CN110158318A - A kind of dress ornament antibacterial crease-resistant type finishing agent and its method for sorting - Google Patents
A kind of dress ornament antibacterial crease-resistant type finishing agent and its method for sorting Download PDFInfo
- Publication number
- CN110158318A CN110158318A CN201910471399.4A CN201910471399A CN110158318A CN 110158318 A CN110158318 A CN 110158318A CN 201910471399 A CN201910471399 A CN 201910471399A CN 110158318 A CN110158318 A CN 110158318A
- Authority
- CN
- China
- Prior art keywords
- parts
- finishing agent
- dress ornament
- crease
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
- D06M11/57—Sulfates or thiosulfates of elements of Groups 3 or 13 of the Periodic System, e.g. alums
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/368—Hydroxyalkylamines; Derivatives thereof, e.g. Kritchevsky bases
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
Abstract
The invention discloses a kind of dress ornament antibacterial crease-resistant type finishing agents and its method for sorting, antibacterial crease-resistant type finishing agent includes the raw material of following parts by weight: natural 30~50 parts of crease-resistant liquid, 10~20 parts of aqueous polyurethane, 5~10 parts of aluminum sulfate, 10~15 parts of cactus extraction, 10~15 parts of Nano silver solution, 1~3 part of methylene-bisacrylamide, 1~2 part of nanoscale silicone oil and 80~120 parts of water, the antibacterial crease-resistant method for sorting of dress ornament, comprising: 1. prerinse；2. drying；3. making finishing agent；4. finishing agent arranges: finishing agent pressurizing atomizing being sprayed on ready-made clothes using spraying machine, makes the liquid carrying rate 70~90% of shirt；5. softening: ready-made clothes is put into 20~30min of immersion in diluted vinegar；6. washing；7. ironing is formed.Finishing agent produced by the present invention can not only assign the good wrinkle resistance of dress ornament, easy-care properties, antibacterial and deodouring, and cooperate the recovery capacity of specific technical data and unique finishing agent enhancing dress ornament itself, keep persistently smooth indeformable.
Description
Technical field
The invention belongs to garment production processing technique fields, and in particular to a kind of antibacterial crease-resistant type finishing agent of dress ornament and its
Method for sorting.
Background technique
With the improvement of the quality of life, requirement of the people to dress-goods is also higher and higher, in addition to fashionable, clothes
The comfort of product, functionality and environmental issue during manufacturing are increasingly by manufacturing person and consumer
Pay attention to.Meanwhile the nursing of dress-goods also becomes more and more important, and especially proposes higher want to the health aspect of clothes
It asks.In recent years, increasingly extensive for the research of antibacterial crease-resistant dress ornament.Even to this day, people have developed some use
In the antibacterial finishing agent of garment production and daily nursing, the resistance finishing agent can be mainly divided into inorganic, organic and day
Right three kinds.Early stage antibacterial agent belongs to organic series substantially, is all kinds of complex compounds of the elements such as nitrogenous, sulphur, chlorine mostly,
Principal item has: quaternary ammonium salt, biguanides, alcohols, phenols, aldehydes, organic metal class, arsenic pyridine class, thiophene-based etc., such is anti-
The short-term bactericidal effect of microbial inoculum is good, but has the shortcomings that heat-resistant stability is poor, the service life is short mostly；In the 21st century, is especially close several
Nian Lai, wherein most of is natural or inorganic antiseptic, natural antibacterial agent is resourceful, biodegradable, absorbent properties are good, nothing
Machine antibacterial finishing agent has a performances such as good antibiotic property, broad spectrum activity, long-term effect, weatherability, drug resistance, safety, but due to
Existing natural antibacterial agent and inorganic antiseptic use at the unreasonable of assignment configuration and finishing technique, in the process used
In, it is poor with the bridging property of clothing fabric, with increasing for dress ornament washing times, biocidal property and crease-resistant function all can greatly under
Drop.Therefore, develop that a kind of formula is unique rationally, stability is strong, at low cost, antibacterial time is lasting, anti-wrinkle effect is significant, dirt
Contaminating small, energy wearing comfort dress ornament with antibacterial crease-resistant type finishing agent and its method for sorting is desirability.
Summary of the invention
In order to solve the problems, such as background technique, it is unique rationally, steady that the purpose of the present invention is to provide a kind of formulas
It is qualitative it is strong, at low cost, antibacterial time is lasting, anti-wrinkle effect is significant, pollution is small, can wearing comfort the antibacterial crease-resistant type of dress ornament
Finishing agent and its method for sorting.
Dress ornament of the present invention is with antibacterial crease-resistant type finishing agent, the raw material including following parts by weight: natural crease-resistant liquid 30~
50 parts, 10~20 parts of aqueous polyurethane, 5~10 parts of aluminum sulfate, 10~15 parts of cactus extraction, Nano silver solution 10~15
Part, 1~3 part of methylene-bisacrylamide, 1~2 part of nanoscale silicone oil and 80~120 parts of water.
It further, also include the triethanolamine of 2~5 parts of parts by weight in the antibacterial crease-resistant type finishing agent.
Further, the preparation method of the natural crease-resistant liquid is: silkworm volume first being carried out degumming using sodium carbonate, later will
Silkworm volume after degumming, which is added in the calcium chloride water that temperature is 80~100 DEG C, mass fraction is 10~12%, to be impregnated, and is impregnated
Viscous fluid is obtained after 30~50min, and acetic acid is then added in viscous fluid and is hydrolyzed, the molar concentration of acetic acid is 20~
30mol/L, the temperature of hydrolysis are 50~100 DEG C, obtain hydrating solution after hydrolyzing 3~5h, ammonia is then added in hydrating solution
Water, the pH value for adjusting hydrating solution is 6.5~7.5, and active carbon is finally added in hydrating solution and carries out decolorization, active carbon
Additional amount be the 2~6% of hydrating solution quality, natural crease-resistant liquid can be obtained in filtering after 5~10min of decolorization.
Further, the production method of the cactus extraction is: first by the neck shear of cactus at several fritters,
Fritter is placed at a temperature of 120~140 DEG C later and is dried, the fritter after drying is then ground into powder, then by powder
It is put into ethyl alcohol, 3~5h is filtered by vacuum standing, cactus extraction can be obtained in rotary evaporation after mixing evenly.
Further, the preparation method of the Nano silver solution is: first by isobaric longan leaf, bodhi leaf and red
After ebon leaf washes with clean water, 120~140 DEG C at a temperature of dry, be then ground into powder, then added powder
Enter into 3~5 times of powder quality of water, heating decocts 20~30min, is filtered after being cooled to room temperature, later by suction filtration
Filtrate is diluted to the extracting solution that mass concentration is 15~20g/L, finally by extracting solution, the fibroin that mass concentration is 0.8~1g/L
After the mixing of the ratio of protein solution and silver nitrate 2~3:1:1~2 in mass ratio, heating water bath reacts 1~2h to 80~100 DEG C
After can be prepared by Nano silver solution.
The antibacterial crease-resistant method for sorting of dress ornament, comprising the following steps:
1. prerinse: the ready-made clothes sewed is sent into cleaning machine and is washed, the process conditions of washing are as follows: washing temperature 30~
40 DEG C, washing time is 10~20min；
2. drying: the ready-made clothes after prerinse is sent into dryer and carries out drying and processing, the side that drying and processing is dried using segmentation
Ready-made clothes is first dried 10~15min by formula in 60~80 DEG C of temperature environment, then dry 5 in 90~110 DEG C of temperature environment
~10min；
3. making finishing agent: according to mass fraction, be added in stirring pool natural 30~50 parts of crease-resistant liquid, aqueous polyurethane 10~
20 parts, 5~10 parts of aluminum sulfate, 10~15 parts of cactus extraction, 10~15 parts of Nano silver solution, methylene-bisacrylamide 1
~3 parts, 1~2 part of nanoscale silicone oil and 80~120 parts of water, temperature is 40~50 DEG C, revolving speed is 1000~2000r/min's
Under the conditions of, finishing agent is made in stirring and dissolving afterwards completely；
4. finishing agent arranges: using spraying machine, by step, 3. finishing agent pressurizing atomizing obtained is sprayed on ready-made clothes, atomizer
Operating pressure be 0.3~0.5MPa, make the liquid carrying rate 70~90% of shirt, later by ready-made clothes set temperature for 70~80 DEG C, it is wet
It spends in the water vapour for 50~60% and carries out decatize, again by ready-made clothes in the environment of temperature is 50~60 DEG C after 5~10min of decatize
Being dried to liquid rate is 20~25%；
5. softening: will be through step 4. treated ready-made clothes is put into diluted vinegar 20~30min of immersion, the diluted vinegar is by vinegar and washes rice
The volume ratio of water composition, vinegar and rice washing water is 1:5~10, and the rice of the rice washing water and the weight ratio of water are 1:8~15；
6. washing: will be after step 5. treated ready-made clothes carries out conventional water wash, by it in the environment of temperature is 40~50 DEG C
Dry 40~50h；
7. ironing is formed: carrying out high-temperature steam sizing ironing, the temperature of ironing to step 6. treated ready-made clothes using presses
Degree is 120~140 DEG C, and the pressure of ironing is 2~3kg/cm2, the time of ironing is 20~30s, later after natural cooling.
Through the above technical solution: natural crease-resistant liquid can be good at the amino acid that reservation silk is rich in and biology is living
Property, bridge formation can be played the role of between the molecule at fiber gap in conjunction with the fiber molecule in clothing fabric, increase and divide
Between son or interfibrous binding force, and it is more stable, it can significantly improve the wrinkle resistance and washing fastness of dress ornament；It is aqueous poly-
Urethane contains the isocyanate group of high activity, on the one hand can crosslink and react with the fiber of dress ornament cloth, forms three dimensional network
Shape structure, cross-bond become the skeleton of fiber and play support fixed function, and then improve the shortcomings that cloth easily wrinkles, on the other hand
Nano silver can also be made to anchor at fiber surface in conjunction with nano silver, further increase washability, guarantee the long-term antibacterial of dress ornament
Property；Nano silver can be adsorbed in bacteria cell wall or enter in cell membrane, and then influence bacterium internal protein, DNA just
Chang Gongneng makes bacterial death, a variety of microorganisms of curing the disease is all had with excellent bactericidal ability, and will not generate drug resistance
Property, it is a kind of environmentally protective and excellent antibacterial performance antibacterial agent；Cactus extraction can change the cotton fiber of cloth
Into being conducive to the stability of nano silver dispersion, further wherein the flavone compound contained is a kind of uvioresistant compound
Improve the antibiotic property and washability of dress ornament；Simultaneously in aluminum sulfate Asia, bisacrylamide and the catalysis of nanoscale silicone oil, stable work
Under, the finishing agent of formation can be reacted with the carboxyl of fabric fibre element, and fiber molecule is connected, and form the three of ester crosslinking
Structure is tieed up, the good wrinkle resistance of dress ornament, easy-care properties, antibacterial and deodouring is assigned, improves the feel of dress ornament, enhance the strong of dress ornament
Power and resistance to disposition.
Clothing fabric is arranged using method for sorting of the invention, can significantly improve the non-ironing, crease-resistant of dress ornament
Performance arranges, facilitates dress ornament after softening and sizing and keep optimal the shapes of the clothes, meanwhile, cooperate specific technical data and
Unique finishing agent can make each ingredient of finishing agent more fully play respective effect in each step, make that treated
The wrinkle-proof effect and resistance effect of dress ornament are more preferable, and can enhance the recovery capacity of dress ornament itself, keep persistently smooth indeformable,
Water resistance is preferable.Through testing, using the dress ornament after finishing agent arrangement, after using and washing 30 times, bacteriostasis rate is remained to
90% or more is kept, wrinkle recovery angle is maintained at 265 ° or more, and flat appearance degree can reach 4 grades or more, biocidal property, wrinkle resistance
It is excellent with the service performance of washability, it has a extensive future, use easy to spread.
Specific embodiment
Below with reference to embodiment, the present invention is further illustrated, but the present invention is limited in any way,
Based on present invention teach that it is made it is any transform or replace, all belong to the scope of protection of the present invention.
Embodiment 1
Antibacterial crease-resistant type finishing agent described in the present embodiment 1, the raw material including following parts by weight: natural 30 parts of crease-resistant liquid, aqueous poly-
10 parts of urethane, 5 parts of aluminum sulfate, 10 parts of cactus extraction, 10 parts of Nano silver solution, 1 part of methylene-bisacrylamide, nanoscale
1 part of silicone oil, 80 parts of water and 5 parts of triethanolamine.
It is arranged in agent prescription in above-mentioned antibacterial crease-resistant type:
The preparation method of the natural crease-resistant liquid is: silkworm volume first being carried out degumming using sodium carbonate, later rolls up the silkworm after degumming
It is added in the calcium chloride water that temperature is 80 DEG C, mass fraction is 10% and impregnates, obtain viscous fluid after impregnating 30min, then
Acetic acid is added in viscous fluid to be hydrolyzed, the molar concentration of acetic acid is 20mol/L, and the temperature of hydrolysis is 50 DEG C, after hydrolyzing 3h
Hydrating solution is obtained, ammonium hydroxide is then added in hydrating solution, the pH value for adjusting hydrating solution is 6.5, finally in hydrating solution
Middle addition active carbon carries out decolorization, and the additional amount of active carbon is the 2% of hydrating solution quality, filters after decolorization 5min
Natural crease-resistant liquid can be obtained, natural crease-resistant liquid can be good at retaining the amino acid and bioactivity that silk is rich in, Neng Gouyu
Fiber molecule in clothing fabric combines, and plays the role of bridge formation between the molecule at fiber gap, increases intermolecular or fine
Binding force between dimension, and it is more stable, it can significantly improve the wrinkle resistance and washing fastness of dress ornament.
Aqueous polyurethane contains the isocyanate group of high activity, on the one hand can crosslink instead with the fiber of dress ornament cloth
It answers, forms tridimensional network, cross-bond becomes the skeleton of fiber and plays support fixed function, and then improves what cloth easily wrinkled
On the other hand disadvantage can also make nano silver anchor at fiber surface, further increase washability in conjunction with nano silver, guarantee
The long-term antibacterial of dress ornament
The production method of the cactus extraction is: first fritter being set to the neck shear of cactus later at several fritters
It is dried at a temperature of 120 DEG C, the fritter after drying is then ground into powder, then powder is put into ethyl alcohol, stirring is equal
3h is filtered by vacuum standing, cactus extraction can be obtained in rotary evaporation after even, and cactus extraction can be to cloth
Cotton fiber improves, wherein the flavone compound contained is a kind of uvioresistant compound, is conducive to the steady of nano silver dispersion
It is qualitative, the further antibiotic property and washability for improving dress ornament
The preparation method of the Nano silver solution is: first by isobaric longan leaf, bodhi leaf and redwood leaf clear water
After wash clean, 120 DEG C at a temperature of dry, be then ground into powder, powder be then added to 3 times of powder quality
In water, heating decocts 20min, is filtered after being cooled to room temperature, and it is 15g/L that the filtrate of suction filtration, which is diluted to mass concentration, later
Extracting solution, finally by extracting solution, mass concentration be 0.8g/L silk fibroin protein solution and silver nitrate 2:1:1 in mass ratio ratio
After example mixing, heating water bath can be prepared by Nano silver solution, containing alkaloids, polyphenol, enzyme in extracting solution after reacting 1h to 80 DEG C
The substances such as class, protein, polysaccharide and chlorophyll, the nano silver made from nitric acid silver reaction during, play reducing agent, stabilizer
Effect improve the antibacterial effect of nano silver, fibroin albumen is natural macromolecular knot while with nano silver there are systemic effect
Nano silver can be fixed in macromolecular structure by structure as protective agent, so that nano silver is preferably protected, while fibroin
Albumen can be reacted with soluble polyurethane, and then face liber surface with the help of soluble polyurethane in dress ornament is formed
Firm protective film, and then improve the bond strength between nano silver and fiber.
The antibacterial crease-resistant method for sorting of dress ornament, comprising the following steps:
1. prerinse: the ready-made clothes sewed is sent into cleaning machine and is washed, the process conditions of washing are as follows: washing temperature 30
DEG C, washing time 10min；
2. drying: the ready-made clothes after prerinse is sent into dryer and carries out drying and processing, the side that drying and processing is dried using segmentation
Ready-made clothes is first dried 10min by formula in 60 DEG C of temperature environment, then the dry 5min in 90 DEG C of temperature environment；
3. making finishing agent according to mass fraction, natural 30 parts of crease-resistant liquid, 10 parts of aqueous polyurethane, sulfuric acid are added in stirring pool
5 parts of aluminium, 10 parts of cactus extraction, 10 parts of Nano silver solution, 1 part of methylene-bisacrylamide, 1 part of nanoscale silicone oil, water 80
Part and 5 parts of triethanolamine, under conditions of temperature is 40 DEG C, revolving speed is 1000r/min, stirring and dissolving obtained arrangement afterwards completely
Agent；
4. finishing agent arranges: using spraying machine, by step, 3. finishing agent pressurizing atomizing obtained is sprayed on ready-made clothes, atomizer
Operating pressure be 0.3MPa, make the liquid carrying rate 70% of shirt, ready-made clothes set into the steaming of temperature is 70 DEG C, humidity is 50% water later
Decatize is carried out in vapour, it is 20% that ready-made clothes is dried to liquid rate in the environment of temperature is 50 DEG C again after decatize 5min；
5. softening: will through step, 4. treated that ready-made clothes is put into diluted vinegar impregnates 20min, the diluted vinegar is by vinegar and rice washing water group
At the volume ratio of vinegar and rice washing water is 1:5, and the rice of the rice washing water and the weight ratio of water are 1:8；
6. washing: will after step 5. treated ready-made clothes carries out conventional water wash, by its in the environment of temperature is 40 DEG C it is dry
40h；
7. ironing is formed: carrying out high-temperature steam sizing ironing, the temperature of ironing to step 6. treated ready-made clothes using presses
Degree is 120 DEG C, and the pressure of ironing is 2kg/cm2, the time of ironing is 20s, later after natural cooling.
Clothing fabric is arranged using method for sorting of the invention, can significantly improve the non-ironing, crease-resistant of dress ornament
Performance arranges, facilitates dress ornament after softening and sizing and keep optimal the shapes of the clothes, meanwhile, cooperate specific technical data and
Unique finishing agent can make each ingredient of finishing agent more fully play respective effect in a step, make that treated
The wrinkle-proof effect and resistance effect of dress ornament are more preferable, and can enhance the recovery capacity of dress ornament itself, keep persistently smooth indeformable,
Water resistance is preferable.Through testing, using the dress ornament after finishing agent arrangement, after using and washing 35 times, bacteriostasis rate remains to protect
92.4% is held, wrinkle recovery angle is maintained at 267.1 °, and flat appearance degree can reach 4.1 grades, biocidal property, wrinkle resistance and washability
Service performance it is excellent, have a extensive future, use easy to spread.
Embodiment 2
Antibacterial crease-resistant type finishing agent described in the present embodiment 2, the raw material including following parts by weight: natural 40 parts of crease-resistant liquid, aqueous poly-
15 parts of urethane, 8 parts of aluminum sulfate, 13 parts of cactus extraction, 12 parts of Nano silver solution, 2 parts of methylene-bisacrylamide, nanoscale
1.5 parts of silicone oil, 100 parts of water and 2 parts of triethanolamine.
It is arranged in agent prescription in above-mentioned antibacterial crease-resistant type:
The preparation method of the natural crease-resistant liquid is: silkworm volume first being carried out degumming using sodium carbonate, later rolls up the silkworm after degumming
It is added in the calcium chloride water that temperature is 90 DEG C, mass fraction is 11% and impregnates, obtain viscous fluid after impregnating 40min, then
Acetic acid is added in viscous fluid to be hydrolyzed, the molar concentration of acetic acid is 25mol/L, and the temperature of hydrolysis is 80 DEG C, after hydrolyzing 4h
Hydrating solution is obtained, ammonium hydroxide is then added in hydrating solution, the pH value for adjusting hydrating solution is 7, finally in hydrating solution
Active carbon is added and carries out decolorization, the additional amount of active carbon is the 5% of hydrating solution quality, after decolorization 8min filtering be
Natural crease-resistant liquid can be obtained, natural crease-resistant liquid can be good at retaining the amino acid and bioactivity that silk is rich in, can be with clothes
Fiber molecule in facework combines, and plays the role of bridge formation between the molecule at fiber gap, increases intermolecular or fiber
Between binding force, and it is more stable, can significantly improve the wrinkle resistance and washing fastness of dress ornament.
Aqueous polyurethane contains the isocyanate group of high activity, on the one hand can crosslink instead with the fiber of dress ornament cloth
It answers, forms tridimensional network, cross-bond becomes the skeleton of fiber and plays support fixed function, and then improves what cloth easily wrinkled
On the other hand disadvantage can also make nano silver anchor at fiber surface, further increase washability in conjunction with nano silver, guarantee
The long-term antibacterial of dress ornament
The production method of the cactus extraction is: first fritter being set to the neck shear of cactus later at several fritters
It is dried at a temperature of 130 DEG C, the fritter after drying is then ground into powder, then powder is put into ethyl alcohol, stirring is equal
4h is filtered by vacuum standing, cactus extraction can be obtained in rotary evaporation after even, and cactus extraction can be to cloth
Cotton fiber improves, wherein the flavone compound contained is a kind of uvioresistant compound, is conducive to the steady of nano silver dispersion
It is qualitative, the further antibiotic property and washability for improving dress ornament
The preparation method of the Nano silver solution is: first by isobaric longan leaf, bodhi leaf and redwood leaf clear water
After wash clean, 130 DEG C at a temperature of dry, be then ground into powder, powder be then added to 4 times of powder quality
In water, heating decocts 25min, is filtered after being cooled to room temperature, and it is 18g/L that the filtrate of suction filtration, which is diluted to mass concentration, later
Extracting solution, finally by extracting solution, mass concentration be 0.9g/L silk fibroin protein solution and silver nitrate 2.5:1:1.5 in mass ratio
Ratio mixing after, heating water bath can be prepared by Nano silver solution after reacting 1.5h to 90 DEG C, it is containing alkaloids in extracting solution,
The substances such as polyphenol, enzyme, protein, polysaccharide and chlorophyll, the nano silver made from nitric acid silver reaction during play reducing agent,
The effect of stabilizer, while there are systemic effects with nano silver, improve the antibacterial effect of nano silver, fibroin albumen is natural big point
Nano silver can be fixed in macromolecular structure by minor structure as protective agent, so that nano silver is preferably protected, simultaneously
Fibroin albumen can be reacted with soluble polyurethane, and then on the face liber surface of dress ornament with the help of soluble polyurethane
Firm protective film is formed, and then improves the bond strength between nano silver and fiber.
The antibacterial crease-resistant method for sorting of dress ornament, comprising the following steps:
1. prerinse: the ready-made clothes sewed is sent into cleaning machine and is washed, the process conditions of washing are as follows: washing temperature 35
DEG C, washing time 15min；
2. drying: the ready-made clothes after prerinse is sent into dryer and carries out drying and processing, the side that drying and processing is dried using segmentation
Ready-made clothes is first dried 12min by formula in 70 DEG C of temperature environment, then the dry 8min in 100 DEG C of temperature environment；
3. making finishing agent according to mass fraction, natural 40 parts of crease-resistant liquid, 15 parts of aqueous polyurethane, sulfuric acid are added in stirring pool
8 parts of aluminium, 13 parts of cactus extraction, 12 parts of Nano silver solution, 2 parts of methylene-bisacrylamide, 1.5 parts of nanoscale silicone oil, water
100 parts and 2 parts of triethanolamine, under conditions of temperature is 45 DEG C, revolving speed is 1500r/min, stirring and dissolving is made whole afterwards completely
Manage agent；
4. finishing agent arranges: using spraying machine, by step, 3. finishing agent pressurizing atomizing obtained is sprayed on ready-made clothes, atomizer
Operating pressure be 0.4MPa, make the liquid carrying rate 80% of shirt, ready-made clothes set into the steaming of temperature is 75 DEG C, humidity is 55% water later
Decatize is carried out in vapour, it is 22% that ready-made clothes is dried to liquid rate in the environment of temperature is 55 DEG C again after decatize 8min；
5. softening: will be through step 4. treated ready-made clothes is put into diluted vinegar 20~30min of immersion, the diluted vinegar is by vinegar and washes rice
The volume ratio of water composition, vinegar and rice washing water is 1:8, and the rice of the rice washing water and the weight ratio of water are 1:12；
6. washing: will after step 5. treated ready-made clothes carries out conventional water wash, by its in the environment of temperature is 45 DEG C it is dry
45h；
7. ironing is formed: carrying out high-temperature steam sizing ironing, the temperature of ironing to step 6. treated ready-made clothes using presses
Degree is 130 DEG C, and the pressure of ironing is 2.5kg/cm2, the time of ironing is 25s, later after natural cooling.
Clothing fabric is arranged using method for sorting of the invention, can significantly improve the non-ironing, crease-resistant of dress ornament
Performance arranges, facilitates dress ornament after softening and sizing and keep optimal the shapes of the clothes, meanwhile, cooperate specific technical data and
Unique finishing agent can make each ingredient of finishing agent more fully play respective effect in a step, make that treated
The wrinkle-proof effect and resistance effect of dress ornament are more preferable, and can enhance the recovery capacity of dress ornament itself, keep persistently smooth indeformable,
Water resistance is preferable.Through testing, using the dress ornament after finishing agent arrangement, after using and washing 40 times, bacteriostasis rate remains to protect
93.7% is held, wrinkle recovery angle is maintained at 268.6 °, and flat appearance degree can reach 4.2 grades, biocidal property, wrinkle resistance and washability
Service performance it is excellent, have a extensive future, use easy to spread.
Embodiment 3
Antibacterial crease-resistant type finishing agent described in the present embodiment 3, the raw material including following parts by weight: natural 50 parts of crease-resistant liquid, aqueous poly-
20 parts of urethane, 10 parts of aluminum sulfate, 15 parts of cactus extraction, 15 parts of Nano silver solution, methylene-bisacrylamide 3 part, nanometer
2 parts of silicone oil of grade, 120 parts of water and 2 parts of triethanolamine.
It is arranged in agent prescription in above-mentioned antibacterial crease-resistant type:
The preparation method of the natural crease-resistant liquid is: silkworm volume first being carried out degumming using sodium carbonate, later rolls up the silkworm after degumming
It is added in the calcium chloride water that temperature is 100 DEG C, mass fraction is 12% and impregnates, obtain viscous fluid after impregnating 50min, so
Acetic acid is added in viscous fluid afterwards to be hydrolyzed, the molar concentration of acetic acid is 30mol/L, and the temperature of hydrolysis is 100 DEG C, hydrolyzes 5h
After obtain hydrating solution, ammonium hydroxide is then added in hydrating solution, adjust hydrating solution pH value be 7.5, finally hydrolyze it is molten
Active carbon is added in liquid and carries out decolorization, the additional amount of active carbon is the 6% of hydrating solution quality, mistake after decolorization 10min
Natural crease-resistant liquid can be obtained in filter, and natural crease-resistant liquid can be good at retaining the amino acid and bioactivity that silk is rich in, can
In conjunction with the fiber molecule in clothing fabric, play the role of bridge formation between the molecule at fiber gap, increase it is intermolecular or
Interfibrous binding force, and it is more stable, it can significantly improve the wrinkle resistance and washing fastness of dress ornament.
Aqueous polyurethane contains the isocyanate group of high activity, on the one hand can crosslink instead with the fiber of dress ornament cloth
It answers, forms tridimensional network, cross-bond becomes the skeleton of fiber and plays support fixed function, and then improves what cloth easily wrinkled
On the other hand disadvantage can also make nano silver anchor at fiber surface, further increase washability in conjunction with nano silver, guarantee
The long-term antibacterial of dress ornament
The production method of the cactus extraction is: first fritter being set to the neck shear of cactus later at several fritters
It is dried at a temperature of 140 DEG C, the fritter after drying is then ground into powder, then powder is put into ethyl alcohol, stirring is equal
H is filtered by vacuum standing, cactus extraction can be obtained in rotary evaporation after even, and cactus extraction can be to the cotton of cloth
Fiber improves, wherein the flavone compound contained is a kind of uvioresistant compound, is conducive to the stabilization of nano silver dispersion
Property, the further antibiotic property and washability for improving dress ornament
The preparation method of the Nano silver solution is: first by isobaric longan leaf, bodhi leaf and redwood leaf clear water
After wash clean, 140 DEG C at a temperature of dry, be then ground into powder, powder be then added to 5 times of powder quality
In water, heating decocts 30min, is filtered after being cooled to room temperature, and it is 20g/L that the filtrate of suction filtration, which is diluted to mass concentration, later
Extracting solution, finally by extracting solution, mass concentration be 1g/L silk fibroin protein solution and silver nitrate 3:1:2 in mass ratio ratio
After example mixing, heating water bath can be prepared by Nano silver solution after reacting 2h to 100 DEG C, containing alkaloids, polyphenol in extracting solution,
The substances such as enzyme, protein, polysaccharide and chlorophyll, the nano silver made from nitric acid silver reaction during, play reducing agent, stabilization
The effect of agent, while there are systemic effects with nano silver, improve the antibacterial effect of nano silver, fibroin albumen is natural macromolecular knot
Nano silver can be fixed in macromolecular structure by structure as protective agent, so that nano silver is preferably protected, while fibroin
Albumen can be reacted with soluble polyurethane, and then face liber surface with the help of soluble polyurethane in dress ornament is formed
Firm protective film, and then improve the bond strength between nano silver and fiber.
The antibacterial crease-resistant method for sorting of dress ornament, comprising the following steps:
1. prerinse: the ready-made clothes sewed is sent into cleaning machine and is washed, the process conditions of washing are as follows: washing temperature 40
DEG C, washing time 20min；
2. drying: the ready-made clothes after prerinse is sent into dryer and carries out drying and processing, the side that drying and processing is dried using segmentation
Ready-made clothes is first dried 15min by formula in 80 DEG C of temperature environment, then the dry 10min in 110 DEG C of temperature environment；
3. making finishing agent according to mass fraction, natural 50 parts of crease-resistant liquid, 20 parts of aqueous polyurethane, sulfuric acid are added in stirring pool
10 parts of aluminium, 15 parts of cactus extraction, 15 parts of Nano silver solution, 3 parts of methylene-bisacrylamide, 2 parts of nanoscale silicone oil, water
120 parts and 2 parts of triethanolamine, under conditions of temperature is 50 DEG C, revolving speed is 2000r/min, stirring and dissolving is made whole afterwards completely
Manage agent；
4. finishing agent arranges: using spraying machine, by step, 3. finishing agent pressurizing atomizing obtained is sprayed on ready-made clothes, atomizer
Operating pressure be 0.5MPa, make the liquid carrying rate 90% of shirt, ready-made clothes set into the steaming of temperature is 80 DEG C, humidity is 60% water later
Decatize is carried out in vapour, it is 25% that ready-made clothes is dried to liquid rate in the environment of temperature is 60 DEG C again after decatize 10min；
5. softening: will be through step 4. treated ready-made clothes is put into diluted vinegar 20~30min of immersion, the diluted vinegar is by vinegar and washes rice
The volume ratio of water composition, vinegar and rice washing water is 1:10, and the rice of the rice washing water and the weight ratio of water are 1:15；
6. washing: will after step 5. treated ready-made clothes carries out conventional water wash, by its in the environment of temperature is 50 DEG C it is dry
50h；
7. ironing is formed: carrying out high-temperature steam sizing ironing, the temperature of ironing to step 6. treated ready-made clothes using presses
Degree is 140 DEG C, and the pressure of ironing is 3kg/cm2, the time of ironing is 30s, later after natural cooling.
Clothing fabric is arranged using method for sorting of the invention, can significantly improve the non-ironing, crease-resistant of dress ornament
Performance arranges, facilitates dress ornament after softening and sizing and keep optimal the shapes of the clothes, meanwhile, cooperate specific technical data and
Unique finishing agent can make each ingredient of finishing agent more fully play respective effect in a step, make that treated
The wrinkle-proof effect and resistance effect of dress ornament are more preferable, and can enhance the recovery capacity of dress ornament itself, keep persistently smooth indeformable,
Water resistance is preferable.Through testing, using the dress ornament after finishing agent arrangement, after using and washing 38 times, bacteriostasis rate remains to protect
91.8% is held, wrinkle recovery angle is maintained at 268.4 °, and flat appearance degree can reach 4.06 grades, biocidal property, wrinkle resistance and washability
Service performance it is excellent, have a extensive future, use easy to spread.
Claims (8)
1. a kind of antibacterial crease-resistant type finishing agent of dress ornament, it is characterised in that: the raw material including following parts by weight: natural crease-resistant liquid 30
~50 parts, 10~20 parts of aqueous polyurethane, 5~10 parts of aluminum sulfate, 10~15 parts of cactus extraction, Nano silver solution 10~15
Part, 1~3 part of methylene-bisacrylamide, 1~2 part of nanoscale silicone oil and 80~120 parts of water.
2. a kind of antibacterial crease-resistant type finishing agent of dress ornament according to claim 1, it is characterised in that: the antibacterial crease-resistant type
It also include the triethanolamine of 2~5 parts of parts by weight in finishing agent.
3. a kind of antibacterial crease-resistant type finishing agent of dress ornament according to claim 1, it is characterised in that: the natural crease-resistant liquid
Preparation method be: first by silkworm volume using sodium carbonate carry out degumming, later by after degumming silkworm volume be added to temperature be 80~100
DEG C, mass fraction be 10~12% calcium chloride water in impregnate, impregnate 30~50min after obtain viscous fluid, then sticky
Acetic acid is added in liquid to be hydrolyzed, the molar concentration of acetic acid is 20~30mol/L, and the temperature of hydrolysis is 50~100 DEG C, hydrolysis 3
Hydrating solution is obtained after~5h, ammonium hydroxide is then added in hydrating solution, and the pH value for adjusting hydrating solution is 6.5~7.5, finally
Active carbon is added in hydrating solution and carries out decolorization, the additional amount of active carbon is the 2~6% of hydrating solution quality, at decoloration
Natural crease-resistant liquid can be obtained in filtering after 5~10min of reason.
4. a kind of antibacterial crease-resistant type finishing agent of dress ornament according to claim 1, it is characterised in that: the cactus is extracted
The production method of liquid is: first by the neck shear of cactus at several fritters, fritter being placed in 120~140 DEG C of temperature later
Lower drying, is then ground into powder for the fritter after drying, then powder is put into ethyl alcohol, stands 3~5h after mixing evenly
It is filtered by vacuum, cactus extraction can be obtained in rotary evaporation.
5. a kind of antibacterial crease-resistant type finishing agent of dress ornament according to claim 1, it is characterised in that: the Nano silver solution
Preparation method be: after first washing with clean water isobaric longan leaf, bodhi leaf and redwood leaf, 120~140
It is dried at a temperature of DEG C, is then ground into powder, be then added to powder in 3~5 times of powder quality of water, heating is decocted
20~30min is boiled, is filtered after being cooled to room temperature, it is 15~20g/L's that the filtrate of suction filtration, which is diluted to mass concentration, later
Extracting solution, finally by extracting solution, the silk fibroin protein solution and silver nitrate 2~3:1:1 in mass ratio that mass concentration is 0.8~1g/L
After~2 ratio mixing, heating water bath can be prepared by Nano silver solution after reacting 1~2h to 80~100 DEG C.
6. a kind of antibacterial crease-resistant method for sorting of dress ornament, which comprises the following steps:
1. prerinse: the ready-made clothes sewed is sent into cleaning machine and is washed, the process conditions of washing are as follows: washing temperature 30~
40 DEG C, washing time is 10~20min；
2. drying: the ready-made clothes after prerinse being sent into dryer and carries out drying and processing；
3. make finishing agent according to mass fraction, be added in stirring pool natural 30~50 parts of crease-resistant liquid, aqueous polyurethane 10~
20 parts, 5~10 parts of aluminum sulfate, 10~15 parts of cactus extraction, 10~15 parts of Nano silver solution, methylene-bisacrylamide 1
~3 parts, 1~2 part of nanoscale silicone oil and 80~120 parts of water, temperature is 40~50 DEG C, revolving speed is 1000~2000r/min's
Under the conditions of, finishing agent is made in stirring and dissolving afterwards completely；
4. finishing agent arranges: using spraying machine, by step, 3. finishing agent pressurizing atomizing obtained is sprayed on ready-made clothes, atomizer
Operating pressure be 0.3~0.5MPa, make the liquid carrying rate 70~90% of shirt, later by ready-made clothes set temperature for 70~80 DEG C, it is wet
It spends in the water vapour for 50~60% and carries out decatize, again by ready-made clothes in the environment of temperature is 50~60 DEG C after 5~10min of decatize
Being dried to liquid rate is 20~25%；
5. softening: will be through step 4. treated ready-made clothes is put into diluted vinegar 20~30min of immersion, the diluted vinegar is by vinegar and washes rice
The volume ratio of water composition, vinegar and rice washing water is 1:5~10；
6. washing: will be after step 5. treated ready-made clothes carries out conventional water wash, by it in the environment of temperature is 40~50 DEG C
Dry 40~50h；
7. ironing is formed: carrying out high-temperature steam sizing ironing, the temperature of ironing to step 6. treated ready-made clothes using presses
Degree is 120~140 DEG C, and the pressure of ironing is 2~3kg/cm2, the time of ironing is 20~30s, later after natural cooling.
7. the antibacterial crease-resistant method for sorting of a kind of dress ornament according to claim 6, it is characterised in that: step 2. in, dry
Ready-made clothes is first dried 10~15min by the way of segmentation drying by dry-cure in 60~80 DEG C of temperature environment, then 90~
Dry 5~10min in 110 DEG C of temperature environment.
8. the antibacterial crease-resistant method for sorting of a kind of dress ornament according to claim 6, it is characterised in that: step 5. in, institute
The weight ratio of the rice and water of stating rice washing water is 1:8~15.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910471399.4A CN110158318A (en) | 2019-05-31 | 2019-05-31 | A kind of dress ornament antibacterial crease-resistant type finishing agent and its method for sorting |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910471399.4A CN110158318A (en) | 2019-05-31 | 2019-05-31 | A kind of dress ornament antibacterial crease-resistant type finishing agent and its method for sorting |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110158318A true CN110158318A (en) | 2019-08-23 |
Family
ID=67630981
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910471399.4A Pending CN110158318A (en) | 2019-05-31 | 2019-05-31 | A kind of dress ornament antibacterial crease-resistant type finishing agent and its method for sorting |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110158318A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110541308A (en) * | 2019-09-12 | 2019-12-06 | 愉悦家纺有限公司 | Preparation method of long-acting antibacterial pure cotton fabric |
| CN115120545A (en) * | 2022-08-23 | 2022-09-30 | 广州市名宇化妆品制造有限公司 | Preparation method of anti-wrinkle spray for cactus |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103668982A (en) * | 2013-11-29 | 2014-03-26 | 南通市通州区大达麻纺织有限公司 | Preparation method of fibroin finishing agent |
| CN105200777A (en) * | 2015-09-23 | 2015-12-30 | 宿州学院 | Crease-resistant non-ironing finishing technology of pure cotton fabric |
| CN108342898A (en) * | 2018-02-02 | 2018-07-31 | 宜州市壮之都丝绸家纺有限公司 | A kind of wrinkle resistant processing method of silk |
| CN109440454A (en) * | 2018-11-07 | 2019-03-08 | 温州格蕾斯服饰有限公司 | A kind of method for sorting of antibacterial shirt |
-
2019
- 2019-05-31 CN CN201910471399.4A patent/CN110158318A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103668982A (en) * | 2013-11-29 | 2014-03-26 | 南通市通州区大达麻纺织有限公司 | Preparation method of fibroin finishing agent |
| CN105200777A (en) * | 2015-09-23 | 2015-12-30 | 宿州学院 | Crease-resistant non-ironing finishing technology of pure cotton fabric |
| CN108342898A (en) * | 2018-02-02 | 2018-07-31 | 宜州市壮之都丝绸家纺有限公司 | A kind of wrinkle resistant processing method of silk |
| CN109440454A (en) * | 2018-11-07 | 2019-03-08 | 温州格蕾斯服饰有限公司 | A kind of method for sorting of antibacterial shirt |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110541308A (en) * | 2019-09-12 | 2019-12-06 | 愉悦家纺有限公司 | Preparation method of long-acting antibacterial pure cotton fabric |
| CN115120545A (en) * | 2022-08-23 | 2022-09-30 | 广州市名宇化妆品制造有限公司 | Preparation method of anti-wrinkle spray for cactus |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| WO2020024517A1 (en) | Method for preparing moisture-retentive, breathable, and antibacterial spunlace non-woven fabric for polyurethane synthetic leather | |
| CN102529277B (en) | Preparation method of waterproof, moisture permeable and antibacterial composite fabric | |
| KR101149061B1 (en) | Chitosan non-woven fabric for mask pack material, and method for manufacturing the non-woven fabric | |
| CN100529246C (en) | Process for preparing poly modified chitosan anti-bacteria wet keeping finishing agent | |
| CN102965964B (en) | Manufacturing method of artificial super-soft abrasion-proof polyurethane shoe lining leather | |
| CN108301201A (en) | The preparation method of graphene compound nonwoven cloth | |
| CN110158318A (en) | A kind of dress ornament antibacterial crease-resistant type finishing agent and its method for sorting | |
| CN107653532A (en) | A kind of environment-friendly type fabric for sportswear of highly hygroscopic perspiration discharging performance and preparation method thereof | |
| CN106592223A (en) | Water-proofing, oil-proofing and antifouling type easy-care finishing liquid of shirt and finishing method of water-proofing, oil-proofing and antifouling type easy-care finishing liquid | |
| CN109440454A (en) | A kind of method for sorting of antibacterial shirt | |
| CN112878041A (en) | High-breathability antibacterial anti-mite fabric and preparation process thereof | |
| CN105970614A (en) | Preparation method for antibacterial acrylic fiber | |
| CN106757494A (en) | A kind of pro-skin antibiotic facing material and its processing method | |
| CN102215815A (en) | Mask pack comprising cosmetic cotton-like material prepared from paper mulberry | |
| CN108797142A (en) | Moisture absorption, antibacterial and water vapor permeability graphene modified polyurethane synthetic leather preparation method | |
| CN105239380B (en) | A kind of antibiotic-mould proof textile fabric and preparation method thereof | |
| CN105256587A (en) | Novel formaldehyde-free low-damage crease-resistant finishing agent and finishing method thereof | |
| CN111607961A (en) | Antibacterial non-woven fabric and four-piece set | |
| CN108754778A (en) | A kind for the treatment of process of silk, blend polyester fabric | |
| CN105220485A (en) | A kind of infant based on ionic liquid is with new modified cotton fiber and preparation method thereof | |
| CN106758200A (en) | The uvioresistant protection type noniron finish liquid and its method for sorting of a kind of shirt | |
| CN107653533A (en) | A kind of preparation method of antibacterial, deodorization summer shirt fabric | |
| CN113417141A (en) | Non-ironing treatment method for cotton shirt | |
| CN104313871A (en) | Preparation method of lyophobic nano fiber fabric | |
| CN112482018A (en) | Production process of nano real silk crease-resistant knitted garment |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information |
Address after: 655000 Southeast Side of Sanyuan Road and Cuihe Road Intersection in Qujing City, Yunnan Province Applicant after: Yunnan George White Clothing Technology Co.,Ltd. Address before: 655000 Southeast Side of Sanyuan Road and Cuihe Road Intersection in Qujing City, Yunnan Province Applicant before: YUNNAN HAOXIANG CLOTHING Co.,Ltd. |
|
| CB02 | Change of applicant information | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190823 |
|
| RJ01 | Rejection of invention patent application after publication |