CN106757494A - A kind of pro-skin antibiotic facing material and its processing method - Google Patents

A kind of pro-skin antibiotic facing material and its processing method Download PDF

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Publication number
CN106757494A
CN106757494A CN201611064445.1A CN201611064445A CN106757494A CN 106757494 A CN106757494 A CN 106757494A CN 201611064445 A CN201611064445 A CN 201611064445A CN 106757494 A CN106757494 A CN 106757494A
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China
Prior art keywords
leaf oil
argyi leaf
volatile argyi
micro
capsule
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CN201611064445.1A
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Chinese (zh)
Inventor
徐晓烨
王成军
孙俊河
王娟娟
仓亚萍
于灿
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Jiangsu Yueda Home Textile Co Ltd
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Jiangsu Yueda Home Textile Co Ltd
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Priority to CN201611064445.1A priority Critical patent/CN106757494A/en
Priority to PCT/CN2016/108433 priority patent/WO2018094765A1/en
Priority to KR1020177037711A priority patent/KR20190086599A/en
Publication of CN106757494A publication Critical patent/CN106757494A/en
Pending legal-status Critical Current

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    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/02—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from cellulose, cellulose derivatives, or proteins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/02—Making microcapsules or microballoons
    • B01J13/06—Making microcapsules or microballoons by phase separation
    • B01J13/10—Complex coacervation, i.e. interaction of oppositely charged particles
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B9/00—Essential oils; Perfumes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B9/00—Essential oils; Perfumes
    • C11B9/02—Recovery or refining of essential oils from raw materials
    • C11B9/022—Refining
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B9/00—Essential oils; Perfumes
    • C11B9/02—Recovery or refining of essential oils from raw materials
    • C11B9/025—Recovery by solvent extraction
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B9/00—Essential oils; Perfumes
    • C11B9/02—Recovery or refining of essential oils from raw materials
    • C11B9/027—Recovery of volatiles by distillation or stripping
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/06—Wet spinning methods
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D01F1/103—Agents inhibiting growth of microorganisms
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/08—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyacrylonitrile as constituent
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/653—Nitrogen-free carboxylic acids or their salts
    • D06P1/6533—Aliphatic, araliphatic or cycloaliphatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • D06P1/67333—Salts or hydroxides
    • D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02—After-treatment
    • D06P5/04—After-treatment with organic compounds
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/13—Physical properties anti-allergenic or anti-bacterial

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Textile Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

The present invention provides a kind of pro-skin antibiotic facing material and its processing method.The method of the present invention comprises the following steps：（1）Extract volatile argyi leaf oil；（2）Volatile argyi leaf oil micro-capsule is prepared with complex coacervation；（3）Prepare volatile argyi leaf oil milk protein fiber：Using cow's milk as base stock, by dehydration, de-oiling, degreasing, separation, purification, MC is made；Again spinning solution is prepared into polyacrylonitrile using being blended, being crosslinked, be grafted；Volatile argyi leaf oil micro-capsule is added in obtained spinning solution, volatile argyi leaf oil milk protein fiber is formed into fibre, solidification, drawing-off, drying, curling, setting, winding filament finally by wet spinning；（4）Weave cotton cloth：Using step（3）Obtained volatile argyi leaf oil milk protein fiber weaves cotton cloth to form fabric as yarn using the conventional method of weaving cotton cloth；（5）Dyeing；（6）Dyeing post processing.Fabric of the invention has a broad-spectrum antibacterial function, and persistence is strong, and up to more than 99%, antibiotic rate is up to more than 80% for natural bacteriostatic function.

Description

A kind of pro-skin antibiotic facing material and its processing method
Technical field：
The present invention relates to a kind of fabric, and in particular to a kind of pro-skin antibiotic facing material and its processing method.
Background technology：
The fabric of household textiles early application only has certain wanting in addition to inherent quality requirement to washing shrinkage and color fastness Ask.With developing rapidly for domestic home textile market, there is requirement higher to the functional form of family's textile fabric.User is to household textile The requirement of product is also more harsh：For bedding, while warmth retention property is pursued, again can not be too thick and heavy；It is any Single natural or chemical fibre is all unable to reach these requirements, can only be whole by the compound and multipath chemistry of multiple fiber Reason reaches these functions to try one's best.Because people is when sleep, skin also works in the metabolism for carrying out him, at this time skin Skin can discharge sweat or other metabolites, if the sweat of people's discharge is not evaporated timely and will hidden always In bed necessaries.Vicious circle is formed and the metabolism of skin between, skin is eventually caused and is played erythema or cause other skin mistakes Quick phenomenon.The flexibility of other bed necessaries gives people good sense of touch, and when people sleeps, soft cotton sense of touch can make one Body is loosened in this soft easy atmosphere, allow people to sleep more feel at ease.Some current antibiotic facing materials, it is fixed at present The technology of antiseptic is limited, and the washability of antiseptic is not good enough, often washed once anti-microbial property and just declines, and general tens Just it is wholly absent after secondary.And easy pilling, become easily infected by dust dirt, skin-proximal and have electric-shock feeling etc..Be difficult to Preferable effect is all reached in upper performance, it is impossible to meet the growing material and cultural needs of the people.
The content of the invention：
The purpose of the present invention is directed to above-mentioned problem and provides a kind of pro-skin antibiotic facing material and its processing method, obtained face Material flexibility, skin-friendly is good, and it is comfortable to make one contact, and wearability, anti-pilling, coloring, is strongly superior to common fabric, With broad-spectrum antibacterial function, persistence is strong, and up to more than 99%, antibiotic rate is up to more than 80% for natural bacteriostatic function.
Above-mentioned purpose is realized by following technical scheme：
A kind of processing method of pro-skin antibiotic facing material, the method comprises the following steps：
（1）Extract volatile argyi leaf oil；
（2）Volatile argyi leaf oil micro-capsule is prepared with complex coacervation；
（3）Prepare volatile argyi leaf oil-milk protein fiber：Using cow's milk as base stock, by dehydration, de-oiling, degreasing, point From, purification, make MC；It is blended using conventional meanses with polyacrylonitrile again, is crosslinked, is grafted, is prepared into spinning Silk stock solution；Step is added in obtained spinning solution（2）In obtained volatile argyi leaf oil micro-capsule, the amount of addition is spinning solution The 0.03-0.6% of quality, Chinese mugwort is formed finally by wet spinning into fibre, solidification, drawing-off, drying, curling, setting, winding filament Leaf volatile oil-milk protein fiber, fineness is 2.62D；
（4）Weave cotton cloth：Using step（3）Obtained volatile argyi leaf oil-milk protein fiber as yarn, using the conventional side of weaving cotton cloth Method weaves cotton cloth to form fabric；
（5）Dyeing；
（6）Dyeing post processing.
The processing method of described pro-skin antibiotic facing material, step（1）Described in the method for extraction volatile argyi leaf oil be：
1. argy wormwood is removed into root, is dried after cleaning, 60 mesh sieves crossed after crushing and is made powder；
2. by obtained powder add the water of 4-10 times of its volume carry out immersion 0.5-1 hours；
3. the 1% of powder weight amylase is added under normal temperature carries out enzymolysis 3-6 hours；
4. after the completion of digesting, using the technique of vacuum distillation, distillate is collected, adds distilled water and repeat distillation 1 ~ 2 time；
5. merge distillate, add the absolute ethyl alcohol extraction of 2 ~ 5 times of distillate volume, and add the nothing of powder weight 1/5 ~ 1/4 Aqueous sodium persulfate is dehydrated；
6. organic solvent is reclaimed using heating water bath, obtains volatile argyi leaf oil.
The processing method of described pro-skin antibiotic facing material, step（2）Described in prepare volatile argyi leaf oil with complex coacervation The specific method of micro-capsule comprises the following steps：
Be added to the water for Arabic gum by I, place 7~10 hours it is naturally swelling after, being heated to 70~90 DEG C makes it be completely dissolved shape Into the gumwater that solid content is 1%~40%；
II is 1 according to the mass ratio of Arabic gum and gelatin：Be added to the water for gelatin by 1 ratio, place 7~10 hours it is naturally molten After swollen, being heated to 40~60 DEG C makes gelatin be completely dissolved the gelatin solution to form that solid content is 1%~40%；
III is 1 according to the mass ratio of Arabic gum and volatile argyi leaf oil：1 ratio is by step（1）The volatile argyi leaf oil of middle extraction It is added in the gumwater of step I, is emulsified, obtains Lavender-acacia emulsions after homogeneous；
IV is added drop-wise to volatile argyi leaf oil-acacia emulsions that step III is obtained in step II in obtained gelatin solution, Constant temperature stirs at 40~60 DEG C, obtains mixed liquor；
V is adjusted to pH of mixed=4 to acidity regulator is added in the mixed liquor in step IV, then adds water 1~2 times of dilution, Micro-capsule suspension is obtained after stirring；
VI accounts for the nano level fine pottery of Arabic gum gross mass 25-40% to being added in obtained micro-capsule suspension in step V Porcelain powder, adds TG enzymes as curing agent after being cooled to 9~12 DEG C, solidify 1~6h, and being subsequently adding poly-vinyl alcohol solution makes body Polyvinyl alcohol mass concentration is 0.8%~1.2% in system, reacts the micro-capsule suspension after 1~2h is solidified, and micro-capsule suspension is taken out Collect micro-capsule after filter, micro-capsule obtains volatile argyi leaf oil micro-capsule through water washing 1~3 time after drying.
The processing method of described pro-skin antibiotic facing material, step（5）Described in the method for dyeing be：By step（4）In In obtained fabric input overflow dyeing machine, 5min is run at 36-40 DEG C, add 0.8g/L glacial acetic acid and 3.2-3.6g/L units Bright powder, runs 8-12min, adds dyestuff, is started to warm up after operation 10-12min, and 1.2 DEG C/min of heating rate works as temperature Stop heating up when reaching 50-65 DEG C, insulation operation 40-50min, discharge opeing is rinsed, bath raio 1: 40
The processing method of described pro-skin antibiotic facing material, step（6）Described in dyeing post processing be by by step（5）Dyeing Fabric afterwards is placed in the liquid of soaping of 8% fabric percentage by weight, 45-55 DEG C for the treatment of 50min, and 3% fabric is then placed in again 35-40 DEG C for the treatment of 10-15min, bath raio in the glacial acetic acid bath of percentage by weight：1 :40
A kind of string blending pro-skin fabric obtained in aforementioned manners.
Beneficial effect：
1st, the present invention, using milk protein fiber, is rich in 18 kinds beneficial to human body since selection in milk protein fiber Amino acid, can promote metabolism of human cell, prevent skin senescence, itch, nutrition skin；With NMF, because This can keep skin moisture content, make skin soft and moist smooth, reduce wrinkle, and with broad-spectrum antibacterial function, persistence is strong, natural suppression Up to more than 99%, antibiotic rate is up to more than 80% for bacterium function.In terms of fiber comfortableness, with the feel as cashmere, its filament number Carefully, light specific gravity, elongation at break, Curl, crimp recovery closest to cashmere and wool, jewelry, expensive clothing and other valuables that fiber is bulk, sense of touch is such as Soft as cashmere, comfortable, cunning is glutinous；Fiber is pale, the natural gloss with silkiness, and outward appearance is graceful, Sun-proof fastness, anti-sweat stain jail Degree is up to 4 ~ 3 grades.Moisture absorption ＆ moisture conductivity aspect, milk protein fiber section is irregular round, and space is covered with section, is longitudinally had perhaps Many grooves, protein molecule is distributed in the surface of fiber, containing native protein moisturizing factor and a large amount of hydrophilic radicals, can inhale rapidly Human sweat is received, is distributed in quickly introducing air by groove, the skin of people is remained dry condition, anti-fluffing, balling-up Property reaches 3 ~ 4 grades.Meanwhile, volatile argyi leaf oil is added in the present invention, using the rationale blood of volatile argyi leaf oil, warm meridians, dispelling cold Wet, analgesic, antibacterial, inflammatory properties, antibacterial effect is further lifted, due to the effumability of volatile argyi leaf oil, the present invention Volatile argyi leaf oil is prepared into slow-releasing microcapsule, fabric is slowly discharged essence by friction and Extrusion during being used as bedding Oil, antibiotic property, comfortableness is good, is highly suitable as bedding.
2. volatile argyi leaf oil micro-capsule of the invention adds nano level fine ceramic powders during preparation, is made face Its anti-microbial property is good after material, and pro-skin is comfortable.
3. fabric of the invention opens the new condition of bedclothes fabric, the need for greatly meeting people's lives.
Specific embodiment：
Embodiment 1：
A kind of processing method of pro-skin antibiotic facing material, the method comprises the following steps：
（1）Extract volatile argyi leaf oil；
（2）Volatile argyi leaf oil micro-capsule is prepared with complex coacervation；
（3）Prepare volatile argyi leaf oil-milk protein fiber：Using cow's milk as base stock, by dehydration, de-oiling, degreasing, point From, purification, make MC；It is blended using conventional meanses with polyacrylonitrile again, is crosslinked, is grafted, is prepared into spinning Silk stock solution；Step is added in obtained spinning solution（2）In obtained volatile argyi leaf oil micro-capsule, the amount of addition is spinning solution The 0.03-0.6% of quality, Chinese mugwort is formed finally by wet spinning into fibre, solidification, drawing-off, drying, curling, setting, winding filament Leaf volatile oil-milk protein fiber, fineness is 2.62D；
（4）Weave cotton cloth：Using step（3）Obtained volatile argyi leaf oil-milk protein fiber as yarn, using the conventional side of weaving cotton cloth Method weaves cotton cloth to form fabric；
（5）Dyeing；
（6）Dyeing post processing.
A kind of string blending pro-skin fabric obtained in aforementioned manners.
Embodiment 2：
The present embodiment is with the difference of embodiment 1, step（1）Described in the method for extraction volatile argyi leaf oil be：
1. argy wormwood is removed into root, is dried after cleaning, 60 mesh sieves crossed after crushing and is made powder；
2. by obtained powder add the water of 4-10 times of its volume carry out immersion 0.5-1 hours；
3. the 1% of powder weight amylase is added under normal temperature carries out enzymolysis 3-6 hours；
4. after the completion of digesting, using the technique of vacuum distillation, distillate is collected, adds distilled water and repeat distillation 1 ~ 2 time；
5. merge distillate, add the absolute ethyl alcohol extraction of 2 ~ 5 times of distillate volume, and add the nothing of powder weight 1/5 ~ 1/4 Aqueous sodium persulfate is dehydrated；
6. organic solvent is reclaimed using heating water bath, obtains volatile argyi leaf oil.
Embodiment 3：
The present embodiment is with the difference of embodiment 1, step（2）Described in prepare volatile argyi leaf oil with complex coacervation micro- The specific method of capsule comprises the following steps：
Be added to the water for Arabic gum by I, place 7~10 hours it is naturally swelling after, being heated to 70~90 DEG C makes it be completely dissolved shape Into the gumwater that solid content is 1%~40%；
II is 1 according to the mass ratio of Arabic gum and gelatin：Be added to the water for gelatin by 1 ratio, place 7~10 hours it is naturally molten After swollen, being heated to 40~60 DEG C makes gelatin be completely dissolved the gelatin solution to form that solid content is 1%~40%；
III is 1 according to the mass ratio of Arabic gum and volatile argyi leaf oil：1 ratio is by step（1）The volatile argyi leaf oil of middle extraction It is added in the gumwater of step I, is emulsified, obtains Lavender-acacia emulsions after homogeneous；
IV is added drop-wise to volatile argyi leaf oil-acacia emulsions that step III is obtained in step II in obtained gelatin solution, Constant temperature stirs at 40~60 DEG C, obtains mixed liquor；
V is adjusted to pH of mixed=4 to acidity regulator is added in the mixed liquor in step IV, then adds water 1~2 times of dilution, Micro-capsule suspension is obtained after stirring；
VI accounts for the nano level fine pottery of Arabic gum gross mass 25-40% to being added in obtained micro-capsule suspension in step V Porcelain powder, adds TG enzymes as curing agent after being cooled to 9~12 DEG C, solidify 1~6h, and being subsequently adding poly-vinyl alcohol solution makes body Polyvinyl alcohol mass concentration is 0.8%~1.2% in system, reacts the micro-capsule suspension after 1~2h is solidified, and micro-capsule suspension is taken out Collect micro-capsule after filter, micro-capsule obtains volatile argyi leaf oil micro-capsule through water washing 1~3 time after drying.
Embodiment 4：
The present embodiment is with the difference of embodiment 1, step（5）Described in the method for dyeing be：By step（4）Middle system In the fabric input overflow dyeing machine for obtaining, 5min is run at 36-40 DEG C, add 0.8g/L glacial acetic acid and 3.2-3.6g/L units bright Powder, runs 8-12min, adds dyestuff, is started to warm up after operation 10-12min, 1.2 DEG C/min of heating rate, when temperature reaches To stopping heating up at 50-65 DEG C, insulation operation 40-50min, discharge opeing is rinsed, bath raio 1: 40
Embodiment 5：
The present embodiment is with the difference of embodiment 1, step（6）Described in dyeing post processing be by by step（5） Fabric after dyeing is placed in the liquid of soaping of 8% fabric percentage by weight, 45-55 DEG C for the treatment of 50min, and 3% is then placed in again 35-40 DEG C for the treatment of 10-15min, bath raio in the glacial acetic acid bath of fabric percentage by weight：1 :40.
Technological means disclosed in the present invention program is not limited only to the technological means disclosed in above-mentioned technological means, also includes The technical scheme being made up of above technical characteristic equivalent.Unaccomplished matter of the invention, belongs to those skilled in the art's Common knowledge.

Claims (6)

1. a kind of processing method of pro-skin antibiotic facing material, it is characterised in that the method comprises the following steps：
（1）Extract volatile argyi leaf oil；
（2）Volatile argyi leaf oil micro-capsule is prepared with complex coacervation；
（3）Prepare volatile argyi leaf oil-milk protein fiber：Using cow's milk as base stock, by dehydration, de-oiling, degreasing, point From, purification, make MC；It is blended using conventional meanses with polyacrylonitrile again, is crosslinked, is grafted, is prepared into spinning Silk stock solution；Step is added in obtained spinning solution（2）In obtained volatile argyi leaf oil micro-capsule, the amount of addition is spinning solution The 0.03-0.6% of quality, Chinese mugwort is formed finally by wet spinning into fibre, solidification, drawing-off, drying, curling, setting, winding filament Leaf volatile oil-milk protein fiber, fineness is 2.62D；
（4）Weave cotton cloth：Using step（3）Obtained volatile argyi leaf oil-milk protein fiber as yarn, using the conventional side of weaving cotton cloth Method weaves cotton cloth to form fabric；
（5）Dyeing；
（6）Dyeing post processing.
2. the processing method of pro-skin antibiotic facing material according to claim 1, it is characterised in that step（1）Described in carry The method for taking volatile argyi leaf oil is：
1. argy wormwood is removed into root, is dried after cleaning, 60 mesh sieves crossed after crushing and is made powder；
2. by obtained powder add the water of 4-10 times of its volume carry out immersion 0.5-1 hours；
3. the 1% of powder weight amylase is added under normal temperature carries out enzymolysis 3-6 hours；
4. after the completion of digesting, using the technique of vacuum distillation, distillate is collected, adds distilled water and repeat distillation 1 ~ 2 time；
5. merge distillate, add the absolute ethyl alcohol extraction of 2 ~ 5 times of distillate volume, and add the nothing of powder weight 1/5 ~ 1/4 Aqueous sodium persulfate is dehydrated；
6. organic solvent is reclaimed using heating water bath, obtains volatile argyi leaf oil.
3. the processing method of pro-skin antibiotic facing material according to claim 1 and 2, it is characterised in that step（2）Described in The specific method for preparing volatile argyi leaf oil micro-capsule with complex coacervation comprises the following steps：
Be added to the water for Arabic gum by I, place 7~10 hours it is naturally swelling after, being heated to 70~90 DEG C makes it be completely dissolved shape Into the gumwater that solid content is 1%~40%；
II is 1 according to the mass ratio of Arabic gum and gelatin：Be added to the water for gelatin by 1 ratio, place 7~10 hours it is naturally molten After swollen, being heated to 40~60 DEG C makes gelatin be completely dissolved the gelatin solution to form that solid content is 1%~40%；
III is 1 according to the mass ratio of Arabic gum and volatile argyi leaf oil：1 ratio is by step（1）The volatile argyi leaf oil of middle extraction It is added in the gumwater of step I, is emulsified, obtains Lavender-acacia emulsions after homogeneous；
IV is added drop-wise to volatile argyi leaf oil-acacia emulsions that step III is obtained in step II in obtained gelatin solution, Constant temperature stirs at 40~60 DEG C, obtains mixed liquor；
V is adjusted to pH of mixed=4 to acidity regulator is added in the mixed liquor in step IV, then adds water 1~2 times of dilution, Micro-capsule suspension is obtained after stirring；
VI accounts for the nano level fine pottery of Arabic gum gross mass 25-40% to being added in obtained micro-capsule suspension in step V Porcelain powder, adds TG enzymes as curing agent after being cooled to 9~12 DEG C, solidify 1~6h, and being subsequently adding poly-vinyl alcohol solution makes body Polyvinyl alcohol mass concentration is 0.8%~1.2% in system, reacts the micro-capsule suspension after 1~2h is solidified, and micro-capsule suspension is taken out Collect micro-capsule after filter, micro-capsule obtains volatile argyi leaf oil micro-capsule through water washing 1~3 time after drying.
4. the processing method of pro-skin antibiotic facing material according to claim 1 and 2, it is characterised in that step（5）Described in The method of dyeing is：By step（4）In in obtained fabric input overflow dyeing machine, run 5min at 36-40 DEG C, add 0.8g/ L glacial acetic acid and 3.2-3.6g/L glauber salt, run 8-12min, add dyestuff, are started to warm up after operation 10-12min, heat up 1.2 DEG C/min of speed, stops heating up when temperature reaches 50-65 DEG C, and insulation operation 40-50min, discharge opeing is rinsed, bath raio 1 : 40。
5. the processing method of pro-skin antibiotic facing material according to claim 1 and 2, it is characterised in that step（6）Described in Dyeing post processing is by by step（5）Fabric after dyeing is placed in the liquid of soaping of 8% fabric percentage by weight, 45-55 DEG C Treatment 50min, is then placed in 35-40 DEG C for the treatment of 10-15min, bath in the bath of the glacial acetic acid of 3% fabric percentage by weight again Than：1 :40.
6. a kind of string blending pro-skin fabric obtained in aforementioned manners.
CN201611064445.1A 2016-11-28 2016-11-28 A kind of pro-skin antibiotic facing material and its processing method Pending CN106757494A (en)

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