CN110185164B - 一种超低能耗建筑用节能保温板及其制备方法 - Google Patents
一种超低能耗建筑用节能保温板及其制备方法 Download PDFInfo
- Publication number
- CN110185164B CN110185164B CN201910556198.4A CN201910556198A CN110185164B CN 110185164 B CN110185164 B CN 110185164B CN 201910556198 A CN201910556198 A CN 201910556198A CN 110185164 B CN110185164 B CN 110185164B
- Authority
- CN
- China
- Prior art keywords
- energy
- heat
- insulating
- insulation board
- ultralow
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000005265 energy consumption Methods 0.000 title claims abstract description 33
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 238000009413 insulation Methods 0.000 claims abstract description 82
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000007788 liquid Substances 0.000 claims abstract description 26
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000003063 flame retardant Substances 0.000 claims abstract description 25
- 239000012774 insulation material Substances 0.000 claims abstract description 19
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims abstract description 14
- 239000004744 fabric Substances 0.000 claims abstract description 11
- 239000003365 glass fiber Substances 0.000 claims abstract description 11
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000010459 dolomite Substances 0.000 claims abstract description 9
- 229910000514 dolomite Inorganic materials 0.000 claims abstract description 9
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 9
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 9
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000843 powder Substances 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 238000000465 moulding Methods 0.000 claims abstract description 7
- 230000000149 penetrating effect Effects 0.000 claims abstract description 4
- 239000000835 fiber Substances 0.000 claims description 18
- 238000010438 heat treatment Methods 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 10
- 239000001307 helium Substances 0.000 claims description 8
- 229910052734 helium Inorganic materials 0.000 claims description 8
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 8
- 230000008595 infiltration Effects 0.000 claims description 6
- 238000001764 infiltration Methods 0.000 claims description 6
- 239000011325 microbead Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 238000012545 processing Methods 0.000 claims description 6
- 238000003860 storage Methods 0.000 claims description 6
- 239000002939 oilproofing Substances 0.000 claims description 5
- 239000000853 adhesive Substances 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 claims description 4
- 238000011049 filling Methods 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- 230000009471 action Effects 0.000 claims description 3
- 239000010426 asphalt Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 238000007789 sealing Methods 0.000 claims description 3
- 239000011230 binding agent Substances 0.000 claims description 2
- 239000012530 fluid Substances 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims description 2
- 230000006835 compression Effects 0.000 abstract description 5
- 238000007906 compression Methods 0.000 abstract description 5
- 238000004321 preservation Methods 0.000 abstract description 4
- 230000000979 retarding effect Effects 0.000 abstract 1
- 238000007493 shaping process Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 17
- 238000012360 testing method Methods 0.000 description 11
- 238000005336 cracking Methods 0.000 description 5
- 239000011810 insulating material Substances 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 3
- 230000032683 aging Effects 0.000 description 3
- 239000012298 atmosphere Substances 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000004888 barrier function Effects 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 239000004519 grease Substances 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000012466 permeate Substances 0.000 description 3
- -1 polypropylene Polymers 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 229920006037 cross link polymer Polymers 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 229920005646 polycarboxylate Polymers 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 229920001410 Microfiber Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000006261 foam material Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- YLGXILFCIXHCMC-JHGZEJCSSA-N methyl cellulose Chemical group COC1C(OC)C(OC)C(COC)O[C@H]1O[C@H]1C(OC)C(OC)C(OC)OC1COC YLGXILFCIXHCMC-JHGZEJCSSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/03—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on magnesium oxide, calcium oxide or oxide mixtures derived from dolomite
- C04B35/04—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on magnesium oxide, calcium oxide or oxide mixtures derived from dolomite based on magnesium oxide
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/71—Ceramic products containing macroscopic reinforcing agents
- C04B35/78—Ceramic products containing macroscopic reinforcing agents containing non-metallic materials
- C04B35/80—Fibres, filaments, whiskers, platelets, or the like
- C04B35/82—Asbestos; Glass; Fused silica
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/4505—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements characterised by the method of application
- C04B41/4535—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements characterised by the method of application applied as a solution, emulsion, dispersion or suspension
- C04B41/4539—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements characterised by the method of application applied as a solution, emulsion, dispersion or suspension as a emulsion, dispersion or suspension
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
- E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
- E04B1/78—Heat insulating elements
- E04B1/80—Heat insulating elements slab-shaped
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/52—Sound-insulating materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/349—Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/36—Glass starting materials for making ceramics, e.g. silica glass
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/442—Carbonates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/658—Atmosphere during thermal treatment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
- C04B2235/9607—Thermal properties, e.g. thermal expansion coefficient
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A30/00—Adapting or protecting infrastructure or their operation
- Y02A30/24—Structural elements or technologies for improving thermal insulation
- Y02A30/242—Slab shaped vacuum insulation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B80/00—Architectural or constructional elements improving the thermal performance of buildings
- Y02B80/10—Insulation, e.g. vacuum or aerogel insulation
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Physics & Mathematics (AREA)
- Architecture (AREA)
- Manufacturing & Machinery (AREA)
- Acoustics & Sound (AREA)
- Electromagnetism (AREA)
- Civil Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Building Environments (AREA)
Abstract
本发明公开了一种超低能耗建筑用节能保温板，包括保温板本体，所述保温板本体由以下重量份的原料组成：白云石粉20~30份，滑石粉5~10份，膨胀玻化微珠3~10份，氧化镁40~50份，减水剂0.1~0.3份，抗裂剂0.15~0.25份，保水剂0.2~0.5份，玻璃丝布5~7份；所述保温板本体的内部间隙均匀分布有液体阻燃剂；所述保温板本体的内部穿设有若干“X”型的线管，若干所述线管在保温板本体的内部均匀分布，所述线管的内部填充有隔音材料，所述线管的两端均与保温板本体的外表面连接；本发明还涉及一种超低能耗建筑用节能保温板的制备方法，包括：备料、制模、成型处理、阻燃处理、隔音处理等步骤。本发明的一种超低能耗建筑用节能保温板能够阻燃、隔音和保温，同时还具备优良的抗压性。
Description
技术领域
本发明涉及建筑材料领域，具体是一种超低能耗建筑用节能保温板及其制备方法。
背景技术
随着经济发展与资源环境矛盾的日趋尖锐，人们环保意识的日益增强，节能环保新材料成为人们的研究热点。目前，建筑的节能保温作为世界建筑发展的一个趋向和当代科学技术的一个新的生长点，对我国实现可持续发展具有重要的意义。
现今，我国建筑物的墙体保温板主要为EPS板、XPS板、PU板和无机保温板等。其中，EPS板、XPS板、PU板均属于有机保温板，其保温材料性能优越，且具备质轻、保温、隔热性好等优点；无机保温板具备极佳的温度稳定性和化学稳定性，有耐酸碱、耐腐蚀、不开裂、不脱落、稳定性高不老化等优点。
但是，目前的墙体的保温板还存在以下重大缺陷：
1.有机保温材料的防火安全性差，易老化，燃烧时烟雾大、毒性大，而施工过程中时常会出现电焊、明火等情况，因此具备引发火灾的重大隐患；
2.无机保温材料的重量重、强度差，不仅施工过程的难度大、成本高，而且极易损坏；
3.由于保温板中一般含有轻质泡沫材料，这些腔体在遭受到重物撞击时会发生变形，影响建筑的美观；同时保温板的拆装和更换操作繁琐，费时费力。
中国专利文献CN200710031860.1，申请日20071130，名称为：改性玻化微珠保温隔热砂浆及其制备方法，公开了一种以有机硅憎水剂处理低品质玻化微珠，再采用改性后的玻化微珠制备出改性玻化微珠保温隔热砂浆的技术方案。
上述专利对膨胀玻化微珠的表面进行了疏水化改性，但关于一种能够阻燃、隔音，并且具备优良的抗压性的节能保温板的技术方案则尚未提出。
发明内容
本发明的目的在于克服现有技术的不足，提供一种超低能耗建筑用节能保温板，以至少达到能够阻燃、隔音和保温，并且具备优良的抗压性的效果。
本发明的另一目的在于提供一种超低能耗建筑用节能保温板的制备方法。
本发明的目的是通过以下技术方案来实现的：一种超低能耗建筑用节能保温板，包括保温板本体，所述保温板本体由以下重量份的原料组成：白云石粉20～30份，滑石粉5～10份，膨胀玻化微珠3～10份，氧化镁40～50份，减水剂0.1～0.3份，抗裂剂0.15～0.25份，保水剂0.2～0.5份，玻璃丝布5～7份；所述保温板本体的内部间隙均匀分布有液体阻燃剂。
通过上述技术方案，在所述原料中添加了膨胀玻化微珠，利用了所述膨胀玻化微珠质轻、隔热防火、耐高低温、抗老化和吸水率小等优点，达到了增强保温板的功能的效果；另外，所述抗裂剂和玻璃丝布的增加，达到了提高保温板的防裂性的效果；除此之外，液体阻燃剂的添加提高了所述保温板本体的阻燃性。
优选的，所述保温板本体由以下重量份的原料组成：白云石粉25份，滑石粉8份，膨胀玻化微珠7份，氧化镁45份，减水剂0.2份，抗裂剂0.2份，保水剂0.3份，玻璃丝布6份。
优选的，所述保温板本体的内部穿设有若干“X”型的线管，若干所述线管在保温板本体的内部均匀分布，所述线管的内部填充有隔音材料，所述线管的两端均与保温板本体的外表面连接。
通过上述技术方案，若干“X”型的线管在所述保温板本体之间形成了两个三角形的支撑力矩，大大提高了所述保温板本体的抗压强度，达到提高所述保温板本体的抗压性的效果；与此同时，在所述线管中填充隔音材料，达到了提高所述保温板本体的隔音能力的效果。
优选的，所述隔音材料由超细纤维、熔融纤维经过防水防油处理后，混合加工而成。
通过上述技术方案，对所述隔音材料进行防水防油处理，达到了提升所述隔音材料的使用寿命的效果。
优选的，所述保温板本体的外部包裹有高阻隔薄膜，所述高阻隔薄膜的周边和保温板的周边粘合构成密封边。
通过上述技术方案，所述高阻隔薄膜紧紧密贴合所述保温板本体，提高了所述保温板本体的阻隔性能。
一种超低能耗建筑用节能保温板的制备方法，包括以下步骤：
S1.备料：按重量份计，取白云石粉20～30份，滑石粉5～10份，膨胀玻化微珠3～10份，氧化镁40～50份，减水剂0.1～0.3份，抗裂剂0.15～0.25份，保水剂0.2～0.5份，玻璃丝布5～7份，将其加入溶剂35～40份中并搅拌均匀得到预处理料，所述溶剂为水；
S2.制模：在保温板成型模具上预留若干用于容纳所述线管的空腔；
S3.成型处理：将所述预处理料置于所述保温板成型模具内，并压实抚平，将所述保温板成型模具和物料同时置于加热装置内加热成型得到预成型板材，再将所述预成型板材脱模并置于加热装置中，同时向所述加热装置中通入氦气，使其烧结成型，得到成型板材；使烧结过程在氦气氛围中进行，可以避免氧气和化学物质进行反应，降低所述成型板材中有机物组分的含量；
S4.阻燃处理：将所述成型板材置于真空渗透设备内，使其一侧为抽真空区域，另一侧为渗透液存储区；将液体阻燃剂加入所述渗透液存储区，并在所述抽真空区进行抽真空工作，使所述液体阻燃剂在负压作用下渗透所述成型板材，干燥得到保温板材；使用抽真空的方式渗透液体阻燃剂，可以使其在负压的条件下充分的填满所述成型板材的空隙，提高制得的保温板本体的阻燃性能；
S5.隔音处理：向所述线管中填充所述隔音材料，然后将所述线管放入预留的空腔内，并用粘结剂将所述线管的两端与保温板材的外表面粘连；
S6.包裹：将所述高阻隔薄膜包裹在S5中得到的保温板材的外表面，并抽真空使其紧密贴合，得到所述保温板本体；通过添加高阻隔薄膜，提高了制得的保温板本体的阻隔性。
优选的，在S3中，所述加热装置包括但不限于微波炉、烘箱、马弗炉。
优选的，在S3中，通入所述氦气的流速为30～100ml/min。
通过上述技术方案，使烧结过程在充分的氦气氛围下进行，防止化学物质与氧气反应，达到了降低所述保温板本体中有机物组分的含量的效果。
优选的，在S5中，所述隔音材料由超细纤维、熔融纤维在喷洒三防液进行防水防油处理之后，按重量比为70～80:20～30混合加工而成。
通过上述技术方案，通过三防液对所述超细纤维和熔融纤维进行防水防油处理，可以在不影响吸引效果的同时，提升所述隔音材料的防水防油的功效，达到了提升所述隔音材料的使用寿命的效果。
优选的，在S5中，所述粘结剂为乳化沥青。
本发明的有益效果是：
1.本发明的一种超低能耗建筑用节能保温板，在所述原料中添加了膨胀玻化微珠，利用了所述膨胀玻化微珠质轻、隔热防火、耐高低温、抗老化和吸水率小等优点，达到了增强保温板的功能的效果；另外，所述抗裂剂和玻璃丝布的增加，达到了提高保温板防裂性的效果。
2.本发明的一种超低能耗建筑用节能保温板，在所述保温板本体中设置了若干“X”型的线管，所述线管在所述保温板本体之间形成了两个三角形的支撑力矩，大大提高了所述保温板本体的抗压强度，达到提高所述保温板本体的抗压性的效果；与此同时，在所述线管内部填充了隔音材料，达到了提高所述保温板本体的隔音能力的效果。
3.本发明的一种超低能耗建筑用节能保温板的制备方法，使加热装置在氦气氛围中进行烧结，避免了氧气和保温板中的化学物质进行反应，达到了降低所述成型板材中有机物组分的含量的效果。
4.本发明的一种超低能耗建筑用节能保温板的制备方法，使用抽真空的方式令所述液体阻燃剂渗透到所述成型板材的空隙，达到了使其充分填充从而提高所述保温板本体的阻燃性能的效果。
附图说明
图1为本发明中所述超低能耗建筑用节能保温板的结构示意图。
图中，1、保温板本体；2、线管；3、高阻隔薄膜；4、隔音材料；。
具体实施方式
下面结合附图进一步详细描述本发明的技术方案，但本发明的保护范围不局限于以下所述。
实施例1
一种超低能耗建筑用节能保温板，包括保温板本体1，保温板本体1由以下重量份的原料组成：白云石粉25份，滑石粉8份，膨胀玻化微珠7份，氧化镁45份，减水剂0.2份，抗裂剂0.2份，保水剂0.3份，玻璃丝布6份；其中，减水剂为聚羧酸减水剂，抗裂剂为聚丙烯抗裂纤维，保水剂为丙烯酰胺-丙烯酸盐共聚交联物。保温板本体1的内部间隙均匀分布有液体阻燃剂，液体阻燃剂采用TL-1液体阻燃剂。
实施例2
一种超低能耗建筑用节能保温板，包括保温板本体1，保温板本体1由以下重量份的原料组成：白云石粉20份，滑石粉5份，膨胀玻化微珠5份，氧化镁40份，减水剂0.1份，抗裂剂0.15份，保水剂0.2份，玻璃丝布5份；其中，减水剂为萘系磺酸盐亚甲基高级缩合物，抗裂剂为聚丙烯抗裂纤维，保水剂为甲基纤维素醚。保温板本体1的内部间隙均匀分布有液体阻燃剂，液体阻燃剂采用TL-1液体阻燃剂。
实施例3
如图1所示，一种超低能耗建筑用节能保温板，包括保温板本体1，保温板本体1的内部均匀穿设有若干“X”型的线管2，线管2的内部填充有由超细纤维、熔融纤维在喷洒三防液进行防水防油处理之后，按重量比为70:20混合加工而成的隔音材料4；通过“X”型的线管2在保温板本体1之间形成的两个三角形的支撑力矩提升了保温板本体1的抗压性，与此同时，填充的隔音材料4提升了保温板本体1的隔音效果。线管2的两端均与保温板本体1的外表面连接。保温板本体1的外部包裹有高阻隔薄膜3，高阻隔薄膜3的周边和保温板的周边粘合构成密封边，提高了保温板本体1的阻隔性。
实施例4
一种超低能耗建筑用节能保温板的制备方法，包括以下步骤：
S1.备料：按重量份计，白云石粉25份，滑石粉8份，膨胀玻化微珠7份，氧化镁45份，减水剂0.2份，抗裂剂0.2份，保水剂0.3份，玻璃丝布6份，将其加入水35份中并搅拌均匀得到预处理料；其中，减水剂为聚羧酸减水剂，抗裂剂为聚丙烯抗裂纤维，保水剂为丙烯酰胺-丙烯酸盐共聚交联物；
S2.制模：在保温板成型模具上预留若干用于容纳线管2的空腔；
S3.成型处理：将预处理料置于保温板成型模具内，并压实抚平，将保温板成型模具和物料同时置于马弗炉内，在200℃下加热15min成型得到预成型板材；再将预成型板材脱模并置于马弗炉中，同时向马弗炉中以50ml/min的流速通入氦气，在800℃下加热3h使其烧结成型，得到成型板材；
S4.阻燃处理：将成型板材置于真空渗透设备内，使其一侧为抽真空区域，另一侧为渗透液存储区；将TL-1液体阻燃剂加入渗透液存储区，并在抽真空区进行抽真空工作，使TL-1液体阻燃剂在负压作用下渗透成型板材，干燥得到保温板材；
S5.隔音处理：向若干线管2中填充由喷洒了三防液的超细纤维和熔融纤维按重量比为70:20混合加工而成的隔音材料4，然后将若干线管2放入预留的空腔内，并用粘结剂将线管2的两端与保温板材的外表面粘连，粘结剂为乳化沥青；
S6.包裹：将高阻隔薄膜3包裹在由S5得到的保温板材的外表面，并抽真空使其紧密贴合，得到保温板本体1。
试验效果
1.为了验证本发明的一种超低能耗建筑用节能保温板的性能，进行了对比试验。试验将保温板分为对照组A、对照组B和实验组3组，其中实验组为采用实施例4中的制备方法得到的保温板，对照组A采用市面上常用的保温板，对照组B采用市面上常用的防火板，实验组、对照组A和对照组B的保温板的厚度均为50mm。试验在相同条件下对实验组、对照组A和对照组B进行了性能测试，结果如下表所示：
由于保温板的导热系数越低，保温性能越好；抗压强度越高，抗压性越好；耐火时长越久，阻燃性能越好。
通过上述对比试验可以得出，本发明的一种超低能耗建筑用节能保温板的保温性能在略高于市面上常用的保温板的同时，耐火极限、抗压强度和隔音性能都大大优于市面上常用的保温板；除此之外，本发明的一种超低能耗建筑用节能保温板的防火性能在略高于市面上常用的防火板的同时，保温性能、抗压强度和隔音性能都明显优于市面上常用的防火板。
2.为了验证本发明的一种超低能耗建筑用节能保温板对抗压性的提升，进行了对比试验。试验将保温板分为对照组和实验组2组；其中实验组为采用本实施例4中的制备方法得到的保温板，对照组为采用本实施例4中除去S2和S4步骤，但同样添加了隔音材料的制备方法得到的保温板，即对照组中的保温板未设置“X”型线管。实验组和对照组的保温板厚度均为50mm。试验在相同条件下，对实验组和对照组进行了抗压性测试，结果如下表所示：
通过上述对比试验可以得出，本发明的一种超低能耗建筑用节能保温板的抗压强度相比于未添加“X”型线管的保温板，抗压性得到了显著的提高。
综上所述，本发明的一种超低能耗建筑用节能保温板不仅能够阻燃、隔音，还具备优良的抗压性。
以上所述仅是本发明的优选实施方式，应当理解本发明并非局限于本文所披露的形式，不应看作是对其他实施例的排除，而可用于各种其他组合、修改和环境，并能够在本文所述构想范围内，通过上述教导或相关领域的技术或知识进行改动。而本领域人员所进行的改动和变化不脱离本发明的精神和范围，则都应在本发明所附权利要求的保护范围内。
Claims (8)
1.一种超低能耗建筑用节能保温板的制备方法，其特征在于：
所述保温板包括保温板本体(1)，所述保温板本体(1)的内部穿设有若干“X”型的线管(2)，若干所述线管(2)在保温板本体(1)的内部均匀分布，所述线管(2)的内部填充有隔音材料(4)，所述线管(2)的两端均与保温板本体(1)的外表面连接；
所述保温板的制备方法包括以下步骤：
S1.备料：按重量份计，取白云石粉20～30份，滑石粉5～10份，膨胀玻化微珠3～10份，氧化镁40～50份，减水剂0.1～0.3份，抗裂剂0.15～0.25份，保水剂0.2～0.5份，玻璃丝布5～7份，将其加入溶剂35～40份中并搅拌均匀得到预处理料，所述溶剂为水；
S2.制模：在保温板成型模具上预留若干用于容纳所述线管(2)的空腔；
S3.成型处理：将所述预处理料置于所述保温板成型模具内，并压实抚平，将所述保温板成型模具和物料同时置于加热装置内加热成型得到预成型板材，再将所述预成型板材脱模并置于加热装置中，同时向所述加热装置中通入氦气，使其烧结成型，得到成型板材；
S4.阻燃处理：将所述成型板材置于真空渗透设备内，使其一侧为抽真空区域，另一侧为渗透液存储区；将液体阻燃剂加入所述渗透液存储区，并在所述抽真空区进行抽真空工作，使所述液体阻燃剂在负压作用下渗透所述成型板材，干燥得到保温板材；
S5.隔音处理：向所述线管(2)中填充所述隔音材料(4)，然后将所述线管(2)放入预留的空腔内，并用粘结剂将所述线管(2)的两端与保温板材的外表面粘连；
S6.包裹：将高阻隔薄膜(3)包裹在S5中得到的保温板材的外表面，并抽真空使其紧密贴合，得到所述保温板本体(1)。
2.根据权利要求1所述的一种超低能耗建筑用节能保温板的制备方法，其特征在于：在S3中，所述加热装置包括但不限于微波炉、烘箱、马弗炉。
3.根据权利要求1所述的一种超低能耗建筑用节能保温板的制备方法，其特征在于：在S3中，通入所述氦气的流速为30～100ml/min。
4.根据权利要求1所述的一种超低能耗建筑用节能保温板的制备方法，其特征在于：在S5中，所述隔音材料(4)由超细纤维、熔融纤维在喷洒三防液进行防水防油处理之后，按重量比为70～80:20～30混合加工而成。
5.根据权利要求1所述的一种超低能耗建筑用节能保温板的制备方法，其特征在于：在S5中，所述粘结剂为乳化沥青。
6.根据权利要求1所述的一种超低能耗建筑用节能保温板的制备方法，其特征在于：所述保温板本体(1)由以下重量份的原料组成：白云石粉25份，滑石粉8份，膨胀玻化微珠7份，氧化镁45份，减水剂0.2份，抗裂剂0.2份，保水剂0.3份，玻璃丝布6份。
7.根据权利要求1所述的一种超低能耗建筑用节能保温板的制备方法，其特征在于：所述隔音材料(4)由超细纤维、熔融纤维经过防水防油处理后，混合加工而成。
8.根据权利要求1所述的一种超低能耗建筑用节能保温板的制备方法，其特征在于：所述保温板本体(1)的外部包裹有高阻隔薄膜(3)，所述高阻隔薄膜(3)的周边和保温板的周边粘合构成密封边。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910556198.4A CN110185164B (zh) | 2019-06-25 | 2019-06-25 | 一种超低能耗建筑用节能保温板及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910556198.4A CN110185164B (zh) | 2019-06-25 | 2019-06-25 | 一种超低能耗建筑用节能保温板及其制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN110185164A CN110185164A (zh) | 2019-08-30 |
| CN110185164B true CN110185164B (zh) | 2024-04-23 |
Family
ID=67723453
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910556198.4A Active CN110185164B (zh) | 2019-06-25 | 2019-06-25 | 一种超低能耗建筑用节能保温板及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110185164B (zh) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN118007816B (zh) * | 2024-04-10 | 2024-06-14 | 山东雅涂新材料有限责任公司 | 结构防火保温板及其生产工艺 |
Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07300913A (ja) * | 1994-05-09 | 1995-11-14 | Riboole:Kk | 軽量断熱防火パネル |
| JP2004190215A (ja) * | 2002-12-06 | 2004-07-08 | Kawakami Sangyo Co Ltd | 断熱ボード |
| CN102093032A (zh) * | 2010-12-24 | 2011-06-15 | 北京工业大学 | 一种轻质耐火板的制造方法 |
| CN102493594A (zh) * | 2011-12-06 | 2012-06-13 | 上海大秦新型建材有限公司 | 一种高强度轻质墙板 |
| CN102808459A (zh) * | 2012-08-16 | 2012-12-05 | 青岛煜志机械科技有限公司 | 一种防火保温板及其制备工艺 |
| WO2013029368A1 (zh) * | 2011-08-31 | 2013-03-07 | 青岛科瑞新型环保材料有限公司 | 外墙高效节能防火保温板及其制备方法 |
| CN103030357A (zh) * | 2011-09-29 | 2013-04-10 | 深圳市爱思宝科技发展有限公司 | 一种保温隔热浆料组合物及其应用 |
| KR101683141B1 (ko) * | 2015-07-23 | 2016-12-07 | 이영대 | 난연성이 부여된 단열재 조성물 및 이를 이용한 건축용 단열재 제조방법 |
| CN107265942A (zh) * | 2017-06-22 | 2017-10-20 | 合肥永泰新型建材有限公司 | 一种保温材料及其制备方法 |
| CN108264326A (zh) * | 2018-02-05 | 2018-07-10 | 合肥华盖光伏科技有限公司 | 一种轻质建筑防火保温板 |
| CN108300290A (zh) * | 2018-01-24 | 2018-07-20 | 合肥万之景门窗有限公司 | 一种保温环保金属门窗用涂料及其制备方法 |
| CN108467262A (zh) * | 2018-04-20 | 2018-08-31 | 佛山汇众森泰科技有限公司 | 一种生活家具用陶瓷及其加工工艺 |
| WO2018176726A1 (zh) * | 2017-03-27 | 2018-10-04 | 苏州顶裕节能设备有限公司 | 一种用于建筑物的节能保温材料及其制备方法 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060234027A1 (en) * | 2005-04-18 | 2006-10-19 | Huusken Robert W | Fire retardant laminate |
| CN103979918B (zh) * | 2014-05-30 | 2016-06-01 | 秦菊霞 | 一种纤维增强防火保温板及其制备工艺 |
-
2019
- 2019-06-25 CN CN201910556198.4A patent/CN110185164B/zh active Active
Patent Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07300913A (ja) * | 1994-05-09 | 1995-11-14 | Riboole:Kk | 軽量断熱防火パネル |
| JP2004190215A (ja) * | 2002-12-06 | 2004-07-08 | Kawakami Sangyo Co Ltd | 断熱ボード |
| CN102093032A (zh) * | 2010-12-24 | 2011-06-15 | 北京工业大学 | 一种轻质耐火板的制造方法 |
| WO2013029368A1 (zh) * | 2011-08-31 | 2013-03-07 | 青岛科瑞新型环保材料有限公司 | 外墙高效节能防火保温板及其制备方法 |
| CN103030357A (zh) * | 2011-09-29 | 2013-04-10 | 深圳市爱思宝科技发展有限公司 | 一种保温隔热浆料组合物及其应用 |
| CN102493594A (zh) * | 2011-12-06 | 2012-06-13 | 上海大秦新型建材有限公司 | 一种高强度轻质墙板 |
| CN102808459A (zh) * | 2012-08-16 | 2012-12-05 | 青岛煜志机械科技有限公司 | 一种防火保温板及其制备工艺 |
| KR101683141B1 (ko) * | 2015-07-23 | 2016-12-07 | 이영대 | 난연성이 부여된 단열재 조성물 및 이를 이용한 건축용 단열재 제조방법 |
| WO2018176726A1 (zh) * | 2017-03-27 | 2018-10-04 | 苏州顶裕节能设备有限公司 | 一种用于建筑物的节能保温材料及其制备方法 |
| CN107265942A (zh) * | 2017-06-22 | 2017-10-20 | 合肥永泰新型建材有限公司 | 一种保温材料及其制备方法 |
| CN108300290A (zh) * | 2018-01-24 | 2018-07-20 | 合肥万之景门窗有限公司 | 一种保温环保金属门窗用涂料及其制备方法 |
| CN108264326A (zh) * | 2018-02-05 | 2018-07-10 | 合肥华盖光伏科技有限公司 | 一种轻质建筑防火保温板 |
| CN108467262A (zh) * | 2018-04-20 | 2018-08-31 | 佛山汇众森泰科技有限公司 | 一种生活家具用陶瓷及其加工工艺 |
Non-Patent Citations (4)
| Title |
|---|
| 新型墙体材料与保温体系的发展思路;屈宏乐;;砖瓦世界;20100131(01);31-36 * |
| 玻化微珠酚醛树脂粉末复合保温浆料的研制;李聚刚;;上海建材;20130630(03);28-31 * |
| 聚苯乙烯隔热保温板在建筑外墙的应用;熊燕等;《合成树脂及塑料》;20181231;87-88 * |
| 膨胀玻化微珠保温板性能试验研究;白玉星等;新型建筑材料;20170831(08);156-158 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN110185164A (zh) | 2019-08-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110922095A (zh) | 一种复合二氧化硅气凝胶毡的制备方法 | |
| CN109020370B (zh) | 一种带防腐涂层的钢结构外墙用界面砂浆 | |
| CN108585924B (zh) | 一种由珍珠岩粉常温发泡制备的新型无机保温板及其制备方法 | |
| CN110185164B (zh) | 一种超低能耗建筑用节能保温板及其制备方法 | |
| CN107619224A (zh) | 一种抗裂保温的再生骨料砂浆及其制备方法 | |
| CN111517708A (zh) | 一种石墨改性聚苯乙烯无机保温板及其制备方法 | |
| CN207032530U (zh) | 一种建筑用保温隔音墙 | |
| CN103821239B (zh) | 一种阻燃的纳米孔SiO2多级复合绝热板及其制备方法 | |
| CN102775097A (zh) | 无机纤维防火保温板 | |
| CN104070717B (zh) | 彩钢夹芯板及其制备方法 | |
| CN108164243B (zh) | 硅酸铝纤维多用食品电磁加热保温套筒 | |
| CN105399439A (zh) | 一种无机发泡保温板及其制备方法 | |
| CN110950625A (zh) | 一种新型可膨胀防火封堵材料的制备及应用 | |
| CN103319149B (zh) | 建筑用真空绝热板内的低导热性保温芯板及其制备工艺 | |
| CN105622164A (zh) | 一种中空微孔无机保温砂浆 | |
| CN104909678A (zh) | 一种ky无机活性保温砂浆及其制备方法 | |
| CN103244028A (zh) | 一种耐高温防火门芯板 | |
| CN205329982U (zh) | 一体化发泡混凝土墙板 | |
| CN103422582A (zh) | 陶瓷复合真空隔热板及其制备方法 | |
| CN203334530U (zh) | 一种新型水泥发泡复合保温板 | |
| CN103360022B (zh) | 一种憎水烤制型复合硅酸盐瓦及其制备工艺 | |
| CN202899324U (zh) | 复合发泡水泥外墙保温系统 | |
| CN102674755A (zh) | 一种建筑用均质复合防火保温板 | |
| CN111592291A (zh) | 新型fbt-x稀土系列复合保温材料及其制备方法 | |
| CN111098569A (zh) | 一种保温隔热用气凝胶夹心材料及其制备方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |