JPS62298519A - Skin cosmetic - Google Patents
Skin cosmeticInfo
- Publication number
- JPS62298519A JPS62298519A JP14376086A JP14376086A JPS62298519A JP S62298519 A JPS62298519 A JP S62298519A JP 14376086 A JP14376086 A JP 14376086A JP 14376086 A JP14376086 A JP 14376086A JP S62298519 A JPS62298519 A JP S62298519A
- Authority
- JP
- Japan
- Prior art keywords
- units
- skin
- general formula
- formula
- silicone oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 18
- 229920002545 silicone oil Polymers 0.000 claims abstract description 12
- 125000001183 hydrocarbyl group Chemical group 0.000 claims abstract description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 3
- 229920002050 silicone resin Polymers 0.000 claims description 13
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 9
- 238000005406 washing Methods 0.000 abstract description 6
- 229920005989 resin Polymers 0.000 abstract description 3
- 239000011347 resin Substances 0.000 abstract description 3
- 230000000694 effects Effects 0.000 description 7
- 239000006210 lotion Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 239000006071 cream Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 229910052681 coesite Inorganic materials 0.000 description 3
- 229910052906 cristobalite Inorganic materials 0.000 description 3
- 239000008269 hand cream Substances 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 229910052682 stishovite Inorganic materials 0.000 description 3
- 229910052905 tridymite Inorganic materials 0.000 description 3
- 206010040880 Skin irritation Diseases 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 230000003301 hydrolyzing effect Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 150000004756 silanes Chemical class 0.000 description 2
- 230000036556 skin irritation Effects 0.000 description 2
- 231100000475 skin irritation Toxicity 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 1
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- MROCJMGDEKINLD-UHFFFAOYSA-N dichlorosilane Chemical compound Cl[SiH2]Cl MROCJMGDEKINLD-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000000118 hair dye Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 239000007764 o/w emulsion Substances 0.000 description 1
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 229920006268 silicone film Polymers 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229940035049 sorbitan monooleate Drugs 0.000 description 1
- 235000011069 sorbitan monooleate Nutrition 0.000 description 1
- 239000001593 sorbitan monooleate Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- ZDHXKXAHOVTTAH-UHFFFAOYSA-N trichlorosilane Chemical compound Cl[SiH](Cl)Cl ZDHXKXAHOVTTAH-UHFFFAOYSA-N 0.000 description 1
- 239000005052 trichlorosilane Substances 0.000 description 1
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000007762 w/o emulsion Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Cosmetics (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野コ
本発明は皮膚化粧料、ざらに詳しくは、水仕事などによ
る肌あれ（主に手あれ）から皮膚を保護する皮膚化粧料
に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a skin cosmetic, and more specifically, to a skin cosmetic that protects the skin from rough skin (mainly rough hands) caused by water work or the like.
［従来の技術］
従来、水仕事などによる肌あれから皮膚を保護するため
にはハンドクリームが汎用されてきた。[Prior Art] Hand creams have conventionally been widely used to protect skin from roughness caused by water work, etc.
ハンドクリームは水仕事などにより失われた皮脂を補給
し、さらに保湿剤や水の配合により皮膚に柔軟性を付与
している。Hand cream replenishes sebum lost due to water work, etc., and also adds moisturizer and water to give skin flexibility.
［発明が解決しようとする問題点］
しかしながら、ハンドクリームは水洗によって容易に洗
い流されてしまうので皮膚保護効果は必ずしも満足でき
るものではない。[Problems to be Solved by the Invention] However, since hand creams are easily washed away with water, the skin protection effect is not necessarily satisfactory.
現に、主婦のなかには炊事、洗濯などの反型なる水仕事
による手あれに悩んでいる人は多い。In fact, many housewives suffer from dry hands due to unconventional water work such as cooking and laundry.
手洗い回数の多い歯科医などでは治療器具や患者に付着
してはならないのでハンドクリームを使用することもで
きず手あれがすすみ、ひどい場合には不快な皮膚炎症に
まで至ることが多い。Dentists and others who frequently wash their hands often cannot use hand creams to avoid contact with treatment instruments or patients, resulting in dry hands and, in severe cases, unpleasant skin irritation.
また、理容師などのなかにも手洗いによる肌あれに加え
て染毛剤、パーマ液による炎症を訴える人が少なくない
。Additionally, many barbers and others complain of skin irritation from washing their hands, as well as irritation from hair dyes and perm solutions.
このようなとくに手あれのひどい職業に従事している人
のための皮膚保護゛科の技術としては、特公昭４８−１
５０３号公報があるが、このものは比較的高粘度のトリ
メチルシリル末端封鎖ジオルガノシロキサンとシリコー
ン樹脂とを組合せて組成物としているため、皮膚に塗布
したときにペタツキ感が強く、接触物への付着も著しい
などの欠点を有する。As a technology for skin protection for people who are engaged in such occupations that require particularly rough hands, there is
No. 503, but since this composition is made by combining a relatively high viscosity trimethylsilyl end-capped diorganosiloxane and a silicone resin, it has a strong sticky feeling when applied to the skin and does not adhere to objects that come in contact with it. It also has significant drawbacks.
また、シリコーン樹脂をメーキャップ化粧料に応用する
技術としては、特開昭６１−１８７０８があるがこれは
例えば有機トリクロロシランと有機ジクロロシランとを
加水分解したのち、縮合し架橋硬化きせ作られるシリコ
ーン樹脂であるため、これを皮膚化粧料に応用しようと
した場合、分子量の小ざいシリコーン樹脂は粘着性に富
みベタつくうえに、十分な皮Ｉｉ？保護効果が得られず
、一方十分な皮膚保護効果を上げる３次元網状構造を形
成きせると、他の化粧品用油分やシリコーンオイル等に
溶けにくくなり、ついには不溶となることや経時で架橋
重合を起こすため、特に高温での製品の安定性が悪いと
いう問題点を有していた。また特願昭５９−１８７１３
８ではＲ３ＳｉＯ１／２単位とＳｉＯ２単位とからなる
シリコーン樹脂を用いており、この皮膚化粧料を読上に
塗布した場合、読上に形成されるシリコーン皮膜が硬過
ぎるため、経時でヒビ割れを生じ皮膚保護効果が劣ると
いう問題点を有していた。In addition, as a technique for applying silicone resin to makeup cosmetics, there is Japanese Patent Application Laid-Open No. 61-18708, which is a silicone resin that is produced by hydrolyzing organic trichlorosilane and organic dichlorosilane, and then condensing and crosslinking and hardening them. Therefore, when trying to apply this to skin cosmetics, silicone resins with small molecular weights are sticky and sticky, and do not have enough skin Ii? On the other hand, if a three-dimensional network structure is formed that provides a sufficient skin protection effect, it becomes difficult to dissolve in other cosmetic oils or silicone oils, and eventually becomes insoluble and undergoes cross-linking polymerization over time. Therefore, there was a problem in that the stability of the product was poor, especially at high temperatures. Also, patent application No. 59-18713
8 uses a silicone resin consisting of R3SiO1/2 units and SiO2 units, and when this skin cosmetic is applied to the skin, the silicone film formed on the skin is too hard, causing cracks over time. The problem was that the skin protection effect was poor.
［問題点を解決するための手段］
本発明者等は、このような事情にかんがみ、水仕事から
効果的に皮膚を保３！Ｊ（特に水洗いを繰返しても保護
効果が失われない）シ、且つざっばりした使用感を有し
ていて接触物への付着も少ない皮膚化粧料を得ることを
目的に鋭意研究を行った結果、特定の有機シリコーン樹
脂を揮発性シリコーン油とともに用いたならば、のびが
よく且つ皮膚に塗布したときにシリコーン油の揮散に伴
ってざっばりした感触で長時間にわたって皮膚を保護し
、水洗などによっても容易に洗い流されない良好な撥水
皮膜が形成されることを見出し、この知見にもとずいて
本発明を完成するに至った。[Means for Solving the Problems] In view of the above circumstances, the present inventors have developed a method to effectively protect the skin from water work. The result of intensive research with the aim of obtaining a skin cosmetic that does not lose its protective effect even after repeated washing with water, has a smooth feel, and has less adhesion to objects it comes in contact with. If a specific organic silicone resin is used together with volatile silicone oil, it spreads well and when applied to the skin, it gives a rough feel as the silicone oil evaporates, protecting the skin for a long time, and it can be easily removed by washing with water. It was discovered that a good water-repellent film was formed that was not easily washed away, and based on this knowledge, the present invention was completed.
［問題点を解決するための手段］
すなわち、本発明は下記（Ａ）で示される有機シリコー
ン樹脂を１〜９０重量％および下記（Ｂ）で示される揮
発性シリコーン油を１０〜９９重量％含有することを特
徴とする皮膚化粧料である。[Means for Solving the Problems] That is, the present invention contains 1 to 90% by weight of an organic silicone resin shown in (A) below and 10 to 99% by weight of a volatile silicone oil shown in (B) below. It is a skin cosmetic product characterized by:
（Ａ）７０モル％以上がＲＳｉＯ３／２単位およびＳｉ
ｇｈ単位からなり、Ｒ３Ｓ ｉ ０１／２単位とＳｉＯ
□単位のモル比が０．５／１〜１．５／１の範囲にあり
、且つＲ２ＳｉＯ単位及び／又はＲＳｉＯ３／。単位を
１〜３０モル％含有する有機シリコーン（！１脂。(A) 70 mol% or more is RSiO3/2 units and Si
Consisting of gh units, R3S i 01/2 units and SiO
The molar ratio of □ units is in the range of 0.5/1 to 1.5/1, and R2SiO units and/or RSiO3/. Organic silicone containing 1 to 30 mol% of units (!1 fat.
（Ｒは炭素数１〜６までの炭化水素基またはフェニル基
を表す。）
（Ｂ）一般式（Ｉ）および一般式（１１）で表される揮
発性シリコーン油の少なくとも一種。(R represents a hydrocarbon group having 1 to 6 carbon atoms or a phenyl group.) (B) At least one type of volatile silicone oil represented by general formula (I) and general formula (11).
（式中ｎは○〜５の整数を示す。）
（式中ｎは３〜７の整数を示す。）
（以下余白）
本発明で用いる上記（Ａ）の有機シリコーンＵ（脂は対
応する既知のシラン類を混合した後、トルエン、ヘキ・
すン等の溶剤で希釈した後加水分解を行ない、更に加熱
重合することにより容易に得ることが出来る、ＳｉＯ２
単位はシラン類のほかに水ガラスを使用しても同様なシ
リコーン樹脂が得られる。(In the formula, n represents an integer of ○ to 5.) (In the formula, n represents an integer of 3 to 7.) (Hereinafter, blank space) The organic silicone U of the above (A) used in the present invention (the fat is a corresponding known After mixing the silanes, toluene, hex.
SiO2 can be easily obtained by diluting it with a solvent such as water, hydrolyzing it, and then polymerizing it by heating.
A similar silicone resin can be obtained by using water glass as a unit in addition to silanes.
配合量は、皮膚化粧料全量中の１〜９０重景％重量る。The blending amount is 1 to 90% by weight based on the total amount of skin cosmetics.
また、本発明で用いる上記一般式（Ｉ）あるいは一般式
（ＩＩ）で表きれる鎮状シリコーン油および環状シリコ
ーン油はいずれも揮発性であって上記有機シリコーン樹
脂に対して溶剤となりうる。Moreover, the quenched silicone oil and the cyclic silicone oil represented by the above general formula (I) or general formula (II) used in the present invention are both volatile and can serve as a solvent for the above organic silicone resin.
配合量は、皮膚化粧料全量中の１０〜９９重量％である
。The blending amount is 10 to 99% by weight based on the total amount of skin cosmetics.
上記の必須成分を含有してなる皮膚化粧料はその配合量
に応じて、溶液状からクリーム状までを呈する。すなわ
ち、揮発性シリコーン油が多いときは溶液状を呈し、有
機シリコーン樹脂が増量するにしたがって固形状になる
。Skin cosmetics containing the above-mentioned essential ingredients take on the form of a solution to a cream depending on the amount incorporated. That is, when there is a large amount of volatile silicone oil, it takes the form of a solution, and as the amount of organic silicone resin increases, it becomes solid.
当然のことながら、上記必須成分に加えて、水性成分お
よび適切な界面活性剤を配合して乳化技術を駆使するこ
とによって、撥水性をうしなわない範囲で油中水型ある
いは水中油型の乳化組成物にすることも可能である。Naturally, in addition to the above essential ingredients, by blending aqueous components and appropriate surfactants and making full use of emulsification technology, water-in-oil or oil-in-water emulsion compositions can be created without sacrificing water repellency. It is also possible to turn it into an object.
本発明の皮膚化粧Ｐ４には上記の他に、目的に応じて本
発明の効果を損なわない量的、質的範囲内で、ざらに油
脂類、ロウ類、薬剤、香料、あるいは他の揮発性成分を
配合してもよい。In addition to the above, the skin cosmetic P4 of the present invention may also contain, depending on the purpose, within a quantitative and qualitative range that does not impair the effects of the present invention. Components may be mixed.
以下、実施例により本発明をざらに詳細に説明する。本
発明は、これらによって限定されるものではない。配合
量はすべて重量％である。EXAMPLES Hereinafter, the present invention will be roughly explained in detail with reference to Examples. The present invention is not limited by these. All compounding amounts are weight %.
実施例１ ハンドローション
（１）ジメチルポリシロキサン １．５ＣＳ ９３
．０％（一般式（Ｉ） 、 ｎ＝２）
（２） （ＣＨ３） ３Ｓ ｉｏ １／２／Ｓ ｉ０２
／ （ＣＨ３） ２Ｓ ｉ。Example 1 Hand lotion (1) Dimethylpolysiloxane 1.5CS 93
．． 0% (general formula (I), n=2) (2) (CH3) 3S io 1/2/S i02
/ (CH3) 2S i.
＝ ２．４／１．６／１．０ よりなる有機シリコー
ンｔ５を脂 ２．０（３）メチルフェニル
ポリシロキサン ５．０（１）〜（３）を７０〜８
０℃で撹拌溶解し、冷却してハンドローションを得た。= 2.4/1.6/1.0 2.0(3) methylphenylpolysiloxane 5.0(1) to (3) 70 to 8
The mixture was stirred and dissolved at 0°C and cooled to obtain a hand lotion.
実施例１はきっばりとした使用感で１９水性も良好であ
り、長時間皮膚を保護する作用を有していた。また、実
施例１を塗布した手で金属などにふれても成分が付着す
ることはなかった。Example 1 had a firm feeling on use, good 19 aqueous properties, and had the effect of protecting the skin for a long time. Further, even if the hand coated with Example 1 touched a metal or the like, the components did not adhere.
実施例２ ハンドローション
（１）ジメチルボ’） シＤ キサン０．６５Ｃ３５０
，０％（一般式（Ｉ）、ｎ＝ｏ）
（２）ジメチルポリシロキサン ２．ＯＣＳ ４１
．０（一般式（Ｉ） 、 ｎ＝３）
（３） （ＣＨ３）３ｓｉｏ＋ｚ。／ＳｉＯ２／ （Ｃ
Ｈ３） ２ｓｉＯ／Ｃｓ１（５ｓｉｏ３．・２＝ １．
０／３．１／１．０１．Ｏよりなる有機シリコーン樹脂
４．０（４）オリーブ油
５．０（１）〜（４）を５０〜６０℃で撹拌溶
解し、冷却してハンドローションを得た。実施例２はき
っばりとした使用感で、撥水性も良好であった。Example 2 Hand lotion (1) dimethylbo') CiD xane 0.65C350
,0% (general formula (I), n=o) (2) Dimethylpolysiloxane 2. OCS 41
．． 0 (general formula (I), n=3) (3) (CH3)3sio+z. /SiO2/ (C
H3) 2siO/Cs1 (5sio3.・2=1.
0/3.1/1.01. Organic silicone resin consisting of O 4.0 (4) Olive oil
5.0(1) to (4) were stirred and dissolved at 50 to 60°C, and cooled to obtain a hand lotion. Example 2 had a sharp feel and good water repellency.
実施例３ハンドクリーム
（１）オクタメチルシクロテトラシロキサン（一般式（
ＩＩ） 、 ｎ ＝４） １５．０％（２）
（Ｃ）１３ｈｓｉＯ＋ｚ２／ＳｉＯ２／ （ＣＨ３ｈＳ
ｉＯ＝４４１５５／１ よりなる
有機シリコーン樹脂 ６５．０（３）マイク
ロクリスタリンワックス ５．０（４）流動パラフ
ィン １５．０（１）〜（４）を７
０〜８０℃で撹拌溶解し、冷却してハンドクリームを得
た。Example 3 Hand cream (1) Octamethylcyclotetrasiloxane (general formula (
II), n = 4) 15.0% (2)
(C)13hsiO+z2/SiO2/ (CH3hS
Organic silicone resin consisting of iO=44155/1 65.0 (3) Microcrystalline wax 5.0 (4) Liquid paraffin 15.0 (1) to (4) to 7
The mixture was stirred and dissolved at 0 to 80°C and cooled to obtain a hand cream.
実施例３はきっばりとした使用感で、長時間皮膚を保護
する作用を有していた。また、実施例３を塗布した手で
コツプなどを持っても成分の付着はみられなっかった。Example 3 had a firm feeling on use and had the effect of protecting the skin for a long time. Further, even when holding a tip with the hand coated with Example 3, no component was observed to adhere.
ざらに実施例３は耐水性に優れており、石鹸で５回洗浄
した後でも良好な撥水性を有していた。In general, Example 3 had excellent water resistance, and even after washing with soap five times, it had good water repellency.
実施例４ ハンドモイスチュアローション（１）デカメ
チルシクロペンタシロキサン ３０．０％（一般式（Ｉ
Ｉ） 、 ｎ＝５ ）
（２） （Ｃｔｈ） ３Ｓ ｉｏ １／２／Ｓ ｉ０２
／ （Ｃｔｌ ３） ２Ｓ ｉＯ／ （ＣＨ３）Ｓ Ｅ
Ｏ３／２＝ １５／１５／２．５／１．０ よりなる
有機シリコーン４Ｘ４脂 ４０．０（３）ソ
ルビタンモノオレート ５．０（４）精製
水 ２２．０（５）ジプロ
ピレングリコール ３．０（１）〜（３）
を７０〜８０℃で撹拌混合し、この中へ（５）を（４）
中へ溶解したものを添加し、乳化してハンドモイスチュ
アローションを得た。Example 4 Hand moisture lotion (1) Decamethylcyclopentasiloxane 30.0% (general formula (I)
I), n=5) (2) (Cth) 3S io 1/2/S i02
/ (Ctl 3) 2S iO/ (CH3)S E
O3/2 = 15/15/2.5/1.0 Organosilicone 4X4 resin 40.0 (3) Sorbitan monooleate 5.0 (4) Purified water 22.0 (5) Dipropylene glycol 3.0 (1)-(3)
Stir and mix at 70-80℃ and add (5) to (4).
The dissolved material was added and emulsified to obtain a hand moisture lotion.
［発明の効果］
本発明の皮膚化粧料は、のびがよく且つ皮膚に塗布した
ときにさっばりした感触で’Ａ Ｕ’ｒ間にわたって皮
膚を保護し、水洗などによっても容易に洗い流されるこ
とがない。ざらに、塗布した手などで触れても対象物に
対する付着が少ない皮膚化粧料である。[Effects of the Invention] The skin cosmetic of the present invention spreads easily, has a light feel when applied to the skin, protects the skin for a long period of time, and is easily washed away by washing with water. do not have. Roughly speaking, it is a skin cosmetic that does not adhere to objects even when touched with the hand after applying it.
Claims (1)
％および下記（Ｂ）で示される揮発性シリコーン油１０
〜９９重量％を含有することを特徴とする皮膚化粧料。 （Ａ）７０モル％以上がＲ＿３ＳｉＯ＿１＿／＿２単位
およびＳｉＯ＿２単位からなり、Ｒ＿３ＳｉＯ＿１＿／
＿２単位とＳｉＯ＿２単位のモル比が０．５／１〜１．
５／１の範囲にあり、且つＲ＿２ＳｉＯ単位および／ま
たはＲＳｉＯ＿３＿／＿２単位を１〜３０モル％含有す
る有機シリコーン樹脂。 （Ｒは炭素数１〜６までの炭化水素基またはフェニル基
を表す。） （Ｂ）一般式（ I ）および一般式（II）で表される揮
発性シリコーン油の少なくとも一種。 一般式（ I ） ▲数式、化学式、表等があります▼（ I ） （式中ｎは０〜５の整数を示す。） 一般式（II） ▲数式、化学式、表等があります▼（II） （式中ｎは３〜７の整数を示す。）[Claims] 1 to 90% by weight of an organic silicone resin represented by (A) below and 10% by weight of a volatile silicone oil represented by (B) below.
A skin cosmetic characterized by containing ~99% by weight. (A) 70 mol% or more consists of R_3SiO_1_/_2 units and SiO_2 units, R_3SiO_1_/
The molar ratio of _2 units and SiO_2 units is 0.5/1 to 1.
5/1 and containing 1 to 30 mol% of R_2SiO units and/or RSiO_3_/_2 units. (R represents a hydrocarbon group having 1 to 6 carbon atoms or a phenyl group.) (B) At least one type of volatile silicone oil represented by general formula (I) and general formula (II). General formula (I) ▲There are mathematical formulas, chemical formulas, tables, etc.▼(I) (In the formula, n represents an integer from 0 to 5.) General formula (II) ▲There are mathematical formulas, chemical formulas, tables, etc.▼(II) (In the formula, n represents an integer from 3 to 7.)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14376086A JPS62298519A (en) | 1986-06-19 | 1986-06-19 | Skin cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14376086A JPS62298519A (en) | 1986-06-19 | 1986-06-19 | Skin cosmetic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS62298519A true JPS62298519A (en) | 1987-12-25 |
Family
ID=15346384
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14376086A Pending JPS62298519A (en) | 1986-06-19 | 1986-06-19 | Skin cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62298519A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04312511A (en) * | 1991-04-09 | 1992-11-04 | Toshiba Silicone Co Ltd | Cosmetic |
| FR2737111A1 (en) * | 1995-07-28 | 1997-01-31 | Oreal | FLEXIBLE PASTE COMPOSITION AND PROCESS FOR PREPARING THE SAME |
| FR2737112A1 (en) * | 1995-07-28 | 1997-01-31 | Oreal | USE OF THE ASSOCIATION OF TWO PARTICULAR OILS IN A PARTICULARLY COSMETIC COMPOSITION, AND COMPOSITION OBTAINED |
| US5676938A (en) * | 1992-09-29 | 1997-10-14 | Toshiba Silicone Co., Ltd. | Cosmetic composition |
| US5965148A (en) * | 1995-07-28 | 1999-10-12 | Societe L'oreal S.A. | Cosmetic/dermatological compositions formulated as supple doughs |
| US6991782B2 (en) | 2000-06-19 | 2006-01-31 | L'oréal | Cosmetic compositions comprising at least one polymethylsilsesquioxane film former |
| US10449138B2 (en) | 2012-12-24 | 2019-10-22 | Conopco, Inc. | Cosmetic composition |
-
1986
- 1986-06-19 JP JP14376086A patent/JPS62298519A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04312511A (en) * | 1991-04-09 | 1992-11-04 | Toshiba Silicone Co Ltd | Cosmetic |
| US5676938A (en) * | 1992-09-29 | 1997-10-14 | Toshiba Silicone Co., Ltd. | Cosmetic composition |
| FR2737111A1 (en) * | 1995-07-28 | 1997-01-31 | Oreal | FLEXIBLE PASTE COMPOSITION AND PROCESS FOR PREPARING THE SAME |
| FR2737112A1 (en) * | 1995-07-28 | 1997-01-31 | Oreal | USE OF THE ASSOCIATION OF TWO PARTICULAR OILS IN A PARTICULARLY COSMETIC COMPOSITION, AND COMPOSITION OBTAINED |
| EP0756865A1 (en) * | 1995-07-28 | 1997-02-05 | L'oreal | Composition in form of a supple paste and preparation process |
| EP0756864A1 (en) * | 1995-07-28 | 1997-02-05 | L'oreal | Use of the association of two particular oils in a cosmetic composition, and the composition obtained thereby |
| US5965148A (en) * | 1995-07-28 | 1999-10-12 | Societe L'oreal S.A. | Cosmetic/dermatological compositions formulated as supple doughs |
| US6780402B1 (en) | 1995-07-28 | 2004-08-24 | L'oreal | Make-up compositions containing phenylated silicone oils, which are resistant to transfer and migration |
| US6991782B2 (en) | 2000-06-19 | 2006-01-31 | L'oréal | Cosmetic compositions comprising at least one polymethylsilsesquioxane film former |
| US10449138B2 (en) | 2012-12-24 | 2019-10-22 | Conopco, Inc. | Cosmetic composition |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US6355724B1 (en) | Cosmetic compositions containing silicone gel | |
| JP2582275B2 (en) | Silicone gel composition and cosmetic containing the same | |
| JPH06157282A (en) | Silicone emulsion for body care | |
| KR20020070972A (en) | Zwitterionic siloxane polymers and ionically cross-linked polymers formed therefrom | |
| JPH0615452B2 (en) | Makeup cosmetics | |
| US4855129A (en) | Skin-protecting or skin-care composition | |
| AU667473B2 (en) | Personal care compositions containing polyalkylsiloxane copolymers | |
| JPH0672085B2 (en) | Makeup cosmetics | |
| JPH10508867A (en) | Lipstick coating composition containing silicone oil and silica | |
| JPS6165808A (en) | Skin cosmetic | |
| KR100762154B1 (en) | Anhydrous, transfer-resistant cosmetic lip compositions | |
| WO2003026596A1 (en) | Topical compositions containing solid particulates and a silicone resin copolymer fluid | |
| JPS62298519A (en) | Skin cosmetic | |
| JPH0459284B2 (en) | ||
| JPS61113646A (en) | Gel composition containing silicone oil | |
| JPH0554868B2 (en) | ||
| JP2539190B2 (en) | Skin cosmetics | |
| JPH01139522A (en) | Hair treating agent | |
| JPH0445155A (en) | Film-forming composition | |
| JPH01190757A (en) | Silicone gel composition and cosmetic containing same | |
| JPS62298518A (en) | Skin cosmetic | |
| JPS62121764A (en) | Gel-like composition | |
| JPS63152308A (en) | Silicon gel composition and cosmetic containing said composition | |
| Berthiaume | Silicones in cosmetics | |
| JPH01175923A (en) | Hair cosmetic |