CN110382454B - 用于生产烯属不饱和羧酸酯的方法及其催化剂 - Google Patents

用于生产烯属不饱和羧酸酯的方法及其催化剂 Download PDF

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Publication number
CN110382454B
CN110382454B CN201780077831.0A CN201780077831A CN110382454B CN 110382454 B CN110382454 B CN 110382454B CN 201780077831 A CN201780077831 A CN 201780077831A CN 110382454 B CN110382454 B CN 110382454B
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formaldehyde
basic metal
metal salt
reactant
methanol
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Chinese (zh)
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CN110382454A (zh
Inventor
格雷厄姆·罗纳德·伊斯特汉
乔纳森·安斯利·艾戈
迈克尔·博蒙特
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Mitsubishi Chemical UK Ltd
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Mitsubishi Chemical UK Ltd
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54—Acrylic acid esters; Methacrylic acid esters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CN201780077831.0A 2016-10-14 2017-10-11 用于生产烯属不饱和羧酸酯的方法及其催化剂 Active CN110382454B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GBGB1617534.1A GB201617534D0 (en) 2016-10-14 2016-10-14 A process for the production of Ethylenically unsaturated carboxylic acid esters and a catalyst therefor
GB1617534.1 2016-10-14
PCT/GB2017/053075 WO2018069702A1 (en) 2016-10-14 2017-10-11 A process for the production of ethylenically unsaturated carboxylic acid esters and a catalyst therefor

Publications (2)

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CN110382454A CN110382454A (zh) 2019-10-25
CN110382454B true CN110382454B (zh) 2023-05-30

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US (1) US10683255B2 (enExample)
EP (1) EP3526191B1 (enExample)
JP (1) JP7058267B2 (enExample)
KR (1) KR102464444B1 (enExample)
CN (1) CN110382454B (enExample)
BR (1) BR112019007526B8 (enExample)
CA (1) CA3041025A1 (enExample)
EA (1) EA201990906A1 (enExample)
ES (1) ES2982755T3 (enExample)
GB (1) GB201617534D0 (enExample)
MX (1) MX2019004301A (enExample)
MY (1) MY191034A (enExample)
SG (1) SG11201903249RA (enExample)
TW (1) TWI736690B (enExample)
WO (1) WO2018069702A1 (enExample)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB785100A (en) * 1955-01-10 1957-10-23 Celanese Corp Production of unsaturated aliphatic esters
WO2000058298A2 (en) * 1999-03-30 2000-10-05 E.I. Du Pont De Nemours And Company PROCESS FOR THE PREPARATION OF α-METHYLENELACTONES AND α-SUBSTITUTED HYDROCARBYLIDENE LACTONES
CN1566057A (zh) * 1998-06-05 2005-01-19 卢西特国际英国有限公司 脱水方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4990662A (en) 1984-07-18 1991-02-05 Amoco Corporation Process for preparation of alpha, beta-unsaturated acids
JP3202802B2 (ja) 1992-07-29 2001-08-27 ダイセル化学工業株式会社 メタクリル酸又はメタクリル酸誘導体の製造方法
GB9807498D0 (en) 1998-04-08 1998-06-10 Ici Plc Production of unsaturated acids therfore and catalysts therfor
US20040006244A1 (en) 2002-05-22 2004-01-08 Manzer Leo Ernest Process for making ethyencially unsaturated acids and acids
JP2006511611A (ja) * 2002-12-20 2006-04-06 シグマ・コーテイングス・ベー・ブイ シリルカルボン酸エステル単量体の製造方法
GB201506308D0 (en) 2015-04-14 2015-05-27 Lucite Int Uk Ltd A process for the production of ethylenically unsaturated carboxylic acids or esters

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB785100A (en) * 1955-01-10 1957-10-23 Celanese Corp Production of unsaturated aliphatic esters
CN1566057A (zh) * 1998-06-05 2005-01-19 卢西特国际英国有限公司 脱水方法
WO2000058298A2 (en) * 1999-03-30 2000-10-05 E.I. Du Pont De Nemours And Company PROCESS FOR THE PREPARATION OF α-METHYLENELACTONES AND α-SUBSTITUTED HYDROCARBYLIDENE LACTONES

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
"Towards a Low Temperature, Liquid Phase Methyl Methacrylate Process through Mechanism-Guided Process Design";Michael Beaumont;《The University of Liverpool Repository》;https://livrepository.liverpool.ac.uk/2037982/;20160901;第1-160页及第i-xvi页 *
Michael Beaumont."Towards a Low Temperature, Liquid Phase Methyl Methacrylate Process through Mechanism-Guided Process Design".《The University of Liverpool Repository》.https://livrepository.liverpool.ac.uk/2037982/,2016,第1-160页及第i-xvi页. *

Also Published As

Publication number Publication date
JP2019532073A (ja) 2019-11-07
TW201829366A (zh) 2018-08-16
TWI736690B (zh) 2021-08-21
CN110382454A (zh) 2019-10-25
BR112019007526B8 (pt) 2022-08-09
WO2018069702A1 (en) 2018-04-19
MY191034A (en) 2022-05-30
BR112019007526B1 (pt) 2022-07-19
EP3526191C0 (en) 2024-05-22
EA201990906A1 (ru) 2019-09-30
US10683255B2 (en) 2020-06-16
GB201617534D0 (en) 2016-11-30
US20190382332A1 (en) 2019-12-19
ES2982755T3 (es) 2024-10-17
JP7058267B2 (ja) 2022-04-21
KR20190061085A (ko) 2019-06-04
BR112019007526A2 (pt) 2019-07-02
CA3041025A1 (en) 2018-04-19
EP3526191A1 (en) 2019-08-21
SG11201903249RA (en) 2019-05-30
KR102464444B1 (ko) 2022-11-07
MX2019004301A (es) 2019-10-30
EP3526191B1 (en) 2024-05-22

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