CN110272207A - A kind of unglazed porcelain matter polished bricks penetration glaze and preparation method thereof - Google Patents
A kind of unglazed porcelain matter polished bricks penetration glaze and preparation method thereof Download PDFInfo
- Publication number
- CN110272207A CN110272207A CN201910500828.6A CN201910500828A CN110272207A CN 110272207 A CN110272207 A CN 110272207A CN 201910500828 A CN201910500828 A CN 201910500828A CN 110272207 A CN110272207 A CN 110272207A
- Authority
- CN
- China
- Prior art keywords
- polished bricks
- penetration
- unglazed porcelain
- penetration glaze
- porcelain matter
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
The present invention provides a kind of unglazed porcelain matter polished bricks penetration glazes and preparation method thereof, belong to polished brick in porcelain character technical field.A kind of unglazed porcelain matter polished bricks penetration glaze carries out neutralization reaction by fluorine zirconic acid aqueous solution and hydramine and obtains.Unglazed porcelain matter polished bricks penetration glaze performance provided by the invention is stablized, it is easy to use, quick, it is not required to return mill, and it is used not only for silk-screen printing, it can also be used to rubber roller printer printing, when in use in the brick face of unglazed porcelain matter polished bricks, penetration glaze be not required to experience course of dissolution, in the form of product original form solution under seep.Embodiment statistics indicate that, unglazed porcelain matter polished bricks penetration glaze provided by the invention is faint yellow clear solution, without precipitating risk, more lively fine and smooth pattern can be obtained for glue roller printing, for silk-screen printing, finer pattern can be obtained, dosage is few and can make ceramic tile that white effect be presented.
Description
Technical field
The present invention relates to polished brick in porcelain character technical field more particularly to a kind of unglazed porcelain matter polished bricks penetration glaze and its preparations
Method.
Background technique
Polished brick in porcelain character has the advantages that hardness is big, beautiful and generous, easy to clean, is widely used in the paving of ground.Porcelain
The pattern decorative of polished bricks is to penetrate into base to generate after firing polishing using the aqueous solution of metal ion, specific to scheme
Case printing process has silk-screen printing and glue roller printing.
Glue roller printing technique is able to achieve automated production.Silk-screen printing technique then needs more labour to assist.With labour
The growth of power cost, glue roller printing replace silk-screen printing to be also trend of the times.
In the prior art, polished brick in porcelain character surface printing white pattern is currently using ammonium fluozirconate, due to ammonium fluozirconate
It is water-soluble very low, water grinding can only be added to become slurry and used, this slurry is dispersion made of ammonium fluozirconate particle and water mixing
Object is printed onto behind brick face dissolution after spraying a large amount of water and enters inside adobe, white is presented after firing.Since ammonium fluozirconate has centainly
Water solubility, this slurry storage when pellet easily grow up, can only use silk-screen printing, and slurry storage the long period after
It need to regrind to reach silk-screen printing requirement.Therefore, the printing process of better quality is not available this if glue roller printing
The slurry that ammonium fluozirconate is ground will cause the phenomenon that blocking roll surfaces hole.
Summary of the invention
In consideration of it, the purpose of the present invention is to provide a kind of unglazed porcelain matter polished bricks penetration glazes and preparation method thereof.This hair
The unglazed porcelain matter polished bricks penetration glaze of bright offer is stablized, and can be used in glue roller printing.
In order to achieve the above-mentioned object of the invention, the present invention the following technical schemes are provided:
The present invention provides a kind of unglazed porcelain matter polished bricks penetration glaze, carries out neutralization reaction by fluorine zirconic acid aqueous solution and hydramine and obtains
It arrives.
Preferably, the fluorine zirconic acid in the fluorine zirconic acid aqueous solution and the molar ratio of hydramine are 1:1~3.
Preferably, the fluorine zirconic acid in the fluorine zirconic acid aqueous solution and the molar ratio of hydramine are 1:1.5~2.5.
Preferably, the hydramine includes monoethanolamine, diethanol amine, triethanolamine, n-propanolamine, monoisopropanolamine, two
Isopropanolamine, triisopropanolamine, N, N- dimethylethanolamine, N, one of N- diethyl ethylene diamine and diglycolamine or more
Kind.
Preferably, the mass concentration of the fluorine zirconic acid aqueous solution is 40~50%, the mass concentration of hydramine is 98~
99.9%.
The present invention also provides the preparation methods of the unglazed porcelain matter polished bricks penetration glaze described in above-mentioned technical proposal, including with
Lower step:
Fluorine zirconic acid aqueous solution and hydramine are subjected to neutralization reaction, obtain the unglazed porcelain matter polished bricks penetration glaze.
Preferably, after the neutralization reaction that gained neutralization reaction product normal heating distillation and concentration or vacuum distillation is dense
Contracting.
Preferably, the temperature of the normal heating distillation and concentration is 100~120 DEG C, and the time is 2~3 hours.
Preferably, the temperature of the normal heating distillation and concentration is 105~115 DEG C.
Preferably, the pressure of the vacuum distillation concentration is -0.01~-0.03MPa, and temperature is 60~110 DEG C, and the time is
2~3 hours.
The present invention provides a kind of unglazed porcelain matter polished bricks penetration glazes, carry out neutralization reaction by fluorine zirconic acid aqueous solution and hydramine
It obtains.Particulate matter, the wind without particle growth when using storage are not present in unglazed porcelain matter polished bricks penetration glaze provided by the invention
Danger, hydramine has bigger molecular weight and more complicated molecular structure relative to monovalent metal alkali, so that reacting with fluorine zirconic acid
To product be difficult to crystallize；Meanwhile hydramine contains a large amount of hydroxyl and hydrone extremely strong affinity, dissolution in water
To spend sufficiently large, these two aspects determines unglazed porcelain matter polished bricks penetration glaze of the invention, and performance is stablized, it is easy to use, quick, no
Mill need to be returned, and is used not only for silk-screen printing, additionally it is possible to print for rubber roller printer, be polished when in use in unglazed porcelain matter
The brick face of brick, penetration glaze be not required to experience course of dissolution, directly in the form of product original form solution under seep.The data of embodiment
Show that unglazed porcelain matter polished bricks penetration glaze provided by the invention is faint yellow clear solution, no precipitating risk is used for glue roller printing
More lively fine and smooth pattern can be obtained, silk-screen printing is used for, finer pattern can be obtained, dosage is few and can make
The effect of white is presented in ceramic tile.
Specific embodiment
The present invention provides a kind of unglazed porcelain matter polished bricks penetration glazes, carry out neutralization reaction by fluorine zirconic acid aqueous solution and hydramine
It obtains.
In the present invention, the fluorine zirconic acid in the fluorine zirconic acid aqueous solution and the molar ratio of hydramine are preferably 1:1~3, more excellent
It is selected as 1:1.5~2.5.
In the present invention, the hydramine preferably includes monoethanolamine, diethanol amine, triethanolamine, n-propanolamine, an isopropyl
Hydramine, diisopropanolamine (DIPA), triisopropanolamine, N, N- dimethylethanolamine, N, one in N- diethyl ethylene diamine and diglycolamine
Kind is a variety of.When the hydramine is preferably mixture, the present invention is not special to the mass ratio of each substance in the mixture
Restriction, using the mixture of any mass ratio.
In the present invention, the mass concentration of the fluorine zirconic acid aqueous solution is preferably 40~50%, and the mass concentration of hydramine is excellent
It is selected as 98~99.9%.
The present invention also provides the preparation methods of the unglazed porcelain matter polished bricks penetration glaze described in above-mentioned technical proposal, including with
Lower step:
Fluorine zirconic acid aqueous solution and hydramine are subjected to neutralization reaction, obtain the unglazed porcelain matter polished bricks penetration glaze.
In the present invention, the temperature of the neutralization reaction is preferably room temperature, and the present invention does not have the time of the neutralization reaction
There is special restriction, neutralization reaction can be made to carry out completely.
In the present invention, preferably by gained neutralization reaction product normal heating distillation and concentration or decompression after the neutralization reaction
Distillation and concentration.
In the present invention, the temperature of the normal heating distillation and concentration is preferably 100~120 DEG C, more preferably 105~
115 DEG C, the time is preferably 2~3 hours.
In the present invention, the temperature of the normal heating distillation and concentration is in the present invention, described to be evaporated under reduced pressure the pressure being concentrated
Power is preferably -0.01~-0.03MPa, and more preferable pressure is -0.01~-0.02MPa, and temperature is preferably 60~110 DEG C, more excellent
70~100 DEG C are selected as, the time is preferably 2~3 hours.
In the present invention, the product preferable flow rate after the normal heating distillation and concentration or vacuum distillation are concentrated is adjusted to
Applying for -4 flow cup delivery times is that room temperature (20~30 DEG C) can be run for 12~30 seconds on roller, more preferably 16~25 seconds,
It can be used in silk screen within 30 seconds or more.
In the present invention, during the neutralization reaction, the pH value of reaction system is preferably 7~9.
In the present invention, it is preferred to which the hydramine is added in the fluorine zirconic acid aqueous solution.
In the present invention, the container of the neutralization reaction preferably in contact surface be it is nonmetallic, and can it is heat-resisting (130 DEG C or with
On).
A kind of unglazed porcelain matter polished bricks penetration glaze provided by the invention and preparation method thereof is carried out below with reference to embodiment
Detailed description, but they cannot be interpreted as limiting the scope of the present invention.
Embodiment 1.
50% fluorine zirconic acid aqueous solution 1000g is slowly added in reaction vessel, 872g tri- is slowly added under stirring condition
Ethanol amine continues to be stirred to react 2h after adding, and obtains clear light yellow viscous solution about 1750g, is measured using -4 flow cups are applied
Flow velocity, time 25s, pH value 8.
Embodiment 2.
50% fluorine zirconic acid aqueous solution 1000g is slowly added in reaction vessel, is slowly added to 507.4g under stirring condition
Diethanol amine continues to stir, after the reaction was completed continuous heating after adding, and keeps the temperature at 105 DEG C, and 2h obtains clarifying yellowish
Color viscous solution about 1050g measures flow velocity, time 20s, pH value 8.3 using -4 flow cups are applied.
Embodiment 3.
50% fluorine zirconic acid aqueous solution 1000g is slowly added in reaction vessel, 254g mono- is slowly added under stirring condition
Ethanol amine continues to stir, after the reaction was completed continuous heating after adding, and keeps the temperature at 110 DEG C, 2h, adds pressure-
0.01MPa obtains clear light yellow viscous solution about 980g, measures flow velocity, time 18s using -4 flow cups are applied, pH value is
8.0。
Embodiment 4.
50% fluorine zirconic acid aqueous solution 1000g is slowly added in reaction vessel, 612g bis- is slowly added under stirring condition
Glycol amine continues to stir, after the reaction was completed continuous heating after adding, and keeps the temperature at 100 DEG C, 2h, adds pressure-
0.02MPa obtains clear light yellow viscous solution about 1263g, measures flow velocity, time 23s using -4 flow cups are applied, pH value is
8.7。
Embodiment 5.
50% fluorine zirconic acid aqueous solution 1000g is slowly added in reaction vessel, 254g mono- is slowly added under stirring condition
Ethanol amine and 1238g triethanolamine, continue to stir, after the reaction was completed continuous heating after adding, and keep the temperature at 105 DEG C of reactions
2h adds pressure -0.03MPa, obtains clear light yellow viscous solution about 1520g, measures flow velocity, time using -4 flow cups are applied
For 38s, pH value 8.9.
Embodiment 6.
50% fluorine zirconic acid aqueous solution 1700g is slowly added in reaction vessel, it is different to be slowly added to 933g under stirring condition
Propanolamine continues to be stirred to react 1h after adding, and obtains clear light yellow viscous solution about 2500g, is measured using -4 flow cups are applied
Flow velocity, time 21s, pH value 8.7.
Embodiment 7.
50% fluorine zirconic acid aqueous solution 1600g is slowly added in reaction vessel, it is different to be slowly added to 293g under stirring condition
1038 grams of diisopropanolamine (DIPA)s of Propanolamine, continue to be stirred to react 1h after adding, and obtain clear light yellow viscous solution about 2500g, make
Flow velocity, time 23s, pH value 8.8 are measured with -4 flow cups are applied.
Embodiment 8.
50% fluorine zirconic acid aqueous solution 1600g is slowly added in reaction vessel, 238g mono- is slowly added under stirring condition
Ethanol amine, 410 grams of diethanol amine and 581.6 grams of triethanolamines, continue to stir, after the reaction was completed continuous heating, make temperature after adding
Degree is maintained at 60 DEG C of reaction 2h, adds pressure -0.02MPa, obtains clear light yellow viscous solution about 2000g, viscous using applying -4
It spends cup and measures flow velocity, time 35s, pH value 8.8.
Embodiment 9.
50% fluorine zirconic acid aqueous solution 1600g is slowly added in reaction vessel, 238g mono- is slowly added under stirring condition
Ethanol amine, 410 grams of diethanol amine and 581.6 grams of triethanolamines, continue to stir, after the reaction was completed continuous heating, make temperature after adding
Degree is maintained at 70 DEG C of reaction 3h, adds pressure -0.03MPa, obtains clear light yellow viscous solution about 2000g, viscous using applying -4
It spends cup and measures flow velocity, time 33s, pH value 8.4.
Unglazed porcelain matter polished bricks penetration glaze made from the embodiment of the present invention 1~9 is faint yellow clear solution, no precipitating wind
Danger.
Comparative example 1.
Unglazed porcelain matter polished bricks penetration glaze 100mL and 100mL conventional white penetration glaze (fluorine zirconic acid made from Example 1
Ammonium dispersed paste), observation is stood, 1 penetration glaze appearance of embodiment is faint yellow clear solution, and conventional white penetration glaze appearance is white
Coloured particles dispersion liquid is crossed 80 mesh screens respectively, can be passed through.After a week, embodiment 1 is yellowish for room temperature (20~30 DEG C) storage time
Color penetration glaze appearance is unchanged, and the layering of conventional white penetration glaze, supernatant liquor, lower layer is white precipitate, crosses 80 mesh screens respectively,
For the faint yellow penetration glaze of embodiment 1 by normal, conventional white penetration glaze then has a large amount of particles that cannot pass through.
Comparative example 2.
(the ammonium fluozirconate point of unglazed porcelain matter polished bricks penetration glaze 50L and 50L conventional white penetration glaze made from Example 1
Dissipate slurry), upper roller test respectively, the faint yellow penetration glaze cloth glaze of embodiment 1 is normal, and roller pattern can clear roll marks when brick passes through
Onto brick.The test of conventional white penetration glaze upper roller, it is imperfect to print off pattern, not by adjusting roller speed, depression depths
Complete pattern, and long-play can be printed off, has envelope roller phenomenon (roller hole is by foreign matters from being blocked), illustrates infiltration of the invention
Glue roller printing can be used in glaze, obtains more lively fine and smooth pattern, and ammonium fluozirconate dispersion cannot then use rubber roller completely
Printing.
Comparative example 3.
Roller crosses brick 10 on unglazed porcelain matter polished bricks penetration glaze 50L made from Example 1, brand-new 50L conventional white
Penetration glaze (ammonium fluozirconate dispersed paste) screen painting 10.Cylinder pattern and halftone pattern are all the same.After firing polishing
Line roughness is measured, 1 faint yellow penetration glaze pattern most thin place lines of embodiment are slightly 1~1.2mm, and conventional white infiltration has pattern
Most thin place lines are slightly 1.5~2mm, illustrate that penetration glaze of the invention can be used for thinner silk to print, obtain finer
Pattern.
Comparative example 4.
Roller crosses brick 10 on unglazed porcelain matter polished bricks penetration glaze 50L made from Example 1, brand-new 50L conventional white
Penetration glaze (ammonium fluozirconate dispersed paste) screen painting 10.Cylinder pattern and halftone pattern are all the same.It is cut after firing
Section, the faint yellow penetration glaze pattern penetration depth of embodiment 1 are 2.5~3mm, and it is 2 that conventional white infiltration, which has pattern penetration depth,
~2.8mm illustrates that the permeance property of penetration glaze of the present invention is eager to excel than traditional penetration glaze, and infiltration is more preferable when use, ammonium fluozirconate point
Granular media just lower after the water dissolution through spraying will seep when using adobe surface, and penetration glaze of the invention is then directly lower seeps, and not have
Course of dissolution, osmotic effect are more preferable.
Comparative example 5.
Unglazed porcelain matter polished bricks penetration glaze 100mL made from Example 1 prepares 100mL ammonium fluozirconate saturated solution, point
Not on identical screen painting to test brick.After firing test brick, the faint yellow penetration glaze pattern of embodiment 1 shows milky, saturation
Ammonium fluozirconate solution pattern then only has extremely slight pattern trace.After polishing test brick, the faint yellow penetration glaze pattern of embodiment 1 is aobvious
White light, saturation ammonium fluozirconate solution pattern have then disappeared.Illustrate, if the transparent molten of similar this patent is made in ammonium fluozirconate
Liquid is as penetration glaze use, and since the solubility of ammonium fluozirconate is very low, the content of zirconium is very low in obtained clear solution, no
The effect for making ceramic tile that white be presented can be played.
Comparative example 6.
50% fluorine zirconic acid aqueous solution 1000g is slowly added in reaction vessel, 200g tri- is slowly added under stirring condition
Ethanol amine continues to stir, persistently stirs 2h after the reaction was completed after adding, and obtains clear light yellow viscous solution about 1158g, uses
It applies -4 flow cups and measures flow velocity, time 10s, pH value 5.5.
When normal heating is concentrated, for temperature less than 100 DEG C, the reaction time is long, cannot reach concentrated effect.
Comparative example 7.
50% fluorine zirconic acid aqueous solution 1000g is slowly added in reaction vessel, 254g mono- is slowly added under stirring condition
Ethanol amine continues to stir, after the reaction was completed continuous heating after adding, and keeps the temperature at 90 DEG C, 8h, and it is viscous to obtain clear light yellow
Thick solution about 1200g measures flow velocity, time 10s, pH value 8.0 using -4 flow cups are applied.Flow velocity is less than normal to cannot be used for roller
Production.
When heating under reduced pressure is concentrated, temperature is greater than 110 DEG C, and temperature height easily decomposes reactant.
Comparative example 8.
50% fluorine zirconic acid aqueous solution 1700g is slowly added in reaction vessel, it is different to be slowly added to 933g under stirring condition
Propanolamine continues to be stirred to react 1h after adding, and solution gradually becomes cloudy on the way for reaction, obtains the sticky turbid of clear light yellow about
2500g, turbid have white precipitate sedimentation and bottom after standing, take supernatant liquor and 6 product of embodiment to print and fire comparison, color
The coloured product of comparative example 8. is partially shallow.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also answered
It is considered as protection scope of the present invention.
Claims (10)
1. a kind of unglazed porcelain matter polished bricks penetration glaze, which is characterized in that carry out neutralization reaction by fluorine zirconic acid aqueous solution and hydramine and obtain
It arrives.
2. unglazed porcelain matter polished bricks penetration glaze according to claim 1, which is characterized in that in the fluorine zirconic acid aqueous solution
Fluorine zirconic acid and the molar ratio of hydramine are 1:1~3.
3. unglazed porcelain matter polished bricks penetration glaze according to claim 2, which is characterized in that in the fluorine zirconic acid aqueous solution
Fluorine zirconic acid and the molar ratio of hydramine are 1:1.5~2.5.
4. unglazed porcelain matter polished bricks penetration glaze according to claim 1, which is characterized in that the hydramine includes an ethyl alcohol
Amine, diethanol amine, triethanolamine, n-propanolamine, monoisopropanolamine, diisopropanolamine (DIPA), triisopropanolamine, N, N- dimethyl ethanol
Amine, N, one of N- diethyl ethylene diamine and diglycolamine or a variety of.
5. unglazed porcelain matter polished bricks penetration glaze according to claim 1, which is characterized in that the matter of the fluorine zirconic acid aqueous solution
Measuring concentration is 40~50%, and the mass concentration of hydramine is 98~99.9%.
6. the preparation method of the described in any item unglazed porcelain matter polished bricks penetration glazes of Claims 1 to 5, which is characterized in that including
Following steps:
Fluorine zirconic acid aqueous solution and hydramine are subjected to neutralization reaction, obtain the unglazed porcelain matter polished bricks penetration glaze.
7. preparation method according to claim 6, which is characterized in that by gained neutralization reaction product after the neutralization reaction
Normal heating distillation and concentration or vacuum distillation concentration.
8. preparation method according to claim 7, which is characterized in that the temperature of the normal heating distillation and concentration is 100
~120 DEG C, the time is 2~3 hours.
9. preparation method according to claim 8, which is characterized in that the temperature of the normal heating distillation and concentration is 105
~115 DEG C.
10. preparation method according to claim 7, which is characterized in that the pressure of the vacuum distillation be -0.01~-
0.03MPa, temperature are 60~110 DEG C, and the time is 2~3 hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910500828.6A CN110272207A (en) | 2019-06-11 | 2019-06-11 | A kind of unglazed porcelain matter polished bricks penetration glaze and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910500828.6A CN110272207A (en) | 2019-06-11 | 2019-06-11 | A kind of unglazed porcelain matter polished bricks penetration glaze and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110272207A true CN110272207A (en) | 2019-09-24 |
Family
ID=67960628
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910500828.6A Pending CN110272207A (en) | 2019-06-11 | 2019-06-11 | A kind of unglazed porcelain matter polished bricks penetration glaze and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110272207A (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5858282A (en) * | 1997-11-21 | 1999-01-12 | Ppg Industries, Inc. | Aqueous amine fluoride neutralizing composition for metal pretreatments containing organic resin and method |
| CN1927771A (en) * | 2006-09-27 | 2007-03-14 | 刘锋 | Boundary effect infiltrated glaze of imitating natural stone texture and manufacture method |
| CN101479214A (en) * | 2006-06-26 | 2009-07-08 | 格拉兹诺·维格拉里 | Composition for coloring ceramic articles |
| CN102795892A (en) * | 2012-09-10 | 2012-11-28 | 杭州诺贝尔陶瓷有限公司 | Soluble salt ceramic tile and production method thereof |
| CN106430968A (en) * | 2016-09-09 | 2017-02-22 | 成都九十度工业产品设计有限公司 | Stereoscopic color-penetrated porcelain tile production method |
| CN107033673A (en) * | 2017-05-25 | 2017-08-11 | 佛山市三水区康立泰无机合成材料有限公司 | A kind of preparation method of inkjet printing cobalt blue ceramic ink |
| CN108754480A (en) * | 2018-06-21 | 2018-11-06 | 上海优梓新材料科技有限公司 | A kind of environmental emission reduction Non-water washing type metal conditioner |
-
2019
- 2019-06-11 CN CN201910500828.6A patent/CN110272207A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5858282A (en) * | 1997-11-21 | 1999-01-12 | Ppg Industries, Inc. | Aqueous amine fluoride neutralizing composition for metal pretreatments containing organic resin and method |
| CN101479214A (en) * | 2006-06-26 | 2009-07-08 | 格拉兹诺·维格拉里 | Composition for coloring ceramic articles |
| CN1927771A (en) * | 2006-09-27 | 2007-03-14 | 刘锋 | Boundary effect infiltrated glaze of imitating natural stone texture and manufacture method |
| CN102795892A (en) * | 2012-09-10 | 2012-11-28 | 杭州诺贝尔陶瓷有限公司 | Soluble salt ceramic tile and production method thereof |
| CN106430968A (en) * | 2016-09-09 | 2017-02-22 | 成都九十度工业产品设计有限公司 | Stereoscopic color-penetrated porcelain tile production method |
| CN107033673A (en) * | 2017-05-25 | 2017-08-11 | 佛山市三水区康立泰无机合成材料有限公司 | A kind of preparation method of inkjet printing cobalt blue ceramic ink |
| CN108754480A (en) * | 2018-06-21 | 2018-11-06 | 上海优梓新材料科技有限公司 | A kind of environmental emission reduction Non-water washing type metal conditioner |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106518170B (en) | Fancy infiltration method for ceramic tile | |
| CN105544244B (en) | A kind of weaving face fabric number transfer printing process | |
| DE50210912D1 (en) | Silicon compound-containing surface coating agent | |
| CN104177922B (en) | Ceramic ink with effect of separating glaze, as well as preparation and using methods and ceramic tile of ceramic ink | |
| CN105949882B (en) | Carrier is that the ceramic tile of polar solvent permeates ink, the ink preparation and application | |
| CN112321170B (en) | Glass etching solution and method for simulating ceramic kiln-transmutation ice-patterned glass by using same | |
| CN108821588A (en) | High alumina titanate ceramics glaze, ink-jet Ceramic Tiles of the glaze of titanate ceramics containing high alumina and preparation method thereof | |
| CN103804993A (en) | Extra-white aqueous ceramic ink-jet ink and preparation method thereof | |
| CN108558446A (en) | A kind of manufacturing method of the Ceramic Tiles with three-dimensional decorative effect | |
| CN114561123B (en) | High-permeability negative ion ceramic ink and preparation method thereof, and negative ion ceramic tile and preparation method thereof | |
| CN110272207A (en) | A kind of unglazed porcelain matter polished bricks penetration glaze and preparation method thereof | |
| CN106565091A (en) | High-temperature quick-burning sand crystal glaze and preparation technology thereof | |
| CN105819869A (en) | Method for improving permeability of oily permeation ink in green tile | |
| CN108274590B (en) | Concrete surface pattern modification method | |
| CN106009793A (en) | Dry powder textured paint | |
| CN105601343A (en) | Production method for color-changing engraved-design archaized brick | |
| CN110204926A (en) | A kind of Vanadium zirconium blue ceramic pigment, Vanadium zirconium blue ceramic ink and preparation method thereof | |
| CN207014537U (en) | A kind of digital art ceramic tile production system | |
| JP2008308363A (en) | Method for improving unevenness of color in cement base cured body | |
| CN111393909B (en) | Ink-jet pattern-bleeding ceramic hyperchromic ink and use method thereof | |
| CN1158192C (en) | Making method of stone texture imitating surface of ceramic tile | |
| CN105838144B (en) | A kind of pink ceramic ink jet infiltration caul-fat ink | |
| CN104004412A (en) | Blue ink for ceramic ink-jet printing and preparation method thereof | |
| CN106431503A (en) | Variable-color engraved archaized tile and preparation method | |
| JPS56166091A (en) | Transfer paper and manufacture thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |