CN110104950A - Cobalt oxide is unglazed microcrystalline glaze and preparation method thereof - Google Patents
Cobalt oxide is unglazed microcrystalline glaze and preparation method thereof Download PDFInfo
- Publication number
- CN110104950A CN110104950A CN201910417791.0A CN201910417791A CN110104950A CN 110104950 A CN110104950 A CN 110104950A CN 201910417791 A CN201910417791 A CN 201910417791A CN 110104950 A CN110104950 A CN 110104950A
- Authority
- CN
- China
- Prior art keywords
- parts
- glaze
- cobalt oxide
- unglazed
- microcrystalline
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
Abstract
The invention discloses unglazed microcrystalline glaze of a kind of cobalt oxide and preparation method thereof, the component and each component mass parts in glaze used in cobalt oxide is unglazed microcrystalline glaze are as follows: 30~35 parts of albite;10~15 parts of calcite;12~15 parts of talcum;10~13 parts of barium carbonate;5~8 parts of titanium oxide;12~15 parts of rutile;15~18 parts of quartz;4~6 parts of kaolin;3~4 parts of cobalt oxide.Sky blue is presented in surface of the present invention, has white micro-crystals precipitation, glaze surface intensity is preferable, and glazing effect is good.
Description
Technical field
The present invention relates to unglazed microcrystalline glazes of a kind of cobalt oxide and preparation method thereof.
Background technique
Currently, all kinds of furniture of life, tableware for daily use is all gradually as enthusiasm of the people to antique-collection constantly increases
Level off to of an antique style, will also start a burst of trend of back-to-ancients.
Summary of the invention
The technical problem to be solved by the present invention is to overcome the deficiencies of existing technologies, a kind of unglazed crystallite of cobalt oxide is provided
Glaze, its surface are presented sky blue, have white micro-crystals precipitation, glaze surface intensity is preferable, and glazing effect is good.
In order to solve the above technical problems, the technical scheme is that a kind of unglazed microcrystalline glaze of cobalt oxide, it is used
Glaze in component and each component mass parts it is as follows:
30~35 parts of albite;
10~15 parts of calcite;
12~15 parts of talcum;
10~13 parts of barium carbonate;
5~8 parts of titanium oxide;
12~15 parts of rutile;
15~18 parts of quartz;
4~6 parts of kaolin;
3~4 parts of cobalt oxide.
Contain in a kind of the step of preparation method of the unglazed microcrystalline glaze of cobalt oxide, method:
A) it stocks up according to each component and each component mass parts:
B) according to mass ratio=1 ︰ 1.6 ︰ 0.5 of You Liao ︰ Qiu ︰ water, wet ball grinding 14~15 hours, the glaze mistake after ball milling
After 200 meshes, the glaze slip for being modulated into 51~53 Baume concentration is stand-by;
C) clean green body, glaze spraying slurry are taken.
D) green body for having sprayed glaze slip is burnt into 1270 DEG C of drawer kiln.
After above-mentioned technical proposal, cobalt oxide of the invention is unglazed microcrystalline glaze is using broad masses' demand as background
Broad masses provide the tableware for daily use product of favorite pseudo-classic class, the cobalt oxide is unglazed microcrystalline glaze, and sky blue is presented in surface, have white
Color crystallite is precipitated, and glaze surface intensity is preferable, which is by firing in 1270 DEG C of shuttle kiln, and appearance is soft and graceful, deep by wide
Large user's likes;Wherein, albite is primary solvent, and calcite, barium carbonate and talcum are major cosolvents, titanium oxide and gold
Red stone is crystallizing agent, quartz and the silica in solvent, and aluminium oxide mainly plays skeleton function, and cobalt oxide is major colorants and portion
Point crystallizing agent effect, by the calculating and experiment being grouped as, obtaining various raw material ratio sections to the glaze: albite 30~
35 parts;10~15 parts of calcite;12~15 parts of talcum;10~13 parts of barium carbonate;5~8 parts of titanium oxide;12~15 parts of rutile;
15~18 parts of quartz;4~6 parts of kaolin;3~4 parts of the cobalt oxide glaze formula sections for the unglazed microcrystalline glaze of the cobalt oxide.
Specific embodiment
In order that the present invention can be more clearly and readily understood, below according to specific embodiment, to the present invention make into
One step detailed description.
Comparative example one:
A kind of unglazed microcrystalline glaze of cobalt oxide, the component and each component mass parts that glaze used in it contains are as follows: sodium is long
30 parts of stone;10 parts of calcite;10 parts of talcum;10 parts of barium carbonate;5 parts of titanium oxide;12 parts of rutile;15 parts of quartz;Kaolin 4
Part;3 parts of cobalt oxide;3 parts of zinc oxide.
The step of microcrystalline glaze production method that cobalt oxide is unglazed, is as follows:
A) the unglazed microcrystalline glaze of cobalt oxide is stocked up according to each component and each component mass parts:
B) 1.6 ︰ 0.5 of the mass ratio of You Liao ︰ Qiu ︰ water=1 ︰, wet ball grinding 14~15 hours, the glaze after ball milling crossed 200
After mesh, it is stand-by to be modulated into 51~53 Baume concentration;
C) clean green body is taken, the unglazed microcrystalline glaze of panchromatic cobalt oxide is sprayed.
D) base of the good panchromatic unglazed microcrystalline glaze of cobalt oxide of above-mentioned spray is burnt into 1270 DEG C of drawer kiln.
Comparative example two:
A kind of unglazed microcrystalline glaze of cobalt oxide, the component and each component mass parts that glaze used in it contains are as follows: sodium is long
35 parts of stone;15 parts of calcite;15 parts of talcum;13 parts of barium carbonate;8 parts of titanium oxide;15 parts of rutile;8 parts of quartz;Kaolin 6
Part;4 parts of cobalt oxide;15 parts of zirconium silicate.
The step of microcrystalline glaze production method that cobalt oxide is unglazed, is as follows:
A) the unglazed microcrystalline glaze of cobalt oxide is stocked up according to each component and each component mass parts:
B) 1.6 ︰ 0.5 of the mass ratio of You Liao ︰ Qiu ︰ water=1 ︰, wet ball grinding 14~15 hours, the glaze after ball milling crossed 200
After mesh, it is stand-by to be modulated into 51~53 Baume concentration;
C) clean green body is taken, the unglazed microcrystalline glaze of panchromatic cobalt oxide is sprayed.
D) base of the good panchromatic unglazed microcrystalline glaze of cobalt oxide of above-mentioned spray is burnt into 1270 DEG C of drawer kiln.
Embodiment one:
A kind of unglazed microcrystalline glaze of cobalt oxide, the component and each component mass parts in glaze used in it are as follows: albite
30 parts;10 parts of calcite;12 parts of talcum;10 parts of barium carbonate;5 parts of titanium oxide;12 parts of rutile;15 parts of quartz;4 parts of kaolin;
3 parts of cobalt oxide.
The step of microcrystalline glaze production method that cobalt oxide is unglazed, is as follows:
A) the unglazed microcrystalline glaze of cobalt oxide is stocked up according to each component and each component mass parts:
B) 1.6 ︰ 0.5 of the mass ratio of You Liao ︰ Qiu ︰ water=1 ︰, wet ball grinding 14~15 hours, the glaze after ball milling crossed 200
After mesh, it is stand-by to be modulated into 51~53 Baume concentration;
C) clean green body is taken, the unglazed microcrystalline glaze of panchromatic cobalt oxide is sprayed.
D) base of the good panchromatic unglazed microcrystalline glaze of cobalt oxide of above-mentioned spray is burnt into 1270 DEG C of drawer kiln.
Embodiment two
A kind of unglazed microcrystalline glaze of cobalt oxide, the component and each component mass parts in glaze used in it are as follows: albite
35 parts;15 parts of calcite;15 parts of talcum;13 parts of barium carbonate;8 parts of titanium oxide;15 parts of rutile;18 parts of quartz;6 parts of kaolin;
4 parts of cobalt oxide.
The step of microcrystalline glaze production method that cobalt oxide is unglazed, is as follows:
A) the unglazed microcrystalline glaze of cobalt oxide is stocked up according to each component and each component mass parts:
B) 1.6 ︰ 0.5 of the mass ratio of You Liao ︰ Qiu ︰ water=1 ︰, wet ball grinding 14~15 hours, the glaze after ball milling crossed 200
After mesh, it is stand-by to be modulated into 51~53 Baume concentration;
C) clean green body is taken, the unglazed microcrystalline glaze of panchromatic cobalt oxide is sprayed.
D) base of the good panchromatic unglazed microcrystalline glaze of cobalt oxide of above-mentioned spray is burnt into 1270 DEG C of drawer kiln.
Embodiment three:
A kind of unglazed microcrystalline glaze of cobalt oxide, the component and each component mass parts in glaze used in it are as follows: albite
32 parts;13 parts of calcite;13 parts of talcum;12 parts of barium carbonate;7 parts of titanium oxide;14 parts of rutile;16 parts of quartz;5 parts of kaolin;
3 parts of cobalt oxide.
The step of microcrystalline glaze production method that cobalt oxide is unglazed, is as follows:
A) the unglazed microcrystalline glaze of cobalt oxide is stocked up according to each component and each component mass parts:
B) 1.6 ︰ 0.5 of the mass ratio of You Liao ︰ Qiu ︰ water=1 ︰, wet ball grinding 14~15 hours, the glaze after ball milling crossed 200
After mesh, it is stand-by to be modulated into 51~53 Baume concentration;
C) clean green body is taken, the unglazed microcrystalline glaze of panchromatic cobalt oxide is sprayed.
D) base of the good panchromatic unglazed microcrystalline glaze of cobalt oxide of above-mentioned spray is burnt into 1270 DEG C of drawer kiln.
Conclusion: comparative example one: the addition of zinc oxide influences the color of the glaze, and the skyblue for showing it is not pure.
Comparative example two: color is partially light, and without crystallization effect.
Embodiment one is to embodiment three: meeting the purpose of this research and development, for the effect in ideal.
In summary comparative example and embodiment, discovery is with embodiment one to embodiment three for ideal developmental achievement.
Particular embodiments described above has carried out further in detail the purpose of the present invention, technical scheme and beneficial effects
It describes in detail bright, it should be understood that the above is only a specific embodiment of the present invention, is not intended to restrict the invention, it is all
Within the spirit and principles in the present invention, any modification, equivalent substitution, improvement and etc. done should be included in guarantor of the invention
Within the scope of shield.
Claims (2)
1. a kind of unglazed microcrystalline glaze of cobalt oxide, it is characterised in that component and each component mass parts in glaze used in it are such as
Under:
30~35 parts of albite;
10~15 parts of calcite;
12~15 parts of talcum;
10~13 parts of barium carbonate;
5~8 parts of titanium oxide;
12~15 parts of rutile;
15~18 parts of quartz;
4~6 parts of kaolin;
3~4 parts of cobalt oxide.
2. a kind of preparation method of the unglazed microcrystalline glaze of cobalt oxide as described in claim 1, it is characterised in that in the step of method
Contain:
A) it stocks up according to each component and each component mass parts:
B) according to 1.6 ︰ 0.5 of mass ratio=1 ︰ of You Liao ︰ Qiu ︰ water, wet ball grinding 14~15 hours, the glaze after ball milling crossed 200
After mesh, the glaze slip for being modulated into 51~53 Baume concentration is stand-by;
C) clean green body, glaze spraying slurry are taken.
D) green body for having sprayed glaze slip is burnt into 1270 DEG C of drawer kiln.
Priority Applications (1)
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CN201910417791.0A CN110104950A (en) | 2019-05-20 | 2019-05-20 | Cobalt oxide is unglazed microcrystalline glaze and preparation method thereof |
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CN201910417791.0A CN110104950A (en) | 2019-05-20 | 2019-05-20 | Cobalt oxide is unglazed microcrystalline glaze and preparation method thereof |
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CN110104950A true CN110104950A (en) | 2019-08-09 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110451804A (en) * | 2019-09-12 | 2019-11-15 | 福建省德化汇远陶瓷有限公司 | Blue Sub-shine glaze, blue Sub-shine glaze ceramic and preparation method thereof |
CN113788618A (en) * | 2021-10-26 | 2021-12-14 | 福建省德化县恒翔工艺有限公司 | Crystalline glaze, crystalline glaze ceramic product and preparation method thereof |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
UA64456C2 (en) * | 2003-06-03 | 2006-05-15 | Univ Ukrainian State Chem Tech | A black matt glaze |
CN101066890A (en) * | 2007-06-01 | 2007-11-07 | 山东茂华硅工有限公司 | Process of forming decorative marble patterns on ceramic product |
-
2019
- 2019-05-20 CN CN201910417791.0A patent/CN110104950A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
UA64456C2 (en) * | 2003-06-03 | 2006-05-15 | Univ Ukrainian State Chem Tech | A black matt glaze |
CN101066890A (en) * | 2007-06-01 | 2007-11-07 | 山东茂华硅工有限公司 | Process of forming decorative marble patterns on ceramic product |
Non-Patent Citations (1)
Title |
---|
范玉容: "高岭土质无光釉", 《中国陶瓷》 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110451804A (en) * | 2019-09-12 | 2019-11-15 | 福建省德化汇远陶瓷有限公司 | Blue Sub-shine glaze, blue Sub-shine glaze ceramic and preparation method thereof |
CN113788618A (en) * | 2021-10-26 | 2021-12-14 | 福建省德化县恒翔工艺有限公司 | Crystalline glaze, crystalline glaze ceramic product and preparation method thereof |
CN113788618B (en) * | 2021-10-26 | 2023-08-08 | 福建省德化县恒翔工艺有限公司 | Crystallized glaze, crystallized glaze ceramic product and preparation method thereof |
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Application publication date: 20190809 |
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