制备方法，属于颗粒滤料制备技术领域，一种陶质除磷颗粒滤料，其各组分的质量份数配比为：黏土60‑70份，化学污泥5‑10份，粉煤灰5‑10份，磁铁矿粉10‑15份，水5‑10份。陶质除磷颗粒滤料的制备方法，包括如下步骤：S1:分别称取60‑70份黏土、5‑10份化学污泥、5‑10份粉煤灰、以及10‑15份磁铁矿粉，并加入5‑10份水进行混合搅匀，S2:将搅匀的混合料送入坯模压实塑形，S3:取出塑形后的坯体，自然风干，S4:将风干后坯体放入窑中烧结，S5:取出烧结形成的坯体，对坯体进行破碎，形成具有不规则表面的颗粒滤料，并进行筛分。本发明制备方法制成的陶质除磷颗粒滤料具有不规则表面，比表面积大，除磷效果好。

Description

一种陶质除磷颗粒滤料及其制备方法
技术领域
本发明属于颗粒滤料制备技术领域，尤其涉及一种陶质除磷颗粒滤料及其制备方法。
背景技术
水体中磷的去除主要有化学除磷、生物除磷和吸附除磷几种方式，其中吸附除磷是利用吸附剂提供的大比表面积、通过磷在吸附剂表面的附着吸附、离子交换或表面沉淀的过程，实现磷的分离。常见的除磷滤料包括天然材料、工业废渣、以及改性材料等。但是上述滤料的吸附量有限。
随着科技的发展和人们研究的深入，陶质滤料在污水处理中的应用得到重视。为了增加陶质滤料的吸附能力，在制备陶质滤料时会采用各种方法进行加工，但是目前达到的效果仍然达不到人们的预期。
滤料的比表面积越大，处理效果更好，现有的陶质除磷颗粒滤料通常为球状颗粒，比表面积小，吸附量少，且除磷效果不理想。
发明内容
为了克服现有技术的缺陷，本发明所要解决的技术问题在于提出一种陶质除磷颗粒滤料及其制备方法，颗粒滤料具有不规则表面，比表面积大，除磷效果好。
为达此目的，本发明采用以下技术方案：
本发明提供的一种陶质除磷颗粒滤料，其各组分的质量份数配比为：黏土60-70份，化学污泥5-10份，粉煤灰5-10份，磁铁矿粉10-15份，水5-10份，化学污泥为污水厂的化学污泥，它含有除磷盐类（铁铝盐），不但废物回用，而且增加有效除磷成分。
优选地，陶质除磷颗粒滤料的粒径为5mm-13mm。
本发明还提供如上述的陶质除磷颗粒滤料的制备方法，包括如下步骤：S1:分别称取60-70份黏土、5-10份化学污泥、5-10份粉煤灰、以及10-15份磁铁矿粉，并加入5-10份水进行混合搅匀，S2:将搅匀的混合料送入坯模压实塑形，S3:取出塑形后的坯体，自然风干，S4:将风干后坯体放入窑中烧结，S5:取出烧结形成的坯体，坯体具有大量细小气孔，一部分细小气孔暴露在坯体外部，另一部分细小气孔位于坯体内部，坯体具有大量细小气孔，对坯体进行破碎，形成具有不规则表面的颗粒滤料，并进行筛分。
优选地，步骤S4中，烧结的升温速率为2-4℃/min。
优选地，步骤S4中，当窑中温度升温至1000-1100℃后，维持当前温度继续烧结6-8h，然后降至室温。
优选地，步骤S5中，筛分的粒径为5mm-13mm。
优选地，步骤S5中，采用颚式破碎机对坯体进行破碎，将大量位于坯体内部的封闭的细小气孔暴露在外。
优选地，细小气孔的孔径为0.08-0.5mm。
本发明的有益效果为：
1、利用化学污泥作为原料，变废为宝，并结合粉煤灰和磁铁矿粉，通过合理控制各组分的配比，制成的颗粒滤料具有良好的除磷效果。
2、在烧结完毕后进行破碎处理，形成具有不规则表面的颗粒滤料，同时将大量封闭在坯体内的细小气孔暴露在外，大大提高比表面积，提高吸附量，进而提高除磷处理效果。
3、采用的原料成本低，制备成本低，具有良好的经济效益。
具体实施方式
现通过具体实施方式对本发明进一步说明。
实施例一：
本实施例中提供的一种陶质除磷颗粒滤料，其各组分的质量份数配比为：黏土60份，化学污泥6份，粉煤灰6份，磁铁矿粉10份，水7份，制成的陶质除磷颗粒滤料的粒径为5mm。
本实施例还提供如上述的陶质除磷颗粒滤料的制备方法，包括如下步骤：
S1:分别称取60份黏土、6份化学污泥、6份粉煤灰、以及10份磁铁矿粉，并加入7份水进行混合搅匀；
S2:将搅匀的混合料送入坯模压实塑形；
S3:取出塑形后的坯体，自然风干；
S4:将风干后坯体放入窑中烧结，以2℃/min的速率进行升温，当窑中温度升温至1000℃后，维持当前温度继续烧结6h，然后降至室温；
S5:取出烧结形成的坯体，坯体具有大量细小气孔，细小气孔的孔径为0.1mm，采用颚式破碎机对坯体进行破碎，形成具有不规则表面的颗粒滤料，将大量位于坯体内部的封闭的细小气孔暴露在外，并进行筛分，筛分的粒径为5mm，形成的颗粒滤料的孔隙率为47%，比表面积为1250m2/g，除磷率为82.2％。
实施例二：
本实施例中提供的一种陶质除磷颗粒滤料，其各组分的质量份数配比为：黏土63份，化学污泥7，粉煤灰7份，磁铁矿粉12份，水8份，制成的陶质除磷颗粒滤料的粒径为6mm。
本实施例还提供如上述的陶质除磷颗粒滤料的制备方法，包括如下步骤：
S1:分别称取63份黏土、7份化学污泥、7份粉煤灰、以及12份磁铁矿粉，并加入8份水进行混合搅匀；
S2:将搅匀的混合料送入坯模压实塑形；
S3:取出塑形后的坯体，自然风干；
S4:将风干后坯体放入窑中烧结，以3℃/min的速率进行升温，当窑中温度升温至1050℃后，维持当前温度继续烧结7h，然后降至室温；
S5:取出烧结形成的坯体，坯体具有大量细小气孔，细小气孔的孔径为0.18mm，采用颚式破碎机对坯体进行破碎，形成具有不规则表面的颗粒滤料，将大量位于坯体内部的封闭的细小气孔暴露在外，并进行筛分，筛分的粒径为6mm，形成的颗粒滤料的孔隙率为45%，比表面积为1100m2/g，除磷率为77.4％。
实施例三：
本实施例中提供的一种陶质除磷颗粒滤料，其各组分的质量份数配比为：黏土68份，化学污泥9，粉煤灰9份，磁铁矿粉14份，水9份，制成的陶质除磷颗粒滤料的粒径为10mm。
本实施例还提供如上述的陶质除磷颗粒滤料的制备方法，包括如下步骤：
S1:分别称取68份黏土、9份化学污泥、9份粉煤灰、以及14份磁铁矿粉，并加入9份水进行混合搅匀；
S2:将搅匀的混合料送入坯模压实塑形；
S3:取出塑形后的坯体，自然风干；
S4:将风干后坯体放入窑中烧结，以4℃/min的速率进行升温，当窑中温度升温至1100℃后，维持当前温度继续烧结8h，然后降至室温；
S5:取出烧结形成的坯体，坯体具有大量细小气孔，细小气孔的孔径为0.25mm，采用颚式破碎机对坯体进行破碎，形成具有不规则表面的颗粒滤料，将大量位于坯体内部的封闭的细小气孔暴露在外，并进行筛分，筛分的粒径为10mm，形成的颗粒滤料的孔隙率为42%，比表面积为1000m2/g，除磷率为74.1％。
本说明书中未作详细描述的内容属于本领域专业技术人员公知的现有技术；以上实施例仅用以说明本发明的技术方案，而非对其限制；尽管参照前述实施例对本发明进行了详细的说明，本领域的普通技术人员应当理解；其依然可以对前述各实施例所记载的技术方案进行修改，或者对其中部分技术特征进行等同替换；而这些修改或者替换，并不使相应技术方案的本质脱离本发明各实施例技术方案的精神和范围。

Claims (8)

1.一种陶质除磷颗粒滤料，其特征在于：
其各组分的质量份数配比为：
黏土60-70份；
化学污泥5-10份；
粉煤灰5-10份；
磁铁矿粉10-15份；
水5-10份。
2.根据权利要求1所述的陶质除磷颗粒滤料，其特征在于：
所述陶质除磷颗粒滤料的粒径为5mm-13mm。
3.如权利要求2所述的陶质除磷颗粒滤料的制备方法，其特征在于，包括如下步骤：
S1:分别称取60-70份黏土、5-10份化学污泥、5-10份粉煤灰、以及10-15份磁铁矿粉，并加入5-10份水进行混合搅匀；
S2:将搅匀的混合料送入坯模压实塑形；
S3:取出塑形后的坯体，自然风干；
S4:将风干后坯体放入窑中烧结；
S5:取出烧结形成的坯体，坯体具有大量细小气孔，对坯体进行破碎，形成具有不规则表面的颗粒滤料，并进行筛分。
4.根据权利要求3所述的陶质除磷颗粒滤料的制备方法，其特征在于：
所述步骤S4中，烧结的升温速率为2-4℃/min。
5.根据权利要求3所述的陶质除磷颗粒滤料的制备方法，其特征在于：
所述步骤S4中，当窑中温度升温至1000-1100℃后，维持当前温度继续烧结6-8h，然后降至室温。
6.根据权利要求3所述的陶质除磷颗粒滤料的制备方法，其特征在于：
所述步骤S5中，筛分的粒径为5mm-13mm。
7.根据权利要求3所述的陶质除磷颗粒滤料的制备方法，其特征在于：
所述步骤S5中，采用颚式破碎机对坯体进行破碎，将大量位于坯体内部的封闭的细小气孔暴露在外。
8.根据权利要求3所述的陶质除磷颗粒滤料的制备方法，其特征在于：
细小气孔的孔径为0.08-0.5mm。
CN201910818158.2A 2019-08-30 2019-08-30 一种陶质除磷颗粒滤料及其制备方法 Pending CN110433767A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910818158.2A CN110433767A (zh) 2019-08-30 2019-08-30 一种陶质除磷颗粒滤料及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910818158.2A CN110433767A (zh) 2019-08-30 2019-08-30 一种陶质除磷颗粒滤料及其制备方法

Publications (1)

Publication Number Publication Date
CN110433767A true CN110433767A (zh) 2019-11-12

Family

ID=68438669

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910818158.2A Pending CN110433767A (zh) 2019-08-30 2019-08-30 一种陶质除磷颗粒滤料及其制备方法

Country Status (1)

Country Link
CN (1) CN110433767A (zh)

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1876580A (zh) * 2006-05-25 2006-12-13 甘肃金桥给水排水设计与工程有限公司 高效生物滤料及其制备方法
CN101293768A (zh) * 2008-06-20 2008-10-29 广州市金龙峰环保设备工程有限公司 一种生物滤料及其制备方法
CN101913898A (zh) * 2010-07-07 2010-12-15 苏州浩波科技股份有限公司 利用安赛蜜生产中的废石膏制造水处理陶粒滤料的工艺
CN102225806A (zh) * 2011-05-24 2011-10-26 合肥工业大学 一种磁性生物载体及其制备方法
CN103570373A (zh) * 2012-08-03 2014-02-12 河南美赛克科技有限公司 一种用于制造滤料陶粒的组合物及滤料陶粒制造方法
CN104163617A (zh) * 2014-07-14 2014-11-26 深圳市环境科学研究院 一种陶粒生产方法及陶粒和陶粒的应用
CN105036709A (zh) * 2015-08-05 2015-11-11 辽宁工业大学 一种利用污水污泥、粉煤灰烧轻质电气石陶粒的制备方法
CN105130491A (zh) * 2015-07-24 2015-12-09 浙江方远建材科技有限公司 一种高吸附性陶粒及其制备方法
CN105753505A (zh) * 2016-02-24 2016-07-13 湖南永清环保研究院有限责任公司 一种多孔陶粒载体及其制备方法
CN106673690A (zh) * 2017-01-20 2017-05-17 李春刚 一种磁铁矿或钒钛磁铁矿尾矿砂膨胀陶粒及其制备方法

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1876580A (zh) * 2006-05-25 2006-12-13 甘肃金桥给水排水设计与工程有限公司 高效生物滤料及其制备方法
CN101293768A (zh) * 2008-06-20 2008-10-29 广州市金龙峰环保设备工程有限公司 一种生物滤料及其制备方法
CN101913898A (zh) * 2010-07-07 2010-12-15 苏州浩波科技股份有限公司 利用安赛蜜生产中的废石膏制造水处理陶粒滤料的工艺
CN102225806A (zh) * 2011-05-24 2011-10-26 合肥工业大学 一种磁性生物载体及其制备方法
CN103570373A (zh) * 2012-08-03 2014-02-12 河南美赛克科技有限公司 一种用于制造滤料陶粒的组合物及滤料陶粒制造方法
CN104163617A (zh) * 2014-07-14 2014-11-26 深圳市环境科学研究院 一种陶粒生产方法及陶粒和陶粒的应用
CN105130491A (zh) * 2015-07-24 2015-12-09 浙江方远建材科技有限公司 一种高吸附性陶粒及其制备方法
CN105036709A (zh) * 2015-08-05 2015-11-11 辽宁工业大学 一种利用污水污泥、粉煤灰烧轻质电气石陶粒的制备方法
CN105753505A (zh) * 2016-02-24 2016-07-13 湖南永清环保研究院有限责任公司 一种多孔陶粒载体及其制备方法
CN106673690A (zh) * 2017-01-20 2017-05-17 李春刚 一种磁铁矿或钒钛磁铁矿尾矿砂膨胀陶粒及其制备方法

Similar Documents

Publication Publication Date Title
CN103894407A (zh) 一种修复重金属污染土壤的方法
CN102718466B (zh) 一种多介质生物滤料及其制备方法
CN106824069B (zh) 用于处理含砷废水的稀土掺杂铁炭材料的制备方法
CN111848130A (zh) 一种高效除磷的改性陶粒及其制备方法
CN109772259A (zh) 利用电镀污泥处理电镀废水的方法和重金属离子吸附剂
CN105948706B (zh) 一种用作盆栽土壤填充物的污泥陶粒的制备方法及其用途
CN110252397A (zh) 一种生物炭基复合材料及其制备方法和应用
CN105107457B (zh) 一种无机粉体材料的制备方法与应用
CN113083236A (zh) 一种磁性MOFs-生物炭复合材料的制备方法及应用
CN102319557A (zh) 一种活性氧化铝/活性炭复合材料及其制备方法
JP2007283206A (ja) フィルター
CN106242603B (zh) 一种烧结承载体及其制作方法
CN110433767A (zh) 一种陶质除磷颗粒滤料及其制备方法
CN108191181A (zh) 一种城市河道淤泥净化剂及其生产方法
CN107903014A (zh) 一种无机‑有机复合多孔陶瓷滤料及其制备方法
CN107138059A (zh) 一种烟气处理设备用除尘膜及制备方法
CN106045058A (zh) 光催化生物吸附剂处理垃圾渗滤液的方法
CN111346619B (zh) 一种改性赤泥质滤料的制备方法及其对低温污水中氨氮的去除
CN111644159B (zh) 一种基于改性蛋壳的磁性吸附剂及其制备方法和应用
CN108636347A (zh) 一种利用硅藻泥制备污水处理吸附剂的方法
CN107522253A (zh) 一种铝改性赤泥滤料去除采油废水中聚丙烯酰胺的方法
CN107282012A (zh) 可处理废液中重金属的珍珠岩压缩营养土的生产方法
KR20030005987A (ko) 굴패각이 함유된 수처리용 세라믹 담체와 그 제조방법
CN110498659A (zh) 一种轻质除磷颗粒滤料及其制备方法
CN111790354A (zh) 一种硫基生物炭材料及其制备方法和应用

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
CB03 Change of inventor or designer information
CB03 Change of inventor or designer information

Inventor after: Wang Zhijie

Inventor after: Li Huabin

Inventor after: Xu Linge

Inventor after: Chen Fenfei

Inventor after: Yang Weiyu

Inventor after: Wang Guangrong

Inventor after: Yan Chuanhong

Inventor before: Wang Zhijie

Inventor before: Yang Weiyu

Inventor before: Wang Guangrong

Inventor before: Yan Chuanhong

RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20191112