CN110358312A - A kind of invertibity lacquerware reparation recruits material and its preparation method and application method - Google Patents

A kind of invertibity lacquerware reparation recruits material and its preparation method and application method Download PDF

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Publication number
CN110358312A
CN110358312A CN201910707986.9A CN201910707986A CN110358312A CN 110358312 A CN110358312 A CN 110358312A CN 201910707986 A CN201910707986 A CN 201910707986A CN 110358312 A CN110358312 A CN 110358312A
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recruits
lacquerware
invertibity
reparation
parts
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CN110358312B (en
Inventor
陈家昌
张良帅
贺思予
陈晓琳
唐静
闫海涛
王鑫光
迟铭
崔新战
刘欣
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Henan Institute Of Cultural Relics And Archaeology
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Henan Institute Of Cultural Relics And Archaeology
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L93/00Compositions of natural resins; Compositions of derivatives thereof
    • C08L93/04Rosin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2206Oxides; Hydroxides of metals of calcium, strontium or barium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045Sulfates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

Abstract

The present invention provides a kind of invertibity lacquerware reparation and recruits material and its preparation method and application method, a kind of invertibity lacquerware reparation recruits material, including following raw material by weight, 15 parts of rosin, 5 parts of paraffin, 1~2 part of lignocellulosic, 5~8 parts of inorganic filler.The material provided by the invention that recruits can carry out invertibity reparation and recruit with good thermoplasticity under the premise of not damaging historical relic, it can be achieved that reprocessing for part material is recruited.The material provided by the invention that recruits is with preferable bonding force and adhesive force, and material cools and solidifies post-shrinkage ratio less than 0.5%, suitable for recruiting for lacquerware.The environmentally protective material feedstock, cheap and easily-available, superior performance, applied widely provided by the invention of recruiting.Operating procedure simplicity when material recruits is recruited using provided by the invention, can be needed to carry out decorative pattern engraving according to historical relic after recruiting, do the repair processes such as old.

Description

A kind of invertibity lacquerware reparation recruits material and its preparation method and application method
Technical field
The present invention relates to historical relics to recruit, in particular to a kind of invertibity lacquerware reparation recruits material and preparation method thereof and answers Use method.
Background technique
China has long wood materials usage history, a large amount of historical relic remnants of being unearthed, these rare cultural relics are reflections The effulgent important geological material of Chinese civilization.Existing a large amount of historical relics experienced long-term land burial or history stream After turning over journey, there are many diseases for presence mostly, and defect is exactly wherein relatively common one of disease.Historical relic defect is serious to be changed The primary morphology for having become implements greatly reduces the researching value and artistic value of historical relic, therefore during Conservative restoration It needs to be recruited using suitable material.
The currently used material that recruits is more, but common problem is to cannot achieve to reprocess, therefore be difficult full The particular/special requirement of sufficient historical relic's protection.
Summary of the invention
To solve the above problems, the present invention, which provides a kind of invertibity lacquerware reparation, recruits material and its preparation method and application Method.
The object of the present invention is achieved in the following manner: a kind of invertibity lacquerware reparation recruits material, including by weight The following raw material of part meter, 15 parts of rosin, 5 parts of paraffin, 1~2 part of lignocellulosic, 5~8 parts of inorganic filler.
Inorganic filler is nano silica, in calcium oxide, aluminium oxide, zinc oxide, ultra-fine gesso, superfine talcum powder At least one.
Inorganic filler is to contain CaSO4·0.5H2Filler, the rosin of O is gum rosin, paraffin is microcrystalline wax or polyethylene Wax.
15 parts of rosin, 5 parts of polyethylene wax, 1 part of lignocellulosic, 6 parts of inorganic filler.
A kind of invertibity lacquerware reparation recruits the preparation method of material, includes the following steps,
(1) rosin, paraffin, lignocellulosic, inorganic filler are weighed;
(2) first rosin, paraffin are placed in 150 DEG C of baking ovens, agitating and heating 20 minutes, until melting completely, are sufficiently mixed;
(3) 165 DEG C -175 DEG C are heated to, adds lignocellulosic by amount, being stirred continuously makes its dispersion;
(4) 220 DEG C~250 DEG C are again heated to, by amount add inorganic filler, stir evenly, be cooled to 35 DEG C hereinafter,.
Invertibity lacquerware reparation recruits the application method of material,
(1) suitable cleaning agent cleaning is selected to recruit position according to different historical relics;
(2) it is heated using heat gun to position is recruited, promotion recruits material in conjunction with the surface for recruiting position, avoids Yin Wen Degree difference is excessive to cause the phenomenon that combining loosely;
(3) it heats to recruiting material, makes to recruit material melts, be then cooled to 145 DEG C -155 DEG C, brush in lacquerware defect Position;Or the material that recruits of fusing is cooled to 86 DEG C -94 DEG C, then to material progress moulding is recruited, will be moulded using heat gun The bonding plane heating and melting for recruiting material of good type, is bonded in defect.
It, can be according to historical relic shape and its defect feelings if the plasticity of step (3) is not inconsistent with historical relic shape and its defect situation Condition further modified to the material that recruits of defect, heat gun can be used to be heated in dressing process, is convenient for Finishing recruit material moulding at shape.
It carries out being heated to 70 DEG C -80 DEG C to position is recruited using heat gun in step (2).
Dehydrated alcohol, acetone or dehydrated alcohol and the deionized water mixing cleaning agent that 1:1 is formed by volume.
Compared with the existing technology, the stickiness of rosin is good, and especially pressure-sensitive, fast stickiness, low temperature stickiness are fine, is suitable for wood Used in matter historical relic reparation, but its cohesive force is poor, since rosin contains double bond and carboxyl, reactivity is higher, therefore to light, Heat, oxygen show that resistance to ag(e)ing is bad, weatherability is bad compared with unstability, are easy to produce dusting and metachromatism.Wax stability Height, toughness is preferable at a certain temperature, but viscosity is larger;Natural rosin is modified using polyethylene wax, can greatly be improved Rosin performance;Softening point can be improved using microcrystalline wax, improve rosin toughness;The addition of inorganic filler, can reinforcing material it is whole Body intensity and softening point significantly improve material against oxidative, thermal stability, resistance to ag(e)ing.And contain water in rosin, water and Contain CaSO4·0.5H2The filler of the O such as plaster of paris reacts, and forms dihydrate gypsum, that is, CaSO4·2H2O support construction, and expand It can offset and recruit the contraction of material in the curing process.The present invention is total using rosin, paraffin, lignocellulosic, inorganic filler The mixed this historical relic's protection prepared recruits material, overcomes rosin, paraffin in historical relic and recruits the technological deficiency in application.
The material provided by the invention that recruits is with good thermoplasticity, under the premise of not damaging historical relic, it can be achieved that benefit Reprocessing with part material can carry out invertibity reparation and recruit.The material provided by the invention that recruits has preferable glue Relay and adhesive force, and material cools and solidifies post-shrinkage ratio less than 0.5%, suitable for recruiting for lacquerware.It is provided by the invention to recruit Material feedstock is environmentally protective, cheap and easily-available, superior performance, applied widely.It is mended using the material provided by the invention that recruits Timing operating procedure is easy, can be needed to carry out decorative pattern engraving according to historical relic after recruiting, do the repair processes such as old.
Detailed description of the invention
Fig. 1 is to recruit to paint defect picture before alms bowl recruits in example 1.
Fig. 2 is the picture after the completion of portion recruits in Fig. 1, that is, recruit in picture.
Fig. 3 is to recruit the picture one painted after the completion of alms bowl recruits in example 1.
Fig. 4 is to recruit the picture two painted after the completion of alms bowl recruits in example 1.
Fig. 5 is to recruit the defect picture that preceding beans disk is recruited in example 2.
Fig. 6 is the back side picture in Fig. 5.
Fig. 7 is to recruit the beans disk after recruiting in example 2, pedestal, beans handle picture.
Fig. 8 is to recruit the beans disk after recruiting in example 2, pedestal, beans handle package assembly picture.
Specific embodiment
A kind of invertibity lacquerware reparation recruits material, including following raw material by weight, 15 parts of rosin, 5 parts of paraffin, 1~2 part of lignocellulosic, 5~8 parts of inorganic filler.
Inorganic filler is nano silica, in calcium oxide, aluminium oxide, zinc oxide, ultra-fine gesso, superfine talcum powder At least one.
Inorganic filler is CaSO4·0.5H2Filler, the rosin of O is gum rosin, paraffin is microcrystalline wax or polyethylene wax.
A kind of invertibity lacquerware reparation recruits the preparation method of material, includes the following steps,
(1) rosin, paraffin, lignocellulosic, inorganic filler are weighed;
(2) first rosin, paraffin are placed in 150 DEG C of baking ovens, agitating and heating 20 minutes, until melting completely, are sufficiently mixed;
(3) 165 DEG C -175 DEG C are heated to, adds lignocellulosic by amount, being stirred continuously makes its dispersion;
(4) 220 DEG C~250 DEG C are again heated to, by amount add inorganic filler, stir evenly, be cooled to 35 DEG C hereinafter,.
Invertibity lacquerware reparation recruits the application method of material,
(1) select the cleaning of suitable cleaning agent to recruit position according to different historical relics, cleaning agent be absolute alcohol, acetone or alcohol with The deionized water mixing cleaning agent that 1:1 is formed by volume;
(2) it is heated using heat gun to position is recruited, promotion recruits material in conjunction with the surface for recruiting position, avoids Yin Wen Degree difference is excessive to cause the phenomenon that combining loosely;
(3) it heats to recruiting material, makes to recruit material melts, be then cooled to 145 DEG C -155 DEG C, brush in lacquerware defect Position;Or the material that recruits of fusing is cooled to 86 DEG C -94 DEG C, then to material progress moulding is recruited, will be moulded using heat gun The bonding plane heating and melting for recruiting material of good type, is bonded in defect.
It (4), can be according to historical relic shape and its defect if the plasticity of step (3) is not inconsistent with historical relic shape and its defect situation Situation further modified to the material that recruits of defect, heat gun can be used to be heated in dressing process, just In finishing recruit material moulding at shape.
Embodiment 1
A kind of invertibity lacquerware reparation recruits material, including following raw material by weight, 15 parts of gum rosin, polyethylene wax 5 Part, 1 part of lignocellulosic, 6 parts of ultra-fine gesso.
The invertibity lacquerware reparation recruits the preparation method of material, includes the following steps,
(1) gum rosin, polyethylene wax, lignocellulosic, ultra-fine gesso are weighed in parts by weight;
(2) first gum rosin, polyethylene wax are placed in 150 DEG C of baking ovens, agitating and heating 20 minutes, until melting completely, are sufficiently mixed;
(3) 170 DEG C are heated to, adds lignocellulosic by amount, being stirred continuously makes its dispersion;
(4) 235 DEG C are again heated to, ultra-fine gesso is added by amount, stirs evenly, be cooled to room temperature 35 DEG C.
Embodiment 2
A kind of invertibity lacquerware reparation recruits material, 15 parts of rosin, 5 parts of paraffin, wooden including following raw material by weight 1 part of cellulose, 5 parts of nano silica.
The invertibity lacquerware reparation recruits the preparation method of material, includes the following steps,
(1) rosin, paraffin, lignocellulosic, nano silica are weighed in parts by weight;
(2) first rosin, paraffin are placed in 150 DEG C of baking ovens, agitating and heating 20 minutes, until melting completely, are sufficiently mixed;
(3) 175 DEG C are heated to, adds lignocellulosic by amount, being stirred continuously makes its dispersion;
(4) 250 DEG C are again heated to, nano silica is added by amount, stirs evenly, be cooled to room temperature 34 DEG C.
Embodiment 3
A kind of invertibity lacquerware reparation recruits material, including following raw material by weight, 15 parts of gum rosin, microcrystalline wax 5 Part, 2 parts of lignocellulosic, 8 parts of calcium oxide.
The invertibity lacquerware reparation recruits the preparation method of material, includes the following steps,
(1) gum rosin, microcrystalline wax, lignocellulosic, calcium oxide are weighed;
(2) first gum rosin, microcrystalline wax are placed in 150 DEG C of baking ovens, agitating and heating 20 minutes, until melting completely, are sufficiently mixed;
(3) 170 DEG C are heated to, adds lignocellulosic by amount, being stirred continuously makes its dispersion;
(4) 230 DEG C are again heated to, calcium oxide is added by amount, stirs evenly, be cooled to room temperature 30 DEG C.
Embodiment 4
A kind of invertibity lacquerware reparation recruits material, including following raw material by weight, 15 parts of gum rosin, polyethylene wax 5 Part, 1.5 parts of lignocellulosic, 6 parts of aluminium oxide.
The invertibity lacquerware reparation recruits the preparation method of material, includes the following steps,
(1) gum rosin, polyethylene wax, lignocellulosic, aluminium oxide are weighed;
(2) first gum rosin, polyethylene wax are placed in 150 DEG C of baking ovens, agitating and heating 20 minutes, until melting completely, are sufficiently mixed;
(3) 168 DEG C are heated to, adds lignocellulosic by amount, being stirred continuously makes its dispersion;
(4) 240 DEG C are again heated to, aluminium oxide is added by amount, stirs evenly, be cooled to room temperature 28 DEG C.
Embodiment 5
A kind of invertibity lacquerware reparation recruits material, including following raw material by weight, 15 parts of rosin, 5 parts of microcrystalline wax, 1.8 parts of lignocellulosic, 7 parts of zinc oxide.
The invertibity lacquerware reparation recruits the preparation method of material, includes the following steps,
(1) rosin, microcrystalline wax, lignocellulosic, zinc oxide are weighed;
(2) first rosin, microcrystalline wax are placed in 150 DEG C of baking ovens, agitating and heating 20 minutes, until melting completely, are sufficiently mixed;
(3) 172 DEG C are heated to, adds lignocellulosic by amount, being stirred continuously makes its dispersion;
(4) 235 DEG C are again heated to, zinc oxide is added by amount, stirs evenly, be cooled to room temperature 25 DEG C.
Embodiment 6
A kind of invertibity lacquerware reparation recruits material, including following raw material by weight, 15 parts of rosin, 5 parts of polyethylene wax, 1.2 parts of lignocellulosic, 6 parts of superfine talcum powder.
The invertibity lacquerware reparation recruits the preparation method of material, includes the following steps,
(1) rosin, polyethylene wax, lignocellulosic, superfine talcum powder are weighed;
(2) first rosin, polyethylene wax are placed in 150 DEG C of baking ovens, agitating and heating 20 minutes, until melting completely, are sufficiently mixed;
(3) 165 DEG C are heated to, adds lignocellulosic by amount, being stirred continuously makes its dispersion;
(4) 250 DEG C are again heated to, superfine talcum powder is added by amount, stirs evenly, be cooled to 20 DEG C.
Embodiment 7
A kind of invertibity lacquerware reparation recruits material, including following raw material by weight, 15 parts of rosin, 5 parts of polyethylene wax, 1.4 parts of lignocellulosic, 2 parts of nano silica, 4 parts of ultra-fine gesso.
The invertibity lacquerware reparation recruits the preparation method of material, includes the following steps,
(1) rosin, polyethylene wax, lignocellulosic, nano silica, ultra-fine gesso are weighed;
(2) first rosin, polyethylene wax are placed in 150 DEG C of baking ovens, agitating and heating 20 minutes, until melting completely, are sufficiently mixed;
(3) 165 DEG C -175 DEG C are heated to, adds lignocellulosic by amount, being stirred continuously makes its dispersion;
(4) 220 DEG C~250 DEG C are again heated to, by the mixture of amount addition nano silica and ultra-fine gesso, stirring is equal It is even, it is cooled to 33 DEG C.
Embodiment 8
A kind of invertibity lacquerware reparation recruits material, including following raw material by weight, 15 parts of rosin, 5 parts of microcrystalline wax, 1 part of lignocellulosic, 3 parts of calcium oxide, 2 parts of aluminium oxide, 2 parts of zinc oxide.
The invertibity lacquerware reparation recruits the preparation method of material, includes the following steps,
(1) rosin, microcrystalline wax, lignocellulosic, calcium oxide, aluminium oxide, zinc oxide are weighed;
(2) first rosin, microcrystalline wax are placed in 150 DEG C of baking ovens, agitating and heating 20 minutes, until melting completely, are sufficiently mixed;
(3) 165 DEG C -175 DEG C are heated to, adds lignocellulosic by amount, being stirred continuously makes its dispersion;
(4) 220 DEG C~250 DEG C are again heated to, by amount addition calcium oxide, the inorganic mixture of aluminium oxide and zinc oxide, stirring is equal It is even, it is cooled to 35 DEG C.
Recruit example 1:
Recruit the paint alms bowl such as Fig. 1 there are defect, diameter 22.5cm, high 9.2cm, wall thickness 0.9cm.Fig. 2-Fig. 4 is the figure after recruiting Piece.
The invertibity lacquerware reparation used when being recruited recruits material, including following raw material by weight, rouge pine Fragrant 15 parts, 5 parts of polyethylene wax, 1 part of lignocellulosic, 6 parts of ultra-fine gesso.
The invertibity lacquerware reparation recruits the preparation method of material, includes the following steps,
(1) gum rosin, polyethylene wax, lignocellulosic, ultra-fine gesso are weighed in parts by weight;
(2) first gum rosin, polyethylene wax are placed in 150 DEG C of baking ovens, agitating and heating 20 minutes, until melting completely, are sufficiently mixed;
(3) 170 DEG C are heated to, adds lignocellulosic by amount, being stirred continuously makes its dispersion;
(4) 235 DEG C are again heated to, ultra-fine gesso is added by amount, stirs evenly, be cooled to room temperature 25 DEG C.
Invertibity lacquerware reparation recruits the application method of material,
(1) position is recruited using cleaning agent cleaning, cleaning agent is absolute alcohol;
(2) it carries out being heated to 70 DEG C to position is recruited using heat gun;
(3) it heats to recruiting material, makes to recruit material melts, the material that recruits of fusing is then cooled to 94 DEG C, then Defect portion is bonded in using heat gun by the bonding plane heating and melting for recruiting material for type of having moulded to material progress moulding is recruited Position.
When lacquerware needs to handle again, as want, recruiting material with other replaces this material or this material aging need to reject Situation can will recruit material and be heated to 88 DEG C -92 DEG C, remove after recruiting material softening, then recruit again.
Recruit example 2:
Recruit the paint beans such as Fig. 5-Fig. 6 there are defect: 14.7 cm of beans disk diameter, 11.1 cm of base diameter, beans shank diameter 2.9 Cm -3.7 cm, leading to high 20.3 cm, Fig. 7 and Fig. 8 is the picture after recruiting.
The invertibity lacquerware reparation used when being recruited recruits material, including following raw material by weight, rouge pine Fragrant 15 parts, 5 parts of polyethylene wax, 1.5 parts of lignocellulosic, 6 parts of ultra-fine gesso.
The invertibity lacquerware reparation recruits the preparation method of material, includes the following steps,
(1) gum rosin, polyethylene wax, lignocellulosic, ultra-fine gesso are weighed in parts by weight;
(2) first gum rosin, polyethylene wax are placed in 150 DEG C of baking ovens, agitating and heating 20 minutes, until melting completely, are sufficiently mixed;
(3) 170 DEG C are heated to, adds lignocellulosic by amount, being stirred continuously makes its dispersion;
(4) 235 DEG C are again heated to, ultra-fine gesso is added by amount, stirs evenly, be cooled to room temperature 28 DEG C.
Invertibity lacquerware reparation recruits the application method of material,
(1) position is recruited using cleaning agent cleaning, cleaning agent is that the mixing that 1:1 is formed by volume of alcohol and deionized water is cleaned Agent;
(2) it carries out being heated to 80 DEG C to position is recruited using heat gun;
(3) it heats to recruiting material, makes to recruit material melts, be then cooled to 145 DEG C -155 DEG C, in the premise of barrier Under, the material that recruits of liquid is poured directly into lacquerware top defect;The material that recruits of fusing is cooled to 86 DEG C, then For the defect at the lacquerware back side, moulding is carried out to material is recruited, is added the bonding plane for recruiting material for type of having moulded using heat gun Heat is melted, and defect is bonded in;
(4) further modify the material that recruits of defect according to historical relic shape and its defect situation, it is trimmed In journey can be used heat gun heated, convenient for modify recruit material moulding at shape.
When lacquerware needs to handle again, it can will recruit material and be heated to 88 DEG C -92 DEG C, be removed after recruiting material softening, It recruits again again.
What has been described above is only a preferred embodiment of the present invention, it is noted that for those skilled in the art, Without depart from that overall concept of the invention, several changes and improvements can also be made, these also should be considered as of the invention Protection scope.

Claims (9)

1. a kind of invertibity lacquerware reparation recruits material, it is characterised in that: including following raw material by weight, rosin 15 Part, 5 parts of paraffin, 1~2 part of lignocellulosic, 5~8 parts of inorganic filler.
2. invertibity lacquerware reparation according to claim 1 or 2 recruits material, it is characterised in that: inorganic filler is nanometer At least one of silica, calcium oxide, aluminium oxide, zinc oxide, ultra-fine gesso, superfine talcum powder.
3. invertibity lacquerware reparation according to claim 1 recruits material, it is characterised in that: inorganic filler be containing CaSO4·0.5H2Filler, the rosin of O is gum rosin, paraffin is microcrystalline wax or polyethylene wax.
4. invertibity lacquerware reparation according to claim 3 recruits material, it is characterised in that: 15 parts of rosin, polyethylene wax 5 Part, 1 part of lignocellulosic, 6 parts of inorganic filler.
5. the preparation method that a kind of invertibity lacquerware reparation recruits material, it is characterised in that: include the following steps,
(1) rosin, paraffin, lignocellulosic, inorganic filler are weighed;
(2) first rosin, paraffin are placed in 150 DEG C of baking ovens, agitating and heating 20 minutes, until melting completely, are sufficiently mixed;
(3) 165 DEG C -175 DEG C are heated to, adds lignocellulosic by amount, being stirred continuously makes its dispersion;
(4) 220 DEG C~250 DEG C are again heated to, by amount add inorganic filler, stir evenly, be cooled to 35 DEG C hereinafter,.
6. the application method that invertibity lacquerware reparation recruits material, it is characterised in that:
(1) suitable cleaning agent cleaning is selected to recruit position according to different historical relics;
(2) it is heated using heat gun to position is recruited, promotion recruits material in conjunction with the surface for recruiting position;
(3) it heats to recruiting material, makes to recruit material melts, be then cooled to 145 DEG C -155 DEG C, brush in lacquerware defect Position;Or the material that recruits of fusing is cooled to 86 DEG C -94 DEG C, then to material progress moulding is recruited, will be moulded using heat gun The bonding plane heating and melting for recruiting material of good type, is bonded in defect.
7. the application method that invertibity lacquerware reparation according to claim 6 recruits material, it is characterised in that: cleaning agent is Dehydrated alcohol, acetone or dehydrated alcohol and the deionized water mixing cleaning agent that 1:1 is formed by volume.
8. the application method that invertibity lacquerware reparation according to claim 6 recruits material, it is characterised in that: step (2) It is middle to carry out being heated to 70 DEG C -80 DEG C to position is recruited using heat gun.
9. the application method that invertibity lacquerware reparation according to claim 6 recruits material, it is characterised in that: if step (3) plasticity is not inconsistent with historical relic shape and its defect situation, can be carried out according to historical relic shape and its defect situation to defect The material that recruits further modified.
CN201910707986.9A 2019-08-01 2019-08-01 Reversible paint device repairing and blending material and preparation method and application method thereof Active CN110358312B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113666663A (en) * 2021-10-20 2021-11-19 佛山市天工嘉荟文化科技有限公司 Large-area reparation ceramic defect material and ancient ceramic repair process

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN85109259A (en) * 1985-12-14 1987-06-24 沈阳市制镜厂 The process of large glass mosaic fresco
CN104356656A (en) * 2014-11-21 2015-02-18 山西大学 Anatomical wax tray and production method thereof
CN104877358A (en) * 2015-06-16 2015-09-02 张学锋 Environment-friendly sculpture mold material
CN105038696A (en) * 2015-06-29 2015-11-11 开平市盈光机电科技有限公司 Bonding agent for bonding optical lenses and manufacturing method of bonding agent
CN105713555A (en) * 2016-03-01 2016-06-29 吴持跃 Binding agent used for porcelain cultural relic repair and preparation method thereof
CN109468103A (en) * 2018-11-13 2019-03-15 柏秀颖 A kind of bonding restorative procedure of porcelain historical relic
CN109735277A (en) * 2019-01-17 2019-05-10 西南交通大学 A kind of historical relic reparation adhesives and preparation method thereof
CN109868106A (en) * 2019-02-21 2019-06-11 北京石油化工学院 A kind of adhesive and its preparation and application for historic building structure reparation

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN85109259A (en) * 1985-12-14 1987-06-24 沈阳市制镜厂 The process of large glass mosaic fresco
CN104356656A (en) * 2014-11-21 2015-02-18 山西大学 Anatomical wax tray and production method thereof
CN104877358A (en) * 2015-06-16 2015-09-02 张学锋 Environment-friendly sculpture mold material
CN105038696A (en) * 2015-06-29 2015-11-11 开平市盈光机电科技有限公司 Bonding agent for bonding optical lenses and manufacturing method of bonding agent
CN105713555A (en) * 2016-03-01 2016-06-29 吴持跃 Binding agent used for porcelain cultural relic repair and preparation method thereof
CN109468103A (en) * 2018-11-13 2019-03-15 柏秀颖 A kind of bonding restorative procedure of porcelain historical relic
CN109735277A (en) * 2019-01-17 2019-05-10 西南交通大学 A kind of historical relic reparation adhesives and preparation method thereof
CN109868106A (en) * 2019-02-21 2019-06-11 北京石油化工学院 A kind of adhesive and its preparation and application for historic building structure reparation

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
冯娜娜等: ""树脂蜡配方用于青铜器补配研究初探"", 《文物鉴定与鉴赏》 *
孔艳菊等: ""传统粘蜡胶的研制及应用性能研究"", 《文物保护与考古科学》 *
张铁成主编: "《最新新型工程材料生产新技术应用与新产品开发研制及行业技术标准实用大全 涂料与胶粘剂卷》", 30 November 2004, 学苑音像出版社 *
故宫博物院编: "《故宫博物院十年论文选(2005-2014年)》", 31 December 2015, 故宫出版社 *
贾文忠编著: "《古玩保养与修复》", 31 October 2000, 北京出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113666663A (en) * 2021-10-20 2021-11-19 佛山市天工嘉荟文化科技有限公司 Large-area reparation ceramic defect material and ancient ceramic repair process
CN113666663B (en) * 2021-10-20 2021-12-21 佛山市天工嘉荟文化科技有限公司 Large-area reparation ceramic defect material and ancient ceramic repair process

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