CN103804993A - Extra-white aqueous ceramic ink-jet ink and preparation method thereof - Google Patents
Extra-white aqueous ceramic ink-jet ink and preparation method thereof Download PDFInfo
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Abstract
The invention relates to extra-white aqueous ceramic ink-jet ink. Ceramic pigment is sol prepared from a zirconium oxide precursor and a silicon oxide precursor through a sol-gel method. The white ceramic pigment is prepared by the sol-gel method, has small particle size and good sphericity, solves the technical problem of long time and high energy consumption when the traditional ceramic ink-jet ink is ground, can keep active groups through the sol-gel reaction, can be sintered at a low temperature, and overcomes the technological difficulty that zirconium oxide pigment in the prior art is required to be sintered and adhered tightly at 1500 DEG C. The preparation method of the extra-white aqueous ceramic ink-jet ink comprises the steps of sol preparation and grinding, the preparation method is simple, the prepared extra-white aqueous ceramic ink-jet ink has the advantages of high whiteness, good ink-jetting effect, suitability for high-precision ink-jet printing cartridge and the like.
Description
Technical field
The present invention relates to ceramic ink jet technical field, particularly relate to a kind of extra white water-based ceramic ink jet ink and preparation method thereof.
Background technology
Ceramic ink jet technology is that ink-jet printed technology is applied to the technology that ceramic surface is decorated, it is that ceramic powder to be formed is made to ceramic ink, utilize printer the ceramic ink configuring directly to be printed to the shaping surface of architectural pottery, then at sintering, wherein, the shape of molding and geometrical dimension are by computer control.The ceramic ink that at present most domestic Ceramics Enterprises uses be mainly the ceramic ink produced take Spain Esmalglass～itaca, Ferro Deng Jijia offshore company of the U.S. as main, the ceramic ink jet ink that domestic ceramic ink is mainly released with Science and Technology Development Co., Ltd. of the Ming Dynasty for 2010.Ceramic ink jet ink both domestic and external is mainly take blue, brown, yellow, tangerine look, golden yellow, black, pink as main, and the ordering of its passage in ceramic ink jet printer also has different orderings according to the product difference of different manufacturers.On the whole, the color of above several ceramic ink jet inks can meet the Production requirement of most of producers and most products substantially, can produce Protean ceramic ink jet product.But, in recent years due to the impact of the popular of ceramic ink jet product and market homogeneity, some producer's urgent needs of producing high-end personalized ceramic product increase extra white color on the chromatic series of ceramic ink jet ink, enrich product, simultaneously the personalization features of outstanding product.
And because ceramic ink jet ink is the ceramic ink that ceramic powder to be formed is made solution shape, utilize printer the ceramic ink configuring directly to be printed to the shaping surface of architectural pottery, and then sintering, owing to being different from ceramic coating in the special preparation of ceramic ink jet ink and use-pattern, both belong to two kinds of different technical fields, make the technology in ceramic coating be difficult to directly apply to ceramic ink jet ink, therefore, for existing problems of the prior art, need badly and provide a kind of extra white ceramic ink jet ink technology to seem particularly important.
Summary of the invention
The object of the invention is to avoid weak point of the prior art and provide that a kind of whiteness is high, ink-jet is effective, be applicable to high precision ink jet printing head, the simple extra white water-based of preparation method ceramic ink jet ink.
Object of the present invention is achieved through the following technical solutions:
A kind of extra white water-based ceramic ink jet ink is provided, and its beramic color is the colloidal sol that the presoma of zirconic presoma and silicon oxide prepares by sol-gel method,
Wherein, in described colloidal sol, silicon oxide and zirconic mole ratio are for being less than or equal to 1:1, or the content of silicon oxide is 0.
Preferably, in described colloidal sol, the mole ratio of zirconium white and silicon oxide is 4:1, and extra white water-based ceramic ink jet ink sintering temperature is now lower, and whiteness is high, and ink-jet sintering effect is good.
Preferably, described zirconic presoma is zirconium oxychloride or oxygen zirconic acid amine; The presoma of described silicon oxide is a kind of or two or more of tetraethoxy-silicane, tetramethoxy-silicane and water glass, and wherein, the modulus of water glass is equal to, or greater than 2.
Above-mentioned extra white water-based ceramic ink jet ink, contains deionized water, aqueous dispersant, tensio-active agent, water-miscible organic solvent and ink addition agent.
Preferably, a kind of extra white water-based ceramic ink jet ink is grouped into by the one-tenth of following weight percent:
Deionized water 20～55%
Colloidal sol 35～60%
Aqueous dispersant and surfactivity 2～10%
Water-miscible organic solvent 2-10%
Ink addition agent 2～6%
Wherein, the dry weight of the weight of colloidal sol after with its calcination calculated.
Preferred, a kind of extra white water-based ceramic ink jet ink is grouped into by the one-tenth of following weight percent:
Deionized water 23%
Colloidal sol 60%
Aqueous dispersant and tensio-active agent 10%.
Water-miscible organic solvent 2%
Ink addition agent 5%
.
Another is preferred, and a kind of extra white water-based ceramic ink jet ink is grouped into by the one-tenth of following weight percent:
Deionized water 25～50%
Colloidal sol 40～60%
Aqueous dispersant and tensio-active agent 4～10%
Water-miscible organic solvent 2～10%
Ink addition agent 3～6%
Wherein, the dry weight of the weight of colloidal sol after with its calcination calculated.
Preferred, a kind of extra white water-based ceramic ink jet ink is grouped into by the one-tenth of following weight percent:
Deionized water 35%
Colloidal sol 45%
Aqueous dispersant and tensio-active agent 8%.
Water-miscible organic solvent 8%
Ink addition agent 4%.
Wherein, described water-miscible organic solvent is ethylene glycol, ethylene glycol monomethyl ether; diethylene glycol monomethyl ether, triethylene glycol monomethyl ether, propylene glycol monomethyl ether; dipropylene glycol monomethyl ether; thanomin, diethanolamine, trolamine; methyl-sulphoxide; morpholine, nitro morpholine, the one of nitrosomorpholine and N-formyl morpholine or two or more.
Another object of the present invention is to avoid weak point of the prior art and provide a kind of and prepare that above-mentioned whiteness is high, ink-jet is effective, be applicable to high precision ink jet printing head, the preparation method of the simple extra white water-based of preparation method ceramic ink jet ink.
Another object of the present invention is achieved through the following technical solutions:
The preparation method that a kind of extra white water-based ceramic ink jet ink is provided, includes following steps:
Step a. colloidal sol processed
The presoma of zirconic presoma and silicon oxide synchronously joins in 50% ethanolic soln lentamente, stir while add, after adding completely, stir hydrolysis reaction 24 hours, leave standstill afterwards 6 little layereds, abandon after supernatant liquid, add deionized water stirring, then leave standstill 6 little layereds, abandon supernatant liquid, repeat above process, until washing pH value is neutral, obtain colloidal sol;
Step a1. adjusts to 1.28 ~ 1.5g/cm by the mode of emitting supernatant liquid by the density of sol system by the colloidal sol after above-mentioned washing
3, add the viscosity of aqueous dispersant, decreasing by surfactant system simultaneously to colloidal sol modifying surface, in adding surface-modifying agent, use high speed dispersor to stir, after feeding in raw material, continue high-speed stirring 45～65 minutes; This step can effectively reduce the viscosity of system, improves the stably dispersing performance of system simultaneously;
Colloidal sol surface modification after step a2. modification completely after, more slowly add aqueous organic solvent, slowly add afterwards ink addition agent, continue high-speed stirring 55～65 minutes;
Step b. just grinds
The mixture that step a2 is obtained first carries out grinding distribution through ball mill, grind just grinding material of acquisition after 1.5～10 hours, milling time and sol gel reaction time are proportional, be ground to sol particle granularity and reach 0.1～1 micron, obtain ceramic ink jet ink, keep in Dark Place for subsequent use.
In step b, described ball mill adopts the zirconium oxide bead that diameter is 0.3mm to grind.
Preferably, in step b, described ball mill adopts the zirconium oxide bead that diameter is 0.3mm to grind.
Beneficial effect of the present invention:
A kind of extra white water-based ceramic ink jet ink, its beramic color is the colloidal sol that the presoma of zirconic presoma and silicon oxide prepares by sol-gel method, wherein, in described colloidal sol, silicon oxide and zirconic mole ratio are for being less than or equal to 1:1, or the content of silicon oxide is 0.The present invention adopts sol-gel method to prepare white beramic color, particle diameter is thinner, and there is good sphericity, can be good at controlling the initial size of material by sol-gel method simultaneously, preparation method is simple, not only solve the grinding technique problem of the long-time and highly energy-consuming of traditional ceramics jetted ink, be applicable to high precision ink jet printing head, guarantee high resolving power and the high precision of ceramic ink jet, and better retain active group by sol gel reaction, make the beramic color of the present invention can be at lesser temps sintering, overcome zirconium white pigment in prior art and needed 1500 ℃ of fastening technical barriers that adhere to of high temperature sinterings ability sintering.Meanwhile, the mole number of the silicon oxide in the present invention is not higher than zirconic mole number, since it effectively reduces ink cost, reduces sintering temperature, can guarantee again required whiteness.In the time that the mole number of silicon oxide is 0, beramic color is zirconia sol, and now, the whiteness of extra white water-based ceramic ink jet ink of the present invention is the highest.
The preparation method of a kind of extra white water-based ceramic ink jet ink of the present invention comprises and prepares colloidal sol step and grinding steps, its preparation method is simple, and the extra white water-based ceramic ink jet ink making has that whiteness is high, ink-jet is effective, be applicable to the advantages such as high precision ink jet printing head.
Embodiment
The invention will be further described with the following Examples.
embodiment 1
The present embodiment a kind of extra white water-based ceramic ink jet ink is provided, its beramic color is the colloidal sol that the presoma of zirconic presoma and silicon oxide prepares by sol-gel method, wherein, the mole number of 0:1≤silicon oxide in described colloidal sol: zirconic mole number≤1:1, in the present embodiment, colloidal sol contains silica sol, and silicon oxide and zirconic mole ratio in colloidal sol be less than or equal to 1:1, and other compositions and common water-based ceramic ink jet ink are basic identical.
In the present embodiment, above-mentioned zirconic presoma is zirconium oxychloride or oxygen zirconic acid amine, and certain zirconic presoma also can be other materials, as long as it can use sol-gel method to prepare zirconia sol; The presoma of above-mentioned silicon oxide is a kind of or two or more of tetraethoxy-silicane, tetramethoxy-silicane and water glass, wherein, the modulus of water glass is equal to, or greater than 2, certainly the presoma of silicon oxide also can be other materials, as long as it can use sol-gel method to prepare silica sol.
The colloidal sol that beramic color of the present invention is chosen to be zirconium white and silicon oxide is applied to ceramic ink jet ink with respect to prior art not obviously, although existing in prior art, zirconium white is used for to ceramic coating, but ceramic coating and ceramic ink jet ink are two different technical fields, the use of ceramic coating is that after being directly overlying on metal base, high temperature hardens into ceramic film, its objective is the not viscosity in order to improve metal base, wear resistance and thermal oxidation resistance are aging, zirconium white has wherein been also hardness and the wear resistance that improves ceramic coating, ceramic ink jet ink is to utilize printer spray printing to pottery, pottery after spray printing sintering again, the technical problem that the zirconium white of extra white water-based ceramic ink jet ink of the present invention solves is to prepare the beramic color of extra white, and energy and water, water-miscible organic solvents etc. are miscible use well.And the zirconium white of colloidal sol of the present invention and the ratio of silicon oxide, be also the creative research and development of contriver, be not that simple limited number of time experiment is available.
embodiment 2
A kind of extra white water-based ceramic ink jet ink of the present embodiment, except other compositions of beramic color are deionized water, aqueous dispersant, tensio-active agent, water-miscible organic solvent and ink addition agent, this extra white water-based ceramic ink jet ink is grouped into by the one-tenth of following weight percent:
Deionized water 20～55%
Colloidal sol 35～60%
Aqueous dispersant and surfactivity 2～10%
Water-miscible organic solvent 2-10%
Ink addition agent 2～6%
Wherein, the zirconium white of the weight of colloidal sol after with ink calcination and the dry weight of silicon oxide are calculated, and the mole ratio of zirconium white and silicon oxide is 1:1.
Wherein, after the weight of deionized water, ink calcination, dry weight, aqueous dispersant and surface-active weight, the quality of water-miscible organic solvent and the weight sum of ink addition agent of colloidal sol are gross weight, and the weight percent of each composition is multiplied by 100% calculating for its weight divided by gross weight.
The extra white water-based ceramic ink jet ink of the present embodiment, environmental protection and retained well high resolving power and the high precision of ceramic ink jet technology both can be used on Sai Er 1001 type shower nozzles, also can on U.S.'s α ursa minoris 512 type shower nozzles, use.And the solid grain size that the colloidal sol of making forms is more even, thinner, then in follow-up process of lapping, saves milling time and raise the efficiency than traditional ceramics ink for ink-jet print, the more activity hydroxy sintering temperature in surface is lower simultaneously.
Described water-miscible organic solvent is ethylene glycol, ethylene glycol monomethyl ether, diethylene glycol monomethyl ether; triethylene glycol monomethyl ether; propylene glycol monomethyl ether, dipropylene glycol monomethyl ether, thanomin; diethanolamine; trolamine, methyl-sulphoxide, morpholine; nitro morpholine, the one of nitrosomorpholine and N-formyl morpholine or two or more.
Described aqueous dispersant can be water-soluble polyacrylate, aqurous ployurethane acrylate etc., and tensio-active agent is mainly alkyl polyoxyethylene ether, polyoxyethylene nonylphenol ether etc., and polyethenoxy ether class nonionic surface active agent.
And ink addition agent mainly contains flow agent, or other can reduce capillary auxiliary agent, can be water miscible organosilicons etc.
The preparation method of above-mentioned a kind of extra white water-based ceramic ink jet ink, includes following steps:
Step a. colloidal sol processed
The presoma of zirconic presoma and silicon oxide synchronously joins in the ethanolic soln of 50% mass percent lentamente, stir while add, after material adds completely, stir hydrolysis reaction 24 hours, leave standstill afterwards 6 little layereds, abandon after supernatant liquid, add deionized water to stir again, then leave standstill 6 little layereds, abandon supernatant liquid, repeat above process, until washing pH value is neutral, obtain colloidal sol;
Step a1.
Colloidal sol after above-mentioned washing is adjusted to 1.28 ~ 1.5g/cm by the mode of emitting supernatant liquid by the density of sol system
3, add the viscosity of aqueous dispersant, decreasing by surfactant system simultaneously to colloidal sol modifying surface, in adding surface-modifying agent, use high speed dispersor to stir, after feeding in raw material, continue high-speed stirring 45～65 minutes; This step can effectively reduce the viscosity of system, improves the stably dispersing performance of system simultaneously;
Step a2.
Colloidal sol surface modification after modification completely after, more slowly add aqueous organic solvent, slowly add afterwards ink addition agent, continue high-speed stirring 55～65 minutes;
Step b. grinds
The mixture that step a2 is obtained first carries out grinding distribution through ball mill, grind just grinding material of acquisition after 1.5～10 hours, milling time and sol gel reaction time are proportional, be ground to the granularity of ceramic pigment in sol particle and reach 0.1～1 micron, obtain ceramic ink jet ink, keep in Dark Place for subsequent use.
The main technical schemes of the present embodiment is substantially the same manner as Example 1, and the feature not laying down a definition in the present embodiment adopts the explanation in embodiment 1, no longer repeats at this.
embodiment 3
The main technical schemes of the present embodiment and embodiment 1 or 2 are basic identical, and the feature not laying down a definition in the present embodiment adopts the explanation in embodiment 1 or embodiment 2, no longer repeats at this.A kind of extra white water-based ceramic ink jet ink of the present embodiment also contains silane coupling agent, while preparing extra white water-based ceramic ink jet ink, in the time adding water-miscible organic solvent, tensio-active agent, add coupling agent, coupling agent mainly contains water miscible silane coupling agent, titanate coupling agent, specifically can be aminopropyl-triethoxy silicon, aminopropyl trimethoxy silicon, epoxypropyl triethoxysilicane, epoxypropyl trimethoxy silicon etc.
embodiment 4
The main technical schemes of the present embodiment and embodiment 1 or 2 are basic identical, and the feature not laying down a definition in the present embodiment adopts the explanation in embodiment 1 or embodiment 2, no longer repeats at this.A kind of extra white water-based ceramic ink jet ink of the present embodiment is grouped into by the one-tenth of following weight percent:
Deionized water 25～50%
Colloidal sol 35～60%
Aqueous dispersant and tensio-active agent 4～10%
Water-miscible organic solvent 2～10%
Ink addition agent 3～6%
Wherein, in described colloidal sol, be only made up of zirconia sol, the content of silicon oxide is 0.In the time preparing colloidal sol, do not add the presoma of silicon oxide, the extra white ceramic ink jet ink whiteness that the colloidal sol of this composition makes is very high.
embodiment 5
The main technical schemes of the present embodiment and embodiment 1 or 2 are basic identical, and the feature not laying down a definition in the present embodiment adopts the explanation in embodiment 1 or embodiment 2, no longer repeats at this.A kind of extra white water-based ceramic ink jet ink of the present embodiment is grouped into by the one-tenth of following weight percent:
Deionized water 23%
Colloidal sol 60%
Aqueous dispersant and tensio-active agent 10%
Water-miscible organic solvent 2%
Ink addition agent 5%,
In the present embodiment, in described colloidal sol, the mole ratio of zirconium white and silicon oxide is 4:1, and extra white water-based ceramic ink jet ink sintering temperature is now lower, and whiteness is high, and ink-jet sintering effect is good.
The preparation method of extra white water-based ceramic ink jet ink in the present embodiment, zirconic presoma is zirconium oxychloride, the presoma of silicon oxide is tetraethoxy-silicane.
embodiment 6
The main technical schemes of the present embodiment and embodiment 1 or 2 are basic identical, and the feature not laying down a definition in the present embodiment adopts the explanation in embodiment 1 or embodiment 2, no longer repeats at this.A kind of extra white water-based ceramic ink jet ink of the present embodiment is grouped into by the one-tenth of following weight percent:
Deionized water 35%
Colloidal sol 45%
Aqueous dispersant and tensio-active agent 8%
Water-miscible organic solvent 8%
Ink addition agent 4%.
Extra white water-based ceramic ink jet ink of the present invention, more environmental protection, retaining well high resolving power and the high precision of ceramic ink jet technology, both can on Sai Er 1001 type shower nozzles, use, also can on U.S.'s α ursa minoris 512 type shower nozzles, use.The preparation method of ceramic ink jet ink of the present invention, adopt sol-gel method to prepare whiteware pigment early stage, particle diameter is thinner, there is good sphericity, can be good at controlling the initial size of material by sol-gel method, having solved traditional ceramics jetted ink needs for a long time, the process of lapping of highly energy-consuming simultaneously, better retained active group by sol gel reaction simultaneously, can be at lesser temps sintering.
embodiment 7
The main technical schemes of the present embodiment and embodiment 1 or 2 are basic identical, and the feature not laying down a definition in the present embodiment adopts the explanation in embodiment 1 or embodiment 2, no longer repeats at this.A kind of extra white water-based ceramic ink jet ink of the present embodiment is grouped into by the one-tenth of following weight percent:
Deionized water 20%
Colloidal sol 39%
Aqueous dispersant and tensio-active agent 2%.
Water-miscible organic solvent 2%
Ink addition agent 2%.
The extra white water-based ceramic ink jet ink whiteness of the present embodiment is high, ink-jet is effective, be applicable to high precision ink jet printing head, preparation method is simple.
embodiment 8
The main technical schemes of the present embodiment and embodiment 1 or 2 are basic identical, and the feature not laying down a definition in the present embodiment adopts the explanation in embodiment 1 or embodiment 2, no longer repeats at this.A kind of extra white water-based ceramic ink jet ink of the present embodiment is grouped into by the one-tenth of following weight percent:
Deionized water 14%
Colloidal sol 60%
Aqueous dispersant and tensio-active agent 10%
Water-miscible organic solvent 10%
Ink addition agent 6%.
The extra white water-based ceramic ink jet ink whiteness of the present embodiment is high, ink-jet is effective, be applicable to high precision ink jet printing head, preparation method is simple.
embodiment 9
The main technical schemes of the present embodiment and embodiment 1 or 2 are basic identical, and the feature not laying down a definition in the present embodiment adopts the explanation in embodiment 1 or embodiment 2, no longer repeats at this.A kind of extra white water-based ceramic ink jet ink of the present embodiment is grouped into by the one-tenth of following weight percent:
Deionized water 50%
Colloidal sol 35%
Aqueous dispersant and tensio-active agent 6%
Water-miscible organic solvent 6%
Ink addition agent 3%.
The extra white water-based ceramic ink jet ink whiteness of the present embodiment is high, ink-jet is effective, be applicable to high precision ink jet printing head, preparation method is simple.
embodiment 10
The main technical schemes of the present embodiment and embodiment 1 or 2 are basic identical, and the feature not laying down a definition in the present embodiment adopts the explanation in embodiment 1 or embodiment 2, no longer repeats at this.A kind of extra white water-based ceramic ink jet ink of the present embodiment is grouped into by the one-tenth of following weight percent:
Deionized water 46%
Colloidal sol 45%
Aqueous dispersant and tensio-active agent 4%
Water-miscible organic solvent 2%
Ink addition agent 5%.
The extra white water-based ceramic ink jet ink whiteness of the present embodiment is high, ink-jet is effective, be applicable to high precision ink jet printing head, preparation method is simple.
embodiment 11
The main technical schemes of the present embodiment and embodiment 1 or 2 are basic identical, and the feature not laying down a definition in the present embodiment adopts the explanation in embodiment 1 or embodiment 2, no longer repeats at this.A kind of extra white water-based ceramic ink jet ink of the present embodiment is grouped into by the one-tenth of following weight percent:
Deionized water 25%
Colloidal sol 56%
Aqueous dispersant and tensio-active agent 8%
Water-miscible organic solvent 8%
Ink addition agent 3%.
The extra white water-based ceramic ink jet ink whiteness of the present embodiment is high, ink-jet is effective, be applicable to high precision ink jet printing head, preparation method is simple.
The experimental result of the embodiment 5 to embodiment 11 of extra white water-based ceramic ink jet ink of the present invention is as following table:
The test result of table 1 Sai Er GS12 shower nozzle 100% gray scale spray ink Printing
As shown in Table 1, the extra white water-based ceramic ink jet ink whiteness of the present embodiment is high, ink-jet is effective, technique is simple, preparation energy consumption is low, cost-saving.
Finally should be noted that; above embodiment is only for illustrating technical scheme of the present invention but not limiting the scope of the invention; although the present invention is explained in detail with reference to preferred embodiment; those of ordinary skill in the art is to be understood that; can modify or be equal to replacement technical scheme of the present invention, and not depart from essence and the scope of technical solution of the present invention.
Claims (10)
1. an extra white water-based ceramic ink jet ink, is characterized in that: its beramic color is the colloidal sol that the presoma of zirconic presoma and silicon oxide prepares by sol-gel method,
Wherein, in described colloidal sol, silicon oxide and zirconic mole ratio are for being less than or equal to 1:1, or the content of silicon oxide is 0.
2. a kind of extra white water-based ceramic ink jet ink according to claim 1, is characterized in that: in described colloidal sol, the mole ratio of zirconium white and silicon oxide is 4:1.
3. a kind of extra white water-based ceramic ink jet ink according to claim 1, is characterized in that: described zirconic presoma is zirconium oxychloride or fluorine zirconic acid amine;
The presoma of described silicon oxide is a kind of or two or more of tetraethoxy-silicane, tetramethoxy-silicane and water glass, and wherein, the modulus of water glass is equal to, or greater than 2.
4. a kind of extra white water-based ceramic ink jet ink according to claim 1, is characterized in that: contain deionized water, aqueous dispersant, tensio-active agent, water-miscible organic solvent and ink addition agent.
5. a kind of extra white water-based ceramic ink jet ink according to claim 4, is characterized in that: the one-tenth by following weight percent is grouped into:
Deionized water 20～55%
Colloidal sol 35～60%
Aqueous dispersant and surfactivity 2～10%
Water-miscible organic solvent 2-10%
Ink addition agent 2～6%
Wherein, the dry weight of the weight of colloidal sol after with its calcination calculated.
6. a kind of extra white water-based ceramic ink jet ink according to claim 5, is characterized in that: the one-tenth by following weight percent is grouped into:
Deionized water 23%
Colloidal sol 60%
Aqueous dispersant and tensio-active agent 10%
Water-miscible organic solvent 2%
Ink addition agent 5%
.
7. a kind of extra white water-based ceramic ink jet ink according to claim 4, is characterized in that: the one-tenth by following weight percent is grouped into:
Deionized water 25～50%
Colloidal sol 40～60%
Aqueous dispersant and tensio-active agent 4～10%
Water-miscible organic solvent 2～10%
Ink addition agent 3～6%
Wherein, the dry weight of the weight of colloidal sol after with its calcination calculated.
8. a kind of extra white water-based ceramic ink jet ink according to claim 7, is characterized in that: the one-tenth by following weight percent is grouped into:
Deionized water 35%
Colloidal sol 45%
Aqueous dispersant and tensio-active agent 8%
Water-miscible organic solvent 8%
Ink addition agent 4%.
9. according to a kind of extra white water-based ceramic ink jet ink described in claim 4 ~ 8 any one, it is characterized in that: described water-miscible organic solvent is ethylene glycol, ethylene glycol monomethyl ether; diethylene glycol monomethyl ether, triethylene glycol monomethyl ether, propylene glycol monomethyl ether; dipropylene glycol monomethyl ether; thanomin, diethanolamine, trolamine; methyl-sulphoxide; morpholine, nitro morpholine, the one of nitrosomorpholine and N-formyl morpholine or two or more.
10. a preparation method for extra white water-based ceramic ink jet ink, is characterized in that: extra white water-based ceramic ink jet ink as described in claim 1 to 9 any one, and its preparation method includes following steps:
Step a. colloidal sol processed
The presoma of zirconic presoma and silicon oxide synchronously joins in 50% ethanolic soln lentamente, stir while add, after adding, stir hydrolysis reaction 24 hours, leave standstill afterwards 6 little layereds, abandon after supernatant liquid, add deionized water after 2 hours, to leave standstill again 6 little layereds in stirring, abandon supernatant liquid, repeat above process, until washing pH value is neutral, obtain colloidal sol;
Step a1.
Colloidal sol after above-mentioned washing is adjusted to 1.28 ~ 1.5g/cm by the mode of emitting supernatant liquid by the density of sol system
3, add the viscosity of aqueous dispersant, decreasing by surfactant system simultaneously to colloidal sol modifying surface, in adding surface-modifying agent, use high speed dispersor to stir, after feeding in raw material, continue high-speed stirring 45～65 minutes;
Step a2.
Colloidal sol surface modification after modification completely after, more slowly add aqueous organic solvent, slowly add afterwards ink addition agent, continue high-speed stirring 55～65 minutes;
Step b. just grinds
The mixture that step a2 is obtained first carries out grinding distribution through ball mill, grind just grinding material of acquisition after 1.5～10 hours, milling time and sol gel reaction time are proportional, be ground to the granularity of ceramic pigment in sol particle and reach 0.1～1 micron, obtain ceramic ink jet ink, keep in Dark Place for subsequent use.
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| CN107778991A (en) * | 2017-11-02 | 2018-03-09 | 武汉理工大学 | One kind is without zirconium ultrawhite inkjet printing aqueous ceramic ink and preparation method thereof |
| CN109641272A (en) * | 2016-08-23 | 2019-04-16 | 保罗·谢勒学院 | It is used to prepare the aqueous additive production method of ceramics and/or metal body |
| CN111454615A (en) * | 2020-06-09 | 2020-07-28 | 佛山市扬子颜料有限公司 | Glaze ink for ink-jet printing and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080125307A1 (en) * | 2006-11-27 | 2008-05-29 | Yanxia Lu | Refractory ceramic composite and method of making |
| CN101549858A (en) * | 2009-01-06 | 2009-10-07 | 浙江大学 | High flux ink-jet printing synthesis method of mesoporous multiple metal oxide |
| CN101723711A (en) * | 2009-12-22 | 2010-06-09 | 江门市道氏标准制釉股份有限公司 | Method for preparing zirconium-iron pink pigment for ceramic inkjet printing |
| CN101760057A (en) * | 2009-12-28 | 2010-06-30 | 上海金力泰化工股份有限公司 | Ceramic coating and preparation method thereof and method for preventing cracking of ceramic coating |
| WO2010146001A1 (en) * | 2009-06-15 | 2010-12-23 | European Aeronautic Defence And Space Company Eads France | Coating compositions including ceramic particles |
| CN102786833A (en) * | 2012-08-17 | 2012-11-21 | 广东蒙娜丽莎新型材料集团有限公司 | Ceramic inkjet ink composition and ceramic glazed tile |
-
2013
- 2013-11-27 CN CN201310610589.2A patent/CN103804993B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080125307A1 (en) * | 2006-11-27 | 2008-05-29 | Yanxia Lu | Refractory ceramic composite and method of making |
| CN101549858A (en) * | 2009-01-06 | 2009-10-07 | 浙江大学 | High flux ink-jet printing synthesis method of mesoporous multiple metal oxide |
| WO2010146001A1 (en) * | 2009-06-15 | 2010-12-23 | European Aeronautic Defence And Space Company Eads France | Coating compositions including ceramic particles |
| CN101723711A (en) * | 2009-12-22 | 2010-06-09 | 江门市道氏标准制釉股份有限公司 | Method for preparing zirconium-iron pink pigment for ceramic inkjet printing |
| CN101760057A (en) * | 2009-12-28 | 2010-06-30 | 上海金力泰化工股份有限公司 | Ceramic coating and preparation method thereof and method for preventing cracking of ceramic coating |
| CN102786833A (en) * | 2012-08-17 | 2012-11-21 | 广东蒙娜丽莎新型材料集团有限公司 | Ceramic inkjet ink composition and ceramic glazed tile |
Non-Patent Citations (1)
| Title |
|---|
| 郭建辉等: "溶胶凝胶法制备片状氧化硅／氧化锆纳米复合材料", 《化学研究》, vol. 22, no. 5, 30 September 2011 (2011-09-30) * |
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| US11742096B2 (en) | 2016-08-23 | 2023-08-29 | Paul Scherrer Institut | Aqueous additive production method for the fabrication of metallic bodies |
| CN109641272B (en) * | 2016-08-23 | 2021-04-13 | 保罗·谢勒学院 | Method for producing a green body of a nuclear fuel body |
| CN107151483B (en) * | 2017-05-31 | 2020-08-18 | 华南理工大学 | Ink for ink-jet printing, preparation method thereof and zirconia film printed by same |
| CN107151483A (en) * | 2017-05-31 | 2017-09-12 | 华南理工大学 | A kind of ink jet ink for printing and preparation method and the zirconia film by its printing |
| CN107129722A (en) * | 2017-05-31 | 2017-09-05 | 华南理工大学 | A kind of inkjet printing zirconium oxide insulating barrier ink and preparation method thereof |
| CN107474631A (en) * | 2017-09-19 | 2017-12-15 | 常州市卜诺赛机电技术有限公司 | A kind of ink-jet ceramic ink and preparation method thereof |
| CN107778991A (en) * | 2017-11-02 | 2018-03-09 | 武汉理工大学 | One kind is without zirconium ultrawhite inkjet printing aqueous ceramic ink and preparation method thereof |
| CN107778991B (en) * | 2017-11-02 | 2021-05-04 | 武汉理工大学 | Zirconium-free ultra-white water-based ceramic ink for ink-jet printing and preparation method thereof |
| CN111454615A (en) * | 2020-06-09 | 2020-07-28 | 佛山市扬子颜料有限公司 | Glaze ink for ink-jet printing and preparation method thereof |
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