CN110212039A - The method that laser sintered tinsel prepares the thin gate line electrode of photovoltaic cell - Google Patents

The method that laser sintered tinsel prepares the thin gate line electrode of photovoltaic cell Download PDF

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Publication number
CN110212039A
CN110212039A CN201910466066.2A CN201910466066A CN110212039A CN 110212039 A CN110212039 A CN 110212039A CN 201910466066 A CN201910466066 A CN 201910466066A CN 110212039 A CN110212039 A CN 110212039A
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CN
China
Prior art keywords
tinsel
gate line
line electrode
photovoltaic cell
thin gate
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CN201910466066.2A
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Chinese (zh)
Inventor
朱学林
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Jiangsu Oudafeng New Energy Technology Development Co Ltd
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Jiangsu Oudafeng New Energy Technology Development Co Ltd
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Priority to CN201910466066.2A priority Critical patent/CN110212039A/en
Publication of CN110212039A publication Critical patent/CN110212039A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0224Electrodes
    • H01L31/022408Electrodes for devices characterised by at least one potential jump barrier or surface barrier
    • H01L31/022425Electrodes for devices characterised by at least one potential jump barrier or surface barrier for solar cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

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  • Engineering & Computer Science (AREA)
  • Electromagnetism (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Photovoltaic Devices (AREA)
  • Electrodes Of Semiconductors (AREA)

Abstract

The invention discloses a kind of methods that laser sintered tinsel prepares the thin gate line electrode of photovoltaic cell, and tinsel is used to substitute traditional method for printing screen as the thin gate line electrode material of photovoltaic cell.Tinsel is attached to photovoltaic cell surface first, then both ends is carried out with silver paste etc. and fixes.Then laser scanning tinsel is used, so that it is melted and is sintered, forms thin gate line electrode on cell piece surface.Using the thin gate line electrode of photovoltaic cell prepared by the present invention, material category range is wide, can be silver, copper, aluminium etc.;The width of gate line electrode is smaller;The material compactness of gate line electrode is good, and after laser sintered and fusion and the bond strength of battery surface is high.

Description

The method that laser sintered tinsel prepares the thin gate line electrode of photovoltaic cell
Technical field
The invention belongs to solar-energy photo-voltaic cell piece fields, particularly relate to a kind of laser sintered tinsel preparation The method of the thin gate line electrode of photovoltaic cell.
Background technique
Gate line electrode is most important structure and material in current photovoltaic cell, and major function is the electricity of collection photovoltaics conversion Stream.Common front gate line electrode includes that main gate line, secondary grid line and thin grid line, width are sequentially reduced.Current gate line electrode is most main The processing method of stream is silk-screen printing.It is promoted to improve the energy conversion efficiency of photovoltaic cell, reduces processing cost, need Screen printing technique is improved.It mainly include at present reducing the width and thickness of thin grid line, to reduce gate line electrode Shading-area and silver paste materials.For thin grid line, width has already decreased to 50 microns hereinafter, this proposes silk screen factor technology Challenge.
Wire prepares the trend that photovoltaic electrode gate line electrode is future.A kind of patent " front of solar battery In electrode structure " (application number 201620380954.4), with wire printer, the basis of silver grating line is brushed in screen printing On, then metal electrode is printed, wire and silver grating line are connected by tin cream.Wire is using materials such as copper, and cost is greatly It reduces.But this method, there are no screen printing technique is abandoned completely, only part uses wire technology, in addition, metal Only being welded by tin cream in individual places between silk and cell piece, connect with silk-screen printing silver grating line.Thus while save A part of electrode material, but collected current ability is to be improved.
Summary of the invention
In order to overcome drawbacks described above, the present invention provides a kind of laser sintered tinsels to prepare the thin grid line of photovoltaic cell The method of electrode is sintered the metal powder grain for being dispersed in photovoltaic cell surface, directly forms the gate electrode of battery.Together When, thinner tinsel is selected, gate line electrode shading-area and metal electrode materials can also be preferably reduced.
The present invention is to solve technical solution used by its technical problem:
A kind of method that laser sintered tinsel prepares the thin gate line electrode of photovoltaic cell, comprising the following steps:
Step 1, prepare tinsel, and do tinsel in a row with fixture, the spacing between tinsel with wait make The spacing for the thin grid line made is consistent;
Step 2, above-mentioned row tinsel is attached to the surface of photovoltaic cell, and the both ends of tinsel are fixed on light It lies prostrate on cell piece, then cuts off the both ends of tinsel, form laterally thin grid line;
Step 3, it is scanned on the tinsel with laser beam, melts tinsel and sintering, obtain lateral thin Gate line electrode;
Step 4, repeat the above steps 1-3, obtains longitudinal thin gate line electrode.
As a further improvement of the present invention, the tinsel in the step 1 be filamentary silver line, aluminium wire line, copper wire line and One of Herba Anoectochili roxburghii.
As a further improvement of the present invention, the diameter of the tinsel in the step 1 is between 10~50 microns.
As a further improvement of the present invention, in the step 2, the tinsel both ends are fixed by silver paste.
As a further improvement of the present invention, in the step 3, the wavelength of the laser beam is 700~1000 nanometers, and Using picosecond pulse.
The beneficial effects of the present invention are: the laser sintered tinsel prepares the method electricity of the thin gate line electrode of photovoltaic cell Pole is good with battery binding force, is the processing method of pure physics;Gate line electrode width can be thinner, is lower than 50 microns, is conducive to subtract The shading-area of few gate line electrode, and save electrode material materials;The present invention prepares the thin grid line of photovoltaic cell with tinsel Electrode, material category range is wide, can be silver, copper, aluminium etc.;The width of gate line electrode is controllable;The material compactness of gate line electrode Good, after laser sintered and fusion and the bond strength of battery surface is high.
Detailed description of the invention
Fig. 1 is method schematic diagram of the invention;
In conjunction with attached drawing, make the following instructions:
1 --- scanning laser beam;2 --- tinsel;
3 --- photovoltaic cell.
Specific embodiment
Below in conjunction with attached drawing, elaborate to a preferred embodiment of the invention.But protection scope of the present invention is not Be limited to following embodiments, i.e., in every case with simple equivalence changes made by scope of the present invention patent and description with repair Decorations, all still belong within the invention patent covering scope.
It refering to fig. 1, is that a kind of laser sintered tinsel of the present invention prepares the thin gate line electrode of photovoltaic cell Method, comprising the following steps:
Step 1, prepare specific tinsel, such as the fine silver silk of 30 micron diameters, and do metal in a row with fixture Silk thread, the spacing between tinsel is according to thin grid line specification institution;
Step 2, above-mentioned row tinsel is attached to the surface of photovoltaic cell, both ends are fixed with silver paste, then cut off The both ends of tinsel form lateral grid line on photovoltaic cell surface;
Step 3, it is scanned on tinsel with laser beam, the wavelength of laser beam is 700~1000 nanometers, and use picosecond Pulse makes tinsel melt and be sintered, obtains lateral thin gate line electrode;
Step 4, repeat the above steps 1-3, obtains longitudinal thin gate line electrode.
Wherein, the tinsel in the step 1 is filamentary silver line, aluminium wire line, copper wire line or Herba Anoectochili roxburghii, but is not limited to This.
Compared to existing silk-screen printing, the tinsel in the present invention prepares thin gate line electrode method, and electrode is in conjunction with battery Power is good, is the processing method of pure physics.In addition, gate line electrode width can be thinner, it is lower than 50 microns.Therefore, it advantageously reduces The shading-area of gate line electrode, and save electrode material materials.

Claims (5)

1. a kind of method that laser sintered tinsel prepares the thin gate line electrode of photovoltaic cell, which is characterized in that including following Step:
Step 1, prepare tinsel, and do tinsel in a row with fixture, the spacing between tinsel and to be produced The spacing of thin grid line is consistent;
Step 2, above-mentioned row tinsel is attached to the surface of photovoltaic cell, and the both ends of tinsel are fixed on photovoltaic electric Then pond on piece cuts off the both ends of tinsel, form laterally thin grid line;
Step 3, it is scanned on above-mentioned tinsel with laser beam, so that tinsel is melted and is sintered, obtain lateral thin grid line Electrode;
Step 4, repeat the above steps 1-3, obtains longitudinal thin gate line electrode.
2. the method that laser sintered tinsel according to claim 1 prepares the thin gate line electrode of photovoltaic cell, special Sign is: the tinsel in the step 1 is one of filamentary silver line, aluminium wire line, copper wire line and Herba Anoectochili roxburghii.
3. the method that laser sintered tinsel according to claim 1 prepares the thin gate line electrode of photovoltaic cell, special Sign is: the diameter of the tinsel in the step 1 is between 10~50 microns.
4. the method that laser sintered tinsel according to claim 1 prepares the thin gate line electrode of photovoltaic cell, special Sign is: in the step 2, the tinsel both ends are fixed by silver paste.
5. the method that laser sintered tinsel according to claim 1 prepares the thin gate line electrode of photovoltaic cell, special Sign is: in the step 3, the wavelength of the laser beam is 700~1000 nanometers, and uses picosecond pulse.
CN201910466066.2A 2019-05-30 2019-05-30 The method that laser sintered tinsel prepares the thin gate line electrode of photovoltaic cell Pending CN110212039A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111276615A (en) * 2020-05-08 2020-06-12 浙江爱旭太阳能科技有限公司 Large-area perovskite solar cell and preparation method
CN114664975A (en) * 2022-03-08 2022-06-24 四川蜀旺新能源股份有限公司 Crystalline silicon solar cell composite electrode and preparation method thereof
CN117410387A (en) * 2023-12-15 2024-01-16 晶澜光电科技(江苏)有限公司 Thin grid structure of crystalline silicon solar cell and preparation method thereof

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US4383164A (en) * 1978-12-16 1983-05-10 Futaba Denshi Kogyo K.K. Method of manufacturing a control grid for fluorescent display tube
US20040097062A1 (en) * 2000-09-19 2004-05-20 Ralf Preu Method of producing a semiconductor-metal contact through a dielectric layer
CN102428573A (en) * 2009-05-20 2012-04-25 纳克公司 Back Contact Solar Cells With Effective And Efficient Design And Corresponding Patterning Processes
CN102956723A (en) * 2011-08-21 2013-03-06 比亚迪股份有限公司 Solar cell and preparation method thereof
CN103918089A (en) * 2011-09-07 2014-07-09 E.I.内穆尔杜邦公司 Process for the production of LFC-PERC silicon solar cells
CN106409930A (en) * 2016-11-04 2017-02-15 上海纳晶科技有限公司 Fine metal wire solar cell grid and preparation method thereof
CN106409953A (en) * 2016-11-04 2017-02-15 上海纳晶科技有限公司 Solar cell film-coated copper wire gate current collector structure and preparation method thereof
CN107946381A (en) * 2017-10-31 2018-04-20 泰州隆基乐叶光伏科技有限公司 The preparation method of electrode of solar battery
CN108878591A (en) * 2018-07-02 2018-11-23 通威太阳能(安徽)有限公司 A kind of laser sintering processes of crystal silicon solar batteries metal electrode

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4383164A (en) * 1978-12-16 1983-05-10 Futaba Denshi Kogyo K.K. Method of manufacturing a control grid for fluorescent display tube
US20040097062A1 (en) * 2000-09-19 2004-05-20 Ralf Preu Method of producing a semiconductor-metal contact through a dielectric layer
CN102428573A (en) * 2009-05-20 2012-04-25 纳克公司 Back Contact Solar Cells With Effective And Efficient Design And Corresponding Patterning Processes
CN102956723A (en) * 2011-08-21 2013-03-06 比亚迪股份有限公司 Solar cell and preparation method thereof
CN103918089A (en) * 2011-09-07 2014-07-09 E.I.内穆尔杜邦公司 Process for the production of LFC-PERC silicon solar cells
CN106409930A (en) * 2016-11-04 2017-02-15 上海纳晶科技有限公司 Fine metal wire solar cell grid and preparation method thereof
CN106409953A (en) * 2016-11-04 2017-02-15 上海纳晶科技有限公司 Solar cell film-coated copper wire gate current collector structure and preparation method thereof
CN107946381A (en) * 2017-10-31 2018-04-20 泰州隆基乐叶光伏科技有限公司 The preparation method of electrode of solar battery
CN108878591A (en) * 2018-07-02 2018-11-23 通威太阳能(安徽)有限公司 A kind of laser sintering processes of crystal silicon solar batteries metal electrode

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111276615A (en) * 2020-05-08 2020-06-12 浙江爱旭太阳能科技有限公司 Large-area perovskite solar cell and preparation method
CN114664975A (en) * 2022-03-08 2022-06-24 四川蜀旺新能源股份有限公司 Crystalline silicon solar cell composite electrode and preparation method thereof
CN117410387A (en) * 2023-12-15 2024-01-16 晶澜光电科技(江苏)有限公司 Thin grid structure of crystalline silicon solar cell and preparation method thereof
CN117410387B (en) * 2023-12-15 2024-02-09 晶澜光电科技(江苏)有限公司 Thin grid structure of crystalline silicon solar cell and preparation method thereof

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Application publication date: 20190906

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