CN110420139A - A kind of sun-proof maintenance cream of the high spf value containing precious Rogor and preparation method thereof - Google Patents
A kind of sun-proof maintenance cream of the high spf value containing precious Rogor and preparation method thereof Download PDFInfo
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- CN110420139A CN110420139A CN201910437458.6A CN201910437458A CN110420139A CN 110420139 A CN110420139 A CN 110420139A CN 201910437458 A CN201910437458 A CN 201910437458A CN 110420139 A CN110420139 A CN 110420139A
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- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
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- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
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Abstract
The present invention discloses a kind of sun-proof maintenance cream of high spf value containing precious Rogor, including Orangic sunscreen and water phase components, the Orangic sunscreen includes the material of following percent mass proportioning: ethylhexyl salicylate 3.5-4.5%, Phenylbenzimidazolesulfonic acid 2-4%, ethylhexyl methoxy cinnamate 8-9%, bis-ethylhexoxyphenol methoxyphenyl triazine 1-2%, methylene bis-benzotriazolyl tetramethyl butyl phenol 0.5-2%, inorganic sunscreen silicic acid anhydride titanium dioxide 8-10%, silicic acid anhydride zinc oxide 3-5% and film forming agent Unimer U-1946 2-5%, remaining group is divided into organic clay 1-2%, the emulsifier 3-6% and poly- trimethicone 11-15% of diphenyl silicon phenyl, dibutyl adipate 7-11% , the water phase components are polyalcohol 4-8%, anti-sensitizer 1-2%, moisturizer 2-4%, precious Rogor powder 1-2% and preservative Phenoxyethanol 0.3-0.5% composition；With excellent water resistant sweat resistance energy, 360 ° of full wave protection are provided for skin.
Description
Technical field
The present invention relates to sun-proof maintenance creams of a kind of high spf value containing precious Rogor and preparation method thereof.
Background technique
After skin receives ultraviolet light overexposure, epidermal cell can be damaged, activates Tyrosinase, accelerates pigment synthesis,
The moisture-keeping functions for destroying skin, make skin become drying, make the elastic fibers in skin corium impaired, generate microgroove, strong
Under irradiation, it also will cause skin inflammation, burn, when having abnormal case, then will become pigmentosa cutaneum carcinoma etc..And with the age
Increase, skin moisture-keeping mechanism is damaged, and the moisture content between skin tissue cell and cell tissue is reduced, and skin is more crisp
It is weak, accelerate dermal melanin deposition and aging aging when skin is corroded by ultraviolet light；In recent years, it has been found that " can
It is light-exposed " (account for solar irradiation 39%) also can injured cutaneous tissue, cause DNA single-strand break and generate reactive oxygen species
(ROS), to cause DNA damage, and most of sunscreen products on the market can effectively resist UVB and UVA, but to visible light
Obvious protection cannot be but provided.So good sunscreen product a now cannot only only go out from the wave band of protection UVB and UVA
Hair, should also consider together the moisturizing maintenance of visible light and skin.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of high SPF containing precious Rogor with all band protection and repair
The sun-proof maintenance cream of value.
To solve the above problems, the present invention adopts the following technical scheme:
A kind of sun-proof maintenance cream of the high spf value containing precious Rogor, including Orangic sunscreen and water phase components, feature exist
In: the Orangic sunscreen includes the material of following percent mass proportioning: ethylhexyl salicylate 3.5-4.5%, phenyl benzo
Imidazole sulfonic acid 2-4%, ethylhexyl methoxy cinnamate 8-9%, bis-ethylhexoxyphenol methoxyphenyl triazine 1-2%, methylene
Base is double-benzotriazole base tetramethyl butyl phenol 0.5-2%, inorganic sunscreen silicic acid anhydride titanium dioxide 8-10%, and hydrophobization
Processing zinc oxide 3-5% and film forming agent Unimer U-1946 2-5%, remaining group are divided into organic clay 1-2%, emulsifier 3-
The 6% and poly- trimethicone 11-15% of diphenyl silicon phenyl, dibutyl adipate 7-11%, the water phase group
It is divided into polyalcohol 4-8%, anti-sensitizer 1-2%, moisturizer 2-4%, precious Rogor powder 1-2% and preservative Phenoxyethanol 0.3-
0.5% composition.
Further, the Orangic sunscreen includes the material of following percent mass proportioning: ethylhexyl salicylate
3.5%, Phenylbenzimidazolesulfonic acid 4%, ethylhexyl methoxy cinnamate 9%, bis-ethylhexoxyphenol methoxyphenyl triazine
2%, methylene bis-benzotriazolyl tetramethyl butyl phenol 2%, inorganic sunscreen silicic acid anhydride titanium dioxide 10% are hydrophobic
Change processing zinc oxide 5% and film forming agent Unimer U-1946 5%, remaining group are divided into organic clay 2%, emulsifier 6% and two
The poly- trimethicone 15% of phenylsilane phenyl, dibutyl adipate 11%, the water phase components are polyalcohol
8%, anti-sensitizer 2%, moisturizer 4%, precious Rogor powder 2% and preservative Phenoxyethanol 0.5% form.
Further, the Orangic sunscreen includes the material of following percent mass proportioning: ethylhexyl salicylate
4.5%, Phenylbenzimidazolesulfonic acid 2%, ethylhexyl methoxy cinnamate 8%, bis-ethylhexoxyphenol methoxyphenyl triazine
1%, methylene bis-benzotriazolyl tetramethyl butyl phenol 0.5%, inorganic sunscreen silicic acid anhydride titanium dioxide 8% are hydrophobic
Change processing zinc oxide 3%, film forming agent Unimer U-1946 2%, remaining group is divided into organic clay 1%, emulsifier 3% and hexichol
The poly- trimethicone 11% of base silyloxyphenyl, dibutyl adipate 7%, the water phase components are polyalcohol 4%, are resisted
Quick dose 1%, moisturizer 2%, precious Rogor powder 1%, the composition of preservative Phenoxyethanol 0.3%.
Further, including Orangic sunscreen and water phase components, it is characterised in that: the Orangic sunscreen includes following matter
Measure the material of per distribution ratio: ethylhexyl salicylate 4%, Phenylbenzimidazolesulfonic acid 3%, ethylhexyl methoxy cinnamate
8.5%, bis-ethylhexoxyphenol methoxyphenyl triazine 1.5%, di-2-ethylhexylphosphine oxide-benzotriazole base tetramethyl butyl phenol 1%, nothing
Machine sun-screening agent silicic acid anhydride titanium dioxide 9%, silicic acid anhydride zinc oxide 4% and film forming agent Unimer U-1946 3%,
Remaining group is divided into organic clay 1.5%, emulsifier 4% and the poly- trimethicone 13% of diphenyl silicon phenyl, oneself two
Dibutyl phthalate 9%, the water phase components are polyalcohol 6%, anti-sensitizer 1.5%, moisturizer 3%, precious Rogor powder 1.5%, anti-corrosion
Agent Phenoxyethanol 0.4% forms.
Another technical problem to be solved by the present invention is that providing a kind of system of the sun-proof maintenance cream of high spf value containing precious Rogor
Preparation Method, comprising the following steps:
Titanium dioxide and zinc oxide are dispersed with 11-15% diphenyl silicon phenyl poly- trimethicone
It is even, powder is ground by exquisiteness by colloid mill or three-roll grinder, by ethylhexyl salicylate, Phenylbenzimidazolesulfonic acid, first
Oxygroup 2-Ethylhexyl cinnamate, methylene bis-benzotriazolyl tetramethyl butyl phenol, double-ethyl hexyl oxy phenol anisyl three
Piperazine and dibutyl adipate are added in emulsion pot 75-80 DEG C of agitating and heating to the dissolution of solid sun-screening agent completely, by polyalcohol, moisturizing
Agent is added to heating stirring in water phase pot and opens 1/3 valve to 75-80 DEG C for raw materials whole in water phase pot and be slowly pumped into emulsion pot
In, in this process, emulsion pot is kept stirring (25 revs/min) and keeps vacuum to -0.06mpa hereinafter, after all exhausting,
Middling speed homogeneous cools down after 2-3 minutes, is cooled to 42 DEG C and precious Rogor powder, anti-sensitizer and the preservative Phenoxyethanol dissolved is added.
The beneficial effects of the present invention are: the precious Rogor powder produced using fresh precious Rogor, multiple nutritional components are demonstrate,proved
Bright is the natural plants functional component for preventing and treating skin photoage, has enhancing DNA repair ability, reduces internal MDA level, increases
Internal SOD content improves body antioxidant activity, mitigates tissue oxidizing damage, mitigates inflammatory reaction caused by UV irradiates, maintains
The dynamic equilibrium of radicals scavenging and generation protects subcutaneous tissue from the damage of free radical, effectively controls skin histology function
The number of mechanisms such as irreversible change and the important efficacy effect deposited.The titanium dioxide for Typical physical sun-screening agent silicic acid anhydride of arranging in pairs or groups
Titanium and zinc oxide and chemical sun ethylhexyl salicylate, Phenylbenzimidazolesulfonic acid, ethylhexyl methoxy cinnamate,
Double-ethyl hexyl oxy phenol anisyl triazine, methylene bis-benzotriazolyl tetramethyl butyl phenol, with film forming agent Unimer
Under U-1946 (VP/ hexadecene copolymer, octyldodecanol) collective effect, excellent water resistant sweat resistance energy mentions for skin
For 360 ° of full wave protection.
Detailed description of the invention
Fig. 1 is protection/decay pattern that UV is obtained by the simulation of the website BASF.
Specific embodiment
A kind of sun-proof maintenance cream of the high spf value containing precious Rogor, including Orangic sunscreen and water phase components, it is described organic anti-
Shine agent include following percent mass proportioning material: ethylhexyl salicylate 3.5-4.5%, Phenylbenzimidazolesulfonic acid 2-4%,
Ethylhexyl methoxy cinnamate 8-9%, bis-ethylhexoxyphenol methoxyphenyl triazine 1-2%, di-2-ethylhexylphosphine oxide-benzotriazole
Base tetramethyl butyl phenol 0.5-2%, inorganic sunscreen silicic acid anhydride titanium dioxide 8-10%, silicic acid anhydride zinc oxide 3-
5% and film forming agent Unimer U-1946 2-5%, remaining group be divided into organic clay 1-2%, emulsifier 3-6% and diphenylmethyl
Siloxy phenyl trimethicone 11-15%, dibutyl adipate 7-11%, the water phase components are polyalcohol 4-
8%, anti-sensitizer 1-2%, moisturizer 2-4%, precious Rogor powder 1-2% and preservative Phenoxyethanol 0.3-0.5% composition.
Preparation method, comprising the following steps: will with the poly- trimethicone of 11-15% diphenyl silicon phenyl
Titanium dioxide and zinc oxide are uniformly dispersed, and powder are ground exquisiteness by colloid mill or three-roll grinder, by salicylic acid ethyl hexyl
Ester, Phenylbenzimidazolesulfonic acid, ethylhexyl methoxy cinnamate, methylene bis-benzotriazolyl tetramethyl butyl phenol, it is double-
75-80 DEG C of agitating and heating is added in emulsion pot to solid sun-screening agent in ethyl hexyl oxy phenol anisyl triazine and dibutyl adipate
Completely, by polyalcohol, moisturizer is added to heating stirring in water phase pot, and, to 75-80 DEG C, opening 1/3 valve will be complete in water phase pot for dissolution
Portion's raw material is slowly pumped into emulsion pot, in this process, emulsion pot be kept stirring (25 revs/min) and keep vacuum to-
Hereinafter, after all exhausting, middling speed homogeneous cools down 0.06mpa after 2-3 minutes, is cooled to 42 DEG C and the precious Rogor dissolved is added
Powder, anti-sensitizer and preservative Phenoxyethanol.
Embodiment 1: the Orangic sunscreen includes the material of following percent mass proportioning: ethylhexyl salicylate 3.5%,
Phenylbenzimidazolesulfonic acid 4%, ethylhexyl methoxy cinnamate 9%, bis-ethylhexoxyphenol methoxyphenyl triazine 2%, Asia
Methyl pair-benzotriazole base tetramethyl butyl phenol 2%, inorganic sunscreen silicic acid anhydride titanium dioxide 10%, silicic acid anhydride
Zinc oxide 5% and film forming agent Unimer U-1946 5%, remaining group are divided into organic clay 2%, emulsifier 6% and diphenylmethyl
Siloxy phenyl trimethicone 15%, dibutyl adipate 11%, the water phase components are polyalcohol 8%, antiallergic
Agent 2%, moisturizer 4%, precious Rogor powder 2% and preservative Phenoxyethanol 0.5% form.Using above-mentioned same method preparation
At.
Embodiment 2: the Orangic sunscreen includes the material of following percent mass proportioning: ethylhexyl salicylate
4.5%, Phenylbenzimidazolesulfonic acid 2%, ethylhexyl methoxy cinnamate 8%, bis-ethylhexoxyphenol methoxyphenyl triazine
1%, methylene bis-benzotriazolyl tetramethyl butyl phenol 0.5%, inorganic sunscreen silicic acid anhydride titanium dioxide 8% are hydrophobic
Change processing zinc oxide 3%, film forming agent Unimer U-1946 2%, remaining group is divided into organic clay 1%, emulsifier 3% and hexichol
The poly- trimethicone 11% of base silyloxyphenyl, dibutyl adipate 7%, the water phase components are polyalcohol 4%, are resisted
Quick dose 1%, moisturizer 2%, precious Rogor powder 1%, the composition of preservative Phenoxyethanol 0.3%.It is prepared using above-mentioned same method
It forms.
Embodiment 3: including Orangic sunscreen and water phase components, it is characterised in that: the Orangic sunscreen includes following matter
Measure the material of per distribution ratio: ethylhexyl salicylate 4%, Phenylbenzimidazolesulfonic acid 3%, ethylhexyl methoxy cinnamate
8.5%, bis-ethylhexoxyphenol methoxyphenyl triazine 1.5%, methylene bis-benzotriazolyl tetramethyl butyl phenol 1%, nothing
Machine sun-screening agent silicic acid anhydride titanium dioxide 9%, silicic acid anhydride zinc oxide 4% and film forming agent Unimer U-1946 3%,
Remaining group is divided into organic clay 1.5%, emulsifier 4% and the poly- trimethicone 13% of diphenyl silicon phenyl, oneself two
Dibutyl phthalate 9%, the water phase components are polyalcohol 6%, anti-sensitizer 1.5%, moisturizer 3%, precious Rogor powder 1.5%, anti-corrosion
Agent Phenoxyethanol 0.4% forms.It is prepared using above-mentioned same method.
Using zinc oxide, titanium dioxide as the first line of defence for stopping ultraviolet light, all band protection is reduced ultraviolet the present invention
Injury of the line to human body, ethylhexyl salicylate, Phenylbenzimidazolesulfonic acid, ethylhexyl methoxy cinnamate can be in UVB waves
Section, which rises, absorbs protective action, and bis-ethylhexoxyphenol methoxyphenyl triazine can then provide the protection of UVA wave band, further protect
Skin is invaded and harassed from ultraviolet light, and methylene bis-benzotriazolyl tetramethyl butyl phenol can absorb UVA and UVB band ultraviolet, mention
It is protected for all band；And VP/ hexadecene copolymer its both sexes structure, excellent water lock moisture-keeping functions can be provided for skin,
Stable sun-screening agent can be firmly wrapped up again using its structure, bring special structure when contacting to powder and water oil, it is automatic to capture
Dynamically formed membrane allows sun-screening agent to give full play to its effect, protects me to the sebum film of the formation one continuous uniform anti-sweat of water resistant
Skin；Recycle nutritional ingredient of the precious Rogor powder as comprehensive skin repair, nutrient abundant, higher protein
Content and essential amino acid and P elements, and the rich multiple nutritional components of precious Rogor itself have proved to be prevention and treatment skin
The natural plants functional component of light aging has enhancing DNA repair ability, reduces internal MDA water with sunscreen product synergy
It puts down, increases internal SOD content, improves body antioxidant activity, mitigate tissue oxidizing damage, it is anti-to mitigate inflammation caused by UV irradiates
The dynamic equilibrium for answering, maintaining radicals scavenging and generation protects subcutaneous tissue from the damage of free radical, effectively controls skin group
The important efficacy effect knitting the number of mechanisms such as the irreversible change of function and depositing.The complementary synergistic combination of inner and outside of three is really done
It is corroded to ultraviolet light is resisted, reduces the damage of skin photoage bring, delay senescence.
Film forming agent Unimer U-1946 (VP/ hexadecene copolymer, octyldodecanol) feature: being a kind of film forming agent,
It is copolymerized for l-vinyl-2-pyrrolidone and 1- hexadecylene hydrocarbon, there is amphiphilic structure, water-wet side can be with skin surface parent
Water film is combined closely, and one layer of softness, close, successional dynamic coverage film are formed, and there is this tunic water lock ability to lock water
Point；Its close ester end facilitates the dispersion of powder, grabs powder by " automatic " benefit of its structure, forms a kind of special construction, work as contact
When to water or oil, it can bring permanent effect, improve and rinse resistance, provide waterproofness to suncream and good powder can be provided
Dispersibility.
Experimental example:
The related raw material data provided according to chemical sun production supplier, and according to country's " cosmetics peace in 2015
Full technical specification " in chemical sun maximum additive amount in table five, gone out using the sun-proof Simulator design that BASF AG provides
Optimal sun-screening agent arranging scheme.
According to the test result (theoretical value) of the sun-proof simulator output of BASF: SPF 59.3, PA+++, ultraviolet filtering effect
Rate (SPF/%UV Filter) 2.0 show that protection/decaying chart of UV can see this sun-screening agent by the simulation of the website BASF
The efficiency before and after sunlight irradiation of arranging in pairs or groups does not decay significantly.As shown in Figure 1.
Note:
Ultraviolet filtering efficiency is the ratio between SPF and total ultraviolet filtering concentration (as a percentage).This value is higher, reaches
The sun-screening agent used to required spf value is fewer, it means that selects the freedom degree of other compositions more in formula of sun screen
It is high.
Sun protection factor (Sun Protection Factor), english abbreviation SPF refer to and are being coated with sun-screening agent protection
Energy needed for generating minimum erythema on skin, with plus on the skin of any protection do not generate same degree erythema needed for the ratio between energy
Value
PFA (protectionfactor of UVA) value, what it reflected is protection effect of the product to UVA, works as sunscreen products
Actual measurement PFA value < 2 when, UVA protection effect must not be identified；It, can be according to the corresponding PA of its numerical identity when 2≤PFA value < 16
Grade, 2-3 PA+, 4-7 PA+, 8-15 PA+, >=16 be PA++++
SPF test method, can according to test method in " cosmetics safety technical specification in 2015 " chapter 8 [5]
Know:
Minimal erythema dose (Minimal erythema dose, MED): cause the erythema that skin is high-visible, range reaches
To the irradiation of ultraviolet light required for point of irradiation major part region lowest dose level (J/m2) or shortest time (second).And SPF
(Sun protection factor, SPF): MED needed for causing the skin protected by sunscreen cosmetic to generate erythemapWith not
MED needed for the skin protected generates erythemauThe ratio between, for the SPF of the sunscreen cosmetic, i.e. SPF=MEDp/MEDu.PA value
Test method is shown in ISO 24442.2011.Since our company is not used for the instrument of the sun-proof spf value test of human body, therefore raw material is entrusted to supply
Answer the Shang dynasty for measurement, precious Rogor sunscreen SPF50, PA+++ human test's result is as follows:
As seen from the above table, the sun protection factor predicted value of the sun-proof SPF50 PA+++ of precious Rogor is 59.3, PA value 8 (PA+++).
And it is 54+ by the result sun protection factor value that human test comes out, PA value is 8 (PA+++).
The above description is merely a specific embodiment, but scope of protection of the present invention is not limited thereto, any
The change or replacement expected without creative work, should be covered by the scope of protection of the present invention.
Claims (4)
1. a kind of sun-proof maintenance cream of high spf value containing precious Rogor, including Orangic sunscreen and water phase components, it is characterised in that:
The Orangic sunscreen includes the material of following percent mass proportioning: ethylhexyl salicylate 3.5-4.5%, phenylbenzimidazol
Sulfonic acid 2-4%, ethylhexyl methoxy cinnamate 8-9%, bis-ethylhexoxyphenol methoxyphenyl triazine 1-2%, methylene
Double-benzotriazole base tetramethyl butyl phenol 0.5-2%, inorganic sunscreen silicic acid anhydride titanium dioxide 8-10%, at hydrophobization
Reason zinc oxide 3-5% and film forming agent Unimer U-1946 2-5%, remaining group are divided into organic clay 1-2%, emulsifier 3-6%
With the poly- trimethicone 11-15% of diphenyl silicon phenyl, dibutyl adipate 7-11%, the water phase components are
Polyalcohol 4-8%, anti-sensitizer 1-2%, moisturizer 2-4%, precious Rogor powder 1-2% and preservative Phenoxyethanol 0.3-0.5% group
At.
2. a kind of sun-proof maintenance cream of high spf value containing precious Rogor as described in claim 1, including Orangic sunscreen and water phase
Component, it is characterised in that: the Orangic sunscreen includes the material of following percent mass proportioning: ethylhexyl salicylate 3.5%,
Phenylbenzimidazolesulfonic acid 4%, ethylhexyl methoxy cinnamate 9%, bis-ethylhexoxyphenol methoxyphenyl triazine 2%, Asia
Methyl pair-benzotriazole base tetramethyl butyl phenol 2%, inorganic sunscreen silicic acid anhydride titanium dioxide 10%, silicic acid anhydride
Zinc oxide 5% and film forming agent Unimer U-1946 5%, remaining group are divided into organic clay 2%, emulsifier 6% and diphenylmethyl
Siloxy phenyl trimethicone 15%, dibutyl adipate 11%, the water phase components are polyalcohol 8%, antiallergic
Agent 2%, moisturizer 4%, precious Rogor powder 2% and preservative Phenoxyethanol 0.5% form.
3. a kind of sun-proof maintenance cream of high spf value containing precious Rogor as described in claim 1, including Orangic sunscreen and water phase
Component, it is characterised in that: the Orangic sunscreen includes the material of following percent mass proportioning: ethylhexyl salicylate 4.5%,
Phenylbenzimidazolesulfonic acid 2%, ethylhexyl methoxy cinnamate 8%, bis-ethylhexoxyphenol methoxyphenyl triazine 1%, Asia
Methyl pair-benzotriazole base tetramethyl butyl phenol 0.5%, inorganic sunscreen silicic acid anhydride titanium dioxide 8%, silicic acid anhydride
Zinc oxide 3%, film forming agent Unimer U-1946 2%, remaining group are divided into organic clay 1%, emulsifier 3% and diphenylmethyl silicon
The poly- trimethicone 11% of alkoxyl phenyl, dibutyl adipate 7%, the water phase components are polyalcohol 4%, anti-sensitizer
1%, moisturizer 2%, precious Rogor powder 1%, the composition of preservative Phenoxyethanol 0.3%.
4. a kind of sun-proof maintenance cream of high spf value containing precious Rogor as described in claim 1, including Orangic sunscreen and water phase
Component, it is characterised in that: the Orangic sunscreen includes the material of following percent mass proportioning: ethylhexyl salicylate 4%, benzene
Base benzimidazole sulfonic acid 3%, ethylhexyl methoxy cinnamate 8.5%, bis-ethylhexoxyphenol methoxyphenyl triazine 1.5%,
Methylene bis-benzotriazolyl tetramethyl butyl phenol 1%, inorganic sunscreen silicic acid anhydride titanium dioxide 9%, silicic acid anhydride
Zinc oxide 4% and film forming agent Unimer U-1946 3%, remaining group are divided into organic clay 1.5%, emulsifier 4% and diphenyl
The poly- trimethicone 13% of silyloxyphenyl, dibutyl adipate 9%, the water phase components are polyalcohol 6%, antiallergic
Agent 1.5%, moisturizer 3%, precious Rogor powder 1.5%, preservative Phenoxyethanol 0.4% form.
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| CN201910437458.6A CN110420139A (en) | 2019-05-23 | 2019-05-23 | A kind of sun-proof maintenance cream of the high spf value containing precious Rogor and preparation method thereof |
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| CN201910437458.6A CN110420139A (en) | 2019-05-23 | 2019-05-23 | A kind of sun-proof maintenance cream of the high spf value containing precious Rogor and preparation method thereof |
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| CN110420139A true CN110420139A (en) | 2019-11-08 |
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Cited By (2)
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| CN113350250A (en) * | 2021-06-11 | 2021-09-07 | 中山市澳臣精细化工实业有限公司 | Multi-effect sunscreen aerosol with high SPF (specific pathogen free) and PFA (Perfluoro alkoxy) values and preparation method thereof |
| CN113576935A (en) * | 2021-07-02 | 2021-11-02 | 曼秀雷敦(中国)药业有限公司 | Sunscreen repair composition and preparation method thereof |
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| CN106176302A (en) * | 2016-08-15 | 2016-12-07 | 广州澳希亚实业有限公司 | Phase-inversion sunscreen composition and preparation method thereof |
| CN108464947A (en) * | 2018-04-12 | 2018-08-31 | 苏州绿叶日用品有限公司 | Include the cosmetic composition and preparation method thereof of film forming agent and microsphere particle |
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| CN103860429A (en) * | 2014-03-13 | 2014-06-18 | 广州市宜健医学技术发展有限公司 | Borojo skin-care product and natural moisturizing, anti-aging, ultraviolet-resistant, antiallergic and skin-whitening applications thereof |
| CN106176302A (en) * | 2016-08-15 | 2016-12-07 | 广州澳希亚实业有限公司 | Phase-inversion sunscreen composition and preparation method thereof |
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| CN113350250A (en) * | 2021-06-11 | 2021-09-07 | 中山市澳臣精细化工实业有限公司 | Multi-effect sunscreen aerosol with high SPF (specific pathogen free) and PFA (Perfluoro alkoxy) values and preparation method thereof |
| CN113576935A (en) * | 2021-07-02 | 2021-11-02 | 曼秀雷敦(中国)药业有限公司 | Sunscreen repair composition and preparation method thereof |
| WO2023273636A1 (en) * | 2021-07-02 | 2023-01-05 | 曼秀雷敦(中国)药业有限公司 | Sunscreen repair composition and preparation method therefor |
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Application publication date: 20191108 |