CN110072515A - Hair care composition - Google Patents

Hair care composition Download PDF

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Publication number
CN110072515A
CN110072515A CN201780058058.3A CN201780058058A CN110072515A CN 110072515 A CN110072515 A CN 110072515A CN 201780058058 A CN201780058058 A CN 201780058058A CN 110072515 A CN110072515 A CN 110072515A
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China
Prior art keywords
oil
hair care
hair
care composition
molecular weight
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Pending
Application number
CN201780058058.3A
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Chinese (zh)
Inventor
李京美
金旼珍
宾圣娥
崔壮源
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Amorepacific Corp
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Amorepacific Corp
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Publication of CN110072515A publication Critical patent/CN110072515A/en
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31—Hydrocarbons
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Cosmetics (AREA)

Abstract

The present invention relates to the hair care compositions comprising nonvolatile oil and ethereal oil, and wherein nonvolatile oil includes the high molecular weight non-volatile silicone oil that weight average molecular weight is 700,000 to 1,500,000g/mol.Hair care composition of the invention allows to reduce the content of nonvolatile oil, and shows slim and graceful and salubrious sense, while showing excellent hair-conditioning effect and improved persistence.

Description

Hair care composition
Technical field
This application claims excellent based on September in 2016 20 days the South Korea patent application submitted the 10-2016-0120224th It first weighs, entire contents are hereby incorporated by reference.
The present invention relates to a kind of hair care composition, more specifically to a kind of following hair care composition, The hair care composition contains high molecular weight non-volatile silicone oil, therefore shows excellent hair-conditioning effect and durable Property, while the content by reducing nonvolatile oil in composition shows slim and graceful salubrious use feeling.
Background technique
Demand and preference of the consumer to conditioning (improvement of the hair situation) product for improving and promoting hair appearance and sense of touch Increasingly increase.
In general, the product for assigning hair-conditioning sense can be divided into the product for needing the product washed and not needing washing.Specifically Ground, the example for the product for needing to wash may include hair moistening liquid (hair rinse), hair conditioner (hair treatment), hair care film (hair pack), hair film (hair mask), concentration hair conditioner (hair ampoules) etc., do not need the reality of the product of washing Example may include hair spraying (hair mist), Hair-conditioning essential oil (hair essence), hair essence (hair serum) and hair Oily (hair oil).Wherein, the product for not needing washing has the effect of improving the appearance and sense of touch of hair immediately, and is easy to It uses, therefore the demand to it is increasing.
The hair care composition for not needing washing is made of higher alcohol, surfactant, silicone oil and natural oil, therefore is contained There are a large amount of non-volatile oil ingredients of viscosity, such as silicone oil and natural oil, to assign gloss and smoothness for hair and improve durable Property.However, in this case, due to oily distinctive viscosity, cleaning hand and inconvenience after use, and be coated in the presence of working as The shortcomings that coating and show wet and sticky use feeling is not easy to when hair.
In order to solve these problems, it has been proposed that improve the composition of the water-based emulsion type of use feeling.However, at this In the case where kind composition, the smoothness of hair or the durability of compliance are significantly reduced, and exist and be difficult to be badly damaged Hair in the problem of obtaining enough Hairsetting senses, compliance and gloss.
Therefore, it is necessary to develop a kind of new hair care composition, the composition shows slim and graceful salubrious use feeling, Excellent conditioning effect and durability are shown simultaneously.
[existing technical literature]
(patent document 1) Korean Patent No. 1029665, the hair care composition of aqueous emulsion form.
Summary of the invention
Technical problem
To solve the above-mentioned problems, the present inventor have studied contain in hair care composition it is various non-volatile Property oil ingredient, as a result completes the present invention.
Therefore, the purpose of the present invention is to provide a kind of hair care composition, which has excellent Use feeling, while showing improved hair-conditioning effect and durability.
Technical solution
To achieve the goals above, the present invention provides a kind of hair care composition, and it includes nonvolatile oils and volatilization Property oil, wherein the nonvolatile oil include weight average molecular weight be 700,000g/mol to 1,500,000g/mol high molecular weight Non-volatile silicone oil.
Beneficial effect
Hair care composition of the invention includes high molecular weight non-volatile silicone oil, therefore non-in composition by reducing The content of ethereal oil shows improved hair-conditioning effect and has excellent lasting effects, while showing slim and graceful clear Refreshing use feeling and excellent coating.
Detailed description of the invention
Fig. 1 is the surface scan image with the hair of the hair care composition of embodiment 1 and comparative example 1 coating.
Fig. 2 is the figure for comparing the compliance of the hair coated with the hair care composition of embodiment 1 and comparative example 1.
Fig. 3 is the figure of the gloss durability of the hair care composition of comparing embodiment 1 and comparative example 1.
Fig. 4 is the figure of the gloss durability of the hair care composition of comparing embodiment 1 to 5 and comparative example 2 and 3.
Fig. 5 is the figure for showing the Analyses Methods for Sensory Evaluation Results of embodiment 2 and comparative example 2 and 3.
Specific embodiment
Hereinafter, the present invention is described in detail, those skilled in the art is allowed easily to implement the present invention.So And the present invention can be embodied in many different forms, and should not be construed as being limited to embodiments set forth herein.
The present invention relates to the hair care composition comprising nonvolatile oil and ethereal oil, wherein nonvolatile oil includes High molecular weight non-volatile silicone oil.
Compared with the non-volatile silicone oil with low molecular weight, high molecular weight non-volatile silicone oil provides excellent a small amount of Different hair-conditioning effect, and there is excellent lasting effect.Therefore, according to the present invention, due to non-volatile in composition The content of oil can be significantly reduced, therefore can improve and moisten and sticky sense as caused by nonvolatile oil.
In the present invention, the weight average molecular weight of high molecular weight non-volatile silicone oil is preferably 700,000g/mol to 1, and 500, 000g/mol。
In general, it is the non-of 350,000g/mol to 650,000g/mol that hair care composition, which includes weight average molecular weight range, Volatile silicone oils.Non-volatile silicone oil with this molecular weight ranges is usually largely included in the composition, to ensure hair Send out the durability of conditioning effect.
However, being homogeneously applied to hair when the nonvolatile oil comprising high-content and being difficult, nonvolatile oil is special The sticky use feeling having becomes obviously, and cleaning hand is pretty troublesome after use.
By the present invention in that replacing conventional non-volatile silicone oil to solve above-mentioned ask with high molecular weight non-volatile silicone oil Topic.
That is, high molecular weight non-volatile silicone oil can mention a small amount of compared with existing non-volatile silicone oil For excellent gloss durability and compliance.Therefore, when mixing high molecular weight non-volatile silicone oil, due to sticky in composition The content of nonvolatile oil can be significantly reduced, therefore can improve use feeling while ensuring hair-conditioning effect.
The type of high molecular weight non-volatile silicone oil is not particularly limited in the present invention, can be used commonly used in the art Substance is without limiting.
Specifically, high molecular weight non-volatile silicone oil can be selected from dimethiconol, ring polydimethylsiloxanes Alkane, dimethyl silicone polymer, phenyl siloxane, alkyl methyl siloxane, dimethicone, dimethicone copolyol, At least one of silicone elastomer and silicone resin.Wherein it is possible to which it is preferable to use dimethiconols.
From only have the dimethicone of methyl different, dimethiconol is in compound external hydrophilic Hydroxyl, therefore there is highly polar and compatibility, and the dimethiconol with high molecular weight provides a small amount of Excellent Hairsetting sense.
Total weight based on composition, the content of high molecular weight non-volatile silicone oil are preferably 1 to 20 weight %, more preferably For 5 to 10 weight %.When the content of high molecular weight non-volatile silicone oil is met the above range, excellent hair tune can be obtained Effect is managed, and the total content of nonvolatile oil can be reduced, to ensure slim and graceful salubrious use feeling and uniform coating.
Meanwhile other than the above-mentioned high molecular weight non-volatile silicone oil as nonvolatile oil, hair according to the present invention Sending out conditioning composition also may include hydrocarbon-type oil.
Compared with the case where high molecular weight non-volatile silicone oil is used alone, when further including this hydrocarbon-type oil, have Benefit is the effect for improving the smoothness and gloss durability of hair.
The type of hydrocarbon-type oil for use in the present invention is not particularly limited, and the example may include selected from C10 to C20's At least one in low molecular weight hydrocarbons oil, mineral oil, saualane, alpha-olefin low polymers, Nexbase 2004 and Parleam Kind.It is preferable to use the low molecular weight hydrocarbons of C10 to C20 oil.
At this point, in order to ensure said effect, the hydrocarbon-type oil in composition is preferably 0.1 to 10 weight %, more preferably 1 to 5 weight %.
The nonvolatile oil for including in hair care composition according to the present invention may include high molecular weight as described above Non-volatile silicone oil can additionally comprise hydrocarbon-type oil, and can further include other nonvolatile oils.
At this point, the total weight based on composition, the total content of nonvolatile oil is preferably 1 to 30 weight %.If non-wave The content of hair property oil is less than 1 weight %, then hair-conditioning effect becomes not significant.If the content of nonvolatile oil is greater than 30 weights % is measured, then is existed and is occurred wet and sticky use feeling due to nonvolatile oil and be difficult to be homogeneously applied to asking for hair Topic.Therefore, the content of nonvolatile oil can be adjusted suitably within the above range.
Hair care composition of the invention includes ethereal oil and nonvolatile oil.
Ethereal oil excessively includes in the composition, and to be used as the dispersing agent of dispersion nonvolatile oil, and is provided Slim and graceful salubrious use feeling.
Ethereal oil used in the present invention is unrestricted, as long as volatile, but preferred viscosities be 0.5cs extremely The ethereal oil of 5cs.
Ethereal oil can be in the linear silicones oil or cyclic polysiloxanes oil that viscosity is 0.5cs to 5cs extremely Few one kind, but not limited to this.
The content for the ethereal oil for being included is preferably 70 to 99 weight % of hair care composition total weight.When being wrapped When the content of the ethereal oil contained is lower than 70 weight %, it is difficult to sufficiently obtain salubrious use feeling.When the content of ethereal oil is big When 99 weight %, the flexibility and durability of hair are deteriorated.Therefore, the content of ethereal oil is appropriately controlled in above range It is interior.
According to the preferred embodiment of the present invention, ethereal oil can be cyclic polysiloxanes (i.e. ring polydimethylsiloxanes Alkane) and linear silicones oily (i.e. dimethicone) mixture.More specifically, ethereal oil can be viscosity is The cyclomethicone and viscosity of 3.5cs to 4.5cs is the mixture of the dimethicone of 0.5cs to 1cs.
Hair care composition according to the present invention includes nonvolatile oil and ethereal oil, thus assigning hair immediately While gloss and smoothness, there is excellent use feeling and pure and fresh smooth coating due to reduced viscosity.Therefore, Even if on impaired hair in use, excellent instant conditioning effect can also be obtained.
The preparation of hair care composition according to the present invention is not particularly limited, but preferably in the hair for not needing washing It is embodied in conditioner preparation.Specifically, hair care composition of the invention can be configured to hair nourishing agent (hair tonic), Hair essence, hair are spraying, hair conditioner, hair jelly, pomade, hair oil, send out agent (hair spray) etc. surely.
In addition, hair care composition of the invention can further include this within the scope of the effect of the invention Common component in inventive technique field.The example of these components include but is not limited to fragrance, thickener, dispersing agent, solubilizer, Surfactant, moisturizer, preservative, vitamin, protein etc..
To facilitate the understanding of the present invention, preferred embodiment is described below.However, aobvious and easy for those skilled in the art See, following embodiment is the description of the invention, and can carry out various change within the scope and spirit of this invention And modification, and obviously these change and modification are fallen within the scope of the appended claims.
Embodiment
Preparation example 1: the preparation of hair care composition
Hair care composition (unit: weight %) is prepared according to the composition of the following table 1.
In this case, use dimethiconol as the raw material of non-volatile silicone oil.However, in embodiment In, using high molecular weight dimethyl silicone polymer alcohol (Mw 800,000 to 1,100,000), but in a comparative example, using previous The dimethiconol (Mw 400,000 to 600,000) of the relatively low molecular weight used.
Table 1:
It sequentially adds raw material shown in table 1 and is stirred (about 250rpm).At this point, being carried out when putting into each raw material Mixing at least 1 minute prepares hair care composition by mixing 30 minutes after final addition.
Experimental example 1: the evaluation of surface roughness (compliance)
Following experiment is carried out to evaluate the hair-conditioning combination of the embodiment 1 and comparative example 1 that prepare in above-mentioned preparation example 1 The compliance of object.
Topknot is cleaned using the alkaline shampoo of not conditioning functions, is rinsed 1 minute, it is 2 minutes dry, then coated to it 100 μ l hair care compositions.Laser scanning is carried out to hair cuticula using 3D laser scanner (Olympus), is then existed Surface roughness value (Sa) is measured on the image of acquisition to evaluate compliance.Fig. 1 is scan image, and Fig. 2 is to show every kind of combination The figure of the compliance of object.
As shown in Figure 1, due to film after coating at once to 5 hours after coating, the combination of the hair-conditioning of embodiment 1 Object shows smooth surface.On the contrary, compared with Example 1, comparative example 1 shows the smooth of reduced levels immediately after application Degree.Further, it can be seen that comparative example 1 shows rough surface after coating 5 hours, therefore durability is also lower than comparative example 1.
This effect can also be seen in Fig. 2.As shown in fig. 2, it can be seen that embodiment 1 exists compared with comparative example 1 It is better than comparative example 1 in terms of compliance, and shows 45% improvement, especially in terms of durability.
As can be seen from the above results, compared with low molecular weight silicone oil, high molecular weight non-volatile silicone oil of the invention is Make that excellent compliance can also be obtained on a small quantity, and there is excellent durability.
Experimental example 2: the evaluation of gloss durability
Following experiment is carried out to confirm the gloss durability of the hair care composition prepared in preparation example 1.
According to mode identical with above-mentioned experimental example 1,100 μ l hair care compositions are coated to washed and dried On topknot, and measure hair luster.Measurement method is as follows.Use SAMBA Hair system (Bossa Nova Technologies) instrument measures the maximum reflectivity of light with -45 to+45 ° of angular illumination hair, and is made using reflectivity For the measurement of gloss.
(1) compare the effect of non-volatile silicone oil according to molecular weight
Fig. 3 is the figure for showing the gloss durability of the hair care composition of embodiment 1 and comparative example 1.
Embodiment 1 shows similar gloss with comparative example 1 immediately after application.It will be appreciated, however, that having in use In the case where the comparative example 1 of the dimethiconol of low molecular weight, over time, gloss sharply declines, and makes 3.8 times of gloss durability has been shown with the embodiment 1 of high molecular weight dimethyl silicone polymer alcohol.
(2) influence of more non-volatile oil component
When preparing hair care composition, when including hydrocarbon-type oil (C12 to C16 alkane), Esters oil (C12 to C15 alkyl Benzoic ether), ethers oily (dicaprylyl ether) or triglyceride oily (caprylic/capric triglyceride) be used as nonvolatile matter When, compare the influence to gloss durability.As a result as shown in Figure 4.
Result as experiment, it was confirmed that compared with the embodiment for using high molecular weight dimethyl silicone polymer alcohol, In the case where using low molecular weight dimethiconol (comparative example 2), even if addition hydrocarbon-type oil, synergistic effect are not also shown It writes, and gloss durability significantly reduces.
Simultaneously, it was demonstrated that when comparing the embodiment 1 to 5 using high molecular weight dimethyl silicone polymer alcohol, when further packet It includes Esters oil, ethers oil and when triglyceride oil, and high molecular weight dimethyl silicone polymer alcohol is used only as non-volatile The embodiment 1 of oil is compared, and durability slightly reduces, and the embodiment 2 for further including hydrocarbon-type oil shows improved hair light Pool and durability.
It can thus be seen that even if in the case where high molecular weight non-volatile silicone oil is used only as nonvolatile oil, Excellent hair-conditioning performance can also be obtained, in addition, even preferably effect can be obtained when using hydrocarbon-type oil simultaneously.
Experimental example 3: sensory evaluation
Sensory evaluation to 11 ages in the hair care composition of 25 to 35 years old women progress embodiments 2, the sense Official's evaluation shows optimum efficiency in the evaluation of the gloss duration to above-mentioned experimental example 2.In addition, with same as Example 2 Mode carry out, the comparative example 2 comprising hydrocarbon-type oil and the comparative example comprising Esters oil 3 is also evaluated.
For each project, assessment is carried out with ten point system, and wherein attribute is higher, and numerical value is higher.As a result (average value) is shown in In the following table 2, and Fig. 5 is the figure for showing the above results.
Table 2:
Gloss Compliance Docile degree Spreadability on hand Hair coating Hair absorbability Salubrious property
Comparative example 2 6.87 6.79 6.42 7.11 7.13 7.05 7.09
Comparative example 3 6.55 6.55 6.36 7.00 7.09 6.91 6.91
Embodiment 2 7.00 7.18 6.64 7.27 7.36 7.18 7.18
As shown in table 2 and Fig. 5, the composition of embodiment 2 is above the composition of comparative example 2 and 3 in all items.Tool For body, the composition of embodiment 2 be evaluated as by reduce nonvolatile oil content hair-conditioning effect such as gloss, It is better than existing composition in terms of compliance and docile degree, while there is good use feeling, such as spreadability, hair coating on hand Property, hair absorbability and salubrious property.
It can be seen that the hair-conditioning of the invention containing high molecular weight non-volatile silicone oil from the result of experimental example 1 to 3 Composition shows excellent hair-conditioning effect containing a small amount of nonvolatile oil, and show excellent durability and Use feeling.When this hair care composition of the invention further includes hydrocarbon-type oil, the effect more enhanced may be implemented Fruit.

Claims (10)

1. a kind of hair care composition includes nonvolatile oil and ethereal oil, wherein the nonvolatile oil includes that weight is equal Molecular weight is the high molecular weight non-volatile silicone oil of 700,000g/mol to 1,500,000g/mol.
2. hair care composition according to claim 1, which is characterized in that the high molecular weight non-volatile silicone oil is Selected from dimethiconol, cyclomethicone, dimethyl silicone polymer, phenyl siloxane, alkyl methyl silicon oxygen At least one of alkane, dimethicone, dimethicone copolyol, silicone elastomer and silicone resin.
3. hair care composition according to claim 1, which is characterized in that the high molecular weight non-volatile silicone oil is Dimethiconol.
4. hair care composition according to claim 1, which is characterized in that the total weight based on the composition, institute The content for stating high molecular weight non-volatile silicone oil is 1 to 20 weight %.
5. hair care composition according to claim 1, which is characterized in that the nonvolatile oil also includes hydro carbons Oil.
6. hair care composition according to claim 5, which is characterized in that the hydrocarbon-type oil is selected from C10 to C20 At least one in low molecular weight hydrocarbons oil, mineral oil, saualane, alpha-olefin low polymers, Nexbase 2004 and Parleam Kind.
7. hair care composition according to claim 5, which is characterized in that the total weight based on the composition, institute The content for stating hydrocarbon-type oil is 0.1 to 10 weight %.
8. hair care composition according to claim 1, which is characterized in that the total weight based on the composition, institute The content for stating nonvolatile oil is 1 to 30 weight %.
9. hair care composition according to claim 1, which is characterized in that the ethereal oil is that viscosity is 0.5cs Linear or cyclic polysiloxanes to 5cs are oily.
10. hair care composition according to claim 1, which is characterized in that the total weight based on the composition, institute The content for stating ethereal oil is 70 to 99 weight %.
CN201780058058.3A 2016-09-20 2017-08-22 Hair care composition Pending CN110072515A (en)

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KR10-2016-0120224 2016-09-20
KR1020160120224A KR102610439B1 (en) 2016-09-20 2016-09-20 Hair conditioning composition
PCT/KR2017/009108 WO2018056590A1 (en) 2016-09-20 2017-08-22 Hair conditioning composition

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AU (1) AU2017330788A1 (en)
MY (1) MY189744A (en)
SG (1) SG11201901711PA (en)
TW (1) TW201813628A (en)
WO (1) WO2018056590A1 (en)

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Publication number Priority date Publication date Assignee Title
CN110200850A (en) * 2018-02-28 2019-09-06 株式会社爱茉莉太平洋 Hair care composition
CN113398012A (en) * 2021-06-11 2021-09-17 广东赛安特新材料有限公司 Ultra-smooth silicone oil composition for hair washing and caring products and application thereof
WO2023123183A1 (en) * 2021-12-30 2023-07-06 L'oreal Composition of oils for caring for keratin material

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CN1219120A (en) * 1996-03-21 1999-06-09 普罗克特和甘保尔公司 Low residue hair care compositions using grafted copolymers
CN1239419A (en) * 1996-11-04 1999-12-22 普罗克特和甘保尔公司 Hair conditioning compsn. comprising silicone emulsion
CN1431891A (en) * 2000-05-30 2003-07-23 宝洁公司 Hair conditioning compsn. comprising silicones and frizz control agents
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110200850A (en) * 2018-02-28 2019-09-06 株式会社爱茉莉太平洋 Hair care composition
CN113398012A (en) * 2021-06-11 2021-09-17 广东赛安特新材料有限公司 Ultra-smooth silicone oil composition for hair washing and caring products and application thereof
WO2023123183A1 (en) * 2021-12-30 2023-07-06 L'oreal Composition of oils for caring for keratin material

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WO2018056590A1 (en) 2018-03-29
AU2017330788A1 (en) 2019-04-11
KR102610439B1 (en) 2023-12-06
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KR20180031491A (en) 2018-03-28
SG11201901711PA (en) 2019-03-28
TW201813628A (en) 2018-04-16

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