CN107974132A - One kind weaving digit printing ink mill base - Google Patents
One kind weaving digit printing ink mill base Download PDFInfo
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- CN107974132A CN107974132A CN201711287728.7A CN201711287728A CN107974132A CN 107974132 A CN107974132 A CN 107974132A CN 201711287728 A CN201711287728 A CN 201711287728A CN 107974132 A CN107974132 A CN 107974132A
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- mill base
- pigment
- printing ink
- digit printing
- paratonere
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D17/00—Pigment pastes, e.g. for mixing in paints
- C09D17/001—Pigment pastes, e.g. for mixing in paints in aqueous medium
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses one kind weaving digit printing ink mill base, belong to weaving digit printing technical field of ink.The mill base includes pigment 10~20%, moisturizer 10~20%, hyper-dispersant 10~25%, resin 10~20%, dispersion aids 0.5~5%, defoamer 0.1~1%, fungicide 0.1~0.5%, pH adjusting agent 0.1~1%, deionized water surplus.After other components in above-mentioned formula in addition to pigment and portions of de-ionized water are mixed evenly, pigment and remaining deionized water are added, it is dispersed in mixed liquor, obtains pretreatment fluid；Circular grinding is carried out to pretreatment fluid, until particle diameter D50≤200nm, D90≤300nm, discharging filtering, up to mill base.The mill base of the present invention has the stronger color fastness of resistance to wet rubbing and washing fastness, and color saturation is high, lightness is good, colour gamut is broad, and stability is good, places for a long time without sedimentation phenomenon.
Description
Technical field
The present invention relates to weaving digit printing technical field of ink, and in particular to one kind weaving digit printing ink color
Slurry.
Background technology
In digital textile printing field, water consumption substitution organic solvent produces water-based direct-injection ink, and having reduces VOC rows
Put, reduce the pollution to environment；It is nonflammable explosive, reduce security risk；It is nontoxic, be conducive to contactee's health；Save stone
Oily resource, be conducive to society sustainable development the advantages that, as the trend of textile printing industry development.Water-based direct-injection ink
Water is mainly made of aqueous color paste and binder two parts, and the aqueous color paste of high stability how is made, and is water-based direct-injection ink
One of key technology of production.
It is very big to the stability influence of aqueous color paste since the surface tension of water is high compared with the common organic solvent of ink, easily
Cause pigment particles to occur reuniting or sedimentation phenomenon, largely effect on the product quality of printing, or even caking layering, make ink product
Scrap, cause larger economic loss.To solve this technical problem, most of in the industry at present is to use Leather Color Paste Carbot
Or Diamond, the stability of pigment paste is good, has the stronger color fastness of resistance to wet rubbing, but Leather Color Paste cost is higher, causes ink
Cost pressure abruptly increase.
The content of the invention
For overcome the deficiencies in the prior art, it is an object of the invention to provide one kind weaving digit printing ink color
Slurry, mill base of the invention have the stronger color fastness of resistance to wet rubbing and washing fastness, and color saturation is high, lightness is good, colour gamut
Broadness, stability of pigment paste is good, places for a long time without sedimentation phenomenon.
To solve the above problems, the technical solution adopted in the present invention is as follows：
One kind weaving digit printing ink mill base, it includes following component by mass percentage：Pigment 10~
20%th, moisturizer 10~20%, hyper-dispersant 10~25%, resin 10~20%, dispersion aids 0.5~5%, defoamer 0.1
~1%, fungicide 0.1~0.5%, pH adjusting agent 0.1~1%, deionized water surplus.
As the preferred embodiment of the present invention, the particle diameter of the mill base is D50≤200nm, D90≤300nm, prevents face
Expect that particle blocks industrial nozzle, so as to ensure print quality.
Preferably, the pigment is pigment black, paratonere, alizarol saphirol or pigment yellow.Wherein pigment black number is carbon black 7#；
Red number of pigment is preferably paratonere 19, pigment red 122, paratonere 176, paratonere 177, paratonere 254, paratonere 57:1、
Paratonere 202, paratonere 205；Pigment blueness number is preferably pigment blue 15:1st, pigment blue 15:2nd, pigment blue 15:3rd, alizarol saphirol
15:4th, pigment blue 15:5；Pigment yellow number is preferably pigment yellow 74, pigment yellow 150, pigment yellow 151, pigment yellow 155, pigment yellow
180th, one kind in pigment yellow 13 9, pigment yellow 83.
Preferably, the moisturizer is glycerine, ethylene glycol, diethylene glycol (DEG), triethylene glycol, 1,2 propane diols, 1,3 propane diols, 1,5
Pentanediol, 1,6 hexylene glycols, PEG400, PEG600, PEG900, PEG10000 are diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, two sweet
Alcohol monobutyl ether, triethylene glycol monomethyl ether, triethylene glycol list ether, triethylene glycol monobutyl ether, poly glycol monomethyl ether, polyethyleneglycol second
Ether, one kind of polyethylene glycol monobutyl ether or any two or more mixing.
Preferably, the hyper-dispersant for anion-nonionic copolymer, acrylic copolymer sodium salt, poly-alkoxyl copolymer,
One kind or any two or more mixing in phosphate.Wherein, anion-nonionic copolymer refers to that anionic dispersing agent (contains
Carboxyl, sulfonic acid group type dispersant) with non-ionic dispersing agent (polyether-type structure) be mixed in a certain ratio the copolymer to be formed.
Preferably, the resin be polyurethane, acrylic resin, one kind in makrolon or any two or more mixed
Close.
Preferably, the defoamer is one kind in mineral oil, higher alcohols, organosilicon, organic silicon modified by polyether.
Preferably, the pH adjusting agent for an ethanol ammonia, diethanolamine, triethanolamine, piece alkali, ammonium hydroxide, acetic acid, hydrochloric acid,
One kind in sulfuric acid, nitric acid, amino acid.
In above-mentioned formula, hyper-dispersant relies on electrostatic repulsion forces and space steric effect double action grappling pigment base
Group, so as to effectively prevent pigment from flocculation phenomenon occurs and makes stable system.Hyper-dispersant is with after pigment grappling and oriented alignment, setting
Fat can carry out second adsorption parcel to pigment group, so that hyper-dispersant, pigment and resin reach best match effect, energy
Mill base wet rubbing performance is enough effectively improved, wet rubbing color fastness reaches 4~4.5 grades.Moisturizer can effectively extend the longevity of industrial nozzle
Life and printing stability；Dispersion aids with solid-liquid interface by substituting solid-air interface, so as to reach efficient wetting effect；Defoaming
Agent be used for defoam, suds, not foam stabilizing；Fungicide can inhibit bacteria, fungi, the growth and breeding of algae.
As the preferred embodiment of the present invention, the mill base is made of following steps：
1) weigh each component by formula ratio, be first uniformly mixed portions of de-ionized water with moisturizer, add hyper-dispersant,
Dispersion aids, defoamer, fungicide, pH adjusting agent stir evenly, and after stirring 30min, add resin while stirring, during stirring
Between 30min, while stirring plus pigment and remaining deionized water, pigment is fully soaked, be dispersed in mixed liquor, will
Said mixture high-speed stirred disperses 120min, so as to obtain pretreatment fluid；
2) obtained pretreatment fluid is poured into sand mill, starts the cycle over grinding, zirconium pearl size is 0.05~2mm, grinding
Rotating speed is 1000~4000rpm, 6~10h of milling time, until particle diameter D50≤200nm, the D90≤300nm of material, discharge,
Filtered using negative pressure filter, filter paper 0.45um, that is, obtain the mill base.
Compared with prior art, the beneficial effects of the present invention are：
It is environment friendly and pollution-free all using aqueous materials in weaving digit printing ink paste formula of the present invention,
With the splendid color fastness of resistance to wet rubbing and washing color fastness, dry-cleaning color fastness is high, and weatherability is stronger, and the colouring time is fast, color
Saturation degree is high, lightness is good, colour gamut is broad, places for a long time without sedimentation phenomenon, stability of pigment paste is greatly enhanced and is fabricated to
This is low, suitable for mass producing and promoting.
Embodiment
The present invention is described in further detail with reference to embodiment.
One kind weaving digit printing ink mill base, it includes following component by mass percentage：Pigment 10~
20%th, moisturizer 10~20%, hyper-dispersant 10~25%, resin 10~20%, dispersion aids 0.5~5%, defoamer 0.1
~1%, fungicide 0.1~0.5%, pH adjusting agent 0.1~1%, deionized water surplus.The particle diameter of above-mentioned mill base for D50≤
200nm、D90≤300nm。
In above-mentioned formula：
Pigment is preferably pigment black, paratonere, alizarol saphirol or pigment yellow.Wherein pigment black number is carbon black 7#, specific excellent
Select following type product：Mitsubishi MA7, MA11, MA77, MA8, MA11, MA100, MA230, MA100R, MA100S, MA220,
MA600 or Capote M600, M700；Red number of pigment is preferably paratonere 19, pigment red 122, paratonere 176, paratonere
177th, paratonere 254, paratonere 57:1st, paratonere 202, paratonere 205；Pigment blueness number is preferably pigment blue 15:1st, pigment
Indigo plant 15:2nd, pigment blue 15:3rd, pigment blue 15:4th, pigment blue 15:5；Pigment yellow number is preferably pigment yellow 74, pigment yellow 150, face
One kind in material Huang 151, pigment yellow 155, pigment yellow 180, pigment yellow 13 9, pigment yellow 83.Moisturizer is preferably glycerine, second two
Alcohol, diethylene glycol (DEG), triethylene glycol, 1,2 propane diols, 1,3 propane diols, 1,5 pentanediols, 1,6 hexylene glycols, PEG400, PEG600,
PEG900, PEG10000, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, triethylene glycol monomethyl ether, triethylene glycol list
Ether, triethylene glycol monobutyl ether, poly glycol monomethyl ether, polyethyleneglycol ether, one kind of polyethylene glycol monobutyl ether or any two
The mixing of the kind above.Hyper-dispersant is preferably anion-nonionic copolymer, acrylic copolymer sodium salt, poly-alkoxyl copolymer, phosphorus
One kind or any two or more mixing in acid esters, the preferred U.S.'s aerochemistry Co., Ltd of specific product model
Surfynol CT-136、CT-171、ZS170、ZS175、ZS179、ZS1200、ZS2300、ZS3800.Resin is preferably poly- ammonia
One kind or any two or more mixing in ester, acrylic resin, makrolon, the preferred Lamberti of specific product model
PU 61、PU 63、PU 71、PU 73、PU 74、PU 39、PU 40、PU 55、PU 56.The preferred US Air gasification of dispersion aids
Learn Co., Ltd Surfynol series of products and Dynol series of products, preferably Surfynol 485,486,440, FS-85,
2502nd, 104PA or Dynol360,800.Defoamer is mineral oil, one kind in higher alcohols, organosilicon, organic silicon modified by polyether,
Preferable product is serial to win wound TEGO series Foamex 800, such as 822,823,831,840,845.The preferably western class of fungicide
Biopol TC-3, TK-1, JM309 of tooth all risk insurance chemical company.PH adjusting agent for an ethanol ammonia, diethanolamine, triethanolamine,
One kind in piece alkali, ammonium hydroxide, acetic acid, hydrochloric acid, sulfuric acid, nitric acid, amino acid.
Above-mentioned mill base is made of following steps：
1) weigh each component by formula ratio, be first uniformly mixed portions of de-ionized water with moisturizer, add hyper-dispersant,
Dispersion aids, defoamer, fungicide, pH adjusting agent stir evenly, and after stirring 30min, add resin while stirring, during stirring
Between 30min, while stirring plus pigment and remaining deionized water, pigment is fully soaked, be dispersed in mixed liquor, will
Said mixture high-speed stirred disperses 120min, so as to obtain pretreatment fluid；
2) obtained pretreatment fluid is poured into sand mill, starts the cycle over grinding, zirconium pearl size is 0.05~2mm, grinding
Rotating speed is 1000~4000rpm, 6~10h of milling time, until particle diameter D50≤200nm, the D90≤300nm of material, discharge,
Filtered using negative pressure filter, filter paper 0.45um, that is, obtain the mill base.
Embodiment：
The mill base composition and dosage of embodiment 1~4 are shown in Table 1.Prepare the mill base of embodiment 1~4 respectively by above-mentioned steps.
1 embodiment of table, 1~4 mill base forms and dosage
Performance test：
By the mill base obtained by above example 1~4, import Carbot mill bases, Diamond mill bases and without resin blank
Group mill base carries out preparation ink by formula as below, its ink set is as follows：
H2O 48.5%, glycerine 15%, diethylene glycol (DEG) 10%, Surfynol 465 0.5%, Biopol TC-3 0.5%,
Triethanolamine 0.5%, mill base 25%.
The ink prepared to more than is tested for the property；The ink that embodiment 1~4 is prepared is being located
Directly ink-jet printed on the cloth managed, pressing drying, obtains PRINTED FABRIC finished product, tests the xerotripsis color jail of PRINTED FABRIC finished product
Degree and wet rubbing color fastness, draw following result：
2 the performance test results of table contrast
As seen from the above table, weaving digit printing ink mill base of the present invention and import Carbot mill bases, Diamond
Mill base and compared without resin blank group mill base, color saturation is high, lightness is good, colour gamut is broad, and stability of pigment paste is good, for a long time
Placement is also substantially improved without sedimentation phenomenon, the stability of mill base.Textile printing end properties made from mill base using the present invention
Excellent, dry-cleaning color fastness is high, Washing is high, and dry and wet rubs more preferably, and weatherability is stronger, and the colouring time is faster and environmental protection is without dirt
Dye, indices meet domestic and EU criteria.
The above embodiment is only the preferred embodiment of the present invention, it is impossible to the scope of protection of the invention is limited with this,
The change and replacement for any unsubstantiality that those skilled in the art is done on the basis of the present invention belong to institute of the present invention
Claimed scope.
Claims (9)
1. one kind weaving digit printing ink mill base, it is characterised in that：Including following component by mass percentage：Pigment
10~20%, moisturizer 10~20%, hyper-dispersant 10~25%, resin 10~20%, dispersion aids 0.5~5%, defoamer
0.1~1%, fungicide 0.1~0.5%, pH adjusting agent 0.1~1%, deionized water surplus.
2. weaving digit printing ink mill base according to claim 1, it is characterised in that：The particle diameter of the mill base is
D50≤200nm、D90≤300nm。
3. weaving digit printing ink mill base according to claim 1, it is characterised in that：The pigment for carbon black 7#,
Paratonere 19, pigment red 122, paratonere 176, paratonere 177, paratonere 254, paratonere 57:1st, paratonere 202, paratonere
205th, pigment blue 15:1st, pigment blue 15:2nd, pigment blue 15:3rd, pigment blue 15:4th, pigment blue 15:5th, pigment yellow 74, pigment yellow
150th, one kind in pigment yellow 151, pigment yellow 155, pigment yellow 180, pigment yellow 13 9, pigment yellow 83.
4. weaving digit printing ink mill base according to claim 1, it is characterised in that：The moisturizer for glycerine,
Ethylene glycol, diethylene glycol (DEG), triethylene glycol, 1,2 propane diols, 1,3 propane diols, 1,5 pentanediols, 1,6 hexylene glycols, PEG400, PEG600,
PEG900, PEG10000, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, triethylene glycol monomethyl ether, triethylene glycol list
Ether, triethylene glycol monobutyl ether, poly glycol monomethyl ether, polyethyleneglycol ether, one kind of polyethylene glycol monobutyl ether or any two
The mixing of the kind above.
5. weaving digit printing ink mill base according to claim 1, it is characterised in that：The hyper-dispersant for it is cloudy-
Non-ionic copolymer, acrylic copolymer sodium salt, poly-alkoxyl copolymer, one kind in phosphate or any two or more mixed
Close.
6. weaving digit printing ink mill base according to claim 1, it is characterised in that：The resin for polyurethane,
One kind or any two or more mixing in acrylic resin, makrolon.
7. weaving digit printing ink mill base according to claim 1, it is characterised in that：The defoamer is mineral
One kind in oil, higher alcohols, organosilicon, organic silicon modified by polyether.
8. weaving digit printing ink mill base according to claim 1, it is characterised in that：The pH adjusting agent is a second
One kind in alcohol ammonia, diethanolamine, triethanolamine, piece alkali, ammonium hydroxide, acetic acid, hydrochloric acid, sulfuric acid, nitric acid, amino acid.
9. weaving digit printing ink mill base according to claim 1, it is characterised in that：The mill base is by following step
Made of rapid：
1) each component is weighed by formula ratio, is first uniformly mixed portions of de-ionized water with moisturizer, added hyper-dispersant, help point
Powder, defoamer, fungicide, pH adjusting agent stir evenly, and after stirring 30min, add resin, mixing time while stirring
30min, adds pigment and remaining deionized water, pigment is fully soaked, be dispersed in mixed liquor while stirring, will be upper
State mixture high-speed stirred and disperse 120min, so as to obtain pretreatment fluid；
2) obtained pretreatment fluid is poured into sand mill, starts the cycle over grinding, zirconium pearl size is 0.05~2mm, grinds rotating speed
For 1000~4000rpm, 6~10h of milling time, until particle diameter D50≤200nm, the D90≤300nm of material, discharge, use
Negative pressure filter, filter paper 0.45um are filtered, that is, obtain the mill base.
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|---|---|---|---|
| CN201711287728.7A CN107974132A (en) | 2017-12-07 | 2017-12-07 | One kind weaving digit printing ink mill base |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711287728.7A CN107974132A (en) | 2017-12-07 | 2017-12-07 | One kind weaving digit printing ink mill base |
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Cited By (4)
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| CN110452577A (en) * | 2018-05-08 | 2019-11-15 | 台湾永光化学工业股份有限公司 | Ultrahigh brightness aqueous white colorant for digital textile printing ink and the composition for ink using it |
| CN110540776A (en) * | 2019-10-12 | 2019-12-06 | 深圳市墨库图文技术有限公司 | Dispersion liquid applied to digital printing pigment |
| CN110591448A (en) * | 2019-09-26 | 2019-12-20 | 珠海佳印数码科技有限公司 | High-pigment-concentration digital direct-injection textile coating ink and preparation method thereof |
| CN114728215A (en) * | 2019-11-06 | 2022-07-08 | 陶氏东丽株式会社 | Water-soluble silicone defoamer composition and water-based coating containing same |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110452577A (en) * | 2018-05-08 | 2019-11-15 | 台湾永光化学工业股份有限公司 | Ultrahigh brightness aqueous white colorant for digital textile printing ink and the composition for ink using it |
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| CN114728215A (en) * | 2019-11-06 | 2022-07-08 | 陶氏东丽株式会社 | Water-soluble silicone defoamer composition and water-based coating containing same |
| CN114728215B (en) * | 2019-11-06 | 2023-09-22 | 陶氏东丽株式会社 | Water-soluble organosilicon defoamer composition and water-based paint containing same |
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