CN110015849A - Copper oxide is unglazed microcrystalline glaze and preparation method thereof - Google Patents
Copper oxide is unglazed microcrystalline glaze and preparation method thereof Download PDFInfo
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- CN110015849A CN110015849A CN201910417978.0A CN201910417978A CN110015849A CN 110015849 A CN110015849 A CN 110015849A CN 201910417978 A CN201910417978 A CN 201910417978A CN 110015849 A CN110015849 A CN 110015849A
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- glaze
- copper oxide
- unglazed
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
- C04B41/5023—Glass-ceramics
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Cosmetics (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses unglazed microcrystalline glaze of a kind of copper oxide and preparation method thereof, the component and each component mass parts in glaze used in copper oxide is unglazed microcrystalline glaze are as follows: 30~35 parts of potassium feldspar；10~15 parts of calcite；10~13 parts of talcum；10~13 parts of barium carbonate；10~12 parts of titanium oxide；8~12 parts of rutile；18~22 parts of quartz；2~3 parts of copper oxide.Light green is presented in surface of the present invention, has white micro-crystals precipitation, glazing effect is good.
Description
Technical field
The present invention relates to unglazed microcrystalline glazes of a kind of copper oxide and preparation method thereof.
Background technique
Currently, all kinds of furniture of life, tableware for daily use is all gradually as enthusiasm of the people to antique-collection constantly increases
Level off to of an antique style, will also start a burst of trend of back-to-ancients.
Summary of the invention
The technical problem to be solved by the present invention is to overcome the deficiencies of existing technologies, a kind of unglazed crystallite of cobalt oxide is provided
Glaze, its surface are presented light green, have white micro-crystals precipitation, glazing effect is good.
In order to solve the above technical problems, the technical scheme is that a kind of unglazed microcrystalline glaze of copper oxide, it is used
Glaze in component and each component mass parts it is as follows:
30~35 parts of potassium feldspar；
10~15 parts of calcite；
10~13 parts of talcum；
10~13 parts of barium carbonate；
10~12 parts of titanium oxide；
8~12 parts of rutile；
18~22 parts of quartz；
2~3 parts of copper oxide.
The present invention also provides a kind of preparation method of the unglazed microcrystalline glaze of copper oxide, the step of method in contain:
A) it stocks up according to each component and each component mass parts:
B) according to mass ratio=1 ︰ 1.6 ︰ 0.6 of You Liao ︰ Qiu ︰ water, wet ball grinding 12~13 hours, the glaze mistake after ball milling
After 160 meshes, the glaze slip for being modulated into 51~53 Baume concentration is stand-by；
C) clean green body, glaze spraying slurry are taken.
D) green body for having sprayed glaze slip is burnt into 1270 DEG C of drawer kiln.
After above-mentioned technical proposal, copper oxide of the invention is unglazed microcrystalline glaze is using broad masses' demand as background
Broad masses provide the tableware for daily use product of favorite pseudo-classic class, the copper oxide is unglazed microcrystalline glaze, and light green is presented in surface, have white
Color crystal is precipitated, which is fired by 1270 DEG C of Suo Shi Kiln, and appearance is soft and graceful, deep to be liked by users；Wherein, potassium
Feldspar is primary solvent, and calcite, barium carbonate, talcum are major cosolvents, and titanium oxide, rutile are crystallizing agent, it is quartzy with it is molten
Silica, aluminium oxide in agent mainly play skeleton function, and copper oxide is major colorants and partially crystallizable agent effect, by this
Glaze obtains various raw material ratio sections at the calculating and experiment being grouped as: 30~35 parts of potassium feldspar；10~15 parts of calcite；
10~13 parts of talcum；10~13 parts of barium carbonate；10~12 parts of titanium oxide；8~12 parts of rutile；18~22 parts of quartz；Copper oxide
2~3 parts；For the glaze formula section of the unglazed microcrystalline glaze of the copper oxide.
Specific embodiment
In order that the present invention can be more clearly and readily understood, below according to specific embodiment, to the present invention make into
One step detailed description.
Comparative example one:
A kind of unglazed microcrystalline glaze of copper oxide, the component and each component mass parts in glaze used in it are as follows: potassium feldspar
30 parts；10 parts of calcite；10 parts of talcum；5 parts of barium carbonate；15 parts of titanium oxide；8 parts of rutile；18 parts of quartz；2 parts of copper oxide；
The step of microcrystalline glaze production method that copper oxide is unglazed, is as follows:
A) the unglazed microcrystalline glaze of copper oxide is stocked up according to each component and each component mass parts:
B) 1.6 ︰ 0.6 of the mass ratio of You Liao ︰ Qiu ︰ water=1 ︰, wet ball grinding 12~13 hours, the glaze after ball milling crossed 160
After mesh, it is stand-by to be modulated into 51~53 Baume concentration；
C) clean green body is taken, the unglazed microcrystalline glaze of panchromatic copper oxide is sprayed.
D) base of the good panchromatic unglazed microcrystalline glaze of copper oxide of above-mentioned spray is burnt into 1270 DEG C of drawer kiln.
Comparative example two:
A kind of unglazed microcrystalline glaze of copper oxide, the component and each component mass parts in glaze used in it are as follows: potassium feldspar
35 parts；15 parts of calcite；8 parts of talcum；13 parts of barium carbonate；12 parts of titanium oxide；12 parts of rutile；25 parts of quartz；3 parts of copper oxide；
The step of microcrystalline glaze production method that copper oxide is unglazed, is as follows:
A) the unglazed microcrystalline glaze of copper oxide is stocked up according to each component and each component mass parts:
B) 1.6 ︰ 0.6 of the mass ratio of You Liao ︰ Qiu ︰ water=1 ︰, wet ball grinding 12~13 hours, the glaze after ball milling crossed 160
After mesh, it is stand-by to be modulated into 51~53 Baume concentration；
C) clean green body is taken, the unglazed microcrystalline glaze of panchromatic copper oxide is sprayed.
D) base of the good panchromatic unglazed microcrystalline glaze of copper oxide of above-mentioned spray is burnt into 1350 DEG C of drawer kiln.
Embodiment one:
A kind of unglazed microcrystalline glaze of copper oxide, the component and each component mass parts in glaze used in it are as follows: potassium feldspar
30 parts；10 parts of calcite；10 parts of talcum；10 parts of barium carbonate；10 parts of titanium oxide；8 parts of rutile；18 parts of quartz；2 parts of copper oxide；
The step of microcrystalline glaze production method that copper oxide is unglazed, is as follows:
A) the unglazed microcrystalline glaze of copper oxide is stocked up according to each component and each component mass parts:
B) 1.6 ︰ 0.6 of the mass ratio of You Liao ︰ Qiu ︰ water=1 ︰, wet ball grinding 12~13 hours, the glaze after ball milling crossed 160
After mesh, it is stand-by to be modulated into 51~53 Baume concentration；
C) clean green body is taken, the unglazed microcrystalline glaze of panchromatic copper oxide is sprayed.
D) base of the good panchromatic unglazed microcrystalline glaze of copper oxide of above-mentioned spray is burnt into 1270 DEG C of drawer kiln.
Embodiment two:
A kind of unglazed microcrystalline glaze of copper oxide, the component and each component mass parts in glaze used in it are as follows: potassium feldspar
35 parts；15 parts of calcite；13 parts of talcum；13 parts of barium carbonate；12 parts of titanium oxide；12 parts of rutile；22 parts of quartz；Copper oxide 3
Part；
The step of microcrystalline glaze production method that copper oxide is unglazed, is as follows:
A) the unglazed microcrystalline glaze of copper oxide is stocked up according to each component and each component mass parts:
B) 1.6 ︰ 0.6 of the mass ratio of You Liao ︰ Qiu ︰ water=1 ︰, wet ball grinding 12~13 hours, the glaze after ball milling crossed 160
After mesh, it is stand-by to be modulated into 51~53 Baume concentration；
C) clean green body is taken, the unglazed microcrystalline glaze of panchromatic copper oxide is sprayed.
D) base of the good panchromatic unglazed microcrystalline glaze of copper oxide of above-mentioned spray is burnt into 1270 DEG C of drawer kiln.
Embodiment three:
A kind of unglazed microcrystalline glaze of copper oxide, the component and each component mass parts in glaze used in it are as follows: potassium feldspar
32 parts；12 parts of calcite；12 parts of talcum；12 parts of barium carbonate；11 parts of titanium oxide；10 parts of rutile；20 parts of quartz；Copper oxide 3
Part；
The step of microcrystalline glaze production method that copper oxide is unglazed, is as follows:
A) the unglazed microcrystalline glaze of copper oxide is stocked up according to each component and each component mass parts:
B) 1.6 ︰ 0.6 of the mass ratio of You Liao ︰ Qiu ︰ water=1 ︰, wet ball grinding 12~13 hours, the glaze after ball milling crossed 160
After mesh, it is stand-by to be modulated into 51~53 Baume concentration；
C) clean green body is taken, the unglazed microcrystalline glaze of panchromatic copper oxide is sprayed.
D) base of the good panchromatic unglazed microcrystalline glaze of copper oxide of above-mentioned spray is burnt into 1270 DEG C of drawer kiln.
Conclusion: comparative example one: glaze temperature is excessively high, and surface is precipitated without white micro-crystals.
Comparative example two: matt state is presented in glaze, and crystallization effect is bad.
Embodiment one is to embodiment three: meeting the purpose of this research and development, for the effect in ideal.
In summary comparative example and embodiment, discovery embodiment one to embodiment three are ideal developmental achievement.
Particular embodiments described above has carried out further in detail the purpose of the present invention, technical scheme and beneficial effects
It describes in detail bright, it should be understood that the above is only a specific embodiment of the present invention, is not intended to restrict the invention, it is all
Within the spirit and principles in the present invention, any modification, equivalent substitution, improvement and etc. done should be included in guarantor of the invention
Within the scope of shield.
Claims (2)
1. a kind of unglazed microcrystalline glaze of copper oxide, it is characterised in that component and each component mass parts in glaze used in it are such as
Under:
30~35 parts of potassium feldspar；
10~15 parts of calcite；
10~13 parts of talcum；
10~13 parts of barium carbonate；
10~12 parts of titanium oxide；
8~12 parts of rutile；
18~22 parts of quartz；
2~3 parts of copper oxide.
2. a kind of preparation method of the unglazed microcrystalline glaze of copper oxide as described in claim 1, it is characterised in that in the step of method
Contain:
A) it stocks up according to each component and each component mass parts:
B) according to 1.6 ︰ 0.6 of mass ratio=1 ︰ of You Liao ︰ Qiu ︰ water, wet ball grinding 12~13 hours, the glaze after ball milling crossed 160
After mesh, the glaze slip for being modulated into 51~53 Baume concentration is stand-by；
C) clean green body, glaze spraying slurry are taken.
D) green body for having sprayed glaze slip is burnt into 1270 DEG C of drawer kiln.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910417978.0A CN110015849A (en) | 2019-05-20 | 2019-05-20 | Copper oxide is unglazed microcrystalline glaze and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910417978.0A CN110015849A (en) | 2019-05-20 | 2019-05-20 | Copper oxide is unglazed microcrystalline glaze and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110015849A true CN110015849A (en) | 2019-07-16 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910417978.0A Pending CN110015849A (en) | 2019-05-20 | 2019-05-20 | Copper oxide is unglazed microcrystalline glaze and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN110015849A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| UA64456C2 (en) * | 2003-06-03 | 2006-05-15 | Univ Ukrainian State Chem Tech | A black matt glaze |
| CN101066890A (en) * | 2007-06-01 | 2007-11-07 | 山东茂华硅工有限公司 | Process of forming decorative marble patterns on ceramic product |
-
2019
- 2019-05-20 CN CN201910417978.0A patent/CN110015849A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| UA64456C2 (en) * | 2003-06-03 | 2006-05-15 | Univ Ukrainian State Chem Tech | A black matt glaze |
| CN101066890A (en) * | 2007-06-01 | 2007-11-07 | 山东茂华硅工有限公司 | Process of forming decorative marble patterns on ceramic product |
Non-Patent Citations (1)
| Title |
|---|
| 范玉容: "高岭土质无光釉", 《中国陶瓷》 * |
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Application publication date: 20190716 |
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