CN110219207A - A kind of moisturizing softening agent and preparation method thereof - Google Patents

A kind of moisturizing softening agent and preparation method thereof Download PDF

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Publication number
CN110219207A
CN110219207A CN201910559993.9A CN201910559993A CN110219207A CN 110219207 A CN110219207 A CN 110219207A CN 201910559993 A CN201910559993 A CN 201910559993A CN 110219207 A CN110219207 A CN 110219207A
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parts
oil
agent
revolving speed
reaction time
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Inventor
刘群鸿
刘主良
刘建国
刘志辉
庄艺伟
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Fujian Yu Cheng Chemical Industry & Trade Co Ltd
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Fujian Yu Cheng Chemical Industry & Trade Co Ltd
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Priority to CN201910559993.9A priority Critical patent/CN110219207A/en
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    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/02—Material of vegetable origin
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/06—Alcohols; Phenols; Ethers; Aldehydes; Ketones; Acetals; Ketals
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/07—Nitrogen-containing compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/11—Halides
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/14—Carboxylic acids; Derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/22—Proteins
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/59—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/002—Tissue paper; Absorbent paper
    • D21H27/004—Tissue paper; Absorbent paper characterised by specific parameters
    • D21H27/005—Tissue paper; Absorbent paper characterised by specific parameters relating to physical or mechanical properties, e.g. tensile strength, stretch, softness

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Absorbent Articles And Supports Therefor (AREA)

Abstract

The present invention discloses a kind of moisturizing softening agent and preparation method thereof, the moisturizing softening agent include the mass parts of major ingredient glycerol be 50-80 parts, the mass parts of hygroscopic agent are 5-30 parts, the mass parts of lubricant are 2-20 parts, the mass parts of soft stabilizer are 2-20 parts, the mass fraction of water is 5-40 parts；Preparation methods steps include: to add hygroscopic agent and water in a kettle, and control revolving speed is 100-800r/min, and temperature is 10-80 DEG C, reaction time 10-50min；Temperature of reaction kettle is increased to 50-90 DEG C, under conditions of revolving speed is 500-1500r/min, is slowly added soft stabilizer, is slowly added lubricant again later, reaction time 20-120min is down to room temperature after reaction；Revolving speed is adjusted to 100-800r/min again and is slowly added major ingredient glycerol, reaction time 20-120min under room temperature；Then it will be packed into container, be sealed after product filtering.Moisturizing softening agent of the present invention is remarkably improved the skin-friction force with skin such as pliability of amenities, moisturizing degree, and significant decrease paper handkerchief, gives the good feeling of user.

Description

A kind of moisturizing softening agent and preparation method thereof
Technical field
The present invention relates to hygiene article sectors, in particular to are suitable on the amenities such as paper handkerchief, paper diaper, sanitary napkin Moisturizing softening agent and preparation method thereof.
Background technique
Life/sanitary paper is the essential product of modern's daily life, especially to the paper for skin wiping Requirement in the functions such as softness, skin care, antibacterial is also higher and higher.All be in the industry at present by add various functional materials come Improve pliability and the performance of keeping humidity etc. of paper handkerchief.Soft paper such as a kind of surface Chinese patent CN103061204A by arrangement, Upper layer is coated with softening agent emulsion compositions, and softening agent emulsion compositions include: diorganopolysiloxaneand, moisturizing Agent, thickener etc.；A kind of moisture-keeping composition of Chinese patent CN103070803A and the paper handkerchief for applying it, with CN103061204A case Similar, two patents are all that constituent is simply mixed, and intermiscibility conflict easily occurs between each component, such as: play lubricating action Component is usually oiliness apolar substance, and the component for playing moisture-keeping function is mainly the hydroaropic substances such as water, alcohols, if each group Divide simple compounding easily grease lamination occur or cloudy state occur, influences the quality and use of paper.
Summary of the invention
In view of the deficiencies of the prior art, the object of the present invention is to provide a kind of moisturizing softening agent, which is used It is more stable in terms of degree of wetting, pliability and stability on the products such as paper handkerchief, and raw material is unlikely to deteriorate between each component.
To achieve the goals above, solution of the invention are as follows:
A kind of moisturizing softening agent, including major ingredient glycerol, hygroscopic agent, lubricant, soft stabilizer, water.The mass parts of the major ingredient It is 50-80 parts, the mass parts of hygroscopic agent are 5-30 parts, and the mass parts of lubricant are 2-20 parts, and the mass parts of soft stabilizer are 2-20 parts, the mass fraction of water is 5-40 parts.
The hygroscopic agent is propylene glycol, 1,3 butylene glycol, hexylene glycol, polyethylene glycol, polyether polyol, D-sorbite, Portugal More than grape sugar, xylitol, mannitol, amino acid, hyaluronic acid, collagen etc. are one or two kinds of.
The lubricant be methyl-silicone oil, vegetable oil (jojoba ester, wheat-germ oil, cupu oil, olive oil, sunflower oil, Peanut oil etc.), cholesterol, animal oil (saualane, cod-liver oil, sheep oil etc.), naphtha etc. it is one or two kinds of more than.
The softness stabilizer is Span (20,40,60,80 etc.), tween (20,40,60,80 etc.), anhydroglucose, 12 Alkyl trimethyl chlorine (bromine) changes ammonium, cetyl trimethyl chlorine (bromine) changes ammonium, lauryl sodium sulfate, neopelex More than one or two kinds of.
It further, is 0.1-2 part antibacterial agents the invention also includes mass parts, the antibacterial agent is nano silver, nano oxidized Titanium, titanium dioxide, gas phase titanium dioxide, magnesia, zinc oxide, magnesium hydroxide, basic copper carbonate, Kocide SD, paraben esters, outstanding person One of the different imidazolone of horse BP, methyl, the propionic ester of β containing chlorine, PHMB, PHMG and quaternary ammonium salt are two or more.
The quaternary ammonium salt includes benzalkonium chloride, benzalkonium bromide, cetyltrimethyl ammonium, double certain herbaceous plants with big flowers base dimethyl ammoniums, alkyl Trimethyl ammonium carbonate.
It further, is 0.01-1 parts of aromatic the invention also includes mass parts, the aromatic is Artemisia stelleriana essential oil, peppermint Alcohol, borneol, radix aucklandiae essential oil, lemon oil, rosemary oil, pelargonium oil, cysteine, peach gum powder, tea tree ethereal oil, milk essence, rose One of rare essential oil, Lavender are two or more.
It is a further object of the present invention to provide the preparation methods of the moisturizing softening agent, comprising the following steps:
Step 1: adding hygroscopic agent and water in a kettle, and control revolving speed is 100-800r/min, and temperature is 10-80 DEG C, reaction Time is 10-50min.
Step 2: temperature of reaction kettle is increased to 50-90 DEG C, under conditions of revolving speed is 500-1500r/min, is slowly added soft Soft stabilizer, is slowly added lubricant again later, and reaction time 20-120min is down to room temperature after reaction.
Step 3: revolving speed is adjusted to 100-800r/min and is slowly added major ingredient glycerol, reaction time under room temperature For 20-120min.
Step 4: it will be packed into container, be sealed after product filtering.
Further, antibacterial agent or/and aromatic are added while major ingredient is added in the step 3.
Further, the preparation method of the moisturizing softening agent, comprising the following steps:
Step 1: being added major ingredient glycerol, antibacterial agent, aromatic in reaction kettle A, and control revolving speed is 300r/min, reaction time For 20min；
Step 2: in another reaction kettle B, hygroscopic agent, water are added, control revolving speed is 600r/min, and temperature is 40 DEG C, reaction Time is 40min；
Step 3: reaction kettle B is increased into temperature to 80 DEG C, under conditions of revolving speed is 1400r/min, is slowly added soft stabilization Agent, is slowly added lubricant again later, and reaction time 80min is down to room temperature after reaction；
Step 4: material in reaction kettle B is poured slowly into reaction kettle A, and control revolving speed is 500r/min, reaction time 20min；
Step 4: it will be packed into container, be sealed after product filtering.
Another object of the present invention is to provide a kind of amenities in direct contact with the skin, and the surface of sanitary applies It is covered with the moisturizing softening agent, the amenities includes toilet paper, face tissue, napkin paper, sanitary napkin, paper diaper, moisture paper tissue papers.
Beneficial effects of the present invention:
Moisturizing softening agent of the present invention mixes the different order of property settings material delivery, speed of agitator and anti-according to each component Between seasonable, gained moisturizing softening agent is less prone to grease lamination or cloudy state occurs；In addition this moisturizing softening agent can The skin-friction force with skin such as pliability, moisturizing degree of amenities, and significant decrease paper handkerchief is significantly improved, user is given Good feeling.
Specific embodiment
For technical solution of the present invention is explained further, the present invention is explained in detail below by specific embodiment It states.
A kind of moisturizing softening agent, including major ingredient glycerol, hygroscopic agent, lubricant, soft stabilizer, antibacterial agent, aromatic.Institute The mass parts for stating major ingredient are 50-80 parts, and the mass parts of hygroscopic agent are 5-30 parts, and the mass parts of lubricant are 2-20 parts, flexible stationary The mass parts for determining agent are 2-20 parts, and the mass fraction of water is 5-40 parts.
Above-mentioned hygroscopic agent can be propylene glycol, 1,3 butylene glycol, hexylene glycol, polyethylene glycol, polyether polyol, sorbose It is mixed more than alcohol, glucose, xylitol, mannitol, amino acid, hyaluronic acid, collagen etc. are one or two kinds of.
Above-mentioned lubricant can be methyl-silicone oil, vegetable oil (jojoba ester, wheat-germ oil, cupu oil, olive oil, certain herbaceous plants with big flowers Caul-fat, peanut oil etc.), cholesterol, animal oil (saualane, cod-liver oil, sheep oil etc.), naphtha etc. it is one or two kinds of more than It is mixed.
It is above-mentioned softness stabilizer can be Span (20,40,60,80 etc.), tween (20,40,60,80 etc.), anhydroglucose, Trimethyl chlorine (bromine) changes ammonium, cetyl trimethyl chlorine (bromine) changes ammonium, lauryl sodium sulfate, detergent alkylate sulphur It is mixed more than sour sodium etc. is one or two kinds of.
Above-mentioned antibacterial agent can be nano silver, nano-titanium oxide, titanium dioxide, gas phase titanium dioxide, magnesia, zinc oxide, Magnesium hydroxide, basic copper carbonate, Kocide SD, paraben esters, outstanding horse BP, the different imidazolone of methyl, the propionic ester of β containing chlorine, PHMB, One of PHMG and quaternary ammonium salt or two or more materials are mixed；The type of the quaternary ammonium salt includes benzalkonium chloride, benzene Prick bromine ammonium, cetyltrimethyl ammonium, double certain herbaceous plants with big flowers base dimethyl ammoniums, alkyl trimethyl ammonium carbonate.
Above-mentioned aromatic can be Artemisia stelleriana essential oil, menthol, borneol, radix aucklandiae essential oil, lemon oil, rosemary oil, fish pelargonium One of oil, cysteine, peach gum powder, tea tree ethereal oil, milk essence, Rosa Damascana, Lavender or two or more materials Material is mixed.
Illustrate effect of the invention below by way of specific embodiment:
Number in following embodiment is mass fraction.
Embodiment 1:
Step 1: being added 15 parts of hygroscopic agents (D-sorbite), 10 parts of water in a kettle, and control revolving speed is 400r/min, temperature It is 25 DEG C, reaction time 20min.
Step 2: temperature is increased to 70 DEG C, under conditions of revolving speed is 1200r/min, is slowly added 10 parts of soft stabilizers (dodecyl trimethyl ammonium chloride) is slowly added 6 parts of lubricants (sheep oil), reaction time 100min, reaction knot later Room temperature is down to after beam.
Step 3: revolving speed is adjusted to 300r/min and is slowly added 60 parts of major ingredients (glycerol) under room temperature, 0.6 part anti- Microbial inoculum (0.3 part of outstanding person horse BP and 0.3 part of cetyltrimethyl ammonium), 0.02 part of aromatic (menthol), reaction time is 80min。
Step 4: it will be packed into (bottle) bucket, be sealed after product filtering.
Embodiment 2:
Step 1: being added 20 parts of hygroscopic agents (10 parts of ethylene glycol and 10 parts of xylitols), 8 parts of water in a kettle, and control revolving speed is 600r/min, temperature are 40 DEG C, reaction time 40min.
Step 2: increasing temperature to 80 DEG C, under conditions of revolving speed is 1400r/min, by being slowly added 8 parts of soft stabilizers (anhydroglucose), is slowly added 3 parts of lubricants (jojoba ester) again later, and reaction time 80min is down to room after reaction Temperature.
Step 3: revolving speed is adjusted to 500r/min and is slowly added 50 parts of major ingredients (glycerol) under room temperature, 0.5 part anti- Microbial inoculum (0.2 part of paraben esters and 0.3 part of point of PHMB), 0.02 part of aromatic (lemon oil), reaction time 60min.
Step 4: it will be packed into (bottle) bucket, be sealed after product filtering.
Embodiment 3:
Step 1: being added 5 parts of hygroscopic agents (hyaluronic acid), 10 parts of water in a kettle, and control revolving speed is 300r/min, and temperature is 30 DEG C, reaction time 20min.
Step 2: temperature is increased to 80 DEG C, under conditions of revolving speed is 1000r/min, is slowly added 5 parts of soft stabilizers (Span 60), is slowly added 5 parts of lubricants (olive oil) again later, and reaction time 80min is down to room temperature after reaction.
Step 3: revolving speed is adjusted to 600r/min and is slowly added 70 parts of major ingredients (glycerol) under room temperature, 0.3 part anti- Microbial inoculum (nano silver), 0.01 part of aromatic (Rosa Damascana), reaction time 60min.
Step 4: it will be packed into (bottle) bucket, be sealed after product filtering.
Embodiment 4:
Step 1: being added 10 parts of hygroscopic agents (amino acid), 10 parts of water in a kettle, and control revolving speed is 600r/min, and temperature is 30 DEG C, reaction time 40min.
Step 2: temperature is increased to 60 DEG C, under conditions of revolving speed is 1200r/min, is slowly added 10 parts of soft stabilizers (hexadecyltrimethylammonium chloride) is slowly added 10 parts of lubricants (silicone oil), reaction time 80min, reaction knot again later Room temperature is down to after beam.
Step 3: revolving speed is adjusted to 600r/min and is slowly added 80 parts of major ingredients (glycerol) under room temperature, 0.3 part anti- Microbial inoculum (benzalkonium bromide), 0.01 part of aromatic (milk essence), reaction time 100min.
Step 4: it will be packed into (bottle) bucket, be sealed after product filtering.
Embodiment 5, its step are as follows:
Step 1: 50 parts of major ingredients (glycerol), 0.5 part of antibacterial agent (0.2 part of paraben esters and 0.3 part point are added in reaction kettle A PHMB), 0.02 part of aromatic (lemon oil), control revolving speed are 300r/min, reaction time 20min.
Step 2: in another reaction kettle B, 20 parts of hygroscopic agents (10 parts of ethylene glycol and 10 parts of xylitols), 8 parts are added Water, control revolving speed are 600r/min, and temperature is 40 DEG C, reaction time 40min.
Step 3: reaction kettle B is increased into temperature to 80 DEG C, revolving speed is soft under conditions of 1400r/min, to be slowly added 8 parts Soft stabilizer (anhydroglucose), is slowly added 3 parts of lubricants (jojoba ester), reaction time 80min again later, and reaction terminates After be down to room temperature.
Step 4: material in reaction kettle B is poured slowly into reaction kettle A, and control revolving speed is 500r/min, reaction time 20min。
Step 4: it will be packed into (bottle) bucket, be sealed after product filtering.
Detection method: the sample that will be prepared is uniformly coated on commercially available common paper handkerchief according to 10% ± 2% upper liquid rate On, it is placed in 25 ± 1 DEG C, in 65% ± 5%RH environment sealed compartment, stands for 24 hours.The paper prepared is successively marked according to embodiment Sample 1, sample 2, sample 3, sample 4, sample 5.Commercially available plain paper is labeled as comparison 1, and commercially available soft paper is labeled as comparison 2.
Tensile index, pliability, 100s suction range are tested according to the method for GB/T20808-2006.Dynamic friction system Number uses MXD-02 friction coefficient instrument, and dynamic friction coefficient is smaller to illustrate that surface is more smooth.Antibacterial bacteriostatic performance according to " experimental method of the antibacterial agent determination of activity under ASTME2149-13a dynamic condition " is tested.
Table 1 lists the testing result of above several embodiments
Sample 1 Sample 2 Sample 3 Sample 4 Sample 5 Comparison 1 Comparison 2
Tensile index 1.65 1.43 1.57 1.38 1.42 2.80 1.80
Pliability 56 48 45 40 47 73 52
100s suction range 42 40 38 39 40 40 38
Dynamic friction coefficient 0.55 0.48 0.45 0.38 0.51 0.92 0.62
Bacteria resistance (Escherichia coli) 89% 92% 96% 99% 92% 55% 80%
By 1 correlation data of table it is found that the sample of preparation has in all opposite plain paper of tensile index, pliability, dynamic friction coefficient Very big raising also has different degrees of promotion than commercially available flexible towelette.100s suction range and commercial product are similar, and Antibacterial bacteriostatic performance is superior to commercially available common and soft paper.
Moisturizing softening agent of the present invention, according to each component mix property settings material delivery different order, speed of agitator with And reaction time, gained moisturizing softening agent are less prone to grease lamination or cloudy state occur；In addition this moisturizing is soft Agent is remarkably improved the skin-friction force with skin such as pliability of amenities, moisturizing degree, and significant decrease paper handkerchief, and giving makes The good feeling of user.
Above-described embodiment and non-limiting product form and style of the invention, the ordinary skill people of any technical field The appropriate changes or modifications (variation of such as reaction step, the replacement of reaction mass, the variation etc. of reaction condition) that member does it, It all should be regarded as not departing from patent category of the invention.

Claims (8)

1. a kind of moisturizing softening agent, which is characterized in that including major ingredient glycerol, hygroscopic agent, lubricant, soft stabilizer, water；It is described The mass parts of major ingredient are 50-80 parts, and the mass parts of hygroscopic agent are 5-30 parts, and the mass parts of lubricant are 2-20 parts, and softness is stablized The mass parts of agent are 2-20 parts, and the mass fraction of water is 5-40 parts；
The hygroscopic agent be propylene glycol, 1,3 butylene glycol, hexylene glycol, polyethylene glycol, polyether polyol, D-sorbite, glucose, More than xylitol, mannitol, amino acid, hyaluronic acid, collagen etc. are one or two kinds of；
The lubricant is methyl-silicone oil, vegetable oil (jojoba ester, wheat-germ oil, cupu oil, olive oil, sunflower oil, peanut Oil etc.), cholesterol, animal oil (saualane, cod-liver oil, sheep oil etc.), naphtha etc. it is one or two kinds of more than；
The softness stabilizer is Span (20,40,60,80 etc.), tween (20,40,60,80 etc.), anhydroglucose, dodecyl Trimethyl chlorine (bromine) changes ammonium, cetyl trimethyl chlorine (bromine) changes ammonium, lauryl sodium sulfate, neopelex etc. one Kind is two or more.
2. a kind of moisturizing softening agent as described in claim 1, which is characterized in that further include mass parts be 0.1-2 parts of antibacterial agents； The antibacterial agent is nano silver, nano-titanium oxide, titanium dioxide, gas phase titanium dioxide, magnesia, zinc oxide, magnesium hydroxide, alkali formula Copper carbonate, Kocide SD, paraben esters, outstanding horse BP, the different imidazolone of methyl, the propionic ester of β containing chlorine, PHMB, PHMG and quaternary ammonium salt One of or it is two or more；
The quaternary ammonium salt includes benzalkonium chloride, benzalkonium bromide, cetyltrimethyl ammonium, double certain herbaceous plants with big flowers base dimethyl ammoniums, alkyl front three Base ammonium carbonate.
3. a kind of moisturizing softening agent as claimed in claim 1 or 2, which is characterized in that further include that mass parts are fragrant for 0.01-1 parts Pastil；The aromatic is Artemisia stelleriana essential oil, menthol, borneol, radix aucklandiae essential oil, lemon oil, rosemary oil, pelargonium oil, half Guang One of propylhomoserin, peach gum powder, tea tree ethereal oil, milk essence, Rosa Damascana, Lavender are two or more.
4. a kind of preparation method of moisturizing softening agent as described in claim 1, which comprises the following steps:
Step 1: adding hygroscopic agent and water in a kettle, and control revolving speed is 100-800r/min, and temperature is 10-80 DEG C, reaction Time is 10-50min；
Step 2: temperature of reaction kettle is increased to 50-90 DEG C, under conditions of revolving speed is 500-1500r/min, is slowly added flexible stationary Determine agent, be slowly added lubricant again later, reaction time 20-120min is down to room temperature after reaction；
Step 3: revolving speed is adjusted to 100-800r/min and is slowly added major ingredient glycerol, reaction time 20- under room temperature 120min；
Step 4: it will be packed into container, be sealed after product filtering.
5. a kind of preparation method of moisturizing softening agent as claimed in claim 3, which comprises the following steps:
Step 1: adding hygroscopic agent and water in a kettle, and control revolving speed is 100-800r/min, and temperature is 10-80 DEG C, reaction Time is 10-50min；
Step 2: temperature of reaction kettle is increased to 50-90 DEG C, under conditions of revolving speed is 500-1500r/min, is slowly added flexible stationary Determine agent, be slowly added lubricant again later, reaction time 20-120min is down to room temperature after reaction；
Step 3: revolving speed is adjusted to 100-800r/min and is slowly added major ingredient glycerol, antibacterial agent or fragrance under room temperature Agent, reaction time 20-120min；
Step 4: it will be packed into container, be sealed after product filtering.
6. a kind of preparation method of moisturizing softening agent as claimed in claim 3, which comprises the following steps:
Step 1: being added major ingredient glycerol, antibacterial agent, aromatic in reaction kettle A, and control revolving speed is 300r/min, reaction time For 20min；
Step 2: in another reaction kettle B, hygroscopic agent, water are added, control revolving speed is 600r/min, and temperature is 40 DEG C, reaction Time is 40min；
Step 3: reaction kettle B is increased into temperature to 80 DEG C, under conditions of revolving speed is 1400r/min, is slowly added soft stabilization Agent, is slowly added lubricant again later, and reaction time 80min is down to room temperature after reaction；
Step 4: material in reaction kettle B is poured slowly into reaction kettle A, and control revolving speed is 500r/min, reaction time 20min；
Step 4: it will be packed into container, be sealed after product filtering.
7. a kind of amenities in direct contact with the skin, which is characterized in that the surface of sanitary is coated with claim 1 Or moisturizing softening agent described in 2, the amenities include toilet paper, face tissue, napkin paper, sanitary napkin, paper diaper, wet tissue Paper.
8. a kind of amenities in direct contact with the skin, which is characterized in that the surface of sanitary is coated with claim 3 The moisturizing softening agent, the amenities include toilet paper, face tissue, napkin paper, sanitary napkin, paper diaper, moisture paper tissue papers.
CN201910559993.9A 2019-06-26 2019-06-26 A kind of moisturizing softening agent and preparation method thereof Pending CN110219207A (en)

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CN114182571A (en) * 2020-09-15 2022-03-15 刘训林 Pearl amino acid paper towel and preparation method thereof
CN114263068A (en) * 2021-12-30 2022-04-01 福建恒安集团有限公司 Soft antibacterial finishing agent, preparation method and application process thereof
EP4219828A4 (en) * 2020-12-10 2024-03-27 Zhejiang Jingxing Paper Joint Stock Co Ltd Method for preparing bacteriostatic household paper

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Application publication date: 20190910