CN108863404A - The fireproof heat preservation decorative board material of pure inorganic material - Google Patents

The fireproof heat preservation decorative board material of pure inorganic material Download PDF

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Publication number
CN108863404A
CN108863404A CN201810841496.3A CN201810841496A CN108863404A CN 108863404 A CN108863404 A CN 108863404A CN 201810841496 A CN201810841496 A CN 201810841496A CN 108863404 A CN108863404 A CN 108863404A
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China
Prior art keywords
heat preservation
decorative board
insulating layer
inorganic material
surface layer
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CN201810841496.3A
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Inventor
张辉
李方勇
王晓峰
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Shandong Ju An Inorganic Insulation Decorative Material Co Ltd
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Shandong Ju An Inorganic Insulation Decorative Material Co Ltd
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Priority to CN201810841496.3A priority Critical patent/CN108863404A/en
Publication of CN108863404A publication Critical patent/CN108863404A/en
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/62204—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products using waste materials or refuse
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • C—CHEMISTRY; METALLURGY
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    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
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    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
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    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
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    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C04B41/85—Coating or impregnation with inorganic materials
    • C04B41/86—Glazes; Cold glazes
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00—Coverings or linings, e.g. for walls or ceilings
    • E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/0875—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements having a basic insulating layer and at least one covering layer
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    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427—Silicates other than clay, e.g. water glass
    • C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
    • C04B2235/3472—Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
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    • C04B2235/3427—Silicates other than clay, e.g. water glass
    • C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
    • C04B2235/3481—Alkaline earth metal alumino-silicates other than clay, e.g. cordierite, beryl, micas such as margarite, plagioclase feldspars such as anorthite, zeolites such as chabazite
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    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/349—Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
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    • C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
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Abstract

The present invention relates to a kind of fireproof heat preservation decorative board materials of pure inorganic material, belong to the production field of exterior walls of buildings insulation and decoration industry；The present invention includes surface layer and plate layer, and the surface layer is the light foamed ceramic plate with decorative effect, and insulating layer is the sintering grow pearlite heat-insulation plate of rigid inorganic material, and surface layer and insulating layer are bonded by inorganic adhesive mortar；The thermal coefficient for obtaining surface layer is 0.06-0.07W/m.K, and insulating layer thermal coefficient is 0.045-0.055W/m.K.Present invention bonding securely because being inorganic material and wall, bonding mortar have natural a knot and power, and because being rigid bonding, will not flexible deformation, so bonding is securely, not easily to fall off, safety is good.

Description

The fireproof heat preservation decorative board material of pure inorganic material
Technical field
The present invention relates to a kind of fireproof heat preservation decorative board materials of pure inorganic material, belong to exterior walls of buildings insulation and decoration industry Production field.
Background technique
Insulation and decoration body plate is to consist of two parts：It plays the surface layer of decorative effect and plays the insulating layer of heat insulation effect.Surface layer Material it is currently used have it is following several：It is coated with the calcium silicate board of the organic coatings such as lacquer, F-C paint, color coated aluminum sheet, day Right or artificial marble etc..There is following disadvantages for current surface material：Organic coating and calcium silicate board with microporous durability are bad, the time Long can weather stain, lose decorative effect.Aluminium sheet price is too high, it is difficult to universal.
Marble is too heavy, is easy to fall off, and causes security risk.The currently used material of insulating layer has following several：It is organic Material has styrofoam (EPS), extruded sheet (XPS), polyurethane (PUR) and phenolic board, inorganic material there was only rock wool board.
The fire-fighting policies and regulations that the fire resistance rating of organic material is not achieved A grades, does not meet country, and the bonding with wall Firmness is not high, is easy to fall off, and the problem of aging of organic material is serious, just loses heat insulation effect within general 20 years or so.Rock Cotton plate is at present using most inorganic heat insulation materials, and fire resistance rating is A grades, but rock wool board equally has volume contraction, moisture absorption swollen It is swollen, tensile strength is low, the problem of being easy to fall off.The bonding of current insulating layer and outside vertical surface of building be all it is flexible, this Kind of elastic adhesive be it is unstable, have cubic deformation over time, the problem of moisture expantion, aging become fragile, almost Heat-insulation system will can not be overhauled again within 20 years or so with the building same service life, to cause manpower and material resources and provide naturally The significant wastage in source.
In conclusion there are following problem to be solved and disadvantages for existing insulation and decoration-body plate：It is easy old Change, cementability is poor, moisture expantion, is easy to fall off.
Summary of the invention
It is insufficient according to prior art, the technical problem to be solved by the present invention is to：A kind of fire prevention of pure inorganic material is provided Heat-insulation decorative slab can be realized heat insulation decoration integrated plate, and does not allow easy to aging and fall off, and can have good bonding Property, long service life is more beautiful, and performance is better.
The technical solution adopted by the present invention to solve the technical problems is：A kind of fireproof heat insulating dress of pure inorganic material is provided Decoratice board, including surface layer and plate layer, the surface layer are the light foamed ceramic plates with decorative effect, and insulating layer is rigid nothing The sintering grow pearlite heat-insulation plate of machine material, surface layer and insulating layer are bonded by inorganic adhesive mortar；
The thermal coefficient for obtaining surface layer is 0.06-0.07W/m.K, and insulating layer thermal coefficient is 0.045-0.055W/ m.K。
It is 400-600kg/m that the light foamed ceramic plate, which obtains density,3。
The insulating layer density is 140-160kg/m3。
The thickness proportion of the surface layer and insulating layer is 15: (60-80).
The surface material is made of bottom material, fabric and glaze, and each section formula is as follows：
The formula of bottom material is made of following mass percent raw material：
Perlite tailing 50-80%
Feldspar 10-40%
Bentonite 5-30%
Kaolin 4-20%
Foaming agent 0.02-0.1%
Water-reducing agent 0.1-0.5%；
The formula of the fabric is made of following mass percent raw material：
Perlite tailing 40-70%；
Feldspar 20-50%；
Bentonite 5-30%；
Kaolin 4.5-20%；
Foaming agent 0.05-0.5%；
Water-reducing agent 0.1-0.5%.
The foaming agent is the silicon carbide micro-powder of 1000 mesh fineness；The water-reducing agent is sodium tripolyphosphate.
The formula of the glaze is made of following mass percent raw material：
Low temperature frit：40-80%
Aluminium oxide：5-15%
Zinc oxide：3-10%
Kaolin：5-10%
Calcium carbonate：5-20%
Sodium tripolyphosphate：0.5-1%
Hydroxymethyl cellulose：0.1-0.5%.
Surface material is made of bottom material, fabric and glaze, passes through secondary material distributing technique, high pressure compacting, dry glazing, dress It sets.
The formula of the insulating layer is made of following mass percent raw material：
Perlite particle：70-80%
Binder：20-30%.
The perlite particle proportion is uniformly distributed for 0.1-8mm；The binder be bentonite, low temperature frit, Aluminium dihydrogen phosphate and water are ground.
The perlite particle is with before needing extruding good.
The beneficial effects of the invention are as follows：
1, A grades of fire prevention material therefors are all inorganic silicate materials, and the present patent application product fire protecting performance is good；
2, heat insulation effect is good, and comprehensive thermal coefficient is 0.05 --- 0.06 (W/m.K)；
3, light-weight whether surface layer or insulating layer have reached lighter weight；
4, bonding because being inorganic material and wall, bonding mortar have natural a knot and power, and because is that rigidity is viscous securely Connect, will not flexible deformation, so bonding securely, not easily to fall off, safety is good；
5, decorative effect is beautiful, durable, because surface material is foamed ceramic, inorganic pigment never takes off by high temperature firing Color sustains its quality through age；
6, long service life, because decorative layer and insulating layer are fired by high temperature, intensity is high, durability mouth, It can achieve the requirement with building with the service life, it is not necessary to insulation and decoration system is overhauled again, to reduce people, material resources and resource Waste etc..
Specific embodiment
The embodiment of the present invention is described further below：
Embodiment 1
A kind of fireproof heat preservation decorative board material of pure inorganic material, including surface layer and plate layer, the surface layer are with decoration The light foamed ceramic plate of effect, insulating layer are the sintering grow pearlite heat-insulation plate of rigid inorganic material, surface layer and insulating layer It is bonded by inorganic high-strength bonding mortar；
The thermal coefficient for obtaining surface layer is 0.06W/m.K, and insulating layer thermal coefficient is 0.045W/m.K.
It is 400kg/m that the light foamed ceramic plate, which obtains density,3。
The insulating layer density is 140kg/m3。
The thickness proportion of the surface layer and insulating layer is 15mm: 60mm.
The surface material is made of bottom material, fabric and glaze, and each section formula is as follows：
The formula of bottom material is made of following mass percent raw material：
Perlite tailing 50%
Feldspar 40%
Bentonite 5%
Kaolin 4.4%
Foaming agent 0.1%
Water-reducing agent 0.5%；
The formula of the fabric is made of following mass percent raw material：
Perlite tailing 70%；
Feldspar 20%；
Bentonite 5%；
Kaolin 4.8%；
Foaming agent 0.1%；
Water-reducing agent 0.1%.
The foaming agent is the silicon carbide micro-powder of 1000 mesh fineness；The water-reducing agent is sodium tripolyphosphate.
The formula of the glaze is made of following mass percent raw material：
Low temperature frit：50%
Aluminium oxide：10%
Zinc oxide：10%
Kaolin：10%
Calcium carbonate：18.9%
Sodium tripolyphosphate：1%
Hydroxymethyl cellulose：0.1%.
The formula of the insulating layer is made of following mass percent raw material：
Perlite particle：70%
Binder：30%.
The perlite particle proportion is uniformly distributed for 0.1-8mm；The binder be bentonite, low temperature frit, Aluminium dihydrogen phosphate and water are ground.
The product fire resistance rating of preparation is A1 grades.
Embodiment 2
A kind of fireproof heat preservation decorative board material of pure inorganic material, including surface layer and plate layer, the surface layer are with decoration The light foamed ceramic plate of effect, insulating layer are the sintering grow pearlite heat-insulation plate of rigid inorganic material, surface layer and insulating layer It is bonded by inorganic adhesive mortar；
The thermal coefficient for obtaining surface layer is 0.07W/m.K, and insulating layer thermal coefficient is 0.055W/m.K.
It is 600kg/m that the light foamed ceramic plate, which obtains density,3。
The insulating layer density is 160kg/m3。
The thickness proportion of the surface layer and insulating layer is 15mm: 80mm.
The surface material is made of bottom material, fabric and glaze, and each section formula is as follows：
The formula of bottom material is made of following mass percent raw material：
Perlite tailing 80%
Feldspar 10%
Bentonite 5.8%
Kaolin 4%
Foaming agent 0.05%
Water-reducing agent 0.15%；
The formula of the fabric is made of following mass percent raw material：
Perlite tailing 40%；
Feldspar 50%；
Bentonite 5%；
Kaolin 4.6%；
Foaming agent 0.1%；
Water-reducing agent 0.3%.
The foaming agent is the silicon carbide micro-powder of 1000 mesh fineness；The water-reducing agent is sodium tripolyphosphate.
The formula of the glaze is made of following mass percent raw material：
Low temperature frit：80%
Aluminium oxide：5%
Zinc oxide：3%
Kaolin：5%
Calcium carbonate：6%
Sodium tripolyphosphate：0.5%
Hydroxymethyl cellulose：0.5%.
The formula of the insulating layer is made of following mass percent raw material：
Perlite particle：80%
Binder：20%.
The perlite particle proportion is uniformly distributed for 0.1-8mm；The binder be bentonite, low temperature frit, Aluminium dihydrogen phosphate and water are ground.
The product fire resistance rating of preparation is A1 grades.
Embodiment 3
A kind of fireproof heat preservation decorative board material of pure inorganic material, including surface layer and plate layer, the surface layer are with decoration The light foamed ceramic plate of effect, insulating layer are the sintering grow pearlite heat-insulation plate of rigid inorganic material, surface layer and insulating layer It is bonded by inorganic adhesive mortar；
The thermal coefficient for obtaining surface layer is 0.065W/m.K, and insulating layer thermal coefficient is 0.050W/m.K.
It is 500kg/m that the light foamed ceramic plate, which obtains density,3。
The insulating layer density is 150kg/m3。
The thickness proportion of the surface layer and insulating layer is 15mm: 70mm.
The surface material is made of bottom material, fabric and glaze, and each section formula is as follows：
The formula of bottom material is made of following mass percent raw material：
Perlite tailing 60%
Feldspar 20%
Bentonite 10%
Kaolin 9.8%
Foaming agent 0.05%
Water-reducing agent 0.15%；
The formula of the fabric is made of following mass percent raw material：
Perlite tailing 50%；
Feldspar 30%；
Bentonite 10%；
Kaolin 9.5%；
Foaming agent 0.2%；
Water-reducing agent 0.3%.
The foaming agent is the silicon carbide micro-powder of 1000 mesh fineness；The water-reducing agent is sodium tripolyphosphate.
The formula of the glaze is made of following mass percent raw material：
Low temperature frit：64%
Aluminium oxide：15%
Zinc oxide：3%
Kaolin：7%
Calcium carbonate：10%
Sodium tripolyphosphate：0.8%
Hydroxymethyl cellulose：0.2%.
The formula of the insulating layer is made of following mass percent raw material：
Perlite particle：75%
Binder：25%.
The perlite particle proportion is uniformly distributed for 0.1-8mm；The binder be bentonite, low temperature frit, Aluminium dihydrogen phosphate and water are ground.
The product fire resistance rating of preparation is A1 grades.
Embodiment 4
A kind of fireproof heat preservation decorative board material of pure inorganic material, including surface layer and plate layer, the surface layer are with decoration The light foamed ceramic plate of effect, insulating layer are the sintering grow pearlite heat-insulation plate of rigid inorganic material, surface layer and insulating layer It is bonded by inorganic adhesive mortar；
The thermal coefficient for obtaining surface layer is 0.066W/m.K, and insulating layer thermal coefficient is 0.049W/m.K.
It is 480kg/m that the light foamed ceramic plate, which obtains density,3。
The insulating layer density is 155kg/m3。
The thickness proportion of the surface layer and insulating layer is 15mm: 72mm.
The surface material is made of bottom material, fabric and glaze, and each section formula is as follows：
The formula of bottom material is made of following mass percent raw material：
Perlite tailing 70%
Feldspar 15%
Bentonite 7%
Kaolin 7.5%
Foaming agent 0.08%
Water-reducing agent 0.42%；
The formula of the fabric is made of following mass percent raw material：
Perlite tailing 50%；
Feldspar 25%；
Bentonite 15%；
Kaolin 9.5%；
Foaming agent 0.4%；
Water-reducing agent 0.1%.
The foaming agent is the silicon carbide micro-powder of 1000 mesh fineness；The water-reducing agent is sodium tripolyphosphate.
The formula of the glaze is made of following mass percent raw material：
Low temperature frit：63.5%
Aluminium oxide：10%
Zinc oxide：8%
Kaolin：7%
Calcium carbonate：10%
Sodium tripolyphosphate：1%
Hydroxymethyl cellulose：0.5%.
The formula of the insulating layer is made of following mass percent raw material：
Perlite particle：72%
Binder：28%.
The perlite particle proportion is uniformly distributed for 0.1-8mm；The binder be bentonite, low temperature frit, Aluminium dihydrogen phosphate and water are ground.
The product fire resistance rating of preparation is A1 grades.

Claims (10)

1. a kind of fireproof heat preservation decorative board material of pure inorganic material, including surface layer and plate layer, feature are bands in the surface layer Have a light foamed ceramic plate of decorative effect, insulating layer is the sintering grow pearlite heat-insulation plate of rigid inorganic material, surface layer and Insulating layer is bonded by inorganic adhesive mortar；
The thermal coefficient for obtaining surface layer is 0.06-0.07W/m.K, and insulating layer thermal coefficient is 0.045-0.055W/m.K.
2. the fireproof heat preservation decorative board material of pure inorganic material according to claim 1, it is characterised in that the lightweight hair It is 400-600kg/m that bubble ceramic wafer, which obtains density,3。
3. the fireproof heat preservation decorative board material of pure inorganic material according to claim 1, it is characterised in that the insulating layer Density is 140-160kg/m3。
4. the fireproof heat preservation decorative board material of pure inorganic material according to claim 1, it is characterised in that the surface layer and The thickness proportion of insulating layer is 15: (60-80).
5. the fireproof heat preservation decorative board material of pure inorganic material according to claim 1, it is characterised in that the surface layer material Material is made of bottom material, fabric and glaze, and each section formula is as follows：
The formula of bottom material is made of following mass percent raw material：
Perlite tailing 50-80%
Feldspar 10-40%
Bentonite 5-30%
Kaolin 4-20%
Foaming agent 0.02-0.1%
Water-reducing agent 0.1-0.5%.
6. the fireproof heat preservation decorative board material of pure inorganic material according to claim 5, it is characterised in that the fabric Formula is made of following mass percent raw material：
Perlite tailing 40-70%；
Feldspar 20-50%；
Bentonite 5-30%；
Kaolin 4.5-20%；
Foaming agent 0.05-0.5%；
Water-reducing agent 0.1-0.5%.
7. the fireproof heat preservation decorative board material of pure inorganic material according to claim 5 or 6, it is characterised in that the foaming Agent is the silicon carbide micro-powder of 1000 mesh fineness；The water-reducing agent is sodium tripolyphosphate.
8. the fireproof heat preservation decorative board material of pure inorganic material according to claim 5, it is characterised in that the glaze Formula is made of following mass percent raw material：
Low temperature frit：40-80%
Aluminium oxide：5-15%
Zinc oxide：3-10%
Kaolin：5-10%
Calcium carbonate：5-20%
Sodium tripolyphosphate：0.5-1%
Hydroxymethyl cellulose：0.1-0.5%.
9. the fireproof heat preservation decorative board material of pure inorganic material according to claim 1, it is characterised in that the insulating layer Formula be made of following mass percent raw material：
Perlite particle：70-80%
Binder：20-30%.
10. the fireproof heat preservation decorative board material of pure inorganic material according to claim 9, it is characterised in that the perlite Grain mixture ratio is uniformly distributed for 0.1-8mm；The binder be bentonite, low temperature frit, aluminium dihydrogen phosphate and water grinding and At.
CN201810841496.3A 2018-07-27 2018-07-27 The fireproof heat preservation decorative board material of pure inorganic material Pending CN108863404A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110282965A (en) * 2019-07-23 2019-09-27 福建省德化琦轩陶瓷工艺有限公司 A kind of anti-scald health-care ceramic product and preparation method thereof
CN119431003A (en) * 2025-01-08 2025-02-14 佛山市科菱斯科技有限公司 A lightweight thermal insulation ceramic material and a preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103216066A (en) * 2013-04-12 2013-07-24 深圳市明远建材科技有限公司 Ceramic tile thermal-insulation decoration composite board as well as manufacture method and installation method thereof
CN108129132A (en) * 2018-01-12 2018-06-08 李珠 Sintering coal gives up expanded perlite thermal-nsulation decoration integrated board and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103216066A (en) * 2013-04-12 2013-07-24 深圳市明远建材科技有限公司 Ceramic tile thermal-insulation decoration composite board as well as manufacture method and installation method thereof
CN108129132A (en) * 2018-01-12 2018-06-08 李珠 Sintering coal gives up expanded perlite thermal-nsulation decoration integrated board and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110282965A (en) * 2019-07-23 2019-09-27 福建省德化琦轩陶瓷工艺有限公司 A kind of anti-scald health-care ceramic product and preparation method thereof
CN119431003A (en) * 2025-01-08 2025-02-14 佛山市科菱斯科技有限公司 A lightweight thermal insulation ceramic material and a preparation method thereof
CN119431003B (en) * 2025-01-08 2025-03-14 佛山市科菱斯科技有限公司 A light thermal insulation ceramic material and preparation method thereof

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