CN110357664A - Heat discoloration ceramic glaze and preparation method thereof - Google Patents
Heat discoloration ceramic glaze and preparation method thereof Download PDFInfo
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- CN110357664A CN110357664A CN201910537551.4A CN201910537551A CN110357664A CN 110357664 A CN110357664 A CN 110357664A CN 201910537551 A CN201910537551 A CN 201910537551A CN 110357664 A CN110357664 A CN 110357664A
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- glaze
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
Abstract
The invention discloses a kind of heat discoloration ceramic glaze and preparation method thereof, the component and each component mass parts contained in the glaze that heat discoloration ceramic glaze uses is as follows: A agent: 100 parts of transparent varnish, 12 parts of temperature-sensitive toner；B agent: 2 parts of magnetized liquid；C agent: 30 parts of acetate butyl, 30 parts of ethyl acetate, 40 parts of methyl ethyl ketone.The present invention allows classical color to become succinct and fashion, extremely simple Joker style, can arrange in pairs or groups with colors, color show different effects according to temperature change with the effect of transparent coloring.
Description
Technical field
The present invention relates to a kind of heat discoloration ceramic glazes and preparation method thereof.
Background technique
Currently, thermochromatic material is in certain temperature range, with the change of temperature significant change occurs for color
Functional material.The comprehensive research and application of thermochromatic material, have had 1 year developing history, in China so far
There is more than 30 years history.By the research and development of decades, methods have been developed inorganic, organic, liquid crystal, polymerization
All kinds of materials with thermochromic properties such as object and large biological molecule.
Currently, heat discoloration concept is fewer on ceramics, it is badly in need of having a kind of heat-resist, adhesive force in the market
By force, incrustation at low cost and paint film can be with the heat discoloration ceramic glazes of temperature automatic color-changing.
Summary of the invention
The technical problem to be solved by the present invention is to overcome the deficiencies of existing technologies, a kind of heat discoloration ceramic glaze is provided,
It allows classical color to become succinct and fashion, extremely simple Joker style, can take with colors with the effect of transparent coloring
Match, color shows different effects according to temperature change.
The technical solution for solving technical problem of the invention is: a kind of heat discoloration ceramic glaze, contains in the glaze that it is used
Some components and each component mass parts are as follows:
A agent: 100 parts of transparent varnish, 12 parts of temperature-sensitive toner；
B agent: 2 parts of magnetized liquid；
C agent: 30 parts of acetate butyl, 30 parts of ethyl acetate, 40 parts of methyl ethyl ketone.
The present invention also provides a kind of preparation method of heat discoloration ceramic glaze, the step of method in contain:
Clear up porcelain billet surface:
According to mixing nature dissolution after component and each component the mass parts stock of glaze, glaze is made；
Glaze is imposed on into porcelain billet surface；
It is dry to be sent into kiln；
It is dried in the environment of 160 DEG C, obtains finished product.
Further, 3-5 minutes dry.
Further, glaze is imposed on into the glazing in porcelain billet surface with a thickness of 10~15 μm.
After above-mentioned technical proposal, heat discoloration ceramic glaze keeps product gloss bright, and qualification rate is high；Firing temperature by
1210 DEG C are down to 160 DEG C, to save paper production time and combustion gas use cost, heat discoloration ceramic glaze product temperature significantly
At 65 DEG C, glaze colours bleaches color, and when temperature is lower than 50 DEG C, glaze becomes black.
Specific embodiment
The present invention provides a kind of heat discoloration ceramic glaze and preparation method thereof, those skilled in the art can be used for reference herein
Content is suitably modified realization of process parameters.In particular, it should be pointed out that all similar substitutions and modifications are to art technology
It is it will be apparent that they shall fall within the protection scope of the present invention for personnel.Method of the invention and application by compared with
Good embodiment is described, related personnel obviously can not depart from the content of present invention, in spirit and scope to methods herein
It is modified or appropriate changes and combinations with application, carrys out implementation and application the technology of the present invention.
A kind of heat discoloration ceramic glaze, the component and each component mass parts contained in the glaze that it is used are as follows:
A agent: 100 parts of transparent varnish, 12 parts of temperature-sensitive toner；
B agent: 2 parts of magnetized liquid；
C agent: 30 parts of acetate butyl, 30 parts of ethyl acetate, 40 parts of methyl ethyl ketone.
Contain in the step of preparation method of the heat discoloration ceramic glaze, method:
Clear up porcelain billet surface:
According to mixing nature dissolution after component and each component the mass parts stock of glaze, glaze is made；
Glaze is imposed on into porcelain billet surface；
It is dry to be sent into kiln；
It is dried in the environment of 160 DEG C, obtains finished product.
Further, 3-5 minutes dry.
Further, glaze is imposed on into the glazing in porcelain billet surface with a thickness of 10~15 μm.
Constituent content becomes more in A agent not will lead to dry phenomenon, color reddens, and color changeable effect is poor, the more blisterings of B agent, less
Colourless or color greening, color changeable effect are poor；C component is not added product and does not do, and glaze falls off.
Heat discoloration ceramic glaze of the invention keeps product gloss bright, and qualification rate is high；Firing temperature is down to 160 by 1210 DEG C
DEG C, to save paper production time and combustion gas use cost, heat discoloration ceramic glaze product temperature glaze discoloration at 65 DEG C significantly
White, when temperature is lower than 50 DEG C, glaze becomes black.
In order that the present invention can be more clearly and readily understood, below according to specific embodiment, to the present invention make into
One step detailed description.
Embodiment one
A kind of heat discoloration ceramic glaze, the component and each component mass parts contained in the glaze that it is used are as follows:
A agent: 100 parts of transparent varnish, 12 parts of temperature-sensitive toner；
B agent: 2 parts of magnetized liquid；
C agent: 30 parts of acetate butyl, 30 parts of ethyl acetate, 40 parts of methyl ethyl ketone.
Contain in a kind of the step of preparation method of heat discoloration ceramic glaze, method:
Clear up porcelain billet surface:
According to mixing nature dissolution after component and each component the mass parts stock of glaze, glaze is made；
Glaze is imposed on into porcelain billet surface；
It is 3 minutes dry to be sent into kiln；
It is dried in the environment of 160 DEG C, obtains finished product.
Glaze is imposed on into the glazing in porcelain billet surface with a thickness of 10 μm.
Embodiment two
A kind of heat discoloration ceramic glaze, the component and each component mass parts contained in the glaze that it is used are as follows: A agent: thoroughly
100 parts, 12 parts of temperature-sensitive toner of Mingguang City's oil；
B agent: 2 parts of magnetized liquid；
C agent: 30 parts of acetate butyl, 30 parts of ethyl acetate, 40 parts of methyl ethyl ketone.
Contain in a kind of the step of preparation method of heat discoloration ceramic glaze, method:
Clear up porcelain billet surface:
According to mixing nature dissolution after component and each component the mass parts stock of glaze, glaze is made；
Glaze is imposed on into porcelain billet surface；
It is 5 minutes dry to be sent into kiln；
It is dried in the environment of 160 DEG C, obtains finished product.
Glaze is imposed on into the glazing in porcelain billet surface with a thickness of 15 μm.
Comparative example one
A kind of heat discoloration ceramic glaze, the component and each component mass parts contained in the glaze that it is used are as follows: A agent: thoroughly
100 parts, 20 parts of temperature-sensitive toner of Mingguang City's oil；
B agent: 2 parts of magnetized liquid；
C agent: 30 parts of acetate butyl, 30 parts of ethyl acetate, 40 parts of methyl ethyl ketone.
Contain in a kind of the step of preparation method of heat discoloration ceramic glaze, method:
Clear up porcelain billet surface:
According to mixing nature dissolution after component and each component the mass parts stock of glaze, glaze is made；
Glaze is imposed on into porcelain billet surface；
It is 3 minutes dry to be sent into kiln；
It is dried in the environment of 160 DEG C, obtains finished product.
Glaze is imposed on into the glazing in porcelain billet surface with a thickness of 10 μm.
Comparative example two
A kind of heat discoloration ceramic glaze, the component and each component mass parts contained in the glaze that it is used are as follows:
A agent: 100 parts of transparent varnish, 5 parts of temperature-sensitive toner；
B agent: 2 parts of magnetized liquid；
C agent: 30 parts of acetate butyl, 30 parts of ethyl acetate, 40 parts of methyl ethyl ketone.
Contain in a kind of the step of preparation method of heat discoloration ceramic glaze, method:
Clear up porcelain billet surface:
According to mixing nature dissolution after component and each component the mass parts stock of glaze, glaze is made；
Glaze is imposed on into porcelain billet surface；
It is 5 minutes dry to be sent into kiln；
It is dried in the environment of 160 DEG C, obtains finished product.
Glaze is imposed on into the glazing in porcelain billet surface with a thickness of 15 μm.
It in the above comparative example and embodiment, is found by comparison, the temperature-sensitive that embodiment one and embodiment two are prepared becomes
Color ceramic glaze can embody transparent coloring effect, and color shows different effects according to temperature change, meets design
It is required that.
The heat discoloration ceramic glaze glaze face color that comparative example one is prepared reddens, and color changeable effect is poor；
The heat discoloration ceramic glaze glaze face color greening that comparative example two is prepared, color changeable effect are poor.
Particular embodiments described above has carried out further in detail the purpose of the present invention, technical scheme and beneficial effects
It describes in detail bright, it should be understood that the above is only a specific embodiment of the present invention, is not intended to restrict the invention,
All within the spirits and principles of the present invention, any modification, equivalent substitution, improvement and etc. done should be included in of the invention
Within protection scope.
Claims (4)
1. a kind of heat discoloration ceramic glaze, which is characterized in that the component and each component mass parts contained in the glaze that it is used is such as
Under:
A agent: 100 parts of transparent varnish, 12 parts of temperature-sensitive toner；
B agent: 2 parts of magnetized liquid；
C agent: 30 parts of acetate butyl, 30 parts of ethyl acetate, 40 parts of methyl ethyl ketone.
2. a kind of preparation method of heat discoloration ceramic glaze as described in claim 1, it is characterised in that contain in the step of method
Have:
Clear up porcelain billet surface:
According to mixing nature dissolution after component and each component the mass parts stock of glaze, glaze is made；
Glaze is imposed on into porcelain billet surface；
It is dry to be sent into kiln；
It is dried in the environment of 160 DEG C, obtains finished product.
3. preparation method according to claim 1, which is characterized in that
It is 3-5 minutes dry.
4. preparation method according to claim 1, which is characterized in that
Glaze is imposed on into the glazing in porcelain billet surface with a thickness of 10~15 μm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910537551.4A CN110357664A (en) | 2019-06-20 | 2019-06-20 | Heat discoloration ceramic glaze and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201910537551.4A CN110357664A (en) | 2019-06-20 | 2019-06-20 | Heat discoloration ceramic glaze and preparation method thereof |
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| CN110357664A true CN110357664A (en) | 2019-10-22 |
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| CN201910537551.4A Pending CN110357664A (en) | 2019-06-20 | 2019-06-20 | Heat discoloration ceramic glaze and preparation method thereof |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101249563A (en) * | 2007-02-23 | 2008-08-27 | 户田工业株式会社 | Black magnetic iron oxide particles |
| CN103396730A (en) * | 2013-08-15 | 2013-11-20 | 东莞市通源达喷涂科技咨询有限公司 | Thermochromic coating for metal, glass and ceramic and preparation method thereof |
| CN109233409A (en) * | 2017-05-18 | 2019-01-18 | 东北林业大学 | Temperature causes preparation and the technique for applying of Reversible Color-Changing Coating |
-
2019
- 2019-06-20 CN CN201910537551.4A patent/CN110357664A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101249563A (en) * | 2007-02-23 | 2008-08-27 | 户田工业株式会社 | Black magnetic iron oxide particles |
| CN103396730A (en) * | 2013-08-15 | 2013-11-20 | 东莞市通源达喷涂科技咨询有限公司 | Thermochromic coating for metal, glass and ceramic and preparation method thereof |
| CN109233409A (en) * | 2017-05-18 | 2019-01-18 | 东北林业大学 | Temperature causes preparation and the technique for applying of Reversible Color-Changing Coating |
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Application publication date: 20191022 |
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