CN1102864C - 含有沸石euo的催化剂及其在含8个碳的芳香化合物的异构化中的应用 - Google Patents

含有沸石euo的催化剂及其在含8个碳的芳香化合物的异构化中的应用 Download PDF

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Publication number
CN1102864C
CN1102864C CN98124082A CN98124082A CN1102864C CN 1102864 C CN1102864 C CN 1102864C CN 98124082 A CN98124082 A CN 98124082A CN 98124082 A CN98124082 A CN 98124082A CN 1102864 C CN1102864 C CN 1102864C
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catalyzer
zeolite
catalyst
group viii
weight
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Expired - Lifetime
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CN98124082A
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English (en)
Chinese (zh)
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CN1233531A (zh
Inventor
E·梅伦
F·阿拉里奥
S·拉孔布
E·伯纳兹
J·F·若利
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IFP Energies nouvelles
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IFP Energies nouvelles
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Priority claimed from FR9716458A external-priority patent/FR2772752B1/fr
Priority claimed from FR9716456A external-priority patent/FR2772642B1/fr
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Publication of CN1233531A publication Critical patent/CN1233531A/zh
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B01J29/7446—EUO-type, e.g. EU-1, TPZ-3 or ZSM-50
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/7246—EUO-type, e.g. EU-1, TPZ-3 or ZSM-50
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/2206—Catalytic processes not covered by C07C5/23 - C07C5/31
    • C07C5/222—Catalytic processes not covered by C07C5/23 - C07C5/31 with crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
    • C07C5/2724—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C07C2529/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 containing iron group metals, noble metals or copper
    • C07C2529/74—Noble metals

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN98124082A 1997-12-22 1998-12-22 含有沸石euo的催化剂及其在含8个碳的芳香化合物的异构化中的应用 Expired - Lifetime CN1102864C (zh)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
FR9716458A FR2772752B1 (fr) 1997-12-22 1997-12-22 Utilisation d'un catalyseur a base de zeolithe de structure euo en isomerisation d'une coupe c8 aromatique
FR9716456A FR2772642B1 (fr) 1997-12-22 1997-12-22 Catalyseur contenant une zeolithe de type structural euo
FR97/16456 1997-12-22
FR97/16458 1997-12-22

Publications (2)

Publication Number Publication Date
CN1233531A CN1233531A (zh) 1999-11-03
CN1102864C true CN1102864C (zh) 2003-03-12

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN98124082A Expired - Lifetime CN1102864C (zh) 1997-12-22 1998-12-22 含有沸石euo的催化剂及其在含8个碳的芳香化合物的异构化中的应用

Country Status (5)

Country Link
EP (1) EP0923987A1 (enExample)
JP (1) JP4269243B2 (enExample)
KR (1) KR100565134B1 (enExample)
CN (1) CN1102864C (enExample)
TW (1) TW533091B (enExample)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2792632B1 (fr) * 1999-04-22 2004-02-13 Inst Francais Du Petrole Procede de production de paraxylene comprenant une etape d'adsorption, une etape d'isomerisation en phase liquide et une etape d'isomerisation en phase gazeuse avec une zeolithe de type eu0
FR2795405B1 (fr) * 1999-06-22 2003-01-10 Inst Francais Du Petrole Production d'un isomere du xylene en trois etapes: separation, isomerisation avec un catalyseur a base de zeolithe euo et transalkylation avec recyclage des aromatiques en c10
FR2795406B1 (fr) 1999-06-22 2002-11-29 Inst Francais Du Petrole Procede de production d'un isomere des xylenes en trois etapes: separation, isomerisation en presence d'un catalyseur a base de zeolithe euo et transalkylation
FR2795407B1 (fr) * 1999-06-22 2001-10-05 Inst Francais Du Petrole Procede de production d'au moins un isomere des xylenes comprenant une etape d'adsorption et une etape d'isomerisation avec un catalyseur de type structural euo
FR2808520B1 (fr) * 2000-05-05 2002-08-02 Inst Francais Du Petrole Procede de preparation d'une zeolithe de type structural euo , la zeolithe obtenue et son utilisation en tant que catalyseur d'isomerisation des c8 aromatiques
FR2874516B1 (fr) * 2004-09-02 2006-12-08 Inst Francais Du Petrole Procede de regeneration d'un catalyseur contenant une zeolithe de type structural euo
FR2895283B1 (fr) * 2005-12-22 2008-02-01 Inst Francais Du Petrole Catalyseur comprenant une zeolithe euo, une zeolithe 10mr et une zeolithe 12mr et son utilisation en isomerisation des composes c8 aromatiques
FR2895282B1 (fr) * 2005-12-22 2008-02-01 Inst Francais Du Petrole Catallyseur bizeolithique comprenant un metal du groupe viii et un metal du groupe iiia et son utilisation en isomerisation des composes c8 aromatiques
FR2895281B1 (fr) * 2005-12-22 2008-09-19 Inst Francais Du Petrole Catalyseur comprenant une zeolithe de type structural nes et une zeolithe de type structural euo et son utilisation en isomerisation des composes c8 aromatiques
FR2909906B1 (fr) 2006-12-13 2009-02-06 Inst Francais Du Petrole Procede d'isomerisation des composes c8 aromatiques en presence d'un catalyseur comprenant une zeolithe euo modifiee
FR2915112B1 (fr) * 2007-04-23 2009-11-20 Inst Francais Du Petrole Procede d'isomerisation d'une coupe c8 aromatique en presence d'un catalyseur a base d'une zeolithe euo desaluminee.
FR2915113B1 (fr) * 2007-04-23 2009-06-26 Inst Francais Du Petrole Zeolithe eu-1 modifiee et son utilisation en isomerisation des composes c8 aromatiques.
FR2920423B1 (fr) * 2007-09-04 2009-11-13 Inst Francais Du Petrole Preparation d'un materiau composite poreux a base de zeolithe eu-1 et sa mise en oeuvre en isomerisation des aromatiques en c8.
US20090093662A1 (en) * 2007-10-08 2009-04-09 Whitchurch Patrick C Aromatic isomerization catalyst
CN102441420B (zh) * 2010-10-12 2013-06-19 中国石油化工股份有限公司 C8芳烃异构催化剂及其制备方法和应用
CN102441418A (zh) * 2010-10-12 2012-05-09 中国石油化工股份有限公司 一种二甲苯异构化催化剂及其制备方法和应用
CN102441419B (zh) * 2010-10-12 2013-06-19 中国石油化工股份有限公司 一种c8芳烃异构催化剂及其制备方法和应用
FR2976941B1 (fr) * 2011-06-24 2014-11-21 IFP Energies Nouvelles Procede ameliore d'isomerisation d'une coupe c8 aromatique
CN102909064B (zh) * 2011-08-01 2015-11-18 中国石油化工股份有限公司 一种甲苯与甲醇烷基化的催化剂及其制备方法和应用
FR2997948B1 (fr) * 2012-11-15 2014-11-28 IFP Energies Nouvelles Procede d'isomerisation d'une coupe c8 aromatique en presence d'un catalyseur a base d'une zeolithe euo et une teneur en sodium particuliere
FR3009207B1 (fr) * 2013-08-02 2021-04-30 Ifp Energies Now Modification de zeolithe de type euo et son utilisation en isomerisation des composes c8 aromatiques
FR3054454B1 (fr) 2016-07-26 2020-04-10 IFP Energies Nouvelles Catalyseur comprenant une zeolithe izm-2 ayant un rapport molaire si/al optimise pour l'isomerisation de coupes c8 aromatiques
FR3059325B1 (fr) 2016-11-30 2019-01-25 IFP Energies Nouvelles Utilisation d'un catalyseur a base de zeolithe izm-2 et d'un catalyseur a base de zeolithe euo pour l'isomerisation de coupes c8 aromatiques
FR3104458B1 (fr) 2019-12-17 2022-01-07 Ifp Energies Now Catalyseur a base de zeolithe izm-2 ayant une teneur en alcalin faible et son utilisation pour l’isomerisation de la coupe c8 aromatique

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4741891A (en) * 1980-06-12 1988-05-03 Imperial Chemical Industries Plc Synthesis of zeolite EU-2
CN1052619A (zh) * 1989-12-20 1991-07-03 法国石油公司 含镓的铝硅酸盐型催化剂在每分子具有5～7个碳原子的轻馏分的芳构化反应中的应用
EP0537389A1 (en) * 1991-10-16 1993-04-21 Council of Scientific and Industrial Research An improved process for the production of cumene

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3165380D1 (en) * 1980-06-12 1984-09-13 Ici Plc Zeolite eu-1
CA1169038A (en) * 1980-11-04 1984-06-12 Koji Sumitani Crystalline aluminosilicate zeolites and process for production thereof
EP0055045B1 (en) * 1980-12-19 1984-09-12 Imperial Chemical Industries Plc Production of ethers
CN1059424C (zh) * 1994-11-23 2000-12-13 埃克森化学专利公司 应用沸石结合沸石催化剂的烃转化过程

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4741891A (en) * 1980-06-12 1988-05-03 Imperial Chemical Industries Plc Synthesis of zeolite EU-2
CN1052619A (zh) * 1989-12-20 1991-07-03 法国石油公司 含镓的铝硅酸盐型催化剂在每分子具有5～7个碳原子的轻馏分的芳构化反应中的应用
EP0537389A1 (en) * 1991-10-16 1993-04-21 Council of Scientific and Industrial Research An improved process for the production of cumene

Also Published As

Publication number Publication date
JPH11244704A (ja) 1999-09-14
EP0923987A1 (fr) 1999-06-23
KR100565134B1 (ko) 2006-07-11
CN1233531A (zh) 1999-11-03
TW533091B (en) 2003-05-21
JP4269243B2 (ja) 2009-05-27
HK1022659A1 (en) 2000-08-18
KR19990063270A (ko) 1999-07-26

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