CN110282965A - A kind of anti-scald health-care ceramic product and preparation method thereof - Google Patents

A kind of anti-scald health-care ceramic product and preparation method thereof Download PDF

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CN110282965A
CN110282965A CN201910665470.2A CN201910665470A CN110282965A CN 110282965 A CN110282965 A CN 110282965A CN 201910665470 A CN201910665470 A CN 201910665470A CN 110282965 A CN110282965 A CN 110282965A
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parts
powder
green body
ceramic product
glaze layer
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郑美琼
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Fujian Dehua Qixuan Ceramic Technology Co Ltd
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Fujian Dehua Qixuan Ceramic Technology Co Ltd
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Abstract

The invention discloses a kind of anti-scald health-care ceramic products, including green body and glaze layer;Green body is by including that the raw material of following parts by weight is made: 30~45 parts of albite, 25~35 parts of anorthite, 12~16 parts of marble, 10~15 parts of bentonite, 12~17 parts of diatomite, 7~11 parts of glass fibre, 4~6.5 parts of alumina silicate fibre;Glaze layer is by including that the raw material of following parts by weight is made: 20~25 parts of albite, 15~20 parts of wollastonite in powder, 17~20 parts of mullite powder, quartzy 10~15 parts, 5~8 parts of talcum powder, 6~10 parts of opal, 4~7 parts of medical stone, 3~5 parts of tourmaline, 14~18 parts of Zijin soil, 9~13 parts of diatomite, 4~8 parts of aerolite powder.Anti-scald health-care ceramic product of the invention, thermal coefficient is low, and thermal and insulating performance is good, can effectively prevent scald user;It can produce far infrared and magnetic field, for activating the water held in ceramic;It can produce anion etc..

Description

A kind of anti-scald health-care ceramic product and preparation method thereof
Technical field
The present invention relates to ceramic fields, and in particular to a kind of anti-scald health-care ceramic product and preparation method thereof.
Background technique
The generation of domestic ceramics can be described as the demand because of people to daily life and generate, people in daily life It is in the most contact and most familiar of porcelain, such as tableware, tea set, coffee tool, drinking utensils, meal tool.
Want to enjoy a good food, not only need good food materials and production method, it is also necessary to a pottery packaged Ceramic products, such as want to bubble out the good tea of a pot and not only need good tealeaves and gimmick of making tea, it is also necessary to a tea set packaged. The various types of the ceramic utensil to circulate on the market at present, mainly have: celadon tea set, black porcelain tea set and faience tea set, these tea Tool all once had brilliant one page in Chinese tea cultural development history, but the tea set general utility functions of existing production are relatively simple, Multiple functions cannot be provided simultaneously with, can not meet people's needs, are further improved.
Summary of the invention
Based on the above situation, the purpose of the present invention is to provide a kind of anti-scald health-care ceramic product and preparation method thereof, Problem above can effectively be solved.
In order to solve the above technical problems, present invention provide the technical scheme that
A kind of anti-scald health-care ceramic product, including green body and the glaze layer for being covered in the billet surface;The green body by Raw material including following parts by weight is made: 30~45 parts of albite, 25~35 parts of anorthite, 12~16 parts of marble, bentonite 10~15 parts, 12~17 parts of diatomite, 7~11 parts of glass fibre, 4~6.5 parts of alumina silicate fibre, the basic sodium sulfonate of dodecane 1.5~2.6 parts, hydroxy-end capped 1.1~1.6 parts of poly- methyl-silicone oil, 0.7~1.2 part of waterglass, the dispersion of aqueous polyacrylamide acid sodium-salt 1.5~3.5 parts of agent;
The glaze layer is by including that the raw material of following parts by weight is made: 20~25 parts of albite, 15~20 parts of wollastonite in powder, not Come 17~20 parts of mountain flour, quartz 10~15 parts, 5~8 parts of talcum powder, 6~10 parts of opal, 4~7 parts of medical stone, tourmaline 3~ 5 parts, 14~18 parts of Zijin soil, 9~13 parts of diatomite, 4~8 parts of aerolite powder, 3~4.5 parts of aluminum oxide, magnesia 2~3.5 Part, 2~4 parts of titanium dioxide, 2.5~4.5 parts of silver.
Preferably, the green body is by including that the raw material of following parts by weight is made: 38 parts of albite, 29.5 parts of anorthite, big 14 parts of fibrous gypsum, 13.2 parts of bentonite, 14.5 parts of diatomite, 8.7 parts of glass fibre, 5.9 parts of alumina silicate fibre, the basic sulphur of dodecane 2.2 parts of sour sodium, hydroxy-end capped 1.4 parts of poly- methyl-silicone oil, 0.95 part of waterglass, 2.8 parts of aqueous polyacrylamide acid sodium-salt dispersing agent;
The glaze layer is by including that the raw material of following parts by weight is made: 23 parts of albite, 17.5 parts of wollastonite in powder, mullite powder 19 parts, 13.5 parts of quartz, 6.8 parts of talcum powder, 8 parts of opal, 5.5 parts of medical stone, 4 parts of tourmaline, Zijin native 16.5 parts, diatom 11.3 parts of soil, 6.6 parts of aerolite powder, 3.5 parts of aluminum oxide, 2.7 parts of magnesia, 2.5 parts of titanium dioxide, 3.6 parts of silver.
Preferably, the aerolite powder is pallasite powder.
Preferably, the aluminum oxide, magnesia, titanium dioxide and silver are respectively nano-aluminium oxide, nano oxygen Change magnesium, nano-titanium dioxide and nano silver.
Preferably, the glaze layer further includes 8~11 parts of rare earth oxide.
Preferably, the rare earth oxide be lanthana, neodymia, thulium oxide and samarium oxide in any one or it is more Kind.
The present invention also provides the preparation methods of the anti-scald health-care ceramic product described in one kind, including the following steps:
A, green body slurry is prepared;
B, green body slurry is crossed into 200 meshes, then carries out de-bubble, then sizing obtains crude green body, it dries in the shade naturally, sharp base, most Afterwards by the way of being gradually warmed up, 900~1000 DEG C are gradually heated to, 2~4h is fired, is then warming up to 1050~1150 again DEG C, continue, fire 3~5h, be finally cooled to 650~700 DEG C, keep the temperature 1~2h, furnace cooling obtains biscuit ware;
C, glaze layer slurry is prepared;
D, glaze layer slurry is crossed into 300 meshes, then carries out froth in vacuum, obtain glaze water, and adjusting glaze water solid content is 58 ~65%, glazing is carried out to the biscuit ware that step B is obtained using glaze water, finally carries out glaze under conditions of 1120~1180 DEG C 2~4 hours are burnt to get the anti-scald health-care ceramic product.
Preferably, in step A, the method for preparing green body slurry are as follows: weigh albite, anorthite, big respectively by weight The basic sodium sulfonate of fibrous gypsum, bentonite, diatomite, glass fibre, alumina silicate fibre, dodecane, hydroxy-end capped poly- methyl-silicone oil, water Glass and aqueous polyacrylamide acid sodium-salt dispersing agent after mixing, are sent into ball mill, carry out 30~45min of ball milling, wherein when ball milling, The weight ratio of mixture, ball and water are as follows: 1:2.2:0.6 obtains green body slurry.
Preferably, in step C, prepare glaze layer slurry method are as follows: weigh respectively by weight albite, wollastonite in powder, Mullite powder, quartz, talcum powder, opal, medical stone, tourmaline, aerolite powder, Zijin soil and diatomite, after mixing, are sent into ball Grinding machine carries out 35~50min of ball milling, wherein when ball milling, the weight ratio of mixture, ball and water are as follows: 1:2.1:0.7;Then by weight Amount part weighs aluminum oxide, magnesia, titanium dioxide and silver respectively, after mixing, is added in the ball mill, continues ball milling mixing 10~15min obtains glaze layer slurry.
Compared with prior art, the present invention have the following advantages that and the utility model has the advantages that
The present invention by the constitutive material of selected green body and glaze layer, and the proportion of optimization green body and glaze layer constitutive material, Anti-scald health-care ceramic product obtained, green body inside are foaming structure, have stomata uniformly fine and close, and thermal coefficient is low, protects Warm heat-proof quality is good, can effectively prevent scald user, use is safer, more popular with consumers;In use, glaze layer can produce Far infrared and magnetic field can make water molecule activation, improve dissolution for activating the water held in ceramic (such as tea set) Degree, is completely dissolved in the effective component in food (such as tealeaves) in water, is conducive to absorption of human body, body immunity can be improved, A variety of pairs of human body beneficial mineral matters and microelement are released simultaneously;Anion can be steadily generated, and anion burst size is big; With good antibacterial effect;Water absorption rate is low;Ceramic product appearance, intensity, quality etc. are comprehensive good.
Anti-scald health-care ceramic product of the invention, green body is with albite, anorthite, marble, bentonite, diatomite For primary raw material, forming temperature is lower, can be energy saving, and can guarantee the intensity of product, and thermal coefficient compares lower;Addition The glass fibre of proper proportion, alumina silicate fibre facilitate the intensity for enhancing product, and further decrease thermal coefficient, increase Strong heat insulation;Using the basic sodium sulfonate of dodecane as foaming agent, with hydroxy-end capped poly- methyl-silicone oil, waterglass in appropriate proportions Make used additives with aqueous polyacrylamide acid sodium-salt dispersing agent, binding force is strong between each component, and foaming forms uniform and densification larger Abscess, green body obtained, density is low, light weight, while having taken into account high porosity and intensity well, more durable.
The present invention introduces the pallasite powder of proper proportion in the constitutive material of glaze layer, protects anti-scald of the invention Strong ceramic glaze layer can produce far infrared and magnetic field, for activating the water held in ceramic (such as tea set), can make Water molecule activation improves solubility, is completely dissolved in the effective component in food (such as tealeaves) in water, is conducive to human body suction It receives.
Anti-scald health-care ceramic product of the invention, glaze layer is with albite, wollastonite in powder, mullite powder, quartz, talcum Powder, opal, medical stone, tourmaline, aerolite powder, Zijin soil and diatomite are main constitutive material, nontoxic, enjoy food Not only heavy metal or hazardous compound the amount of dissolution are very low when (such as infusing tea), and body immunity can be improved, while releasing more Kind is to human body beneficial mineral matter and microelement.
The present invention introduces the opal, medical stone, tourmaline of proper proportion in the constitutive material of glaze layer, makes the present invention Anti-scald health-care ceramic product can steadily generate anion, and anion burst size is big.
The present invention introduced in the constitutive material of glaze layer the aluminum oxide of proper proportion, magnesia, titanium dioxide and Silver makes anti-scald health-care ceramic product of the invention have good antibacterial (antibacterial) effect, and makes ceramic of the invention Smooth in appearance, glossiness it is good.
Specific embodiment
It is right combined with specific embodiments below in order to make those skilled in the art more fully understand technical solution of the present invention The preferred embodiments of the invention are described, but should not be understood as the limitation to this patent.
Test method described in following embodiments or test method are unless otherwise specified conventional method;The reagent And material is obtained from routine business approach, or prepare in conventional manner unless otherwise specified.
Embodiment 1:
A kind of anti-scald health-care ceramic product (such as ceramic utensil), including green body and the glaze for being covered in the billet surface Layer;The green body is by including that the raw material of following parts by weight is made: 30~45 parts of albite, 25~35 parts of anorthite, marble 12 ~16 parts, 10~15 parts of bentonite, 12~17 parts of diatomite, 7~11 parts of glass fibre, 4~6.5 parts of alumina silicate fibre, 12 1.5~2.6 parts of alkyl this sodium sulfonate, hydroxy-end capped 1.1~1.6 parts of poly- methyl-silicone oil, 0.7~1.2 part of waterglass, aqueous poly- third 1.5~3.5 parts of olefin(e) acid sodium salt dispersing agent;
The glaze layer is by including that the raw material of following parts by weight is made: 20~25 parts of albite, 15~20 parts of wollastonite in powder, not Come 17~20 parts of mountain flour, quartz 10~15 parts, 5~8 parts of talcum powder, 6~10 parts of opal, 4~7 parts of medical stone, tourmaline 3~ 5 parts, 14~18 parts of Zijin soil, 9~13 parts of diatomite, 4~8 parts of aerolite powder, 3~4.5 parts of aluminum oxide, magnesia 2~3.5 Part, 2~4 parts of titanium dioxide, 2.5~4.5 parts of silver.
In the present embodiment, the green body is by including that the raw material of following parts by weight is made: 38 parts of albite, anorthite 29.5 Part, 14 parts of marble, 13.2 parts of bentonite, 14.5 parts of diatomite, 8.7 parts of glass fibre, 5.9 parts of alumina silicate fibre, dodecane Basic 2.2 parts of sodium sulfonate, hydroxy-end capped 1.4 parts of poly- methyl-silicone oil, 0.95 part of waterglass, aqueous polyacrylamide acid sodium-salt dispersing agent 2.8 part;
The glaze layer is by including that the raw material of following parts by weight is made: 23 parts of albite, 17.5 parts of wollastonite in powder, mullite powder 19 parts, 13.5 parts of quartz, 6.8 parts of talcum powder, 8 parts of opal, 5.5 parts of medical stone, 4 parts of tourmaline, Zijin native 16.5 parts, diatom 11.3 parts of soil, 6.6 parts of aerolite powder, 3.5 parts of aluminum oxide, 2.7 parts of magnesia, 2.5 parts of titanium dioxide, 3.6 parts of silver.
In the present embodiment, the aerolite powder is pallasite powder.
In the present embodiment, the aluminum oxide, magnesia, titanium dioxide and silver be respectively nano-aluminium oxide, Nano magnesia, nano-titanium dioxide and nano silver.
In the present embodiment, the glaze layer further includes 8~11 parts of rare earth oxide.
In the present embodiment, the rare earth oxide is any one in lanthana, neodymia, thulium oxide and samarium oxide Or it is a variety of.
In the present embodiment, the preparation method of the anti-scald health-care ceramic product, which is characterized in that including following step It is rapid:
A, green body slurry is prepared;
B, green body slurry is crossed into 200 meshes, then carries out de-bubble, then sizing obtains crude green body, it dries in the shade naturally, sharp base, most Afterwards by the way of being gradually warmed up, 900~1000 DEG C are gradually heated to, 2~4h is fired, is then warming up to 1050~1150 again DEG C, continue, fire 3~5h, be finally cooled to 650~700 DEG C, keep the temperature 1~2h, furnace cooling obtains biscuit ware;
C, glaze layer slurry is prepared;
D, glaze layer slurry is crossed into 300 meshes, then carries out froth in vacuum, obtain glaze water, and adjusting glaze water solid content is 58 ~65%, glazing is carried out to the biscuit ware that step B is obtained using glaze water, finally carries out glaze under conditions of 1120~1180 DEG C 2~4 hours are burnt to get the anti-scald health-care ceramic product.
In the present embodiment, in step A, the method for preparing green body slurry are as follows: it is long to weigh albite, calcium respectively by weight The basic sodium sulfonate of stone, marble, bentonite, diatomite, glass fibre, alumina silicate fibre, dodecane, hydroxy-end capped poly- methyl silicon Oil, waterglass and aqueous polyacrylamide acid sodium-salt dispersing agent after mixing, are sent into ball mill, carry out 30~45min of ball milling, wherein ball When mill, the weight ratio of mixture, ball and water are as follows: 1:2.2:0.6 obtains green body slurry.
In the present embodiment, in step C, the method for preparation glaze layer slurry are as follows: weigh albite, silicon ash respectively by weight Mountain flour, mullite powder, quartz, talcum powder, opal, medical stone, tourmaline, aerolite powder, Zijin soil and diatomite, after mixing, It is sent into ball mill, carries out 35~50min of ball milling, wherein when ball milling, the weight ratio of mixture, ball and water are as follows: 1:2.1:0.7;So It weighs aluminum oxide, magnesia, titanium dioxide and silver respectively by weight afterwards, after mixing, is added in the ball mill, continue ball Mill 10~15min of mixing, obtains glaze layer slurry.
Embodiment 2:
A kind of anti-scald health-care ceramic product (such as ceramic utensil), including green body and the glaze for being covered in the billet surface Layer;The green body is by including that the raw material of following parts by weight is made: 30 parts of albite, 25 parts of anorthite, 12 parts of marble, bentonite 10 parts, 12 parts of diatomite, 7 parts of glass fibre, 4 parts of alumina silicate fibre, 1.5 parts of the basic sodium sulfonate of dodecane, hydroxy-end capped poly- first 1.1 parts of base silicone oil, 0.7 part of waterglass, 1.5 parts of aqueous polyacrylamide acid sodium-salt dispersing agent;
The glaze layer is by including that the raw material of following parts by weight is made: 20 parts of albite, 15 parts of wollastonite in powder, mullite powder 17 Part, 10 parts of quartz, 5 parts of talcum powder, 6 parts of opal, 4 parts of medical stone, 3 parts of tourmaline, Zijin native 14 parts, 9 parts of diatomite, aerolite 4 parts of powder, 3 parts of aluminum oxide, 2 parts of magnesia, 2 parts of titanium dioxide, 2.5 parts of silver.
In the present embodiment, the aerolite powder is pallasite powder.
In the present embodiment, the aluminum oxide, magnesia, titanium dioxide and silver be respectively nano-aluminium oxide, Nano magnesia, nano-titanium dioxide and nano silver.
In the present embodiment, the glaze layer further includes 8 parts of rare earth oxide.
In the present embodiment, the rare earth oxide is lanthana.
In the present embodiment, the preparation method of the anti-scald health-care ceramic product, which is characterized in that including following step It is rapid:
A, green body slurry is prepared;
B, green body slurry is crossed into 200 meshes, then carries out de-bubble, then sizing obtains crude green body, it dries in the shade naturally, sharp base, most Afterwards by the way of being gradually warmed up, 900 DEG C are gradually heated to, fires 4h, is then warming up to 1050 DEG C again, is continued, fires 5h, most After be cooled to 650 DEG C, keep the temperature 2h, furnace cooling obtains biscuit ware;
C, glaze layer slurry is prepared;
D, glaze layer slurry is crossed into 300 meshes, then carries out froth in vacuum, obtain glaze water, and adjusted glaze water solid content and be 58%, glazing is carried out to the biscuit ware that step B is obtained using glaze water, glaze firing 4 hours is finally carried out under conditions of 1120 DEG C, Up to the anti-scald health-care ceramic product.
In the present embodiment, in step A, the method for preparing green body slurry are as follows: it is long to weigh albite, calcium respectively by weight The basic sodium sulfonate of stone, marble, bentonite, diatomite, glass fibre, alumina silicate fibre, dodecane, hydroxy-end capped poly- methyl silicon Oil, waterglass and aqueous polyacrylamide acid sodium-salt dispersing agent after mixing, are sent into ball mill, carry out ball milling 30min, wherein when ball milling, The weight ratio of mixture, ball and water are as follows: 1:2.2:0.6 obtains green body slurry.
In the present embodiment, in step C, the method for preparation glaze layer slurry are as follows: weigh albite, silicon ash respectively by weight Mountain flour, mullite powder, quartz, talcum powder, opal, medical stone, tourmaline, aerolite powder, Zijin soil and diatomite, after mixing, It is sent into ball mill, carries out ball milling 35min, wherein when ball milling, the weight ratio of mixture, ball and water are as follows: 1:2.1:0.7;Then it presses Parts by weight weigh aluminum oxide, magnesia, titanium dioxide and silver respectively, after mixing, are added in the ball mill, and it is mixed to continue ball milling 10min is closed, glaze layer slurry is obtained.
Embodiment 3:
A kind of anti-scald health-care ceramic product (such as ceramic utensil), including green body and the glaze for being covered in the billet surface Layer;The green body is by including that the raw material of following parts by weight is made: 45 parts of albite, 35 parts of anorthite, 16 parts of marble, bentonite 15 parts, it is 17 parts of diatomite, 11 parts of glass fibre, 6.5 parts of alumina silicate fibre, 2.6 parts of the basic sodium sulfonate of dodecane, hydroxy-end capped poly- 1.6 parts of methyl-silicone oil, 1.2 parts of waterglass, 3.5 parts of aqueous polyacrylamide acid sodium-salt dispersing agent;
The glaze layer is by including that the raw material of following parts by weight is made: 25 parts of albite, 20 parts of wollastonite in powder, mullite powder 20 Part, 8 parts of talcum powder, 10 parts of opal, 7 parts of medical stone, 5 parts of tourmaline, 18 parts of Zijin soil, 13 parts of diatomite, is fallen from the sky or outer space at 15 parts of quartz 8 parts of mountain flour, 4.5 parts of aluminum oxide, 3.5 parts of magnesia, 4 parts of titanium dioxide, 4.5 parts of silver.
In the present embodiment, the aerolite powder is pallasite powder.
In the present embodiment, the aluminum oxide, magnesia, titanium dioxide and silver be respectively nano-aluminium oxide, Nano magnesia, nano-titanium dioxide and nano silver.
In the present embodiment, the glaze layer further includes 11 parts of rare earth oxide.
In the present embodiment, the rare earth oxide is the thulium oxide and samarium oxide that mass ratio is 1:1.2.
In the present embodiment, the preparation method of the anti-scald health-care ceramic product, which is characterized in that including following step It is rapid:
A, green body slurry is prepared;
B, green body slurry is crossed into 200 meshes, then carries out de-bubble, then sizing obtains crude green body, it dries in the shade naturally, sharp base, most Afterwards by the way of being gradually warmed up, 1000 DEG C are gradually heated to, fires 2h, is then warming up to 1150 DEG C again, is continued, 3h is fired, 700 DEG C are finally cooled to, 1h is kept the temperature, furnace cooling obtains biscuit ware;
C, glaze layer slurry is prepared;
D, glaze layer slurry is crossed into 300 meshes, then carries out froth in vacuum, obtain glaze water, and adjusted glaze water solid content and be 65%, glazing is carried out to the biscuit ware that step B is obtained using glaze water, glaze firing 2 hours is finally carried out under conditions of 1180 DEG C, Up to the anti-scald health-care ceramic product.
In the present embodiment, in step A, the method for preparing green body slurry are as follows: it is long to weigh albite, calcium respectively by weight The basic sodium sulfonate of stone, marble, bentonite, diatomite, glass fibre, alumina silicate fibre, dodecane, hydroxy-end capped poly- methyl silicon Oil, waterglass and aqueous polyacrylamide acid sodium-salt dispersing agent after mixing, are sent into ball mill, carry out ball milling 45min, wherein when ball milling, The weight ratio of mixture, ball and water are as follows: 1:2.2:0.6 obtains green body slurry.
In the present embodiment, in step C, the method for preparation glaze layer slurry are as follows: weigh albite, silicon ash respectively by weight Mountain flour, mullite powder, quartz, talcum powder, opal, medical stone, tourmaline, aerolite powder, Zijin soil and diatomite, after mixing, It is sent into ball mill, carries out ball milling 50min, wherein when ball milling, the weight ratio of mixture, ball and water are as follows: 1:2.1:0.7;Then it presses Parts by weight weigh aluminum oxide, magnesia, titanium dioxide and silver respectively, after mixing, are added in the ball mill, and it is mixed to continue ball milling 15min is closed, glaze layer slurry is obtained.
Embodiment 4:
A kind of anti-scald health-care ceramic product (such as ceramic utensil), including green body and the glaze for being covered in the billet surface Layer;The green body is by including that the raw material of following parts by weight is made: 38 parts of albite, 29.5 parts of anorthite, 14 parts of marble, swelling Native 13.2 parts, 14.5 parts of diatomite, 8.7 parts of glass fibre, 5.9 parts of alumina silicate fibre, 2.2 parts of the basic sodium sulfonate of dodecane, hydroxyl Base blocks poly- 1.4 parts of methyl-silicone oil, 0.95 part of waterglass, 2.8 parts of aqueous polyacrylamide acid sodium-salt dispersing agent;
The glaze layer is by including that the raw material of following parts by weight is made: 23 parts of albite, 17.5 parts of wollastonite in powder, mullite powder 19 parts, 13.5 parts of quartz, 6.8 parts of talcum powder, 8 parts of opal, 5.5 parts of medical stone, 4 parts of tourmaline, Zijin native 16.5 parts, diatom 11.3 parts of soil, 6.6 parts of aerolite powder, 3.5 parts of aluminum oxide, 2.7 parts of magnesia, 2.5 parts of titanium dioxide, 3.6 parts of silver.
In the present embodiment, the aerolite powder is pallasite powder.
In the present embodiment, the aluminum oxide, magnesia, titanium dioxide and silver be respectively nano-aluminium oxide, Nano magnesia, nano-titanium dioxide and nano silver.
In the present embodiment, the glaze layer further includes 9.6 parts of rare earth oxide.
In the present embodiment, the rare earth oxide is the neodymia and samarium oxide that mass ratio is 1:0.85.
In the present embodiment, the preparation method of the anti-scald health-care ceramic product, which is characterized in that including following step It is rapid:
A, green body slurry is prepared;
B, green body slurry is crossed into 200 meshes, then carries out de-bubble, then sizing obtains crude green body, it dries in the shade naturally, sharp base, most Afterwards by the way of being gradually warmed up, 950 DEG C are gradually heated to, fires 3h, is then warming up to 1120 DEG C again, is continued, fires 4h, most After be cooled to 675 DEG C, keep the temperature 1.5h, furnace cooling obtains biscuit ware;
C, glaze layer slurry is prepared;
D, glaze layer slurry is crossed into 300 meshes, then carries out froth in vacuum, obtain glaze water, and adjusted glaze water solid content and be 62%, glazing is carried out to the biscuit ware that step B is obtained using glaze water, glaze firing 3 hours is finally carried out under conditions of 1160 DEG C, Up to the anti-scald health-care ceramic product.
In the present embodiment, in step A, the method for preparing green body slurry are as follows: it is long to weigh albite, calcium respectively by weight The basic sodium sulfonate of stone, marble, bentonite, diatomite, glass fibre, alumina silicate fibre, dodecane, hydroxy-end capped poly- methyl silicon Oil, waterglass and aqueous polyacrylamide acid sodium-salt dispersing agent after mixing, are sent into ball mill, carry out ball milling 40min, wherein when ball milling, The weight ratio of mixture, ball and water are as follows: 1:2.2:0.6 obtains green body slurry.
In the present embodiment, in step C, the method for preparation glaze layer slurry are as follows: weigh albite, silicon ash respectively by weight Mountain flour, mullite powder, quartz, talcum powder, opal, medical stone, tourmaline, aerolite powder, Zijin soil and diatomite, after mixing, It is sent into ball mill, carries out ball milling 45min, wherein when ball milling, the weight ratio of mixture, ball and water are as follows: 1:2.1:0.7;Then it presses Parts by weight weigh aluminum oxide, magnesia, titanium dioxide and silver respectively, after mixing, are added in the ball mill, and it is mixed to continue ball milling 12min is closed, glaze layer slurry is obtained.
The obtained anti-scald health-care ceramic product of embodiment 2 to 4 and ordinary pottery products are tested for the property, tied Fruit is as shown in table 1.
Table 1
The above is only the preferred embodiment of the present invention, it is noted that above-mentioned preferred embodiment is not construed as pair Limitation of the invention, protection scope of the present invention should be defined by the scope defined by the claims..For the art For those of ordinary skill, without departing from the spirit and scope of the present invention, several improvements and modifications can also be made, these change It also should be regarded as protection scope of the present invention into retouching.

Claims (9)

1. a kind of anti-scald health-care ceramic product, which is characterized in that including green body and the glaze layer for being covered in the billet surface;Institute Green body is stated by including that the raw material of following parts by weight is made: 30~45 parts of albite, 25~35 parts of anorthite, marble 12~16 Part, 10~15 parts of bentonite, 12~17 parts of diatomite, 7~11 parts of glass fibre, 4~6.5 parts of alumina silicate fibre, dodecyl 1.5~2.6 parts of this sodium sulfonate, hydroxy-end capped 1.1~1.6 parts of poly- methyl-silicone oil, 0.7~1.2 part of waterglass, aqueous polyacrylamide acid 1.5~3.5 parts of sodium salt dispersing agent;The glaze layer is by including that the raw material of following parts by weight is made: 20~25 parts of albite, wollastonite 15~20 parts of powder, 17~20 parts of mullite powder, 10~15 parts of quartz, 5~8 parts of talcum powder, 6~10 parts of opal, medical stone 4~ 7 parts, 3~5 parts of tourmaline, 14~18 parts of Zijin soil, 9~13 parts of diatomite, 4~8 parts of aerolite powder, aluminum oxide 3~4.5 Part, 2~3.5 parts of magnesia, 2~4 parts of titanium dioxide, 2.5~4.5 parts of silver.
2. anti-scald health-care ceramic product according to claim 1, which is characterized in that the green body is by including following weight The raw material of part is made: 38 parts of albite, 29.5 parts of anorthite, 14 parts of marble, 13.2 parts of bentonite, 14.5 parts of diatomite, glass 8.7 parts of glass fiber, 5.9 parts of alumina silicate fibre, 2.2 parts of the basic sodium sulfonate of dodecane, hydroxy-end capped 1.4 parts of poly- methyl-silicone oil, water 0.95 part of glass, 2.8 parts of aqueous polyacrylamide acid sodium-salt dispersing agent;
The glaze layer is by including that the raw material of following parts by weight is made: 23 parts of albite, 17.5 parts of wollastonite in powder, mullite powder 19 Part, 13.5 parts of quartz, 6.8 parts of talcum powder, 8 parts of opal, 5.5 parts of medical stone, 4 parts of tourmaline, Zijin native 16.5 parts, diatomite 11.3 parts, 6.6 parts of aerolite powder, 3.5 parts of aluminum oxide, 2.7 parts of magnesia, 2.5 parts of titanium dioxide, 3.6 parts of silver.
3. anti-scald health-care ceramic product according to claim 1, which is characterized in that the aerolite powder is pallasite Powder.
4. anti-scald health-care ceramic product according to claim 1, which is characterized in that the aluminum oxide, magnesia, Titanium dioxide and silver are respectively nano-aluminium oxide, nano magnesia, nano-titanium dioxide and nano silver.
5. anti-scald health-care ceramic product according to claim 1, which is characterized in that the glaze layer further includes rare-earth oxidation 8~11 parts of object.
6. anti-scald health-care ceramic product according to claim 5, which is characterized in that the rare earth oxide is oxidation Any one or more in lanthanum, neodymia, thulium oxide and samarium oxide.
7. a kind of preparation method of such as anti-scald health-care ceramic product as claimed in any one of claims 1 to 6, which is characterized in that Include the following steps:
A, green body slurry is prepared;
B, green body slurry is crossed into 200 meshes, then carries out de-bubble, then sizing obtains crude green body, dries in the shade naturally, sharp base is finally adopted With the mode being gradually warmed up, 900~1000 DEG C are gradually heated to, 2~4h is fired, is then warming up to 1050~1150 DEG C again, after It is continuous, 3~5h is fired, is finally cooled to 650~700 DEG C, keeps the temperature 1~2h, furnace cooling obtains biscuit ware;
C, glaze layer slurry is prepared;
D, glaze layer slurry is crossed into 300 meshes, then carries out froth in vacuum, obtain glaze water, and adjust glaze water solid content be 58~ 65%, glazing is carried out to the biscuit ware that step B is obtained using glaze water, finally carries out glaze firing 2 under conditions of 1120~1180 DEG C ~4 hours to get the anti-scald health-care ceramic product.
8. the preparation method of anti-scald health-care ceramic product according to claim 7, which is characterized in that in step A, preparation The method of green body slurry are as follows: weigh respectively by weight albite, anorthite, marble, bentonite, diatomite, glass fibre, The basic sodium sulfonate of alumina silicate fibre, dodecane, hydroxy-end capped poly- methyl-silicone oil, waterglass and the dispersion of aqueous polyacrylamide acid sodium-salt Agent after mixing, is sent into ball mill, carries out 30~45min of ball milling, wherein when ball milling, the weight ratio of mixture, ball and water are as follows: 1: 2.2:0.6 obtains green body slurry.
9. the preparation method of anti-scald health-care ceramic product according to claim 7, which is characterized in that in step C, preparation The method of glaze layer slurry are as follows: weigh respectively by weight albite, wollastonite in powder, mullite powder, quartz, talcum powder, opal, Medical stone, tourmaline, aerolite powder, Zijin soil and diatomite, after mixing, are sent into ball mill, carry out 35~50min of ball milling, wherein When ball milling, the weight ratio of mixture, ball and water are as follows: 1:2.1:0.7;Then aluminum oxide, oxidation are weighed respectively by weight Magnesium, titanium dioxide and silver after mixing, are added in the ball mill, continue 10~15min of ball milling mixing, obtain glaze layer slurry.
CN201910665470.2A 2019-07-23 2019-07-23 A kind of anti-scald health-care ceramic product and preparation method thereof Pending CN110282965A (en)

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